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Biosorption of methylene blue dye using banana floret:: kinetic, equilibrium, thermodynamic and mass transfer studies 香蕉花吸附亚甲基蓝染料的动力学、平衡、热力学和传质研究
IF 1.1 4区 工程技术 Q4 ENGINEERING, CHEMICAL Pub Date : 2023-01-01 DOI: 10.5004/dwt.2023.29348
Clint Sutherland, Beverly Chittoo, Vikash Laltoo
Colour removal from effluents remains one of the most challenging requirements faced by indus - tries due to the difficulty of degrading dyes which consequently escape conventional wastewater treatment processes and persist in the environment. This study aimed to assess and optimise the dye adsorption performance of banana floret, a novel biosorbent. Batch experiments were con - ducted to assess the effects of particle size, pH, agitation, temperature, initial concentration and sorbent dose. Kinetic and equilibrium data were modelled, and mass transfer studies were con - ducted to elucidate the mechanisms of biosorption. Equilibrium data were best simulated using the Sips and Langmuir isotherm models. At an optimum pH of 6.0, biosorbent dose of 1.0 mg·L –1 and temperature of 300 K, a maximum sorption capacity of 219 mg·g –1 was observed. The kinetic data were best represented by the pseudo-second-order model. The dominant transport mechanism was attributed to intraparticle diffusion, while the dominant attachment mechanism was phys - ical sorption. The Taguchi method, in combination with analysis of variance, was used to deter - mine the optimum levels of operational parameters for maximising the biosorption of methylene blue by banana floret. The parameter group which produced the highest biosorption capacity and percent removal was determined to be A3-B1-C3 (initial concentration = 200 mg·L –1 , biosorbent dose = 500 mg·L –1 , contact time = 60 min) and A1-B3-C3 (initial concentration = 50 mg·L –1 , biosor - bent dose = 2000 mg·L –1 , contact time = 20 min), respectively. Among these parameters, the initial concentration had the most significant effect on the biosorption capacity, while sorbent dose was most significant on percent removal. A predictive model based on a quadratic equation which incorporates the factor interactions was successfully developed and validated.
由于染料难以降解,因此从废水中去除颜色仍然是工业面临的最具挑战性的要求之一,这些染料因此无法逃脱传统的废水处理工艺并持续存在于环境中。本研究旨在评价和优化新型生物吸附剂香蕉小花对染料的吸附性能。通过批量实验考察了粒径、pH、搅拌、温度、初始浓度和吸附剂用量对吸附效果的影响。对动力学和平衡数据进行了建模,并进行了传质研究以阐明生物吸附的机理。平衡数据用Sips和Langmuir等温线模型模拟效果最好。在最佳pH为6.0、生物吸附剂剂量为1.0 mg·L -1、温度为300 K的条件下,最大吸附量为219 mg·g -1。动力学数据最好用伪二阶模型表示。主要的输运机制是颗粒内扩散,而主要的附着机制是物理吸附。采用田口法,结合方差分析,确定了香蕉小花对亚甲基蓝生物吸附的最佳操作参数水平。结果表明,吸附量和去除率最高的参数组分别为A3-B1-C3(初始浓度= 200 mg·L - 1,生物吸附剂剂量= 500 mg·L - 1,接触时间= 60 min)和A1-B3-C3(初始浓度= 50 mg·L - 1,生物弯曲剂量= 2000 mg·L - 1,接触时间= 20 min)。其中,初始浓度对生物吸附能力的影响最为显著,而吸附剂剂量对去除率的影响最为显著。成功地建立并验证了基于二次方程的综合因素相互作用的预测模型。
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引用次数: 0
Efficient removal of polyethylene and polyvinyl chloride microplastics from water using a modified coagulation process supported by the addition of a surfactant 用添加表面活性剂的改性混凝法有效去除水中的聚乙烯和聚氯乙烯微塑料
IF 1.1 4区 工程技术 Q4 ENGINEERING, CHEMICAL Pub Date : 2023-01-01 DOI: 10.5004/dwt.2023.29398
Sabina Ziembowicz, M. Kida, P. Koszelnik
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引用次数: 1
How membrane fouling evolves during electrodialysis treatment of cold-rolling wastewater? 冷轧废水电渗析处理过程中膜污染是如何演变的?
IF 1.1 4区 工程技术 Q4 ENGINEERING, CHEMICAL Pub Date : 2023-01-01 DOI: 10.5004/dwt.2023.29273
Yinghua Li, Shijie Zhang, Jie-feng Qian, F. Su, Haibo Li
{"title":"How membrane fouling evolves during electrodialysis treatment of cold-rolling wastewater?","authors":"Yinghua Li, Shijie Zhang, Jie-feng Qian, F. Su, Haibo Li","doi":"10.5004/dwt.2023.29273","DOIUrl":"https://doi.org/10.5004/dwt.2023.29273","url":null,"abstract":"","PeriodicalId":11260,"journal":{"name":"Desalination and Water Treatment","volume":"140 1","pages":""},"PeriodicalIF":1.1,"publicationDate":"2023-01-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"77688818","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Effects of copper and zinc on pollutants removal in horizontal subsurface flow constructed wetlands 铜和锌对水平潜流人工湿地污染物去除的影响
IF 1.1 4区 工程技术 Q4 ENGINEERING, CHEMICAL Pub Date : 2023-01-01 DOI: 10.5004/dwt.2023.29220
Yan Zhang, Hongyun Dong, Xinhua Li, P. Lens, Nan Wang, Hongyuan Liu, Yanjun Wang, Ying Li
{"title":"Effects of copper and zinc on pollutants removal in horizontal subsurface flow constructed wetlands","authors":"Yan Zhang, Hongyun Dong, Xinhua Li, P. Lens, Nan Wang, Hongyuan Liu, Yanjun Wang, Ying Li","doi":"10.5004/dwt.2023.29220","DOIUrl":"https://doi.org/10.5004/dwt.2023.29220","url":null,"abstract":"","PeriodicalId":11260,"journal":{"name":"Desalination and Water Treatment","volume":"51 1","pages":""},"PeriodicalIF":1.1,"publicationDate":"2023-01-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"75147970","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Variation of total dissolved solids, conductivity and surface tensions of selected solutions under magnetic treatment 磁性处理下溶液的总溶解固形物、电导率和表面张力的变化
IF 1.1 4区 工程技术 Q4 ENGINEERING, CHEMICAL Pub Date : 2023-01-01 DOI: 10.5004/dwt.2023.29327
Abdelmnim M. Altwaiq, Leen Ali, M. Esaifan, R. Abdel-Rahem
{"title":"Variation of total dissolved solids, conductivity and surface tensions of selected solutions under magnetic treatment","authors":"Abdelmnim M. Altwaiq, Leen Ali, M. Esaifan, R. Abdel-Rahem","doi":"10.5004/dwt.2023.29327","DOIUrl":"https://doi.org/10.5004/dwt.2023.29327","url":null,"abstract":"","PeriodicalId":11260,"journal":{"name":"Desalination and Water Treatment","volume":"13 1","pages":""},"PeriodicalIF":1.1,"publicationDate":"2023-01-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"75223989","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Citric acid-pyrolysis synthesis of bismuth titanate series compounds and their photocatalytic degradation 柠檬酸-热解合成钛酸铋系列化合物及其光催化降解
IF 1.1 4区 工程技术 Q4 ENGINEERING, CHEMICAL Pub Date : 2023-01-01 DOI: 10.5004/dwt.2023.29532
Yuhai Mo, B. Tuo, Jianli Wang, G. Nie, Yun Tang
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引用次数: 0
A review on harmful algae blooms in Arabian Gulf: causes and impacts on desalination plants 阿拉伯湾有害藻华的成因及对海水淡化厂的影响
IF 1.1 4区 工程技术 Q4 ENGINEERING, CHEMICAL Pub Date : 2023-01-01 DOI: 10.5004/dwt.2023.29482
A. Al-Rawajfeh, Ebtehal Alzalabieh, Ghada A. Al Bazedi, G. Al-Mazaideh, M. Shalayel
The harmful algal bloom (red tides) (HAB) phenomenon is an issue for desalination facilities. This paper reviews the causes and impacts of HABs on desalination plants. Some HABs are linked to the creation of natural pollutants, dissolved oxygen depletion, and other negative consequences. Because desalination facilities are the principal source of freshwater for communities, agriculture, and industry for middle eastern arid nations, the disruption of plant operations by red tide poses a danger to the availability of drinkable water and can constitute an extraordinary HABs impact. Desalination plants are responsible for pollutants added to the Gulf seawater via outfall systems. Consequently, desalination projects must undergo an environmental impact assessment (EIA), considering accepted environmental characteristics and criteria. EIA assesses the potential effects on air, land, and sea water qualities, techniques to mitigate their impact.
有害藻华(赤潮)(HAB)现象是海水淡化设施面临的一个问题。本文综述了海水淡化厂中有害藻华的成因及影响。一些有害藻华与自然污染物的产生、溶解氧的消耗和其他负面后果有关。由于海水淡化设施是中东干旱国家社区、农业和工业的主要淡水来源,赤潮对工厂运作的破坏对饮用水的供应构成了威胁,并可能构成非同寻常的有害藻华影响。海水淡化厂要为通过排放系统添加到海湾海水中的污染物负责。因此,海水淡化项目必须经过环境影响评估(EIA),考虑公认的环境特征和标准。环境影响评估评估对空气、土地和海水质量的潜在影响,以及减轻其影响的技术。
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引用次数: 0
Facile synthesis of Cu-complex for visible-light photodegradation of organic dyes and sulfonamide antibiotics with added H2O2 添加H2O2的cu配合物在可见光下降解有机染料和磺胺类抗生素的简易合成
IF 1.1 4区 工程技术 Q4 ENGINEERING, CHEMICAL Pub Date : 2023-01-01 DOI: 10.5004/dwt.2023.29506
Dawei Wang, Xue-bin Ji, Zhengjun Shi
In this article, copper complex [Cu(biba) 2 ]·H 2 O (biba = 2-(1H-benzoimidazol-2-yl)benzoic acid) was synthesized via hydrothermal method, and structurally characterized by single-crystal X-ray diffraction, powder X-ray diffraction, UV-Vis diffuse reflectance spectra, Raman spectra and Fourier-transform infrared spectroscopy. [Cu(biba) 2 ]·H 2 O exhibited good photocatalytic activities in degradation of methylene blue (MB) dye and sulfadiazine (SD) antibiotic under visible light with added H 2 O 2 . The degradation efficiency of MB was up to 93.1% after reacting for 80 min, and the degradation efficiency of SD was over 96.8% after reacting for 60 min. The degradation kinetics of MB and SD under [Cu(biba) 2 ]·H 2 O/H 2 O 2 catalytic system was studied, and the observed first-order kinetics rate constants ( k ) were 0.0340 and 0.0573 min –1 , respectively. Based on the experimental results, a reasonable mechanism was proposed to interpret the photo-Fenton oxidation process.
本文采用水热法合成了铜配合物[Cu(biba) 2]·h2o (biba = 2-(1h -苯并咪唑-2-基)苯甲酸),并用单晶x射线衍射、粉末x射线衍射、紫外-可见漫反射光谱、拉曼光谱和傅里叶变换红外光谱对其进行了结构表征。[Cu(biba) 2]·h2o在可见光下对亚甲基蓝(MB)染料和磺胺嘧啶(SD)抗生素的降解表现出良好的光催化活性。反应80 min后,MB的降解效率可达93.1%,反应60 min后,SD的降解效率可达96.8%以上。研究了[Cu(biba) 2]·h2o / h2o催化体系对MB和SD的降解动力学,观察到一级动力学速率常数(k)分别为0.0340和0.0573 min -1。基于实验结果,提出了一种合理的光- fenton氧化机理。
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引用次数: 0
Persulfates to degrade a mixture of dyes (rhodamine B, methylene blue) in the presence of glucose and visible light 过硫酸盐在葡萄糖和可见光存在下降解染料混合物(罗丹明B,亚甲基蓝)
IF 1.1 4区 工程技术 Q4 ENGINEERING, CHEMICAL Pub Date : 2023-01-01 DOI: 10.5004/dwt.2023.29288
P. Zawadzki
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引用次数: 0
Electrochemical properties of Ti/Sb/SnO2-SiO2 anode for electrocatalytic oxidation of Acid Red 18 Ti/Sb/SnO2-SiO2阳极电催化氧化酸性红18的电化学性能
IF 1.1 4区 工程技术 Q4 ENGINEERING, CHEMICAL Pub Date : 2023-01-01 DOI: 10.5004/dwt.2023.29222
Yanfang Song, Jiaman Liu, Jiping Jia, Honghua Ge, Xinjing Meng, Yuzeng Zhao
{"title":"Electrochemical properties of Ti/Sb/SnO2-SiO2 anode for electrocatalytic oxidation of Acid Red 18","authors":"Yanfang Song, Jiaman Liu, Jiping Jia, Honghua Ge, Xinjing Meng, Yuzeng Zhao","doi":"10.5004/dwt.2023.29222","DOIUrl":"https://doi.org/10.5004/dwt.2023.29222","url":null,"abstract":"","PeriodicalId":11260,"journal":{"name":"Desalination and Water Treatment","volume":"1 1","pages":""},"PeriodicalIF":1.1,"publicationDate":"2023-01-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"82245359","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
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Desalination and Water Treatment
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