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Experimental investigation of double basin solar still integrated with solar flat plate collector and solar pond with modified design 改进设计的太阳能平板集热器与太阳能池集成的双盆太阳能蒸馏器试验研究
IF 1.1 4区 工程技术 Q4 ENGINEERING, CHEMICAL Pub Date : 2023-01-01 DOI: 10.5004/dwt.2023.29454
M. Muthu Kumar, S. Rajesh, S. J. P. Gnanaraj
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引用次数: 0
Inhibition performance of benzotriazole-based composite inhibitor against carbon steel corrosion in stone processing wastewater 苯并三唑基复合缓蚀剂对石材加工废水中碳钢的缓蚀性能
IF 1.1 4区 工程技术 Q4 ENGINEERING, CHEMICAL Pub Date : 2023-01-01 DOI: 10.5004/dwt.2023.29451
Jingjing Xiang, Hao Peng, Likun Li, Heng Liu, Qiaoyun Zhu, Yanjun Huang, Yi Wang, G. Fan, Lei Zhang
The cutting saw blade with diamond blade and carbon steel matrix is widely used in stone cutting because of its high strength, impact resistance and good thermal stability. However, the carbon steel matrix is easy to corrode in the circulating cooling water, which shortens its service life. In this study, a new highly efficient benzotriazole-based (BMN) composite inhibitor was synthesized and investigated against the corrosion of carbon steel in stone processing wastewater. The corro- sion inhibition properties and mechanism of prepared BMN for carbon steel in real stone processing wastewater were evaluated and deduced using the experimental weight loss, electrochemical and surface morphology characterization techniques. Weight loss methods results showed that a high inhibition efficiency of 99.59% in stone processing wastewater was achieved at ambient temperature, with the stirring speed 200 rpm, the immersion time 7 d, and the BMN concentration is 50 mL·L –1 . Electrochemical impedance spectroscopy indicated that resistance from the surface films ( R 2 ) and charge transfer resistance ( R 3 ) were enhanced with increase in BMN concentration. Polarisation results revealed the BMN acted as an anodic inhibitor, owing to the addition of BMN resulted in the significant change of anodic Tafel slopes ( β a ). Scanning electron microscopy results indicated BMN formed a protective film on the surface of carbon steel through adsorption. In short, the prepared BMN composite inhibitor exhibited superior anti-corrosion performance for saw blade corrosion in stone processing wastewater, which had great application potential in industries.
金刚石刀片和碳钢基体的切割锯片因其强度高、抗冲击、热稳定性好,广泛应用于石材切割。但碳钢基体在循环冷却水中容易腐蚀,缩短了其使用寿命。本文合成了一种新型高效苯并三唑基(BMN)复合缓蚀剂,并对其在石材加工废水中对碳钢的腐蚀进行了研究。采用实验失重、电化学和表面形貌表征等方法,对制备的BMN对碳钢在石材加工废水中的缓蚀性能和机理进行了评价和推导。失重试验结果表明,在常温条件下,搅拌速度200 rpm,浸泡时间7 d, BMN浓度为50 mL·L -1,对石材加工废水的缓蚀率高达99.59%。电化学阻抗谱分析表明,表面膜电阻(r2)和电荷转移电阻(r3)随着BMN浓度的增加而增强。极化结果表明,BMN的加入导致阳极Tafel斜率(β a)发生显著变化,从而起到了阳极抑制剂的作用。扫描电镜结果表明,BMN通过吸附在碳钢表面形成一层保护膜。综上所述,所制备的BMN复合缓蚀剂对石材加工废水中的锯片腐蚀具有良好的防腐性能,具有很大的工业应用潜力。
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引用次数: 0
Factorial design and optimization of pinecone seed powder as a natural coagulant for organic and heavy metals removal from industrial wastewater 松果籽粉作为天然混凝剂去除工业废水中有机和重金属的析因设计与优化
IF 1.1 4区 工程技术 Q4 ENGINEERING, CHEMICAL Pub Date : 2023-01-01 DOI: 10.5004/dwt.2023.29199
M. Abujazar, S. U. Karaağaç, S. A. Abu Amr, S. Fatihah, M. Bashir, M. Alazaiza, A. Yusof, Mohamad Abou Auda
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引用次数: 0
Optimizing of ultraviolet initiated template polymerization of cationic polyacrylamide by response surface methodology 响应面法优化紫外光引发阳离子聚丙烯酰胺模板聚合
IF 1.1 4区 工程技术 Q4 ENGINEERING, CHEMICAL Pub Date : 2023-01-01 DOI: 10.5004/dwt.2023.29475
Zhengan Zhang, Juanfang Shang, Yuying Li, Lin Li, Yujiao Ye, Xia Hua, Bailian Li
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引用次数: 0
Adsorption and photocatalytic degradation investigation of organic dyes on TiO2-bentonite surface in aqueous solution 有机染料在tio2 -膨润土表面的吸附及光催化降解研究
IF 1.1 4区 工程技术 Q4 ENGINEERING, CHEMICAL Pub Date : 2023-01-01 DOI: 10.5004/dwt.2023.29470
R. Cherouaki, Youssef Gherraby, R. Bassam, S. Belaaouad, J. Naja
This work investigates the adsorption and the photocatalytic degradation performance of dyes (methylene blue (MB) and methyl orange (MO)) on the surface of raw bentonite (Raw-B) and doped bentonite with titanium oxide (TiO 2 -B). The bentonite was selected from the Nador region in north- ern Morocco, it was doped with various TiO 2 mass ratios. The structural, mineralogical and mor- phological composition of Raw-B and TiO 2 -B was characterized using several techniques including inductively coupled plasma atomic emission spectroscopy, X-ray diffraction, Fourier-transform infrared, transmission electron microscopy, and energy-dispersive X-ray analysis. The adsorption process of MB and MO were affected according to the Langmuir and Freundlich isotherms. The maximum removal capacity of MB and MO were around 60.97 and 142.85 mg/g, respectively. MB and MO degression ratios achieved 100% under a lamp irradiation at 245 nm. The results obtained show that the application of titanium oxide-doped bentonite has a very high performance in wastewater treatment.
本文研究了染料(亚甲基蓝(MB)和甲基橙(MO))在原料膨润土(raw -B)和掺杂氧化钛(tio2 -B)膨润土表面的吸附和光催化降解性能。该膨润土选自摩洛哥北部的纳多尔地区,掺有不同的二氧化钛质量比。利用电感耦合等离子体原子发射光谱、x射线衍射、傅里叶变换红外、透射电镜和能量色散x射线分析等技术对Raw-B和tio2 - b的结构、矿物学和生理组成进行了表征。根据Langmuir等温线和Freundlich等温线对MB和MO的吸附过程产生影响。对MB和MO的最大去除率分别为60.97和142.85 mg/g左右。在245 nm的灯照射下,MB和MO的降解率达到100%。结果表明,掺钛膨润土在废水处理中具有很高的性能。
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引用次数: 0
Nature-based solutions enhanced by reactive materials for the protection of urban water bodies 基于自然的解决方案,通过活性材料增强,保护城市水体
IF 1.1 4区 工程技术 Q4 ENGINEERING, CHEMICAL Pub Date : 2023-01-01 DOI: 10.5004/dwt.2023.28859
A. Bus, A. Karczmarczyk, A. Baryła
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引用次数: 0
Chicken bone ash is a cost-effective and efficient adsorbent for phenol removal from aqueous solution 鸡骨灰是一种经济高效的去除水中苯酚的吸附剂
IF 1.1 4区 工程技术 Q4 ENGINEERING, CHEMICAL Pub Date : 2023-01-01 DOI: 10.5004/dwt.2023.29141
M. Fawzy, H. M. Ahmed, Hossam F. Nassar
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引用次数: 2
Separation of organic pesticide (insecticide): lambda-cyhalothrin from wastewater using magnetic carbon nanocomposites 磁性碳纳米复合材料分离废水中有机农药(杀虫剂):高效氯氟氰菊酯
IF 1.1 4区 工程技术 Q4 ENGINEERING, CHEMICAL Pub Date : 2023-01-01 DOI: 10.5004/dwt.2023.29588
Muhammad Zahoor, Azmat Ullah, Jawad Ikram, Muhammad Naveed Umar, Riaz Ullah
In this study, a potato wastes based magnetic carbon nanocomposite (PMCNC) was synthesized and explored for its possible applications as adsorbent in removal of lambda-cyhalothrin from synthetically contaminated water. The nanocomposites were characterized through energy-dispersive X-ray, X-ray diffraction analysis, scanning electron microscopy, Fourier-transform infrared spectrophotometry, zero-point charge (pH pzc ) and thermogravimetric/differential thermal analysis. For the demonstration of adsorption efficiency of the nanocomposite, batch adsorption experiments were carried out. Maximum removal of selected pollutant was achieved in 30 min. Several kinetic and isotherm models were applied to the sorption kinetics and isothermal data. The pseudo-sec-ond-order kinetics fitted well the data. The X max (maximum adsorption) at 50°C was recorded as 14.025 mg/g with K 2 (pseudo-second-order kinetics constant) value of 0.0162 and R 2 value of 0.99. The adsorption isotherm data fitted well the Langmuir isotherm model. The optimum pH for the removal of lambda-cyhalothrin was achieved at pH 5. 0.1 g of PMCNC was used as optimum dose in all experiments. The negative value of Gibbs free energy reveals that the removal of lambda-cyhalo-thrin is a spontaneous process. Due to the excellent adsorption capability and easy separation from slurry after use through the application of magnet the PMCNC can be effectively used as an effective sorbent alternative to activated carbon for the removal of inorganic and organic contaminants from aquatic media. This nanocomposite could compete with other adsorbents in the field of surface chemistry warranting further experimentation.
本研究合成了一种马铃薯废物基磁性碳纳米复合材料(PMCNC),并探索了其作为吸附剂去除合成污染水中的高效氯氟氰菊酯的可能性。通过能量色散x射线、x射线衍射分析、扫描电镜、傅里叶变换红外分光光度计、零点电荷(pH pzc)和热重/差热分析对纳米复合材料进行了表征。为了验证纳米复合材料的吸附效率,进行了批量吸附实验。选定污染物的最大去除在30分钟内实现。几种动力学和等温模型应用于吸附动力学和等温数据。拟二、二阶动力学与数据拟合较好。50℃时最大吸附量为14.025 mg/g,准二级动力学常数k2为0.0162,r2为0.99。吸附等温线数据与Langmuir等温线模型拟合良好。pH为5时,氯氟氰菊酯脱除效果最佳。所有实验均以0.1 g PMCNC为最佳剂量。吉布斯自由能为负值,表明氯氰菊酯的去除是一个自发过程。由于优异的吸附能力和使用后易于从浆料中分离,通过磁铁的应用,PMCNC可以有效地用作活性炭的有效吸附剂,用于去除水生介质中的无机和有机污染物。这种纳米复合材料可以在表面化学领域与其他吸附剂竞争,需要进一步的实验。
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引用次数: 0
Contents Vol. 284 目录第284卷
IF 1.1 4区 工程技术 Q4 ENGINEERING, CHEMICAL Pub Date : 2023-01-01 DOI: 10.5004/dwt.2023.29462
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引用次数: 0
Effective separation of toxic azo dyes from water system using the activated carbon derived from Prosopis juliflora roots 用黄豆根活性炭有效分离水中有毒偶氮染料
IF 1.1 4区 工程技术 Q4 ENGINEERING, CHEMICAL Pub Date : 2023-01-01 DOI: 10.5004/dwt.2023.29216
J. Nayagam, K. Prasanna, P. Senthil kumar
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引用次数: 0
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Desalination and Water Treatment
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