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Detrital zircon U-Pb geochronology of a metasomatic calc-silicate in the Tsäkkok Lens, Scandinavian Caledonides 斯堪的纳维亚喀里多尼系Tsäkkok Lens中交代钙硅酸盐碎屑锆石U-Pb年代学研究
IF 0.8 Q4 ENVIRONMENTAL SCIENCES Pub Date : 2021-04-23 DOI: 10.7494/GEOL.2021.47.1.21
Chris Barnes, J. Majka, M. Bukała, E. Nääs, S. Rousku
The Tsäkkok Lens of the Seve Nappe Complex in the Scandinavian Caledonides comprises eclogite bodies hosted within metasedimentary rocks. These rocks are thought to be derived from the outermost margin of Baltica along the periphery of the Iapetus Ocean, but detrital records from the sedimentary rocks are lacking.Many metasedimentary outcrops within the lens expose both well-foliated metapelitic rocks and massive calc-silicates. The contacts between these two lithologies are irregular and are observed to trend at all angles to the high-pressure foliation in the metapelites. Where folding is present in the metapelites, the calc-silicate rocks are also locally folded. These relationships suggest metasomatism of the metapelites during the Caledonian orogenesis. Zircon U-Pb geochronology was conducted on sixty-one zircon grains from a calc-silicate sample to investigate if they recorded the metasomatic event and to assess the detrital zircon populations. Zircon grains predominantly show oscillatory zoning, sometimes with thin, homogeneous rims that have embayed contacts with the oscillatory-zoned cores. The zircon cores yielded prominent early Stenian, Calymmian, and Statherian populations with a subordinate number of Tonian grains. The zircon rims exhibit dissolution-reprecipitation of the cores or new growth and provide ages that span similar time frames, indicating overprinting of successive tectonic events. Altogether, the zircon record of the calc-silicate suggests that the Tsäkkok Lens may be correlated to Neoproterozoic basins that are preserved in allochthonous positions within the northern extents of the Caledonian Orogen.
斯堪的纳维亚加里东构造中Seve推覆复合体的Tsäkkok透镜体由位于变质沉积岩中的榴辉岩体组成。这些岩石被认为来自沿Iapetus海洋边缘的波罗的海的最外边缘,但沉积岩的碎屑记录缺乏。透镜体内的许多变质沉积岩露头既暴露出片理良好的变质岩,也暴露出块状的钙硅酸盐。这两种岩性之间的接触是不规则的,在各个角度上都趋向于变质岩中的高压片理。在变质长岩中褶皱存在的地方,钙硅酸盐岩石也局部褶皱。这些关系表明,加里东造山过程中存在变质岩的交代作用。对某钙硅酸盐样品中的61粒锆石进行了锆石U-Pb年代学研究,以考察其是否记录了交代事件,并对碎屑锆石种群进行了评价。锆石颗粒主要表现为振荡带状,有时具有与振荡带状岩心接触的薄而均匀的边缘。锆石岩心显示出突出的早期斯坦世、加里米世和斯塔瑟世种群,其中托尼世颗粒数量较少。锆石边缘显示出岩心的溶蚀-再沉淀或新生长,并提供了跨越相似时间框架的年龄,表明连续构造事件的重叠。总的来说,钙硅酸盐的锆石记录表明Tsäkkok透镜体可能与新元古代盆地有关,这些盆地保存在加里东造山带北部的异地位置。
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引用次数: 0
Portable XRF spectrometer with helium flow as a tool for lithological interpretation 便携式XRF光谱仪与氦流作为岩石解释的工具
IF 0.8 Q4 ENVIRONMENTAL SCIENCES Pub Date : 2021-01-29 DOI: 10.7494/GEOL.2020.46.4.315
R. Skupio
Portable EDXRF (Energy Dispersive X-Ray Fluorescence) spectrometer with the ability to perform rock tests in a helium atmosphere was applied to prepare unique calibration coefficients and mineralogical models. These data could be used for the chemical profiling, chemostratigraphy, gamma-ray, TOC and lithological interpretation of borehole geological profile. The measurements were conducted on 19 samples of sandstones and compared to the XRF data without helium flow. The acquired dataset was calibrated to the chemical laboratory tests (ICP-MS), gamma-ray spectrometry measurements (RT-50) and combined with the mineralogical data (XRD). The new methodology enables the measurement of sodium and enhances the possibility of detecting magnesium, thorium and uranium, compared to standard handheld XRF spectrometers. The applied method is dedicated to whole cores (without sample preparation) or cuttings which must be cleaned, dried, milled and pressed.
便携式EDXRF(能量色散x射线荧光)光谱仪能够在氦气氛中进行岩石测试,用于制备独特的校准系数和矿物学模型。这些数据可用于井眼地质剖面的化学剖面、化学地层学、伽马射线、TOC和岩性解释。在19个砂岩样品上进行了测量,并与没有氦流的XRF数据进行了比较。获取的数据集经过化学实验室测试(ICP-MS)、伽马射线能谱测量(RT-50)校准,并结合矿物学数据(XRD)。与标准手持式XRF光谱仪相比,新方法可以测量钠,并增强检测镁,钍和铀的可能性。所应用的方法是专用于整个岩心(没有样品制备)或岩屑,必须清洗,干燥,研磨和压制。
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引用次数: 2
The application of volume texture extraction to three-dimensional seismic data – lithofacies structures exploration within the Miocene deposits of the Carpathian Foredeep 体积纹理提取在三维地震资料中的应用——喀尔巴阡前深中新世沉积岩相构造勘探
IF 0.8 Q4 ENVIRONMENTAL SCIENCES Pub Date : 2021-01-26 DOI: 10.7494/GEOL.2020.46.4.301
M. Łukaszewski
There are numerous conventional fields of natural gas in the Carpathian Foredeep, and there is also evidence to suggest that unconventional gas accumulations may occur in this region. The different seismic signatures of these geological forms, the small scale of amplitude variation, and the large amount of data make the process of geological interpretation extremely time consuming. Moreover, the dispersed nature of information in a large block of seismic data increasingly requires automatic, self-learning cognitive processes. Recent developments with Machine Learning have added new capabilities to seismic interpretation, especially to multi-attribute seismic analysis. Each case requires a proper selection of attributes. In this paper, the Grey Level Co-occurrence Matrix method is presented and its two texture attributes: Energy and Entropy. Haralick’s two texture parameters were applied to an advanced interpretation of the interval of Miocene deposits in order to discover the subtle geological features hidden between the seismic traces. As a result, a submarine-slope channel system was delineated leading to the discovery of unknown earlier relationships between gas boreholes and the geological environment. The Miocene deposits filling the Carpathian Foredeep, due to their lithological and facies diversity, provide excellent conditions for testing and implementing Machine Learning techniques. The presented texture attributes are the desired input components for self-learning systems for seismic facies classification.
喀尔巴阡前深区有大量的常规气田,也有证据表明该地区可能存在非常规天然气聚集。这些地质形态的地震特征不同,振幅变化规模小,数据量大,使得地质解释过程非常耗时。此外,大量地震数据中信息的分散性越来越需要自动、自学习的认知过程。机器学习的最新发展为地震解释,特别是多属性地震分析增加了新的能力。每种情况都需要正确选择属性。本文提出了灰度共生矩阵方法及其两个纹理属性:能量和熵。为了发现隐藏在地震痕迹之间的微妙地质特征,将Haralick的两个结构参数应用到中新世矿床层段的高级解释中。在此基础上,圈定了一个海底斜坡河道系统,从而发现了天然气钻孔与地质环境之间未知的早期关系。充填喀尔巴阡前深的中新世沉积物,由于其岩性和相的多样性,为测试和实施机器学习技术提供了良好的条件。所提出的纹理属性是用于地震相分类的自学习系统所需的输入成分。
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引用次数: 1
Change-point detection and trend analysis in monthly, seasonal and annual air temperature and precipitation series in Bartın province in the western Black Sea region of Turkey 土耳其黑海西部Bartın省气温和降水序列月、季、年变化点探测及趋势分析
IF 0.8 Q4 ENVIRONMENTAL SCIENCES Pub Date : 2021-01-19 DOI: 10.7494/GEOL.2020.46.3.223
B. Yaman, M. Ertuğrul
Studies associated with climate change and variability are of great importance at both the global and local scale in the global climate crisis. In this study, change-point detection and trend analysis were carried out on mean, maximum, minimum air temperatures and total precipitation based on monthly, seasonal and annual scale in Bartin province located in the western Black Sea Region of Turkey. For this aim, 4-different homogenei - ty tests (von Neumann test, Pettitt test, Buishand range test and standard normal homogeneity test) for change- point detection, Modified Mann–Kendall test and Şen’s innovative trend test for trend analysis, and Sen’s slope test for the magnitude estimation of trends were used. According to the test results, the summer temperatures in particular show increasing trends at the 0.001 significance level. Mean maximum temperature in August, mean minimum temperature in June and August, and mean temperature in July and August are in increasing trend at the 0.001 significance level. Over a 51 year period (1965–2015) in Bartin province, the highest rate of change per decade in air temperatures is in August (0.55°C for T max , 0.46°C for T min and 0.43°C for T mean ) based on Sen’s slope. However, the study showed that apart from October precipitation, there is no significant trend in monthly, seasonal and annual precipitation in Bartin. Increasing trends in mentioned climate variables are also visually very clear and strong in Şen’s innovative trend method, and they comply with the statistical results. As a result, the study revealed some evidence that temperatures will increase in the future in Bartin and its environs.
在全球气候危机中,与气候变化和变率相关的研究在全球和局部尺度上都具有重要意义。本研究对位于土耳其黑海西部地区巴尔丁省的平均、最高、最低气温和总降水量进行了基于月、季、年尺度的变化点检测和趋势分析。为此,我们使用4种不同的同质性检验(von Neumann检验、Pettitt检验、Buishand极差检验和标准正态同质性检验)进行变化点检测,使用修正Mann-Kendall检验和Şen的创新趋势检验进行趋势分析,使用Sen的斜率检验进行趋势的幅度估计。根据检验结果,特别是夏季气温在0.001显著水平上呈上升趋势。8月平均最高气温、6月和8月平均最低气温、7月和8月平均气温均呈上升趋势,均达到0.001显著水平。在巴尔丁省51年(1965-2015)期间,根据森氏斜率,每十年气温变化率最高的是8月份(最高气温0.55°C,最低气温0.46°C,平均气温0.43°C)。但研究表明,除10月降水量外,巴尔丁地区月、季、年降水量均无显著变化趋势。在Şen的创新趋势方法中,上述气候变量的增加趋势在视觉上也非常清晰和强烈,并且符合统计结果。因此,这项研究揭示了一些证据,表明未来巴尔丁及其周边地区的气温将会上升。
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引用次数: 2
Spatial distribution of radiogenic heat in the Iullemmeden basin – Precambrian basement transition zone, NW Nigeria 尼日利亚西北部Iullemmeden盆地-前寒武纪基底过渡带放射性成因热的空间分布
IF 0.8 Q4 ENVIRONMENTAL SCIENCES Pub Date : 2021-01-19 DOI: 10.7494/GEOL.2020.46.3.238
Joseph Aisabokhae, M. Adeoye
The area which transcends the Precambrian basement complex onto the Sokoto sector of the Iullemme-den basin in northwestern Nigeria presents a unique prospect for geothermal exploration research in the absence of regional heat production data, despite its tectonic history and depositional characteristics. In this study, geophysical exploration employing radiometric technique was adopted to classify the petrologic units within the fringes of the Iullemmeden basin and the adjoining crystalline basement complex so as to estimate the radiogenic heat potential within the terrain that may support geothermal considerations. Airborne radiometric measurements acquired over the area were digitized and processed to obtain radioelement concentration maps and the K/Th/U ternary map. Results show that the ranges of measured concentrations of 40K, 238U and 232Th are 4.6 to 18.9%, 0.7 to 4.9 ppm and 4.6 to 18.9 ppm respectively. Radiogenic heat estimation derived from radioelement data within eight petrologic units comprising quaternary sediments, schist, carbonates, shale/clay, younger granites, older granites, gneissic rock and migmatite showed that the lowest radiogenic heat production estimates ranging from 0.27–0.66 μW∙m−3 were recorded in the sedimentary terrain within the quaternary sediments while the highest radiogenic heat production values of between 2.04 to 2.34 μW∙m−3 were recorded in the basement com-plex within gneissic rocks. The spatial distribution of radiogenic heat in the area showed an increased heat gradient within the basement complex and a diminishing heat gradient over the Iullemmeded basin.
尼日利亚西北部Iullemme-den盆地的前寒武纪基底复合体和Sokoto区域,尽管其构造历史和沉积特征,但在缺乏区域产热数据的情况下,为地热勘探研究提供了独特的前景。本研究采用地球物理辐射探测技术,对Iullemmeden盆地边缘及邻近结晶基底杂岩进行了岩石学单元分类,估算了地表辐射成因热势,支持地热研究。对该地区的航空辐射测量数据进行数字化处理,得到放射性元素浓度图和K/Th/U三元图。结果表明,40K、238U和232Th的测量浓度范围分别为4.6 ~ 18.9%、0.7 ~ 4.9 ppm和4.6 ~ 18.9 ppm。根据8个岩石学单元(包括第四纪沉积物、片岩、碳酸盐岩、页岩/粘土、较年轻花岗岩、较老花岗岩、片麻岩和混辉岩显示,第四纪沉积岩中沉积地型的放射生热值最低,为0.27 ~ 0.66 μW∙m−3;片麻岩中基底杂岩的放射生热值最高,为2.04 ~ 2.34 μW∙m−3。辐射成因热的空间分布表现为基底复合体内部热梯度增大,盆地上方热梯度减小。
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引用次数: 4
Progress in the development of the semi-empirical calibration of neutron probes based on Monte Carlo modeling 基于蒙特卡罗模型的中子探测器半经验定标研究进展
IF 0.8 Q4 ENVIRONMENTAL SCIENCES Pub Date : 2021-01-19 DOI: 10.7494/GEOL.2020.46.3.251
U. Woźnicka
The method of the semi-empirical calibration of a neutron well logging probe was developed by Jan Andrzej Czubek on the concept of the general neutron parameter ( GNP ) and tested positively at the neutron calibration station in Zielona Gora, Poland. The neutron probe responses in a wide range of neutron parameters (and thus lithology, porosity and saturation) were also computed using the Monte Carlo method. The obtained simulation results made it possible to determine the calibration curves using the Czubek concept in a wider range than by means of the original method. The very good compatibility of both methods confirms the applicability of the GNP as well as the Monte Carlo numerical experiments, which allow for a significant extension of the semi-empirical calibration in complex well geometries taking into account e.g., casing or invaded zones.
Jan Andrzej Czubek根据一般中子参数(GNP)的概念提出了中子测井探头的半经验校准方法,并在波兰Zielona Gora的中子校准站进行了验证。利用蒙特卡罗方法计算了各种中子参数(包括岩性、孔隙度和饱和度)下的中子探针响应。得到的仿真结果使得利用Czubek概念确定比原方法更大范围的校准曲线成为可能。两种方法的良好兼容性证实了GNP和蒙特卡罗数值实验的适用性,这使得考虑到套管或侵入层等复杂井的几何形状,可以大大扩展半经验校准。
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引用次数: 0
Relationship between geomorphology of the ocean seafloor with the tectonic structure of the Earth's crust and anomalous geophysical fields: Makran Trench, Arabian Sea 海洋海底地貌与地壳构造结构及地球物理异常场的关系:阿拉伯海马克兰海沟
IF 0.8 Q4 ENVIRONMENTAL SCIENCES Pub Date : 2021-01-19 DOI: 10.7494/geol.2020.46.3.205
Polina Lemenkova
This study examined the relationships between topographic structure and submarine geomorphology, sediment thickness, geophysical anomaly fields, geological settings and tectonic lineament stretching of the Arabian Sea region, Carlsberg Ridge morphology, Makran Trench depths by GMT. The study included spatial analysis of the high-resolution datasets (GEBCO, EGM96, GlobSed) and geomorphological modeling of the 300km-width cross-section profiles of the Makran Trench. The analysis shown correlation between complex geologic and tectonic structure, asymmetric geomorphology and geophysical anomaly fields. The Makran Trench is formed in the subduction zone of the Arabian and Eurasian plates at the basement of the continental margin of Pakistan. Submarine geomorphic structure of the Arabian Sea is complicated by the Carlsberg Ridge, Owen Fracture Zone, Aden-Owen- Carlsberg Triple junction, numerous faults and rifts. The geophysical fields of the marine free- air gravity correlate with distribution of these geomorphic structures. Bathymetric analysis of the trench revealed the most frequent depth (448 samples) at -3,250 to -3,500 m, following by intervals: -3,000 to -3,250 m (225 samples), -2,750 to -3,000 m (201 samples). Gently declining continental slope of the coastal elevations correlate with gradually decreasing depths, as equally distributed bins: 124 samples (-2,500 to -2,750 m), 96 (-2,250 to -2,500 m), 86 (-2,000 to -2,250 m). Makran Trench has asymmetric geomorphology with a high slope steepness on the continental slope of Pakistan and low steepness with flat valley on the oceanward side.
本研究考察了阿拉伯海地区的地形结构与海底地貌、沉积物厚度、地球物理异常场、地质环境和构造线条拉伸、嘉士伯海岭形态、Makran海沟深度之间的关系。该研究包括对高分辨率数据集(GEBCO、EGM96、GlobSed)的空间分析和对Makran海沟300公里宽剖面剖面的地貌建模。分析表明,复杂地质构造、不对称地貌与地球物理异常场之间存在相关性。马克兰海沟形成于巴基斯坦大陆边缘基底的阿拉伯板块和欧亚板块俯冲带。阿拉伯海海底地貌结构复杂,有嘉士伯海岭、欧文断裂带、亚丁-欧文-嘉士伯三联结、大量断裂和裂谷。海洋自由空气重力的地球物理场与这些地貌结构的分布有关。海沟测深分析显示,最常见的深度(448个样本)为- 3250至- 3500米,其次是- 3000至- 3250米(225个样本),- 2750至- 3000米(201个样本)。沿海海拔缓慢下降的大陆坡度与深度逐渐下降相关,呈均匀分布的箱形分布:124个样本(- 2500至- 2750米),96个样本(- 2250至- 2500米),86个样本(- 2000至- 2250米)。马克兰海沟的地貌不对称,巴基斯坦大陆斜坡坡度高,向海一侧坡度低,山谷平坦。
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引用次数: 17
Statistical evaluation of the geochemical data for prospecting polymetallic mineralization in the Suoi Thau – Sang Than region, Northeast Vietnam 越南东北索陶-桑丹地区多金属成矿地球化学资料的统计评价
IF 0.8 Q4 ENVIRONMENTAL SCIENCES Pub Date : 2020-12-30 DOI: 10.7494/GEOL.2020.46.4.285
Pham Nhu Sang, N. Phuong, Vu Thai Linh, B. V. Sang
In Northeast Vietnam, Suoi Thau-Sang Than is considered as a high potential area of polymetallic deposits. 1,720 geochemical samples were used to investigate polymetallic mineralization; thereby polymetallic ore occurrences in this study region were discovered and the statistical and multivariate analysis helps to define geochemical anomalies in some northeastern regions, namely Suoi Thau, Sang Than, and Ban Kep. The statistical method and cluster analysis of geochemical data indicate that the Cu, Pb, and Zn elements are good indicators, and most of them comply with the lognormal or gamma distribution. Based on the third-order threshold, the geochemical anomalies of the content of the Cu, Pb, and Zn elements reflect the concentration of copper forming ore bodies in the mineralized zone, and clearly show the concentration in three distinct zones. The trend surface analysis which was employed to determine spatial variations and relationships among these good indicator elements and anomalous areas revealed relative changes in the content of the indicator elements, and they can be considered as regular. Moreover, the goodness of fit obtained trend functions of Pb and Zn, and Cu elements is a third-degree trend surface model. These results indicate that the models can be useful in studying geochemical anomalies and analyzing the tendency of the concentration of indicator elements in the Suoi Thau-Sang Than region. Additionally, it is suggested that the statistical analysis shows a remarkable potential to use the bottom river sediments in the region to investigate polymetallic mineralization. Moreover, geochemical data can help to evaluate geochemical anomalies of the pathfinder elements and potential mineral mapping of the Suoi Thau-Sang Than region in Northeast Vietnam.
在越南东北部,Suoi Thau-Sang Than被认为是多金属矿床的高潜力地区。利用地球化学样品1720份进行了多金属成矿研究;通过统计分析和多元分析,确定了东北部分地区的地球化学异常,即索陶、桑丹、班克普等。地球化学数据的统计方法和聚类分析表明,Cu、Pb和Zn元素是较好的指标,且大部分符合对数正态分布或伽马分布。基于三阶阈值,Cu、Pb、Zn元素含量的地球化学异常反映了成矿带内铜成矿矿体的富集程度,并清晰地表明了三个不同带的富集程度。通过趋势面分析确定各指标元素与异常区之间的空间变化和关系,揭示了指标元素含量的相对变化,具有一定的规律性。拟合优度得到的Pb、Zn、Cu元素的趋势函数为三度趋势面模型。这些结果表明,该模型可用于研究索都-桑丹地区的地球化学异常和分析指示元素的浓度趋势。此外,统计分析表明,利用该地区底河沉积物进行多金属成矿研究具有显著的潜力。此外,地球化学数据还有助于评价探路者元素的地球化学异常和越南东北部索陶-桑丹地区的潜在矿物填图。
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引用次数: 2
Seismic stratigraphic analysis for hydrocarbon exploration in the Beta Field, Coastal Swamp Depobelt, Niger Delta 尼日尔三角洲滨海沼泽沉积带Beta油田油气勘探地震地层分析
IF 0.8 Q4 ENVIRONMENTAL SCIENCES Pub Date : 2020-12-22 DOI: 10.7494/GEOL.2020.46.4.259
M. A. Adeleye, Kazeem Oladayo Yekeen, Sikiru A. Amidu
Hydrocarbon exploration analysis from a seismic stratigraphic approach was carried out within the Beta Field, Coastal Swamp Depobelt, Niger Delta, to identify system tracts and sequence boundaries that could be associated with potential hydrocarbon accumulation. 3D seismic volume and data from four wells were analyzed. Depositional sequences, system tracts, sequence boundaries, and candidate maximum flooding surfaces were picked from logs, while reflection patterns and terminations were interpreted from seismic sections. Log shapes from gamma rays in combination with seismic facies analysis were interpreted in order to delineate lithology, depositional environments and depositional sequences. Seismic attributes were extracted and were draped on gridded surfaces from the interpreted seismic horizons. These were integrated with structure maps to obtain structural and stratigraphic trends, and possible presence of reservoir sand. Five depositional sequences and nine seismic facies were identified within the field. The depositional sequences were designated Sequences S1 to S5 based on the depth of the occurrences and stacking patterns. This study reveals a progression from fluvial depositional settings to the shelf. The main reservoirs identified are the sand units of the highstand and lowstand within three depositional sequences (S1, S4 and S5) although interbedded sands within the TST of S4 and S5 are also suspected of being potential reservoirs. The channel sand deposits within the study area are suspected to be hydrocarbon bearing as they occurred within the complex fault trapping system popular in the Niger Delta. The application of seismic stratigraphy, as shown in this study, serves to encourage exploration in the Niger Delta where it could be effectively employed for reducing risk in hydrocarbon exploration.
利用地震地层学方法对尼日尔三角洲沿海沼泽沉积带Beta油田进行了油气勘探分析,以确定可能与潜在油气聚集有关的体系域和层序边界。对4口井的三维地震体和数据进行了分析。从测井中提取沉积层序、体系域、层序边界和候选最大泛水面,同时从地震剖面中解释反射模式和终端。结合地震相分析,解释了伽马射线测井曲线形状,以圈定岩性、沉积环境和沉积层序。提取地震属性,并将其覆盖在解释地震层的网格表面上。这些数据与构造图相结合,以获得构造和地层趋势,以及可能存在的储层砂。圈定了5个沉积层序和9个地震相。根据产状深度和叠置模式划分为S1 ~ S5层序。该研究揭示了从河流沉积环境到陆架的一个递进过程。发现的主要储层是S1、S4和S5 3个沉积层序内的高、低水位砂单元,S4和S5层序内的互层砂也被认为是潜在的储层。研究区内的河道砂体发育在尼日尔三角洲复杂的断裂圈闭体系中,被怀疑是含油气的。如本研究所示,地震地层学的应用有助于鼓励在尼日尔三角洲的勘探,在那里它可以有效地用于降低油气勘探的风险。
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引用次数: 0
A determination of areas of biocorrosion development on the route of a main gas pipeline in the Western region of Ukraine 确定乌克兰西部地区一条主要天然气管道路线上的生物腐蚀发展区域
IF 0.8 Q4 ENVIRONMENTAL SCIENCES Pub Date : 2020-11-06 DOI: 10.7494/GEOL.2020.46.4.273
M. Polutrenko, Yevstakhiy Kryzhanivs’kyy, Ya. T. Fedorovych
A determination of soil corrosivity on three sections of a main gas pipeline in the Western region of Ukraine has been carried out. We have distinguished areas of development of biocorrosive processes with the participation of sulphate-reducing bacteria (SRB). Soil evaluation by the degree of corrosivity has been conducted. We used weight, titrimetric, gravimetric methods, pH-metry, ten-fold limit dilution method and Postgate nutrient medium B for culturing SRB. It has been established that the soil in the first area selected along the lower generatrix of the main gas pipeline has a high degree of corrosivity. It was ascertained that corrosive metal damage increases in the “ferrozone” with the growth of metal exposition time from 24 to 72 hours. The soil selected in the middle part and from above the pipeline refers to soils with a normal degree of corrosive activity. Innovative biostable insulating coatings based on bituminous-polymerous mastic MBPID-1 have been developed, modified with organic inhibitors from the class of quaternary ammonium salts and amines. Regularities of influence of nature of nitrogen-containing corrosion inhibitors of industrial production M, N, L, H and K on the corrosion rate of 17G1S steel for 180 days have been established. It was found that the corrosion rate of steel specimens remained unchanged throughout the study in variants with the presence of inhibitors H and K in the test systems, which indicated their bioresistance to the effect of SRB bacteria.
对乌克兰西部地区一条主要天然气管道的三段进行了土壤腐蚀性测定。在硫酸盐还原菌(SRB)的参与下,我们区分了生物腐蚀过程的发展领域。通过腐蚀程度对土壤进行了评价。采用重量法、滴定法、重量法、ph法、十倍极限稀释法和Postgate营养培养基B培养SRB。确定了沿主输气管道下母线选取的第一区域土壤具有较高的腐蚀性。结果表明,随着金属暴露时间从24小时增加到72小时,“铁氧区”中的腐蚀金属损伤增加。管道中部及以上选取的土壤是指具有正常腐蚀活性的土壤。采用季铵盐和胺类有机抑制剂进行改性,开发了一种新型生物稳定绝缘涂料。建立了工业生产中含氮缓蚀剂M、N、L、H、K的性质对17G1S钢180天腐蚀速率的影响规律。研究发现,在整个研究过程中,在测试系统中存在抑制剂H和K的变体中,钢试件的腐蚀速率保持不变,这表明它们对SRB细菌的影响具有生物抗性。
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引用次数: 0
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Geology, Geophysics and Environment
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