We provide improved constraints on the timing, geometry and kinematics of the fault that may control the northern submerged morpho-structural relief termed Monte Giove, offshore from the town of Polignano a Mare. We have integrated onshore and offshore data, and interpreted seismic profiles from the ViDEPI project pertaining to the offshore Adriatic Sea of the Murge area, and made field observations north of Polignano a Mare. The fault has been surveyed onshore and mainly offshore along a distance of ~25 km. Generally striking E–W, it dips at high angle to the NNE in the west and to the N in the east. Active since at least the Cretaceous, this was reactivated after the Early Pleistocene with dextral oblique-slip kinematics. It borders the Monte Giove submerged relief/structural high, and continues eastwards in the Adriatic Sea into the Northern Deformation Zone/”Murge basse” graben, that in turn affected the onshore Murge area. Fault reactivation may have been related to a strain field in the outer part of the gentle buckle fold that involved the continental lithosphere of the Apulian Foreland (i.e., the areas of the Murge onshore and the Adriatic Sea offshore) since the Middle Pleistocene, as roll-back of the subducting lithosphere halted. Besides its tectonic reactivation, this fault has important implications as regards local seismic hazard, as well as the morphology influencing the present-day bioherm.
The composition of spherules and particles of native metals from the Pivdenna kimberlite pipe, Ukraine, was studied using the SEM/EDS method. Three varieties of spherules have been distinguished: titanium-manganese-iron-silicate (TMIS) spherules, Ca-rich silicate spherules, and magnetite-wustite-iron (MW-I) spherules. TMIS spherules are composed of homogeneous glass, some having a native iron core. Large TMIS spherules may contain a crystalline phase with needle-like armalcolite. Ca-rich silicate spherules can be subdivided into two subtypes: calcium-silicate (CS) spherules where SiO2 and CaO are the dominant constituents, and calcium-iron-silicate (CIS) spherules with significant FeO content. CS spherules may contain a core consisting of native phases (Fe, Fe-Si, and Mn-Si-Fe). Native metal particles are represented by native Cu and native Zn. The spherule varieties from the Pivdenna pipe are similar to those from other kimberlite pipes in the world. We infer that the formation of spherules occurred in gas-melt streams, separately from the kimberlites, and propose a model for the formation of the most common variety of spherules (TMIS and MW-I varieties) in the region of the core-mantle boundary (CMB). First, a melt of the Fe-Ti-Mn-Si-O system was formed in ultra-low-velocity zones (ULVZ) as a result of thermochemical reactions (reduction) between the molten core and solid oxide-silicate rocks. The melt then migrates to shallower levels, where a decrease in temperature initiates oxidation with the formation of SiO2-TiO2-FeO-MnO-Fe0 melt, i.e. parent melt of TMIS and MW-I spherules. We interpret the formation of native metals in kimberlites as a result of the decomposition of nitrides, which came from the Earth’s core via intratelluric flows
Palaeobiological data, supplemented by new 14C dates in conjunction with palaeobotanical and lithological information, have allowed reconstruction of Middle Weichselian (MIS 3) environmental fluctuations in the southern Eastern Baltic region. Palaeoenvironmental reconstructions implying non-glacial conditions during the Middle Weichselian (MIS 3) are supported by the spatial and temporal context of recently discovered remains of Mammuthus primigenius Blumenbach and Rangifer tarandus Linnaeus, 1758. Recording both cold and warm climatic reversals of MIS 3, representatives of the megafauna thrived in an environment characterized by a heterogeneity of vegetation and climate. 14C dating shows that the majority of the megafaunal remains analysed represent the 38–45 cal kyr BP time-interval, which correlates with the Nemunas 2c cold interval (cryomer), and the 31–34 cal kyr BP or Mickñnai 3 thermomer. From pollen data, the palaeovegetation pattern varied from tree-less tundra to birch-predominating forest with an admixture of temporal tree species providing additional information about the diet and habitat preferences of these herbivores in the context of the MIS 3 climatic events.
Disc- and cylindrical-shaped clasts of fine-grained calcareous and ferruginous rock, each with a central tunnel, occur in shallow marine brackish Miocene sandy deposits of the Egyházasgerge Formation in Hungary. Previously, these have been interpreted as enigmatic biogenic (?) structures. After field and laboratory examination and comparisons with sub-recent rhizoclasts in subsoils developed on Quaternary fine-grained deposits in SE Poland, they are re-interpreted as redeposited rhizocretions possibly washed out of the coeval continental deposits of the Salgótarján Lignite Formation. Most are fragmented and abraded. They are termed rhizoclasts and are presented as an example of zombie structures inherited from another environment where they played a different role. Such rhizoclasts can be considered as an indicator of the source of the clastic material transported from a vegetated landmass on which moderate or poorly drained soils develop and plant roots penetrate the fine-grained substrate. In such soils, iron was mobilized, then fixed by oxidation, as the water table and oxygen levels fluctuated.
Chlorite-mica-quartz schist in the Gierczyn-Przecznica area in SW Poland contains polymetallic ores which were the source of tin and cobalt in the past. This mineralogical study revealed the presence of silver-bearing minerals including members of the tetrahedrite (Ag <3 apfu) and freibergite series (3 < Ag < 8 apfu), galena (0.26–1.48 wt.% Ag), and a phase with the chemical composition of Te-rich canfieldite Ag8Sn(S,Te)6. In Przecznica Sn-sulphides are represented by stannite while cobaltite is the most abundant host for cobalt, followed by Co-bearing arsenopyrite. Glaucodot, ullmannite and members of the löllingite-rammelsbergite solid-solution series (Fe,Ni,Co)As2 also contain cobalt but are scarce in the samples. An exposure in the “Psi Grzbiet” area is characterized by the presence of Ag, Ni, Sb and Te minerals accompanied by very small amounts of As-bearing phases (represented by arsenopyrite) while the mineralogical composition in the Przecznica area is characterized by an abundance of As phases and a lack of Sb minerals. Sulphur isotopes of sulphides from Przecznica are heavier than in most deposits related to the Karkonosze Granite intrusion, while their Pb isotope signature in galena suggests an Early Paleozoic pre-Variscan affinity rather than a Variscan one.
Many coal seams of varied thickness and aerial extent occur in the Upper Silesia and Lublin basins within Mississippian and Pennsylvanian coal-bearing deposits. Well-documented data on coal quantity in the seams identified allows visualization of their variation within the stratigraphic succession and analysis of the time-dependent coal accumulation process. Some characteristic features of this variation were observed. Coal seams of the Mississippian age (Serpukhovian, Paralic Series), formed within a near-shore environment, most often constitute small resources. There were only two intervals of increased coal accumulation in seams of >100 million tons, in the lower and uppermost parts of the Paralic Series. Within the Pennsylvanian coal-bearing succession of terrestrial fluvio-lacustrine origin, a specific, wave-like pattern of seam resource variations and four intervals of increased coal accumulation are observed. In the Lublin Coal Basin, the Lublin Beds only, deposited during the Late Bashkirian, are coal-bearing, in which a bell-shaped pattern of seam resource variation in the stratigraphic succession is observed. The location of enhanced coal accumulation events in the stratigraphic succession suggests their repetition at ~1–4 My intervals. The characteristic features of the quantitative variation in these coal seams may be correlated with glacial-interglacial and climate humidity changes, and interpreted as a response to variable volcanogenic CO2 supply.