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Exploring the Possible Pathways for Enhancing the Photovoltaic Performance of Indium Tin Oxide/Si Heterojunction Solar Cells 探索提高氧化铟锡/硅异质结太阳能电池光电性能的可能途径
IF 3.6 4区 工程技术 Q3 ENERGY & FUELS Pub Date : 2025-12-12 DOI: 10.1002/ente.202501208
Dibyendu Kumar Ghosh, Sukanta Bose, Shiladitya Acharyya, Gourab Das, Sumita Mukhopadhyay, Anindita Sengupta

In this contribution, the photovoltaic performance of indium tin oxide (ITO)/p-Si heterojunction solar cell was investigated both theoretically and experimentally. The practical device demonstrated a conversion efficiency of 1.79% with Voc  = 180 mV, Jsc  = 24.2 mA/cm2 and FF = 41%. The possible reasons behind such realized photovoltaic performance were investigated using Automat FOR Simulation of HETerostructures v2.5 (AFORS-HET) software. The study unveiled that high defect density at the ITO/p-Si interface might be responsible for realizing such conversion efficiency. Moreover, the impact of electron affinity and the dielectric constant of the ITO layer on the power conversion efficiency of the device architecture was studied theoretically. However, significant improvement in the device performance was perceived by introducing a thermally grown 1.5 nm SiOx surface passivation layer at the heterointerface. In this case, the best device showed a conversion efficiency of 3.01% with Voc = 240 mV, Jsc  = 24.10 mA/cm2, and FF = 52%. Furthermore, the simulation study demonstrated that introducing a back surface field layer might also enable the realization of adequate power output.

本文对氧化铟锡(ITO)/p-Si异质结太阳能电池的光电性能进行了理论和实验研究。实际装置的转换效率为1.79%,Voc = 180 mV, Jsc = 24.2 mA/cm2, FF = 41%。利用Automat FOR Simulation of HETerostructures v2.5 (AFORS-HET)软件对实现这种光伏性能的可能原因进行了研究。研究表明,ITO/p-Si界面上的高缺陷密度可能是实现这种转换效率的原因。此外,还从理论上研究了电子亲和力和ITO层介电常数对器件结构功率转换效率的影响。然而,通过在异质界面处引入热生长的1.5 nm SiOx表面钝化层,器件性能得到了显着改善。在这种情况下,最佳器件的转换效率为3.01%,Voc = 240 mV, Jsc = 24.10 mA/cm2, FF = 52%。此外,仿真研究表明,引入后表面电场层也可以实现足够的功率输出。
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引用次数: 0
Investigation of Transient Erosion Behavior of Single and Dual-Tapered Pipe Components 单、双锥形管构件瞬态侵蚀性能研究
IF 3.6 4区 工程技术 Q3 ENERGY & FUELS Pub Date : 2025-12-08 DOI: 10.1002/ente.202500948
An Chen, Yonggang Yu, Shuo Xiao

This study investigated the erosion wear characteristics of a forcing cone (FC) induced by high-speed dense propellant particle groups during the initial internal ballistic phase of a launching system. By coupling the computational fluid dynamics and discrete element method (CFD-DEM) with the initial internal ballistics model, the transient erosion behaviors of two FC components with distinct tapered structures were quantitatively assessed. The FLUENT software was adopted for the CFD simulations. The findings revealed that the mass losses of both types of FCs experience exponential growth over time. In the single-stage FC, the erosion pattern at the left end was characterized by a ring-like distribution, whereas the middle and right ends exhibited irregular cloud-like distributions. In the dual-stage FC, erosion was predominantly concentrated in the first section. The mass loss of the dual-stage FC was significantly lower, showing a 7.3% reduction compared to that of the single-stage FC. From the perspective of erosion evaluation, the dual-stage FC exhibits superior structural performance.

研究了高速密集推进剂颗粒群在发射系统初始内弹道阶段对强制锥的冲蚀磨损特性。通过将计算流体力学和离散元法(CFD-DEM)与初始内弹道模型相结合,定量评估了两种不同锥形结构的FC构件的瞬态侵蚀行为。采用FLUENT软件进行CFD仿真。研究结果表明,随着时间的推移,两种类型fc的质量损失都呈指数增长。在单阶段FC中,侵蚀模式在左端呈环状分布,而中端和右端呈不规则云状分布。在双阶段FC中,侵蚀主要集中在第1段。双级FC的质量损失明显较低,与单级FC相比减少了7.3%。从侵蚀评价的角度来看,双级FC表现出优越的结构性能。
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引用次数: 0
Flexible Sodium Alginate/Silk Triboelectric Sensor for Self-Powered Motion Monitoring in Traditional Physical Training of Children with Autism Spectrum Disorder 柔性海藻酸钠/丝绸摩擦电传感器在自闭症谱系障碍儿童传统体能训练中的自供电运动监测
IF 3.6 4区 工程技术 Q3 ENERGY & FUELS Pub Date : 2025-12-08 DOI: 10.1002/ente.202501245
Xiaogang Fu, Xinghao Wang, Wenting Zhang

Wearable self-powered sensors offer significant potential for real-time monitoring and behavioral assessment in personalized rehabilitation and neurodevelopmental interventions. In this work, a sodium alginate/silk (SA/silk) composite film–based triboelectric nanogenerator (SS-TENG) is developed for bio-mechanical energy harvesting and motion monitoring in traditional physical training programs for children with autism spectrum disorder. The SA/silk composite provides high mechanical flexibility and stable surface morphology, ensuring consistent triboelectric output during dynamic movements. The SS-TENG delivers a peak open-circuit voltage (VOC) of 195.3 V, short-circuit current (ISC) of 58.8 μA, and transferred charge (QSC) of 174.5 nC, with a maximum power of 4.3 mW. Its output is highly sensitive to changes in force, frequency, and displacement, enabling precise detection of activity intensity. The device also demonstrates strong energy storage capability by effectively charging capacitors. When integrated into footwear, the SS-TENG enables battery-free, real-time monitoring of gait and movement. Notably, it distinguishes between neurotypical and autistic motor behaviors during walking, running, and jumping based on characteristic signal patterns. These results demonstrate the SS-TENG's potential as a wearable, self-powered platform for quantitative evaluation of sports-based interventions, supporting early diagnosis and personalized training in autism spectrum disorder therapy.

可穿戴自供电传感器为个性化康复和神经发育干预的实时监测和行为评估提供了巨大的潜力。在这项工作中,开发了一种基于海藻酸钠/丝绸(SA/silk)复合薄膜的摩擦电纳米发电机(SS-TENG),用于自闭症谱系障碍儿童传统体育训练项目中的生物机械能收集和运动监测。SA/丝绸复合材料提供高机械灵活性和稳定的表面形态,确保在动态运动中一致的摩擦电输出。SS-TENG的峰值开路电压(VOC)为195.3 V,短路电流(ISC)为58.8 μA,转移电荷(QSC)为174.5 nC,最大功率为4.3 mW。它的输出对力、频率和位移的变化高度敏感,能够精确检测活动强度。该装置还通过有效充电电容器展示了强大的能量存储能力。当集成到鞋类中时,SS-TENG可以实现无电池、实时监控步态和运动。值得注意的是,它根据特征信号模式区分了行走、跑步和跳跃时的神经正常和自闭症运动行为。这些结果表明,SS-TENG有潜力成为一种可穿戴的、自驱动的平台,用于定量评估基于运动的干预措施,支持自闭症谱系障碍治疗的早期诊断和个性化培训。
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引用次数: 0
Artificial Intelligence-Based Defect Prediction in Photovoltaic Panels Coupling with Nondestructive Detection Techniques: A Comprehensive Review 基于人工智能的光伏板缺陷预测与无损检测技术综述
IF 3.6 4区 工程技术 Q3 ENERGY & FUELS Pub Date : 2025-12-08 DOI: 10.1002/ente.202502065
Yunzhi Wang, Yue Xing

Defects in photovoltaic (PV) panels significantly influence solar PV generation, necessitating accurate determination of defect location, size, and severity. Conventional detection methods suffer from limitations such as complexity, long cycle times, and high costs, which hinder rapid, large-scale reliability assessments. Recently, imaging approaches have emerged as nondestructive, rapid, and high-throughput alternatives for PV defect evaluation. This review provides a systematic investigation of the research progress at the intersection of imaging-based methods and AI algorithms for PV defect detection. The advantages and disadvantages of integrating imaging techniques with AI algorithms across various aspects of PV panel defect evaluation are comprehensively discussed to clarify the application prospects for practical defect assurance in PV panels. Compared to traditional inspection methods, the integrated approach combining imaging-based techniques with AI algorithms enables real-time, precise, and intelligent defect detection in PV panels. Furthermore, future trends of combining these imaging techniques with AI algorithms across various aspects of PV panel defect evaluation are also comprehensively introduced in this study.

光伏板中的缺陷对太阳能光伏发电有很大影响,因此需要准确确定缺陷的位置、大小和严重程度。传统的检测方法存在复杂性、周期长、成本高等局限性,阻碍了快速、大规模的可靠性评估。最近,成像方法已成为无损、快速和高通量的PV缺陷评估替代方法。本文综述了基于成像的方法和人工智能算法在光伏缺陷检测中的交叉研究进展。综合讨论了成像技术与人工智能算法在光伏板缺陷评估各个方面的优缺点,阐明了光伏板实际缺陷保证的应用前景。与传统检测方法相比,该方法将基于成像的技术与人工智能算法相结合,实现了光伏板缺陷的实时、精确和智能检测。此外,本研究还全面介绍了将这些成像技术与人工智能算法结合起来,在光伏板缺陷评估的各个方面的未来趋势。
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引用次数: 0
Preparation and Capacitive Performance of Nitrogen-Doped Natural Integrated Carbon Sheets Derived From Waste Leather 废皮革氮掺杂天然集成碳片的制备及其电容性能
IF 3.6 4区 工程技术 Q3 ENERGY & FUELS Pub Date : 2025-12-08 DOI: 10.1002/ente.202501688
Fei Ma, Hongfeng ZHAO

Waste leather (pig/cattle/sheep) was converted into nitrogen-doped carbon sheets via high-temperature carbonization and CO2 activation. Characterization via thermogravimetric analysis, a scanning electron microscopy, nitrogen adsorption–desorption, and an X-ray photoelectron spectroscopy revealed nitrogen-doped carbon sheets feature a 748 m2 g−1 surface area, hierarchical micro-mesopores, and 4.55 at% nitrogen. Electrochemical tests in 6 M KOH showed SL-CAC electrodes exhibit 197.6 F g−1 capacitance (0.3 A g−1), 61.3% rate retention (0.3–5 A g−1), and 98.36% stability over 10 000 cycles. Performance gains stem from enhanced ion transport via porous structure, nitrogen-induced pseudocapacitance, and reduced resistance from integrated design. This work enables sustainable leather waste recycling and advanced supercapacitor electrode development.

利用猪/牛/羊废皮革经高温炭化和CO2活化制备掺氮碳片。通过热重分析、扫描电子显微镜、氮吸附-解吸和x射线光电子能谱进行表征,发现氮掺杂碳片具有748 m2 g−1的表面积、分层微介孔和4.55 %的氮。电化学测试表明,在6 M KOH中,SL-CAC电极的电容为197.6 F g−1 (0.3 A g−1),保持率为61.3% (0.3 - 5 A g−1),超过10,000次循环的稳定性为98.36%。性能的提高源于通过多孔结构增强离子传输,氮诱导的赝电容,以及集成设计降低的电阻。这项工作使皮革废物的可持续回收和先进的超级电容器电极的开发成为可能。
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引用次数: 0
Water-in-Salt Electrolyte Supercapacitors with Electrophoretically Deposited Graphene–Biomass Carbon Electrodes 含石墨烯-生物质碳电极的盐水电解质超级电容器
IF 3.6 4区 工程技术 Q3 ENERGY & FUELS Pub Date : 2025-12-08 DOI: 10.1002/ente.202501601
Barun Kumar Chakrabarti, Koray Bahadır Dönmez, Züleyha Kudaş, Zehra Çobandede, Reza Afshar Ghotli, Kamal Asadipakdel, Shamik Chaudhuri, Farouq S. Mjalli, Lewis W. Le Fevre, Andrew J. Forsyth, Robert A. W. Dryfe, Mustafa Kemal Bayazıt, Chee Tong John Low

This study explores sustainable alternatives for supercapacitor fabrication by integrating environmentally friendly carbon materials and efficient electrode processing techniques. Traditional supercapacitors rely heavily on expensive, nonrenewable, chemically synthesized carbon nanomaterials and are typically fabricated via time-intensive N-methyl-2-pyrrolidone (NMP)-based slurry casting. To address these limitations, two complementary approaches are presented. First, high-performance graphene-like carbon is synthesized from commercial AC (YEC-8B), using electrochemical exfoliation (EEG). Second, electrophoretic deposition (EPD) is demonstrated as a scalable method for depositing biomass-based (derived from waste hazelnut shells) activated carbon (BAC) or composites of BAC and EEG onto nickel foam current collectors, achieving a specific capacitance of 150 F g−1 and a power density of 21 kW kg−1. These electrodes are tested with both pure and hybrid water-in-salt electrolytes in A7 pouch cell supercapacitors. The pouch cell configuration that is equipped with commercially sourced composite AC and EEG electrodes shows superior capacitance retention, with 10% improvements at 10–40 A g−1 during cycling, compared to the counterparts prepared from waste biomass.

本研究通过整合环保碳材料和高效电极加工技术,探索超级电容器制造的可持续替代方案。传统的超级电容器严重依赖于昂贵的、不可再生的、化学合成的碳纳米材料,并且通常是通过耗时的n -甲基-2-吡罗烷酮(NMP)浆料铸造来制造的。为了解决这些限制,提出了两种互补的方法。首先,利用电化学剥离(EEG)技术从商用AC (YEC-8B)合成高性能类石墨烯碳。其次,电泳沉积(EPD)被证明是一种可扩展的方法,可将生物质活性炭(源自废榛子壳)或BAC和EEG的复合材料沉积到镍泡沫集流器上,实现150 F g−1的比电容和21 kW kg−1的功率密度。这些电极在A7袋状电池超级电容器中使用纯盐水和混合盐水电解质进行测试。配备商用复合交流和脑电图电极的袋状电池结构显示出优越的电容保持能力,与用废弃生物质制备的电池相比,在循环过程中,在10-40 A g−1下,电容保持能力提高了10%。
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引用次数: 0
Effect of Cu/Fe Mass Ratio on Chemical Looping Combustion Performance of Bayan Obo Iron Concentrate-Based Cu-Fe Composite Oxygen Carriers Cu/Fe质量比对白云鄂博铁精矿基Cu-Fe复合氧载体化学环燃烧性能的影响
IF 3.6 4区 工程技术 Q3 ENERGY & FUELS Pub Date : 2025-12-08 DOI: 10.1002/ente.202501667
Zifeng Sui, Wenjie Hu, Aimin Han, Zifeng Zhang, Zhanpeng Huo, Yuliang Sun, Weipeng Chen

In order to explore efficient oxygen carriers (OCs) for chemical looping combustion (CLC), this article investigates Bayan Obo iron concentrate-based Cu-Fe composite OCs with varying Cu/Fe mass ratios (1:1, 1:1.5, 1:2) for CLC performance using thermogravimetric analysis (temperature-programmed reduction (TPR), isothermal reduction, redox cycling) and characterization (Brunauer–Emmett–Teller (BET), X-ray diffraction (XRD), scanning electron microscopy (SEM)). The TPR tests reveal a three-stage reduction pathway of CuFe2O4 with CO: CuFe2O4 → Cu + Fe3O4 → FeO → Fe. The 1:1 Cu/Fe ratio OCs exhibit good reducibility, with a 4.32% higher mass loss than raw iron concentrate, lower mass-loss commencing temperature than other ratios (280°C), higher oxygen release than other ratios above 806°C under N2, which intensifies with temperature, and high kinetic activity (always the first to reach equilibrium in isothermal reduction test). In 11 thermogravimetric redox cycles, the 1:1 Cu/Fe ratio sample maintains high reduction conversion, showing a maximum mass loss difference of 5.09% compared to the iron concentrate. Its stable mass loss over the initial seven cycles demonstrates its good cycling stability.

为了探索用于化学环燃烧(CLC)的高效氧载体(OCs),本文采用热重分析(程序升温还原(TPR)、等温还原、氧化还原循环)和表征(布鲁诺尔-埃米特-泰勒(BET)、x射线衍射(XRD)、扫描电镜(SEM))研究了不同Cu/Fe质量比(1:1、1:1.5、1:2)的白云鄂博铁精矿基Cu-Fe复合氧载体(OCs)的化学环燃烧性能。TPR实验显示CuFe2O4与CO的还原过程为CuFe2O4→Cu + Fe3O4→FeO→Fe三个阶段。在N2条件下,Cu/Fe比为1:1的oc具有良好的还原性,其失重比生铁精矿高4.32%,失重起始温度低于其他配比(280℃),在806℃以上比其他配比的oc具有更高的氧释放量,且随温度升高而增强,且动力学活性高(等温还原试验中总是首先达到平衡)。在11个热重氧化还原循环中,Cu/Fe比为1:1的样品保持了较高的还原转化率,与铁精矿相比,最大质量损失差达5.09%。在最初的7个循环中,其稳定的质量损失证明了其良好的循环稳定性。
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引用次数: 0
Electrochemical Properties for Hydrogen Production of Nitrogen-Doped Sponge-Like Carbon Nanotubes as High-Surface Area Catalyst 氮掺杂海棉状碳纳米管作为高比表面积催化剂产氢的电化学性能
IF 3.6 4区 工程技术 Q3 ENERGY & FUELS Pub Date : 2025-12-08 DOI: 10.1002/ente.70308
Brenda Irais Orea-Calderón, Eduardo Gracia-Espino, Alice Kuzhikandathil, Julio C. Chacón-Torres, Claudia G. Castillo, Florentino Lopéz-Urías, Emilio Muñoz-Sandoval

The cover image is based on the article Electrochemical Properties for Hydrogen Production of Nitrogen-Doped Sponge-Like Carbon Nanotubes as High-Surface Area Catalyst by IPICYT López-Urías et al., https://doi.org/10.1002/ente.202500964.

封面图片基于IPICYT López-Urías et al., https://doi.org/10.1002/ente.202500964的文章《氮掺杂海棉状碳纳米管作为高表面积催化剂的产氢电化学性能》。
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引用次数: 0
Performance Optimization of Molten Salt Thermocline Storage System with Coupling Thermal Resistance 耦合热阻的熔盐温跃层存储系统性能优化
IF 3.6 4区 工程技术 Q3 ENERGY & FUELS Pub Date : 2025-12-08 DOI: 10.1002/ente.202500794
Yuanyuan Zhang, Yang Ye, Yecheng Yao, Jing Ding, Weilong Wang, Jianfeng Lu

Molten salt thermocline storage systems provide significant cost advantages for concentrated solar power, although their thermal performance is constrained by internal thermal resistance within solid fillers. This study establishes a coupled model integrating solid heat conduction and molten salt convection to analyze thermal resistance between molten salt and solid interfaces. System optimization evaluates key parameters including solid thermal conductivity, filler diameter, molten salt thermal conductivity, and inlet velocity. Results indicate that solid thermal resistance impedes solid-salt heat transfer, with optimal solid thermal conductivity maximizing discharging efficiency. As filler diameter increases from 0.025 to 0.045 m, the optimal solid thermal conductivity rises by 3 W (m K)−1, while the discharging efficiency decreases ≈1.8%. At the optimal solid thermal conductivity, moderate reduction of molten salt thermal conductivity increases discharging efficiency by 3.46%. Reduced inlet velocity further diminishes efficiency, requiring elevated molten salt thermal conductivity to enhance thermal performance at lower flow rates. These findings demonstrate that synergistic optimization of solid thermal conductivity and molten salt thermal conductivity under variable operating conditions can significantly enhance thermocline storage efficiency.

熔盐温跃层存储系统为聚光太阳能发电提供了显著的成本优势,尽管它们的热性能受到固体填料内部热阻的限制。本文建立了固体热传导与熔盐对流相结合的耦合模型,分析了熔盐与固体界面的热阻。系统优化评估了包括固体导热系数、填料直径、熔盐导热系数和入口速度在内的关键参数。结果表明,固体热阻阻碍了固体-盐传热,最佳的固体热导率使放电效率最大化。当填料直径从0.025 m增加到0.045 m时,最佳固体导热系数提高了3 W (m K)−1,而放电效率降低了约1.8%。在最佳固体导热系数下,适度降低熔盐导热系数可使放电效率提高3.46%。入口速度的降低进一步降低了效率,需要提高熔盐导热系数来提高低流速下的热性能。这些结果表明,在不同的工作条件下,协同优化固体导热系数和熔盐导热系数可以显著提高温跃层储存效率。
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引用次数: 0
Impact of Dopant-Free Hole Transport Materials on the Performance of Layered Cs3Sb2I9 Perovskite Solar Cells 无掺杂空穴传输材料对层状Cs3Sb2I9钙钛矿太阳能电池性能的影响
IF 3.6 4区 工程技术 Q3 ENERGY & FUELS Pub Date : 2025-12-08 DOI: 10.1002/ente.202501795
Brian Owuor, Gerrit Boschloo, Fuxiang Ji, Priyabrata Sadhukhan, Hanmandlu Chintam, Francis Nyongesa, Bernard Aduda, Sebastian Waita

Perovskite solar cells (PSCs) have rapidly advanced in photovoltaic research, achieving power conversion efficiencies up to 27%. However, the toxicity of lead (Pb) and the inherent instability of these materials hinder their commercial adoption. To address these issues, Pb-free perovskites such as layered (2-dimensional) cesium antimony iodide (Cs3Sb2I9) have been investigated for their environmental compatibility and promising optoelectronic properties. However, their efficiencies remain lower than those of Pb-based analogs, and stability is still a challenge. A significant contributor to device instability is the use of doped hole-transport materials, where hygroscopic dopant salts promote moisture ingress and accelerate degradation. Herein, we examine the influence of dopant-free hole transport materials, P3HT, PTB7, and CuSCN, on the performance and stability of layered Cs3Sb2I9 PSCs. Planar devices incorporating PTB7 and CuSCN achieved power conversion efficiencies (PCEs) of 2.05% and 2.26%, respectively, while P3HT yielded the highest PCE of 2.44%, ranking among the best efficiencies reported for this type of solar cell. These findings highlight the potential of dopant-free HTMs to enhance both efficiency and stability in lead-free PSCs.

钙钛矿太阳能电池(PSCs)在光伏研究中迅速发展,实现了高达27%的功率转换效率。然而,铅(Pb)的毒性和这些材料固有的不稳定性阻碍了它们的商业应用。为了解决这些问题,无铅钙钛矿如层状(二维)碘化铯锑(Cs3Sb2I9)因其环境兼容性和有前途的光电性能而被研究。然而,它们的效率仍然低于基于铅的类似物,并且稳定性仍然是一个挑战。器件不稳定性的一个重要因素是掺杂空穴输运材料的使用,其中吸湿性掺杂盐促进水分进入并加速降解。在此,我们研究了无掺杂的空穴传输材料P3HT、PTB7和CuSCN对层状Cs3Sb2I9 PSCs性能和稳定性的影响。结合PTB7和CuSCN的平面器件的功率转换效率(PCE)分别为2.05%和2.26%,而P3HT的PCE最高,为2.44%,是同类太阳能电池中效率最高的器件之一。这些发现强调了无掺杂HTMs在提高无铅psc的效率和稳定性方面的潜力。
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引用次数: 0
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Energy technology
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