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Effect of internal recycle ratio on the denitrification process and nirS-containing bacteria of an anaerobic/anoxic/oxic (A²/O) wastewater treatment process 内循环比对厌氧/缺氧/氧(A²/O)废水处理过程中反硝化过程及含nirs细菌的影响
IF 0.6 4区 环境科学与生态学 Q4 ENGINEERING, ENVIRONMENTAL Pub Date : 2019-01-01 DOI: 10.37190/epe190306
Xungang Yan, Jia-xi Zheng, Yunping Han, Jianwei Liu, Jianhui Sun
Internal recycle (IR) ratio is an important operation parameter for the anaerobic/anoxic/oxic (A2O) wastewater treatment process. Three laboratory-scale A2O wastewater treatment processes with IR ratios of 100%, 200%, and 300% were set up to study its influence on the denitrification process and nirS gene-containing bacteria. Results showed the removal rate of chemical oxygen demand (COD), ammonia nitrogen (NH4-N), total nitrogen (TN) and total phosphorus (TP) increased at different levels as the IR rate augmented from 100% to 300%. NirS gene numbers were increased from 1.8×108 to 3.2×108 copies/g MLSS, which was positively correlated with the denitrification rate in anoxic areas. Moreover, similarities were observed in the community structures of denitrifying bacteria that contained the nirS gene under different operation modes. These results indicated that increasing the IR rate in the A2O treatment process could benefit nirS gene-containing bacteria and improve denitrification ability observably while maintaining the stability of the community structure of the system.
内循环(IR)比是厌氧/缺氧/好氧(A2O)废水处理工艺的重要运行参数。建立了3个实验室规模的A2O废水处理工艺,IR比分别为100%、200%和300%,研究其对反硝化过程和含nirS基因细菌的影响。结果表明:随着IR率从100%增加到300%,化学需氧量(COD)、氨氮(NH4-N)、总氮(TN)和总磷(TP)的去除率均有不同程度的提高。NirS基因数从1.8×108拷贝/g MLSS增加到3.2×108拷贝/g MLSS,与缺氧区反硝化速率呈正相关。此外,在不同操作模式下,含nirS基因的反硝化细菌的群落结构也存在相似性。上述结果表明,在A2O处理过程中提高IR率有利于含nirS基因的细菌,在保持系统群落结构稳定的同时,可以明显提高其反硝化能力。
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引用次数: 0
Effectiveness of indicator bacteria removal in vertical flow filters filled with natural materials 天然材料填充垂直流过滤器去除指示菌的效果
IF 0.6 4区 环境科学与生态学 Q4 ENGINEERING, ENVIRONMENTAL Pub Date : 2019-01-01 DOI: 10.37190/epe190206
E. Wa̧sik, K. Chmielowski
The effectiveness of removing indicator bacteria from domestic sewage using a vertical flow filter filled with natural materials has been analysed. The count of Escherichia coli and coliform bacteria was measured in raw and treated sewage and effectiveness of their removal under variable conditions of hydraulic load and depending on the filter filling (type, size and filling proportions) was assessed. A single-layer sand or zeolite filter was the most effective in reducing bacterial contamination. The sand-filled filter allowed the removal of 99.993–99.997% of Escherichia coli and the one filled with fine zeolite of 99.995%. The principal component analysis was used to comprehensively evaluate the filter performance. Three principal components were identified and they were responsible for 81% of raw data variability. The effectiveness of indicator bacteria removal depended mainly on the filling grain size and did not on filling proportions or its type.
分析了天然填料垂直流过滤器去除生活污水中指示菌的效果。测量了未经处理和处理过的污水中大肠杆菌和大肠菌群的数量,并评估了在不同水力负荷条件下,根据过滤器填充(类型、大小和填充比例)去除它们的有效性。单层砂或沸石过滤器在减少细菌污染方面最有效。砂填充过滤器对大肠杆菌的去除率为99.993 ~ 99.997%,细沸石填充过滤器对大肠杆菌的去除率为99.995%。采用主成分分析法对滤波器性能进行综合评价。确定了三个主要成分,它们负责81%的原始数据变异性。指示菌的去除效果主要取决于充填颗粒的大小,而与充填比例和充填类型无关。
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引用次数: 5
Photocatalytic degradation of reactive dyes and real textile composite wastewater using TiO2/MWCNT nanocomposite under UVA and UVA-LED irradiation. A comparative study UVA和UVA- led照射下TiO2/MWCNT纳米复合材料光催化降解活性染料和真实纺织复合废水比较研究
IF 0.6 4区 环境科学与生态学 Q4 ENGINEERING, ENVIRONMENTAL Pub Date : 2019-01-01 DOI: 10.37190/EPE190207
D. S. Kumar, Kanmani Sellappa
Nano TiO2 and TiO2/MWCNT nanocomposite synthesized by the sol-gel method were characterized by XRD, BET, SEM, EDAX and FTIR techniques. These nanoparticles were used for photocatalytic decolorisation and degradation of three different reactive dyes such as Reactive Orange 16 (RO 16), Reactive Yellow 145 (RY 145) and Reactive Red 195 (RR 195) and real textile composite wastewater under the UVA and UVA-LED irradiation at room temperature. The maximum color removal of 96% and COD removal of 72% were achieved after 5 h in the presence of TiO2/MWCNT and H2O2 under UVA-LED irradiation. The kinetic studies obey pseudo-first order kinetics which is discussed in terms of the Langmuir–Hinshelwood kinetic model. The maximum degradation of 50% was achieved after 5 h in the presence of H2O2 using TiO2/MWCNT/UVA-LED for real textile composite wastewater. This study revealed that TiO2/MWCNT has improved the photocatalytic activity when compared to that of bare TiO2 under similar conditions. UVA-LED could be an alternative light source for the replacement of the conventional UV light for the photocatalytic treatment of reactive dyes.
采用XRD、BET、SEM、EDAX和FTIR等技术对溶胶-凝胶法制备的纳米TiO2和TiO2/MWCNT纳米复合材料进行了表征。这些纳米颗粒在UVA和UVA- led的室温照射下,用于光催化脱色和降解三种不同的活性染料,如活性橙16 (RO 16)、活性黄145 (RY 145)和活性红195 (RR 195)和真实纺织复合废水。在UVA-LED照射下,TiO2/MWCNT和H2O2存在5 h后,去色率达96%,COD去除率达72%。动力学研究服从拟一阶动力学,这是根据Langmuir-Hinshelwood动力学模型讨论的。使用TiO2/MWCNT/UVA-LED处理真实纺织复合废水,H2O2存在5 h后降解率达到50%。研究表明,在相同条件下,TiO2/MWCNT比裸TiO2具有更高的光催化活性。UVA-LED可作为替代传统紫外光的光源用于活性染料的光催化处理。
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引用次数: 3
Application of biological methods to assess the toxicity of soils contaminated with heavy metals and the effectiveness of stabilisation processes 应用生物方法评估重金属污染土壤的毒性和稳定过程的有效性
IF 0.6 4区 环境科学与生态学 Q4 ENGINEERING, ENVIRONMENTAL Pub Date : 2019-01-01 DOI: 10.37190/epe190403
Natalia Tatuśko-Krygier, M. Jakubus
Short-term biotests were used to determine the effectiveness of the use of compost and fly ash in the stabilization of heavy metals in contaminated soil. For this purpose, in two independent experiments, either compost (3:1) or fly ash (1:1) were added to soil contaminated with heavy metals. To assess seed germination and root elongation of Sorghum saccharatum L., Lepidium sativum L., Sinapis alba L. after three days a Phy-totoxkit test was used. Seedling emergence and biomass yield after 21 days were evaluated. Obtained data indicate better practical applicability of the seedling emergence test thanks to the longer duration resulting in more reliable conclusions provided in that test. A short, 3-day test did not confirm any effective stabilising role of theapplied additives. Sorghum saccharatum L. turned out to be most sensitive to the altered soil conditions, while Lepidium sativum L. was most tolerant.
短期生物试验用于确定堆肥和粉煤灰在稳定污染土壤中重金属方面的有效性。为此,在两个独立的试验中,在重金属污染的土壤中分别添加堆肥(3:1)和粉煤灰(1:1)。以糖高粱、枸杞、白刺为研究对象,采用菌毒素测定法测定3 d后的种子萌发率和根伸长。测定21 d后幼苗出苗率和生物量产量。获得的数据表明,出苗试验的持续时间更长,得出的结论更可靠,具有较好的实用性。一个简短的,为期3天的测试没有证实任何有效的稳定作用的添加剂。高粱对土壤条件的变化最敏感,而枸杞的耐受性最强。
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引用次数: 1
Characteristic of mercury on the surface of ash originating from electrostatic precipitators of lignite and bituminous coal-fired power plants 褐煤和烟煤电厂静电除尘器烟尘表面汞的特征
IF 0.6 4区 环境科学与生态学 Q4 ENGINEERING, ENVIRONMENTAL Pub Date : 2019-01-01 DOI: 10.37190/epe190404
V. Veselý, Z. Szeliga, Z. Vávrová, B. Čech, P. Regucki, R. Krzyżyńska
Mercury concentrations in ash taken from electrostatic precipitations (ESPs) installed in bituminous coal and lignite power plants have been analyzed by the X-ray fluorescence (XRF) method and leaching test supported by detailed coal and ash compositions’ analyses, surface scans and particles size distribution studies. The results showed that mercury was present on the surface of ash particles. Its concentration decreased upon increasing size of ash particles. Leaching tests showed that only small part of mercury was removed with water which suggests the fact that it occurred mostly in the form of insoluble compounds such as Hg, HgO, HgS and Hg2Cl2. There existed ash particles of the diameters from 50 to 60 μm, characterizing by the maximum capability to adsorb mercury and its compounds. The authors suggest that metals like copper and lead formed ash active centers that were preferably occupied by molecules containing atoms of mercury. It was highly possible to expect that content of these elements in ash would have a significant effect on sorption of mercury from combustion gases.
采用x射线荧光(XRF)方法和浸出试验对安装在烟煤和褐煤电厂的静电沉淀法(esp)中煤灰的汞浓度进行了分析,并对详细的煤和煤灰成分分析、表面扫描和颗粒大小分布进行了研究。结果表明,火山灰颗粒表面存在汞。其浓度随灰粒尺寸的增大而减小。浸出试验表明,只有一小部分汞被水除去,这表明汞主要以不溶性化合物的形式存在,如Hg、HgO、HgS和Hg2Cl2。灰分粒径在50 ~ 60 μm之间,对汞及其化合物的吸附能力最大。作者认为,像铜和铅这样的金属形成了火山灰活性中心,这些活性中心最好被含有汞原子的分子占据。很有可能期望灰烬中这些元素的含量会对从燃烧气体中吸收汞产生重大影响。
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引用次数: 0
The effect of nitrate on fluoride removal by batch electrodialysis 硝酸盐对间歇电渗析除氟的影响
IF 0.6 4区 环境科学与生态学 Q4 ENGINEERING, ENVIRONMENTAL Pub Date : 2019-01-01 DOI: 10.37190/epe190407
A. Ahmed, Martyna Grzegorzek, K. Majewska-Nowak
Fluoride and nitrate are common pollutants in drinking water and their presence deteriorates the quality of drinking water. According to WHO guidelines, the fluoride content in drinking water cannot be higher than 1.5 mg F – /dm 3 . The purpose of this paper was to evaluate the efficiency of fluoride removal from model aqueous solutions under the presence of nitrate. The experiments were conducted with the use of laboratory installation PCCell BED-1 System at a constant current density (0.78, 1.72, and 2.34 mA/cm 2 ) with the use of monovalent selective ion-exchange membranes. The influence of initial nitrate concentration (15, 30, 45 mg NO 3– /dm 3 ) and initial fluoride concentration (5, 10, 15 mg F – /dm 3 ) on the process performance was studied. The degree of desalination varied from 85 to 91.7% depending on the solution composition and the applied current density, whereas the fluoride removal was in the range of 70–90%. The presence of coexisting NO 3– ions in fluoride solutions improved process efficiency in view of fluoride removal by batch electrodialysis.
氟化物和硝酸盐是饮用水中常见的污染物,它们的存在会使饮用水质量恶化。根据世卫组织的指导方针,饮用水中的氟化物含量不得高于1.5 mg F - /dm 3。本文的目的是评价硝酸盐存在下模型水溶液的除氟效率。实验使用实验室安装的PCCell BED-1系统,在恒定电流密度(0.78、1.72和2.34 mA/ cm2)下,使用单价选择性离子交换膜进行。研究了硝态氮初始浓度(15、30、45 mg no3 - /dm 3)和氟初始浓度(5、10、15 mg F - /dm 3)对工艺性能的影响。根据溶液组成和施加电流密度的不同,脱盐程度从85%到91.7%不等,而氟化物去除率在70-90%之间。间歇式电渗析除氟工艺中存在共存的no3离子,提高了工艺效率。
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引用次数: 2
Activated carbon adsorption behaviour of toluene at various temperatures and relative humidity 不同温度和相对湿度下活性炭对甲苯的吸附行为
IF 0.6 4区 环境科学与生态学 Q4 ENGINEERING, ENVIRONMENTAL Pub Date : 2019-01-01 DOI: 10.37190/epe190109
Adnan Görgülü, Hüseyin Yağlı, Yıldız Koç, A. Koç, E. Baltacioǧlu
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引用次数: 10
Analysis of legal and technical solutions in terms of odours in Poland 分析波兰有关气味的法律和技术解决方案
IF 0.6 4区 环境科学与生态学 Q4 ENGINEERING, ENVIRONMENTAL Pub Date : 2019-01-01 DOI: 10.37190/EPE190110
I. Sówka, U. Miller, L. Karski
Despite solutions available in the Polish law system which could be used in conflictual situations connected with odour emission, the amount of odour complaints in Poland has been increasing. Currently applied legal solutions in Poland used in private-law and public-law ways in odour issues have been characterised. The results of analyses of available and developed technical solutions aiming to eliminate odour nuisance have been presented as well. Additionally, the results of research conducted in laboratory conditions and in chosen municipal waste management and industry facilities have been displayed. A conducted analysis pointed out the limited character of Polish legal solutions concerning odours. Therefore, the need to create an administrative and legal regulation dedicated directly to the preventing odour nuisance in Poland was emphasized. Such a regulation should include issues concerning, inter alia, emission, immision and technological standards.
尽管波兰法律制度中有解决办法可用于与气味散发有关的冲突情况,但波兰的气味投诉数量一直在增加。目前适用的法律解决办法在波兰使用的私法和公法的方式在气味问题的特点。分析现有的和开发的技术解决方案的结果,旨在消除气味的滋扰也已提出。此外,还展示了在实验室条件下以及在选定的城市废物管理和工业设施中进行的研究结果。一项已进行的分析指出了波兰有关气味的法律解决办法的局限性。因此,强调有必要制定一项行政和法律条例,直接专门用于在波兰防止气味滋扰。这种条例除其他外应包括有关排放、排放和技术标准的问题。
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引用次数: 2
Testing properties of sewage sludge for energy use 用于能源利用的污水污泥的性能试验
IF 0.6 4区 环境科学与生态学 Q4 ENGINEERING, ENVIRONMENTAL Pub Date : 2019-01-01 DOI: 10.37190/epe190405
K. Król, K. Iskra, W. Ferens, Jan M. Miodoński
The properties of sewage sludge in the context of their further energy use have been examined. For this purpose, 34 samples of sewage sludge from municipal sewage treatment plants from the area of Lower Silesia with a capacity higher than the 2000 population equivalent (PE) with separate sludge management were tested. As part of the study, tests were made to determine the technological useful-ness of fuels and their elemental composition, i.e., technical analyses and elemental analyses. The obtained results show a large diversity of basic physicochemical properties of the tested sewage sludge. The share of volatile components important for energetic use ranged from 38.4 to 59.8 wt. %. The content of carbon (C) in the mass of tested sewage sludge ranged from 22.4 to 39.2 wt. %, which means that they have a lower content of elemental carbon compared to solid fuels. The higher heating value ( HHV ) of sewage sludge ranged from 9.3 to 17.4 MJ/kg dry mass.
污水污泥在其进一步的能源利用的背景下的性质进行了检查。为此,对来自下西里西亚地区的34个城市污水处理厂的污水污泥样本进行了测试,这些污水处理厂的处理能力高于2000年人口当量(PE),并进行了单独的污泥管理。作为研究的一部分,进行了测试,以确定燃料及其元素组成的技术有用性,即技术分析和元素分析。所得结果表明,所测污泥的基本理化性质存在很大差异。挥发性成分在能量使用中的重要份额从38.4%到59.8%不等。所测试的污水污泥质量中的碳(C)含量在22.4%至39.2% wt. %之间,这意味着与固体燃料相比,它们具有较低的元素碳含量。污泥的较高热值(HHV)为9.3 ~ 17.4 MJ/kg干质量。
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引用次数: 3
Growth and heavy metals uptake by Vicia faba in mining soil and tolerance of its symbiotic rhizobacteria 蚕豆在矿区土壤中的生长、重金属吸收及其共生根瘤菌的耐受性
IF 0.6 4区 环境科学与生态学 Q4 ENGINEERING, ENVIRONMENTAL Pub Date : 2019-01-01 DOI: 10.37190/epe190107
A. E. Alaoui, N. Bechtaoui, Loubna Benidire, A. E. Gharmali, W. Achouak, K. Daoui, B. Imziln, K. Oufdou
Faba bean plants in the 1/8 mixture with soil had the ability to accumulate Pb, Zn and Cu. 95% of the absorbed Pb were in the roots, and Cu and Zn were found in the shoots by 35% and 45%, respec-tively. There was a decrease in the root hairs and the number of cell layers of the root cortex alongside epidermis lesions. From the 50 tested rhizobacterial strains, 20 were able to grow at 150 mg/dm 3 of Pb, 6 were resistant to 150 mg/dm 3 of Zn and 8 resisted to 20 mg/dm 3 of Cu. Best four strains had adsorp-tion potentials and the biosorption was higher for Cu. These strains were capable of producing auxin and exopolysaccharides. The most tolerant strains (FD1 and FD2) isolated near the mining site produced siderophores and high amounts of exopolysaccharides. The use of such strains and V. faba could be of important biotechnological value in decreasing heavy metal pollution of mining soils. _________________________
1/8配土条件下蚕豆植株对Pb、Zn和Cu的吸收能力较好,95%的Pb吸收在根系,35%和45%的Cu和Zn吸收在茎部。根毛和根皮层细胞层数随表皮病变而减少。50株根瘤菌中,20株能在150 mg/dm的Pb浓度下生长,6株能抵抗150 mg/dm的Zn, 8株能抵抗20 mg/dm的Cu。结果表明,4株菌株对铜的生物吸附能力较强。这些菌株能够产生生长素和外多糖。在矿区附近分离的耐受性最强的菌株(FD1和FD2)产生铁载体和大量的胞外多糖。利用这些菌株和蚕豆菌对降低矿区土壤重金属污染具有重要的生物技术价值。_________________________
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引用次数: 8
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Environment Protection Engineering
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