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Improving the performance of a pyramid solar still using different wick materials and reflectors in Iraq 在伊拉克使用不同的灯芯材料和反射器来提高金字塔太阳能的性能
IF 1.1 4区 工程技术 Q4 ENGINEERING, CHEMICAL Pub Date : 2023-01-01 DOI: 10.5004/dwt.2023.29226
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引用次数: 3
Removal of azithromycin from aqueous solutions using Fe2O3/Ag/Zn nanocomposites Fe2O3/Ag/Zn纳米复合材料去除水溶液中阿奇霉素的研究
IF 1.1 4区 工程技术 Q4 ENGINEERING, CHEMICAL Pub Date : 2023-01-01 DOI: 10.5004/dwt.2023.29485
Rasoul Hosseini, F. Keshavarzi, Nahid Haghnazari, C. Karami
Drugs are essential pollutants in the environment due to their resistant structure, and their high consumption in treating humans and animals. The entry of antibiotics as hospital waste into aquatic environments is considered one of the critical environmental means due to their high stability. The design and synthesis of Fe 2 O 3 /Ag/Zn as a new structure of Fe 2 O 3 were reported, because of its resis- tance of the structure to air and high temperature, the adsorbent of azithromycin in wastewater was studied. After characterization of Fe 2 O 3 /Ag/Zn by scanning electron microscopy, energy-dis- persive X-ray spectroscopy, mapping, transmission electron microscopy, X-ray diffraction and Fourier-transform infrared spectroscopy. Then, to remove azithromycin, the effect of factors such as pH, the concentration of azithromycin solution, adsorbent dose, time and temperature was evalu-ated using an optimization process. The results showed that the optimal conditions for removing of 96% of azithromycin (10 mg/L) with 1.5 g/L of Fe 2 O 3 /Ag/Zn, pH = 5, and 30 min at room temperature, In other words, the nano absorbent has a good ability to remove azithromycin from water solution, which is very important from environmental aspects.
药物由于其耐药结构,以及在治疗人类和动物时的高消耗,是环境中必不可少的污染物。抗生素作为医院废弃物进入水生环境,由于其高稳定性,被认为是关键的环境手段之一。本文设计合成了fe2o3 /Ag/Zn作为一种新型fe2o3结构,由于该结构对空气和高温的抗性,对废水中阿奇霉素的吸附剂进行了研究。通过扫描电镜、能量色散x射线能谱、作图、透射电镜、x射线衍射和傅里叶变换红外光谱对fe2o3 /Ag/Zn进行表征。然后,采用优化工艺考察了pH、阿奇霉素溶液浓度、吸附剂用量、时间、温度等因素对去除阿奇霉素的影响。结果表明,在1.5 g/L Fe 2o3 /Ag/Zn、pH = 5、30 min的室温条件下,纳米吸附剂对阿奇霉素(10 mg/L)的去除率为96%,表明纳米吸附剂对水溶液中阿奇霉素的去除率较好,具有重要的环境意义。
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引用次数: 0
A novel dual-heated water and power cogeneration system using solar driven humidification-dehumidification cycle 一种新型的利用太阳能驱动的加湿-除湿循环的水电双热电联产系统
IF 1.1 4区 工程技术 Q4 ENGINEERING, CHEMICAL Pub Date : 2023-01-01 DOI: 10.5004/dwt.2023.29516
Weifeng He, Qile Shi, Zihui Zhang, Zhao Yao, Pengfei Su, D. Han
A novel dual-heated water and power cogeneration system (WPCS), in which photovoltaic/thermal (PV/T) is used for seawater heating and electricity generation, and solar collector is applied for air heating, based on the humidification–dehumidification (HDH) cycle, is proposed. Comprehensive performance of the dual-heated WPCS is obtained, and the parametric analysis, from the pinch enthalpy difference (PED) within the humidifier and solar intensity, are accomplished. It is found the peak gained-output-ratio (GOR), water production and water production cost (WPC) 2.55, 76.32 kg·h –1 and 15.14 $t –1 , with an uneconomical payback period (PBP). The parametric analysis implies a lower PED and higher solar intensity are profitable to raise the water production, while the GOR will decrease instead when the solar intensity rises. Furthermore, it is illustrated a higher PED and solar intensity can reduce the PBP. It is concluded the combined applications of the PV/T and solar collector can result in the advantages, to neutralize the features of the single heated, water-or air-heated HDH systems, HDH desalination methods for raising water production and GOR. However, the impossibility to recover the cost of the dual-heated WPCS within the working lifetime is also discovered, although this is of less importance in areas with water shortages.
提出了一种基于加湿-除湿(HDH)循环,利用光伏/热(PV/T)进行海水加热和发电,利用太阳能集热器进行空气加热的新型双热水电热电联产系统(WPCS)。从加湿器内捏缩焓差(PED)和太阳强度两方面对双加热WPCS进行了参数分析,得到了其综合性能。结果表明,最大产出比(GOR)、产水量和产水成本(WPC)分别为2.55、76.32 kg·h -1和15.14美元·t -1,投资回收期(PBP)不经济。参数分析表明,较低的PED和较高的太阳强度有利于提高采出水量,而随着太阳强度的增加,GOR反而会降低。此外,较高的PED和太阳强度可以降低PBP。结论是,PV/T和太阳能集热器的联合应用可以产生优势,以抵消单一加热,水或空气加热HDH系统的特点,HDH脱盐方法提高产水量和GOR。然而,人们还发现,在工作寿命内回收双加热WPCS的成本是不可能的,尽管这在缺水地区不太重要。
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引用次数: 0
Simultaneous removal of Methylene Blue and Direct Blue 71 with Pb(II) ions from multi-component systems: application of the multi-component Langmuir model 多组分体系中Pb(II)离子同时去除亚甲基蓝和直接蓝71:多组分Langmuir模型的应用
IF 1.1 4区 工程技术 Q4 ENGINEERING, CHEMICAL Pub Date : 2023-01-01 DOI: 10.5004/dwt.2023.29357
G. Polat, Ezgi Türkeş, Y. Sağ Açıkel
This study aims to investigate the simultaneous removal of Methylene Blue (MB), Direct Blue 71 (DB71), and Pb(II) ions, which are frequently found together at high concentrations in different industrial wastewaters, such as textile, paper, leather, paint, and plastic manufacturing waste- waters. The simultaneous removal of Pb(II) ions with MB and DB71 from binary mixtures was investigated by the adsorption method. Magnetic halloysite nanotubes-alginate (MHNTs-ALG) hybrid beads were used to remove these components from the binary adsorption media. For this purpose, a magnetic property was gained to halloysite nanotubes using the “co-precipitation method”. Magnetic halloysite nanotubes (MHNTs) were composited with alginate (ALG) biopoly - mers through the “extrusion dripping method”. The adsorption capacities and efficiency of these synthesized MHNTs-ALG hybrid beads were investigated according to their anionic and cationic pollutant content in binary mixtures, and the synergistic and antagonistic effects of these compo- nents on each other were investigated by comparing them according to single systems. The compatibility with the multi-component Langmuir adsorption model for binary systems was examined using equilibrium adsorption data, and the values of the constants showing the adsorption capacity and affinity were calculated. In binary mixtures of Pb(II)-MB, the maximum amounts of Pb(II) and MB adsorbed per unit adsorbent weight calculated from the multi-component Langmuir model were 248.46 mg/g ( q Pb, m ) and 946.92 mg/g ( q MB, m ), respectively. The maximum adsorption capacities of Pb(II) and Direct Blue 71 from binary systems were determined as 203.14 mg/g ( q Pb, m ) and 118.96 mg/g ( q DB71, m ), respectively. The co-presence of Pb(II) and MB was concluded to cre- ate a synergistic effect compared to the adsorption of Pb(II) ions alone and an antagonistic effect compared to the adsorption of MB alone. The co-presence of Pb(II) and DB71 was observed to form a synergistic effect compared to the individual presence of Pb(II) ions and an antagonistic-synergistic mixed effect compared to the individual presence of DB71.
本研究旨在研究同时去除亚甲基蓝(MB)、直接蓝71 (DB71)和铅(II)离子,这三种离子在纺织、造纸、皮革、油漆和塑料等工业废水中经常以高浓度共存。采用吸附法研究了MB和DB71同时去除二元混合物中的Pb(II)离子。采用磁性高岭土纳米管-海藻酸盐(MHNTs-ALG)杂化微珠从二元吸附介质中去除这些成分。为此,采用“共沉淀法”获得了高岭土纳米管的磁性能。采用挤压滴法制备了磁性高岭土纳米管(MHNTs)和海藻酸盐(ALG)生物聚合物。根据所合成的MHNTs-ALG杂化微珠在二元混合物中的阴离子和阳离子污染物含量,考察了它们的吸附能力和效率,并以单一体系为对照,考察了它们之间的协同和拮抗作用。利用平衡吸附数据考察了其与二元体系多组分Langmuir吸附模型的相容性,并计算了表征吸附容量和亲和力的常数值。在Pb(II)-MB二元混合物中,根据多组分Langmuir模型计算,单位吸附剂重量对Pb(II)和MB的最大吸附量分别为248.46 mg/g (q Pb, m)和946.92 mg/g (q MB, m)。二元体系对Pb(II)和Direct Blue 71的最大吸附量分别为203.14 mg/g (q Pb, m)和118.96 mg/g (q DB71, m)。与单独吸附Pb(II)离子相比,Pb(II)和MB的共存产生了协同作用,而与单独吸附MB相比,Pb(II)离子的共存产生了拮抗作用。与单独存在的Pb(II)离子相比,Pb(II)和DB71离子的共存形成了协同效应,与单独存在的DB71离子相比,形成了拮抗协同混合效应。
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引用次数: 0
Modeling of stormwater infiltration basin enhanced with drywells technique 干井技术增强的雨水入渗盆地建模
IF 1.1 4区 工程技术 Q4 ENGINEERING, CHEMICAL Pub Date : 2023-01-01 DOI: 10.5004/dwt.2023.29518
Zakaria Helles, Y. Mogheir
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引用次数: 0
Construction of specific nickel-based electrode using N, N-dimethylformamide/water as solvent and the application in metronidazole detection 以N, N-二甲基甲酰胺/水为溶剂的镍基电极的构建及其在甲硝唑检测中的应用
IF 1.1 4区 工程技术 Q4 ENGINEERING, CHEMICAL Pub Date : 2023-01-01 DOI: 10.5004/dwt.2023.29529
Yun Lu, Ruibin Wang, Guoping Wang, Nian Chen
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引用次数: 0
Degradation of Reactive Black 5 by ultrasound-activated persulfate process: kinetics, mineralization, and by-products 超声活化过硫酸盐法降解活性黑5:动力学、矿化和副产物
IF 1.1 4区 工程技术 Q4 ENGINEERING, CHEMICAL Pub Date : 2023-01-01 DOI: 10.5004/dwt.2023.29317
P. Anthony, Ş. Doğan
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引用次数: 0
Effect of lateritic iron and hydrogen peroxide for degradation and mineralization of pyridine compound 2-aminopyridines 红土铁和过氧化氢对吡啶类化合物2-氨基吡啶降解矿化的影响
IF 1.1 4区 工程技术 Q4 ENGINEERING, CHEMICAL Pub Date : 2023-01-01 DOI: 10.5004/dwt.2023.29521
R. Karale, D. V. Wadkar, S. Mane, M. Wagh
Pyridine is an important raw material in the pharmaceutical industry. Aminopyridines are key intermediates for the synthesis of important pharmaceutical products. 2-Aminopyridine is used in the production of antibacterial and several antihistamines drugs. Pyridine compounds have harmful effects on the liver, kidneys, immune systems, and reproductive functions, and have potential carcinogenicity. It is very essential to degrade 2-aminopyridines from an aqueous environment on a priority basis. Large-scale application of Fenton/photo-Fenton processes employing ferrous salts Fe 2+ may prove costlier for the complete treatment of contaminated water/wastewater containing such recalcitrant compounds. 100% degradation of 2-aminopyridine (10 mg·L –1 ) by the Fenton process required 180 min out of which 58% degradation was achieved in the first 60 min of the reaction. The pho-to-Fenton oxidation process showed an improved rate of degradation. Parameters like pH, the dosage of hydrogen peroxide, and iron extracted from laterite soil are optimized for the effective degradation and mineralization of 2-aminopyridine in water. Kinetic studies were also conducted using the optimum conditions for 2-aminopyridine degradation and, the pseudo-first-order kinetic equation has been fit up to the reaction time of 30 min. High-performance liquid chromatography analysis was also carried out to confirm the cleavage of the pharmaceutical compound 2-aminopyridine.
吡啶是医药工业的重要原料。氨基吡啶是合成重要医药产品的关键中间体。2-氨基吡啶用于生产抗菌药和几种抗组胺药。吡啶类化合物对肝脏、肾脏、免疫系统和生殖功能有有害影响,并具有潜在的致癌性。优先从水环境中降解2-氨基吡啶是非常重要的。大规模应用Fenton/光Fenton工艺,采用亚铁盐fe2 +,可能会证明完全处理含有这种顽固化合物的污染水/废水的成本更高。Fenton法对2-氨基吡啶(10 mg·L -1)的100%降解需要180 min,其中前60 min的降解率为58%。磷- fenton氧化工艺的降解速率明显提高。对pH、双氧水用量、提取铁等参数进行了优化,以保证水中2-氨基吡啶的有效降解和矿化。对2-氨基吡啶的最佳降解条件进行了动力学研究,拟一阶动力学方程拟合反应时间为30 min。高效液相色谱分析证实了药物化合物2-氨基吡啶的裂解。
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引用次数: 0
Performance of polymeric nanofiltration membranes for non-aqueous systems: experimental results and modeling 聚合物纳滤膜在非水系统中的性能:实验结果和模型
IF 1.1 4区 工程技术 Q4 ENGINEERING, CHEMICAL Pub Date : 2023-01-01 DOI: 10.5004/dwt.2023.29155
H. Shi, Limeng Li, Jiahui Lu, Shengyuan Xu, X. Hu, Rong-xian Zhang, Guoxing Zhu, Weihua Zhu
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引用次数: 0
Removal of eosin yellow from wastewaters by the commercial anion exchange membrane BI 商业阴离子交换膜BI去除废水中的伊红黄
IF 1.1 4区 工程技术 Q4 ENGINEERING, CHEMICAL Pub Date : 2023-01-01 DOI: 10.5004/dwt.2023.29368
Khalida Parveen, S. Zafar, Muhammad Imran Khan, Ramsha Anwer, A. Shanableh
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引用次数: 0
期刊
Desalination and Water Treatment
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