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Investigating the physicochemical characteristics of monovalent metal-doped nickel oxide thin films 研究单价金属掺杂氧化镍薄膜的物理化学特性
IF 0.9 4区 材料科学 Q4 Materials Science Pub Date : 2024-03-26 DOI: 10.15251/djnb.2024.191.359
C. Maghni, C. Zaouche, L. Dahbi, S. Saggai, E. Guedda
The effect of Ag doping on the optical, structural, and electrical properties of deposited Ni1-xAgxO thin films deposited on glass substrates by spray pyrolysis has been studied. This work aims to investigate the optical and physical characteristics variations of Ni1- xAgxO thin films fabricated into semiconductors with varying doping levels x. The values of 0 at.%, 2 at.%, 4 at.%, 6 at.%, and 8 at.% are these levels. The transmission spectra demonstrate the good optical transparency of the Ni1-xAgxO thin films in the visible range of 70% to 85%. The thin films of Ni1-xAgxO exhibited optical gap energies ranging from 3.63 to 3.71eV. Between 329 and 430meV was the range of the Urbach energy. Nonetheless, numerous flaws with the highest Urbach energy are observed in Ni0.92Ag0.08O thin films. The lowest optical gap energy is found in Ni0.92Ag0.08O thin sheets. A maximum of 0.024(Ω.cm)-1 electrical conductivity was observed in the Ni0.92Ag0.08O thin films. Our films have an average electrical conductivity of approximately 0.0176(Ω.cm)-1 . The Ni1- xAgxO thin film XRD patterns show that the films have a cubic structure and are polycrystalline.
研究了掺银对通过喷雾热解沉积在玻璃基底上的 Ni1-xAgxO 薄膜的光学、结构和电学特性的影响。这项工作旨在研究不同掺杂水平 x 的 Ni1- xAgxO 薄膜在制作成半导体时的光学和物理特性变化。透射光谱显示,Ni1-xAgxO 薄膜在 70% 至 85% 的可见光范围内具有良好的光学透明度。Ni1-xAgxO 薄膜的光隙能在 3.63 至 3.71eV 之间。厄巴赫能量范围在 329 至 430meV 之间。然而,在 Ni0.92Ag0.08O 薄膜中观察到许多具有最高乌巴赫能的缺陷。Ni0.92Ag0.08O 薄膜的光隙能最低。在 Ni0.92Ag0.08O 薄膜中观察到最高的 0.024(Ω.cm)-1 电导率。我们的薄膜的平均电导率约为 0.0176(Ω.cm)-1。Ni1- xAgxO 薄膜的 XRD 图谱显示,薄膜具有立方结构,并且是多晶体。
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引用次数: 0
Preparation of magnetic Fe3O4/PAM composite microspheres by inverse emulsion polymerization 利用反向乳液聚合法制备磁性 Fe3O4/PAM 复合微球
IF 0.9 4区 材料科学 Q4 Materials Science Pub Date : 2024-03-26 DOI: 10.15251/djnb.2024.191.435
Q. Y. Huang, S. Z. Wang, L. Dong, C. Chen, X. L. Zhao
The stable micro-aqueous groups (MAGs) were prepared by using sodium dodecyl sulfate (SDS) and sorbitan fatty acid ester (Span80) as emulsifiers. Fe3O4/PAM composite microspheres (CMPs) were obtained by inverse emulsion polymerization in MAGs. The experimental results showed that the size of the spherical Fe3O4/PAM CMPs was about 135-420nm and the saturation magnetization value of them was about 23.3emu/g. In the Fe3O4/PAM CMPs, the mass fraction of PAM was about 76.5%. The viscosity of the emulsion containing Fe3O4/PAM CMPs increased with the increase of current and decreased with the increase of shear rate
以十二烷基硫酸钠(SDS)和山梨醇脂肪酸酯(Span80)为乳化剂制备了稳定的微水团(MAGs)。Fe3O4/PAM 复合微球(CMPs)是在 MAGs 中进行反乳液聚合得到的。实验结果表明,球形 Fe3O4/PAM CMPs 的尺寸约为 135-420nm,饱和磁化值约为 23.3emu/g。在 Fe3O4/PAM CMP 中,PAM 的质量分数约为 76.5%。含有 Fe3O4/PAM CMPs 的乳液的粘度随电流的增加而增加,随剪切速率的增加而降低。
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引用次数: 0
Fabrication of high-durability superhydrophobic coatings based on dual-sized SiC particles 基于双尺寸 SiC 颗粒的高耐久性超疏水涂层的制造
IF 0.9 4区 材料科学 Q4 Materials Science Pub Date : 2024-03-26 DOI: 10.15251/djnb.2024.191.383
Z. Y. Xue, C. Q. Li, H. W. Niu, J. F. Ou, F. J. Wang, X. Z. Fang, W. Li, A. Amirfazl
In recent years, inspired by “biomimicry”, superhydrophobic surfaces have gained significant attention. Superhydrophobic surfaces demonstrate notable advantages in addressing interfacial issues, and superhydrophobic coatings exhibit excellent waterproofness, anti-fouling, self-cleaning, anti-corrosion, and additional capabilities, making them promising next-generation waterproof materials. However, the complex preparation process, coupled with poor wear resistance and environmental durability, severely limits their practical applications. Therefore, this article started from simplifying the preparation process and improving the durability of the coatings. Epoxy resin (E51) was used as the film-forming material, and carbon nanotubes (CNTs) and dual-sized SiC particles (nano-SiC and micro-SiC) were used as the fillers. Room temperature vulcanized silicone rubber (RTV) was used as a binder interacting with epoxy resin to promote the interface interaction between the fillers and the polymers. This process resulted in the successful preparation of superhydrophobic coatings with outstanding comprehensive performance. When the ratio of μ-SiC to n-SiC was 1:1, the prepared coating exhibited the best superhydrophobic properties with a water contact angle (WCA) of 167.4° and a sliding angle (SA) of 4.6°. Even after undergoing severe mechanical tests, such as sandpaper abrasion for 1000 cycles, sand impact for 100 cycles, cross-cut test, and tape-peeling for 70 cycles, the coatings still maintained their non-wetting Cassie-Baxter state. Furthermore, even after immersion in strong acid, strong alkali and 3.5 wt% NaCl solutions for 6 days, keeping at 500 ℃ for 2 hours, and exposure to ultraviolet for 6 days, the coatings still exhibited excellent superhydrophobicity. This suggested that the prepared coating had excellent chemical stability and high-temperature resistance. In addition, the superhydrophobic coating exhibited exceptional capabilities in self-cleaning, anti-corrosion, anti-icing, and de-icing properties. Furthermore, this coating, applicable to diverse substrates including board, steel, paper, and glass, demonstrated an impressive water contact angle (WCA) and sliding angle (SA). The spraying method offers the benefits of simplicity and cost-effectiveness. This is poised to significantly broaden its practical applications in various fields, including construction, transportation, and the chemical industry.
近年来,受 "仿生学 "的启发,超疏水表面备受关注。超疏水表面在解决界面问题方面表现出明显的优势,超疏水涂层具有优异的防水、防污、自洁、防腐蚀等性能,是很有前途的下一代防水材料。然而,复杂的制备工艺,加上较差的耐磨性和环境耐久性,严重限制了它们的实际应用。因此,本文从简化制备工艺和提高涂层耐久性入手。采用环氧树脂(E51)作为成膜材料,碳纳米管(CNT)和双尺寸 SiC 颗粒(纳米 SiC 和微米 SiC)作为填料。室温硫化硅橡胶(RTV)被用作与环氧树脂相互作用的粘合剂,以促进填料与聚合物之间的界面相互作用。这一工艺成功制备出了综合性能优异的超疏水涂层。当μ-SiC与n-SiC的比例为1:1时,制备出的涂层具有最佳的超疏水性能,水接触角(WCA)为167.4°,滑动角(SA)为4.6°。即使在经历了 1000 次砂纸磨损、100 次沙粒冲击、横切试验和 70 次胶带剥离等严酷的机械测试后,涂层仍能保持卡西-巴克斯特无湿状态。此外,即使在强酸、强碱和 3.5 wt% 的氯化钠溶液中浸泡 6 天,在 500 ℃ 下保温 2 小时,并在紫外线下曝晒 6 天,涂层仍表现出优异的超疏水性能。这表明制备的涂层具有优异的化学稳定性和耐高温性。此外,超疏水涂层还具有优异的自清洁、防腐蚀、防结冰和除冰性能。此外,这种涂层还适用于板材、钢材、纸张和玻璃等各种基材,并显示出令人印象深刻的水接触角(WCA)和滑动角(SA)。喷涂方法具有操作简单、成本效益高的优点。这将大大拓宽其在建筑、运输和化工等各个领域的实际应用。
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引用次数: 0
Effects of Al content on microstructure and corrosion behavior of Zn-Al alloy coatings 铝含量对锌铝合金涂层微观结构和腐蚀行为的影响
IF 0.9 4区 材料科学 Q4 Materials Science Pub Date : 2024-03-26 DOI: 10.15251/djnb.2024.191.409
A. Touane, M. Diafi, S. Benamor, D. Sahnoune
Alloying Zn with other metals is an alternative method to create advanced alloys with better corrosion properties, in this work the electrodeposition of Zn-Al binary alloy in sulphate-based acidic bath and with different Al2O12S3 content from 0.03 to 0.1M on a treated copper substrates was studied, the structure and microstructure of the coatings were analysed by X-ray diffraction (XRD) and scanning electron microscope (SEM) supported by (EDX) analysis, the microhardness was measured, the corrosion resistance was evaluated by potentiodynamic polarization (Tafel), the effect of Al ions was visible on the structure, (XRD) spectra showed zinc phase (η-phase), and Al phase (α-Al phase) with Al peak intensity increasing along with the increase of Al concentration, the microhardness also enhanced gradually to 252.33 HV, the corrosion current density decreased by almost 13 times and the corrosion resistance was drastically improved at 0.1M Al.
在这项工作中,研究了在硫酸盐基酸性镀液中,在处理过的铜基板上电沉积锌铝二元合金,Al2O12S3 含量从 0.03 到 0.1M 不等。通过 X 射线衍射 (XRD) 和扫描电子显微镜 (SEM) 以及 EDX 分析,对涂层的结构和微观结构进行了分析,测量了微硬度,并通过电位极化 (Tafel) 评估了耐腐蚀性、铝离子对结构的影响是显而易见的,(XRD)光谱显示出锌相(η 相)和铝相(α-Al 相),铝峰强度随着铝浓度的增加而增加,显微硬度也逐渐增加到 252.33 HV,腐蚀电流密度降低了近 13 倍,0.1M Al 时的耐腐蚀性能显著提高。
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引用次数: 0
The fabrication process of polydimethylsiloxane (PDMS) nanostructured films with antimicrobial properties against methicillin-resistant staphylococcus aureus (MRSA) 具有抗耐甲氧西林金黄色葡萄球菌(MRSA)特性的聚二甲基硅氧烷(PDMS)纳米结构薄膜的制作工艺
IF 0.9 4区 材料科学 Q4 Materials Science Pub Date : 2024-03-26 DOI: 10.15251/djnb.2024.191.325
N. L. M. Shamsuddin, K. Mohamed
Physical topography modification is an approach to fabricate nanostructures surfaces with antimicrobial properties. Lithography-based technologies offer an effective technique to develop the desired sizes and geometry. The replica molding technique was employed to fabricate the PDMS nanostructures using the PMMA imaging layer and characterized using a FESEM and AFM. The cell viability of gram-positive bacteria on structural diminished by almost 80% and the cells were deformed and ruptured once attached to the structured surface. Thus, the PDMS structured surface enhanced the bactericidal properties of the film, which effectively inhibit bacterial attachment.
物理形貌修饰是制造具有抗菌特性的纳米结构表面的一种方法。基于光刻技术的方法是开发所需尺寸和几何形状的有效技术。利用 PMMA 成像层复制成型技术制造了 PDMS 纳米结构,并使用 FESEM 和 AFM 对其进行了表征。结构表面上革兰氏阳性细菌的细胞活力降低了近 80%,细胞一旦附着到结构表面就会变形和破裂。因此,PDMS 结构表面增强了薄膜的杀菌性能,有效抑制了细菌的附着。
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引用次数: 0
Enhancement of the anti-corrosion performance based on the zeolitic imidazolate framework 基于沸石咪唑酸盐框架的防腐蚀性能增强技术
IF 0.9 4区 材料科学 Q4 Materials Science Pub Date : 2024-03-26 DOI: 10.15251/djnb.2024.191.401
J. W. Shen, X. Z. Fang, Z. W. Feng, X. Huang
In this work, a zeolite-imidazole framework (ZIF-8) was first synthesized and used as a corrosion inhibitor container to enhance the anti-corrosion property. After encapsulated the benzotriazole (BTA) corrosion inhibitor and coated with epoxy resin (EP) on the surface of Cu plate, the obtained sample B-ZIF-8@EP exhibited enhanced corrosion protection with high impedance and positive self-corrosion potential due to the release of BTA in the corrosion process. It is believed that this work is very helpful for extending the diversity of anti-corrosion coatings.
在这项工作中,首先合成了一种沸石-咪唑框架(ZIF-8),并将其用作缓蚀剂容器,以增强其防腐蚀性能。将苯并三唑(BTA)缓蚀剂封装后,用环氧树脂(EP)涂覆在铜板表面,得到的样品 B-ZIF-8@EP 由于在腐蚀过程中释放了 BTA,因此具有高阻抗和正自腐蚀电位的增强防腐性能。相信这项工作对扩展防腐蚀涂层的多样性很有帮助。
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引用次数: 0
Ultra-sensitive LC MEMS for bladder pressure monitoring using modified slotted diaphragm 利用改良开槽隔膜进行膀胱压力监测的超灵敏 LC MEMS
IF 0.9 4区 材料科学 Q4 Materials Science Pub Date : 2024-03-26 DOI: 10.15251/djnb.2024.191.351
L. Tahar, K. Malika
In this paper, we have designed and simulated an implantable MEMS-based LC pressure sensor for bladder pressure monitoring. The device is composed of metal-insulator-metal capacitive sensor in which the size of the diaphragm is 1 mm × 1 mm of 5 µm thickness. Besides, novel modified-slotted diaphragm is developed to improve the sensitivity by decreasing the mechanical rigidity of the membrane. We used the COMSOL Multiphysics a tool for design and simulation. According to the results, the frequency response to the variable pressure is varied within the range of 35.23 to 119.72 MHz, the results also yield a value obtained of the quality factor is worth 32 with high value of 4.22 kHz/Pa sensor sensitivity. Hence, this sensor with a novel modified-slotted diaphragm has a high-pressure sensitivity, which shows 2.91 times more sensitivity than clamped diaphragm.
本文设计并模拟了一种用于膀胱压力监测的植入式基于 MEMS 的 LC 压力传感器。该装置由金属-绝缘体-金属电容式传感器组成,其中膜片的尺寸为 1 mm × 1 mm,厚度为 5 µm。此外,我们还开发了新型改良开槽膜片,通过降低膜片的机械刚性来提高灵敏度。我们使用 COMSOL Multiphysics 工具进行设计和仿真。结果表明,对可变压力的频率响应在 35.23 至 119.72 MHz 范围内变化,结果还得出了品质因数值为 32,传感器灵敏度值高达 4.22 kHz/Pa。因此,这种带有新型改良开槽膜片的传感器具有较高的压力灵敏度,其灵敏度是夹紧膜片的 2.91 倍。
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引用次数: 0
Investigation on spinnability of low molecular weight alkaline lignin to fabricate biobased carbon fiber 研究低分子量碱性木质素的可纺性,以制造生物基碳纤维
IF 0.9 4区 材料科学 Q4 Materials Science Pub Date : 2024-03-26 DOI: 10.15251/djnb.2024.191.417
C. Shen, J. Li, D. Guo, L. Sha
Using acetic acid instead of dimethylformamide as solvent, lignin-based nanofibers were prepared by electrospinning with industrial low molecular weight lignin. After pre-oxidation and carbonization, the fibril was transformed into carbon fiber. The results showed that different viscosity of spinning solution and different parameters of electrospinning have great influence on the morphology of fibers. The diameter of fibers could be concentrated in 300-500nm by using the best electrospinning process. After carbonizing the fibers, it was found that the lignin fibers could retain the morphology of the fibers after carbonization at a suitable heating rate and holding temperature. This study showed the conditions required for the preparation of carbon fiber from low molecular weight lignin, and provided a way for high value utilization of waste biomass and green preparation of carbon fiber.
以乙酸代替二甲基甲酰胺作为溶剂,通过电纺丝法利用工业低分子量木质素制备了木质素基纳米纤维。经过预氧化和碳化后,纤维被转化为碳纤维。结果表明,不同的纺丝溶液粘度和不同的电纺参数对纤维的形态有很大影响。采用最佳的电纺丝工艺,纤维直径可集中在 300-500nm 之间。碳化纤维后发现,在合适的加热速率和保温温度下,木质素纤维可以保持碳化后的纤维形态。该研究表明了利用低分子量木质素制备碳纤维所需的条件,为废弃生物质的高值化利用和碳纤维的绿色制备提供了一条途径。
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引用次数: 0
Fabrication and anti-corrosion performances of robust superhydrophobic surface on NAB via solution-etching 通过溶液蚀刻在 NAB 上制作坚固的超疏水表面并提高其防腐蚀性能
IF 0.9 4区 材料科学 Q4 Materials Science Pub Date : 2024-03-26 DOI: 10.15251/djnb.2024.191.337
K. Chen, G. D. Fan, Y. M. Xia, J. F. Ou
A labyrinth microstructure interconnected by micron and submicron acicular structures was successfully prepared by immersing nickel-aluminum bronze in 9 wt% FeCl3·6H2O solution at room temperature for 40 min. After being modified with 1H, 1H, 2H, 2H-perfluorodecyltriethoxysilane (FAS-17), the microstructure surface displays robustly low-adhesion superhydrophobicity, and the water contact angle is above 160 ° on it. In addition, the superhydrophobic surface exhibits excellent corrosion resistance and stability in 3.5wt % NaCl aqueous solution and corrosion solution with different pH values.
室温下将镍铝青铜浸泡在 9 wt% 的 FeCl3-6H2O 溶液中 40 分钟,成功制备出了由微米和亚微米针状结构相互连接的迷宫式微结构。经 1H、1H、2H、2H-全氟癸基三乙氧基硅烷(FAS-17)改性后,微结构表面显示出强大的低粘附性超疏水性,其水接触角大于 160°。此外,该超疏水表面在 3.5wt % 的氯化钠水溶液和不同 pH 值的腐蚀溶液中表现出优异的耐腐蚀性和稳定性。
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引用次数: 0
Characterization of composite bioplastic from Cassava starch with titanium dioxide and zinc oxide 木薯淀粉与二氧化钛和氧化锌的复合生物塑料的表征
IF 0.9 4区 材料科学 Q4 Materials Science Pub Date : 2024-03-01 DOI: 10.15251/djnb.2024.191.275
U. Werapun, W. Werapun, A. Phatthiya
This study focused on bioplastics and composite bioplastics with incorporated ZnO and TiO2. The ZnO gave a film more transparent than that made with TiO2. The effects of these additives on physical and mechanical properties, biodegradability, surface morphology, and thermal properties of the films were investigated. The functional groups O-H, C-H, C=O, and C-O in the bioplastic and the composites were confirmed by FT-IR. The addition of ZnO and TiO2 could increase thermal stability. The composites exhibited higher tensile strength than the control bioplastic film. The bioplastic film was 100% biodegradable compared to 14.71% and 14.59% for ZnO and TiO2 containing bioplastic films, respectively.
这项研究的重点是含有氧化锌和二氧化钛的生物塑料和复合生物塑料。与使用二氧化钛制成的薄膜相比,氧化锌制成的薄膜更加透明。研究了这些添加剂对薄膜的物理和机械性能、生物降解性、表面形态和热性能的影响。傅立叶变换红外光谱确认了生物塑料和复合材料中的官能团 O-H、C-H、C=O 和 C-O。ZnO 和 TiO2 的添加可提高热稳定性。复合材料的拉伸强度高于对照生物塑料薄膜。生物塑料薄膜的生物降解率为 100%,而含有 ZnO 和 TiO2 的生物塑料薄膜的生物降解率分别为 14.71% 和 14.59%。
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引用次数: 0
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Digest Journal of Nanomaterials and Biostructures
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