Environmental Technology最新文献

The concept and analysis of integrating membrane distillations (MD) with reversal once-through Multistage Flash (RV-MSF) desalination is presented. The analysis is based on numerical simulation. The MD vessels are integrated into the terminal ends of the RV-MSF system to leverage the thermal energy associated with these terminal streams. Hybridisation at the last MSF stage, i.e. by replacing the brine cooler, contributes marginally to the overall production rate which amounts to 2%. However, it is found that hybridisation at stage one, i.e. utilising the energy of the MSF reject brine can increase the overall production rate by 65%. For seawater feed temperature of 80 ^oC and 24 MSF stages, 5 MD vessels in series can be integrated with the RV-MSF process. This ultimate hybridisation helped improve the recovery ratio from 7 to 23%, decreasing the specific cooling water requirement from 23 to 12 kg/kg and reducing the specific energy consumption from 129 to 41 kWh/m³ with respect to the stand-alone RV-MSF system. However, this achievement incurs an additional specific area for heat transfer which increased from 29 to 65 m²/(kg/s). This is because a large number of MD modules are incorporated into the hybridisation.

In this work, a new type of composite nanoparticles, 'pearl chain', was developed by linking titanium dioxide and silicon dioxide by polyacrylic acid polymer chains, and the prepared TiO₂-PAA-SiO₂ composite nanoparticles were analysed by SEM, Fourier transform infrared spectroscopy, x-ray photoelectron spectroscopy and thermogravimetric analysis, zeta potential, x-ray diffraction, etc. The success of this work was verified by the successful linking of TiO₂-PAA-SiO₂ composite nanoparticles.TiO₂-PAA-SiO₂ composite nanoparticles were analysed to verify the successful attachment of pearl chains. The obtained TiO₂-PAA-SiO₂ were subsequently blended in different ratios to prepare polyvinylidene fluoride (PVDF) ultrafiltration membranes. The membrane performance was tested by porosity and water contact angle measurements, scanning electron microscopy, as well as experiments using bovine serum proteins and MTBE interception. The results showed that when a certain amount of TiO₂-PAA-SiO₂ was added, the surface wettability, porosity and permeability of the prepared modified composite membranes were significantly improved, and the BSA adsorption rate was increased from 71.59% to 80.86%, and the retention rate of MTBE was increased by 77%, in addition to showing a better anti-pollution effect (FRR: 91.07%). It was finally concluded that the prepared membranes embedded with 1.0 wt.% TiO₂-PAA-SiO₂ nanofillers showed good overall filtration performance, better contamination resistance and remarkable durability. The present work successfully demonstrated the feasibility of using polyacrylic acid chemical chains to connect nanoparticles with different functions to prevent particle loss and substantially enhance membrane performance, which is valuable for bridging connection of composite nanoparticles and exploring the development of high-performance ultrafiltration membranes.

In order to improve the functionality of cellulosic materials research and development of high performance soluble materials. Therefore, the Fe₃O₄/CMS composite membrane was prepared by using carboxymethyl salix powder (CMS) and Fe₃O₄ as raw materials, 1-propenyl-3-methylimidazolium chloride and dimethyl sulfoxide as dissolution system. The effects of swelling time, swelling temperature, pH and ionic strength on the swelling performance of Fe₃O₄/CMS composite membranes and the swelling kinetics of the composite membranes were studied. The structure of the composite membrane was characterized by SEM, FT-IR, XRD and TG. The results showed that the swelling degree reached 5.54 g·g^-1, when the swelling time was 45 min, the swelling temperature was 65°C, the pH was 5 and the ionic strength was 0.08 mol·L^-1. The initial phase of dissolution of the composite membrane fits well with the Fickian diffusion model, and the whole dissolution process belongs to the Schott model, indicating that the main role of the dissolution process is the diffusion of water molecules, while the composite membrane can be preserved for a long time at high temperature, which provides sustainability for the composite membrane. The characterization results showed that the surface of Fe₃O₄/CMS composite film was rough with small grooves. The O-H effect was enhanced and the Fe-O absorption peak appeared at 600 cm^-1, indicating that Fe₃O₄ had been successfully loaded onto the cellulose membrane. The Fe₃O₄/CMS composite membrane belonged to cellulose type II structure, meanwhile, the composite membrane had good thermal stability.

This research involved conducting continuous adsorption experiments to assess fluoride elimination from drinking water achieved by utilizing biocomposites created from the peels of oranges and apples, which were impregnated with zirconium (Zr), to form BOP-Zr and BAP-Zr, respectively. The findings from the experimental data indicate that BOP-Zr and BAP-Zr are effective biosorbents with a solid ability to remove fluoride selectively. Additionally, these biosorbents were found to be stable, as they do not release Zr into the treated water. Notably, these environmentally friendly biosorbents are derived from renewable sources and enhance the value of waste materials. The study employed various empirical models, including Bohart-Adamas, Thomas, Yoon-Nelson, BDST, Clark, Yan, and Woolborska, to elucidate the mechanisms and crucial parameters involved in fluoride adsorption within packed bed columns. The Yan model demonstrated the highest correlation among these models, indicating a chemical adsorption process with kinetics following a pseudo-second-order pattern. BOP-Zr and BAP-Zr exhibited a maximum adsorption capacity of 59.3 and 47.5 mg/g, respectively, under a flow rate of 4 mL/min and an inlet fluoride concentration of 25 mg/L. The analysis of mass transfer coefficients revealed that the primary step governing the adsorption procedure was diffusion through pores. Consequently, the study conclusively establishes that BOP-Zr and BAP-Zr biocomposites, originating from lignocellulosic biomass remains, present a practical and competitive choice for eliminating fluoride from water. These materials surpass waste materials in performance and rival more expensive options in efficiency and performance.

To overcome the shortcomings of Fe(Ⅱ)/peroxydisulfate (PDS) system including the limited working pH range and large iron sludge production, a Fe-doped alginate (Fe-Alg) catalyst was prepared and combined with hydroxylamine (HA) to continuously activate PDS for the removal of organic pollutants in neutral condition. Due to the strong reductive capability of HA, it could significantly enhance the catalytic capability of Fe-Alg for PDS. The results of characterization suggested that Fe(Ⅲ)/Fe(Ⅱ) was evenly distributed in Alg through its complexation with carboxyl groups, and the reduction of Fe(Ⅲ) to Fe(Ⅱ) initiated by HA enabled Orange G (OG) to be continuously degraded in the Fe-Alg/HA/PDS system. The results of quenching experiments suggested that $S{O}_4^{\bullet -}$ and HO^• played a dominant role for OG removal in the Fe-Alg/HA/PDS process. The effect of influence factors (e.g. initial pH, HA concentration, Fe-Alg dose and PDS concentration) and water matrix components (i.e. $S{O}_4^{2-}$, $N{O}_3^{-}$, Cl^-, $\mathrm{HC}{O}_3^{-}$ and dissolved organic matters (DOM)) on the performance of Fe-Alg/HA/PDS system was systematically investigated. Other refractory organic contaminants, including diclofenac (DCF), sulfamethoxazole (SMX), oxytetracycline (OTC) and bisphenol AF (BPAF) were also efficiently eliminated in Fe-Alg/HA/PDS system, suggesting the feasibility of this system for the treatment of organic pollutants. This work provides a method to optimize Fe(Ⅱ)/PDS system and a novel process applied to degrade refractory pollutants.

Oxygen-doped g-C₃N₄ with pyridine ring (POCN) was synthesized by easily thermal polymerization of urea, pyridine solution, and ammonium acetate to improve photocatalytic hydrogen production. The experimental results indicate that pyridine was incorporated into the tri-s-triazine structure of g-C₃N₄. The O atoms were modified to g-C₃N₄ by replacing the N atoms (C-N=C) of the triazine ring. The photocatalytic activity for the hydrogen production rate of optimized POCN was 1018 µmol g^-1 h^-1, approximately 30 times higher than that of bulk g-C₃N₄ (CN) under visible light irradiation (λ > 420 nm). The high stability of POCN was confirmed through cycling tests for 30-h, XRD patterns, and SEM images. The pyridine incorporation can significantly enhance surface charge transfer efficiency. The oxygen modification can greatly promote visible light absorption (600 nm) and photogenerated electron-hole pairs separation. This work provides a suitable strategy to synthesize g-C₃N₄ based on metal-free photocatalysts for highly efficient photocatalytic hydrogen generation performance.

During coal combustion, the harmful element arsenic can be released into environment and cause potential significant harm to human beings. Therefore, it is very important to study the removal of arsenic from coal before combustion. In this work, simulated SO₂-containing flue gas was used to leach arsenic from coal in a 1 L UV photoreactor. The effects of FeCl₃, ultraviolet (UV), pH and the Cl^-/Fe³⁺ molar ratio on arsenic leaching and SO₂ removal were experimentally investigated and the enhancing mechanism was analysed. Experimental results demonstrated that FeCl₃ and UV could efficiently increase iron and arsenic leaching percentages and SO₂ removal efficiency. UV irradiation could induce the oxidation of most trivalent arsenic. The arsenic leaching percentage was significantly larger than that of iron. Low pH was favourable for iron and arsenic leaching. The optimal Cl^-/Fe³⁺ molar ratio was determined to be 3:1. The introduced ferric chloride could not only increase the concentrations of free radicals and ferric iron oxidants, the chloride ion might also impede the formation of passive coatings, thus increasing the arsenic leaching percentage, intensifying the oxidation of trivalent arsenic and enhancing the removal of SO₂.

In recycled hydroponics, successive crop cultivation by maintaining electrical conductivity (EC) suffers lower growth performance due to accumulating autotoxic root exudates. In this study, the efficiency of alternate current electro degradation (AC-ED) was evaluated for degrading allelochemicals and recovering retarded lettuce yield cultivated in EC-adjusted repeatedly used nutrient solutions. From benzoic acid (BA)-added nutrient solution, BA was completely degraded after 24 h by applying AC-ED at 551 and 940 Hz frequency with 50 and 80% electrical duty. In lettuce bioassay, fresh mass was negatively affected without the AC-ED-treated solution. Finally, lettuce seedlings were hydroponically grown in a plant factory using a half-strength Enshi nutrient solution. Culture solutions were unchanged in non-renewed solutions. Nutrient elements were supplied based on the EC (1.42 dS m^-1) of culture solutions. The fresh weight of lettuce was gradually decreased in subsequent cultures. Nutrient absorption rate was reduced in non-renewed solutions though enough of all nutrient elements were available in the solution. In the final culture, the highest shoot fresh weight (SFW) was recorded in the renewed (83.0 g plant^-1) solution which was similar to the AC-ED-treated solution (81.0 g plant^-1) and the lowest (58.0 g plant^-1) was in the non-renewed solution. By applying AC-ED, 40% lettuce yield was recovered in the EC-adjusted solution without renewing. Therefore, it is recommended that the continuous application of AC-ED with the capacity of 551 Hz and 50% duty would be applied for recovering the retarded lettuce yield cultivated with repeatedly used culture solutions in recycled hydroponics.

Response Surface Methodology (RSM) with Box-Behnken Design (BBD) is used to optimise the Phenanthrene (PHE) degradation process by Klebsiella pneumoniae (K bacteria) and Pseudomonas aeruginosa (P bacteria). Wherein substrate concentration, temperature, and pH at three levels are used as independent variables, and degradation rate of PHE as dependent variables (response). The statistical analysis, via ANOVA, shows coefficient of determination R² as 0.9848 with significant P value 0.0001 fitting in second-order quadratic regression model for PAHs removal by Klebsiella pneumonia, and R² as 0.9847 with significant P value 0.0001 by P bacteria. According to the model analysis, temperature (P < 0.0006) is the most influential factor for PHE degradation efficiency by K bacteria, while pH (P < 0.0001) is the most influential factor for PHE degradation by P bacteria. The predicted optimum parameters for K bacteria, namely, temperature, substrate concentration, and pH are found to be 34.00℃, 50.80 mg/L, and 7.50, respectively, and those for P bacteria are 33.30℃, 52.70 mg/L, and 7.20, respectively. At these optimum conditions, the observed PHE removal rates by two bacteria are found to be 83.36% ± 2.1% and 81.23% ± 1.6% in validation experiments, respectively. Thus RSM can optimise the biodegradation conditions of both bacteria for PHE.

Automotive catalysts are the largest consumption source of platinum group metals (PGMs). When it exceeds its useful life, spent automotive catalysts (SACs) are the most important secondary PGMs resource and are classified as hazardous solid waste. Recycling SAC is a promising solution to alleviate the shortage of PGMs resources for projects and reduce environmental pollution. The technology for recovering PGMs by iron-melting collection can obtain Fe-PGMs alloy and harmless glass slag. In this paper, the spontaneous aggregation and growth behaviour of Fe and PGMs in slag at melting temperature were studied, and the settling velocity of Fe-PGMs particles in the slag was calculated to be 6.68 × 10^-3 m/s. The effects of melting time, melting temperature and Fe dosage on PGMs recovery were determined, and the optimal conditions were 10 wt% Fe, 1500°C and 40 min. The toxicity test verifies that the slag obtained is a clean slag harmless to the environment. This work explains the mechanism of Fe collection of PGMs and provides a pathway for efficient and harmless recovery of PGMs from SAC.