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Assessment of Heavy Metal Contaminations in Groundwater and Surface Water Resources of Sukinda Valley, Odisha, India 印度奥里萨邦苏金达河谷地下水和地表水重金属污染评价
IF 2.2 4区 地球科学 Q3 GEOSCIENCES, MULTIDISCIPLINARY Pub Date : 2025-05-12 DOI: 10.1002/gj.5227
Pintu Prusty, Sandip Kumar Mohakud, Asim Ranjan Mandal, Khursheed Ahmad Parray, Syed Hilal Farooq

The increasing demand for heavy metals has led to extensive excavation of their ore deposits. The leaching of heavy metals from active and abandoned mines can contaminate the water resources available nearby. The present study evaluates the extent and spatio-temporal variability of heavy metal concentrations in groundwater and surface water resources around the chromite mining regions of the Sukinda Valley, Odisha, India. Twelve surface water samples were collected from the major stream flowing through the region, and 30 tube wells located close to the mining regions were also sampled for groundwater. The samples from the same sites were collected twice, once during pre-monsoon and again in post-monsoon seasons. All samples were analysed for major ion and heavy metal concentrations. Major ion chemistry indicates that the water is of Ca-Mg-HCO3 type during both seasons. There are no large-scale seasonal variations in the groundwater chemistry; however, a significant seasonal change in the hydrochemistry of surface water has been observed. Heavy metals such as Cr, Fe, Mn, Ni and Zn were detected (> 5 μg/L) in more than 30% of samples, out of which Fe and Cr were identified as the major contaminants. Iron concentrations above the WHO prescribed limit in drinking water have been found in more than 70% of groundwater samples, while higher Cr concentrations were observed in 20%–23% of groundwater samples. Heavy metal pollution indices suggested around 50%–60% of groundwater samples were contaminated with heavy metals, while the surface waters were close to critical condition. Groundwater contaminations with these heavy metals are prominent mainly in the densely populated central regions of the study area. Bivariate cross-plots of major ions indicated the hydrochemistry of the area to be controlled by sediment–water interactions, especially silicate weathering and carbonate dissolution. Multivariate analyses combined the measured water quality parameters based on their analogous behaviour and confirmed the above processes controlling the water chemistry. From a combined statistical analysis and pollution indices, it has been confirmed that geogenic and mining-related activities are responsible for heavy metal contaminations both in groundwater and surface water resources of the region. Weathering of the local lithology, leaching and discharges from the mines were identified as the dominant contributors of heavy metals to the water resources.

对重金属日益增长的需求导致了对其矿床的广泛挖掘。从活跃的和废弃的矿山中浸出的重金属会污染附近可用的水资源。本研究评估了印度奥里萨邦苏金达河谷铬铁矿矿区地下水和地表水资源中重金属浓度的程度和时空变异。从流经该地区的主要河流中采集了12个地表水样本,并在靠近矿区的30个管井中采集了地下水样本。从同一地点收集了两次样本,一次是在季风前,另一次是在季风后。对所有样品进行了主要离子和重金属浓度分析。主要离子化学特征表明,两季水体均为Ca-Mg-HCO3型。地下水化学特征不存在大尺度的季节变化;然而,已观察到地表水的水化学有显著的季节变化。超过30%的样品中检出了Cr、Fe、Mn、Ni、Zn等重金属(≤5 μg/L),其中Fe和Cr为主要污染物。在70%以上的地下水样本中发现饮用水中的铁浓度超过世卫组织规定的限值,而在20%至23%的地下水样本中观察到较高的铬浓度。重金属污染指数显示,地下水样品重金属污染约为50%-60%,地表水接近临界状态。这些重金属对地下水的污染主要发生在研究区人口稠密的中部地区。主要离子的二元交叉图表明该地区的水化学受沉积物-水相互作用的控制,特别是硅酸盐风化和碳酸盐溶解。多变量分析结合实测水质参数的相似行为,证实了上述过程对水化学的控制作用。综合统计分析和污染指数,证实了地质活动和采矿活动是造成该地区地下水和地表水资源重金属污染的主要原因。当地岩性的风化作用、矿山的浸出和排放是水资源中重金属的主要来源。
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引用次数: 0
Relationship Between Fault Systems and Fracturing in Complex Fractured Carbonate Reservoir in the Tunisian Pelagian Block Using Integrated Seismic and Petrophysical Analysis: Implications for Petroleum Exploration and Development 突尼斯伯拉纠区块复杂裂缝性碳酸盐岩储层断裂系统与压裂关系的地震岩石物理综合分析:对石油勘探开发的启示
IF 2.2 4区 地球科学 Q3 GEOSCIENCES, MULTIDISCIPLINARY Pub Date : 2025-05-12 DOI: 10.1002/gj.5233
Wafa Abdelkhalek, Radhouane Khouni, Seifeddine Gaidi, Abdelhamid Ben Salem, Fetheddine Melki, Ahmed E. Radwan

The Abiod carbonate reservoir of the Campanian-Early Maastrichtian age represents a major oil reservoir In the Pelagian block of eastern Tunisia, forming complex fractured networks that are poorly understood. Given the total absence of geological outcrops of Campanian-Maastrichtian age in the study area, 2D seismic reflection, geological modelling and well log datasets were integrated to characterise the subsurface geodynamic structures, investigate the petrophysical characteristics, the relationship between fault systems and fracturing and define their implications for petroleum exploration. Analysis of seismic profiles, lithostratigraphic logs, borehole data and geological modelling has shown the prevalence of three major fault networks: northwest–southeast (NW–SE), E–W and northeast-southwest (NE–SW). These faults have controlled the thickness of the limestones of the Abiod reservoir, favouring highly subsiding NW–SE trending zones where the thickness has exceeded 500 m. Based on responses of the Gamma Ray (GR) and Sonic curves, this formation is made up of four different lithological units (U1–U4). The wireline log analyses concluded that the gross thickness of the Abiod reservoir includes good reservoir property intervals with average effective porosity ranging from 8.6% to 20.6% and average shale volume ranging from 2% to 17%. Furthermore, analysis of the fracturing affecting the Abiod reservoir, based on oil well FMS image logs, has shown the presence of open and partially open fractures that are key to hydrocarbon accumulations. The rose diagrams of fracture directions at the wells and the rose diagram of major fault directions of the map are in perfect agreement with the clear predominance of the NW–SE directions. Beyond the main uplift faults, the structural features that impact the studied area's stratigraphy are divided into three main categories. This study showed that the brittle tectonics play a role in the enhancement of the petrophysical characteristics of the studied limestone reservoir and controlled the charge access of the hydrocarbons into the reservoir. The majority of the fractures affecting the Abiod reservoir are parallel to the large fault and have the same direction of movement, while the others are distributed in a conjugate family close to perpendicular to the large fault and with complementary directions of movement. The combination of geological factors and logging parameters indicates that the tectonic legacy and structural inversions play an important role in the structuring of the cover and the evolution of the petroleum system, which have made this chalk one of the most important oil reservoirs in eastern Tunisia. Finally, the developed 3D structural model suggests favourable locations for high-potential areas in the studied region and provides insights for the reservoir development.

坎帕尼亚—马斯特里赫特早期的Abiod碳酸盐岩储层是突尼斯东部Pelagian区块的主要油藏,形成了复杂的裂缝网络,但人们对其了解甚少。考虑到研究区完全没有坎帕尼亚-马斯特里赫特时代的地质露头,研究人员综合了二维地震反射、地质建模和测井数据集,以表征地下地球动力结构,研究岩石物理特征、断层系统与压裂之间的关系,并确定其对石油勘探的意义。通过对地震剖面、岩石地层测井、钻孔资料和地质模型的分析,发现该区存在西北-东南(NW-SE)、东西向(E-W)和东北-西南(NE-SW)三大断层网。这些断裂控制了Abiod储层灰岩的厚度,有利于NW-SE向的高沉降带,厚度超过500 m。根据伽马射线(GR)和声波曲线的响应,该地层由四个不同的岩性单元(U1-U4)组成。电缆测井分析表明,Abiod储层的总厚度包括良好的储层性质,平均有效孔隙度为8.6% ~ 20.6%,平均页岩体积为2% ~ 17%。此外,基于油井FMS图像测井,对Abiod储层的压裂影响进行了分析,发现存在张开和部分张开的裂缝,这是油气聚集的关键。井处裂缝方向玫瑰图和主断裂方向玫瑰图与NW-SE向明显优势相吻合。除主要隆升断裂外,影响研究区地层的构造特征主要分为三类。研究表明,脆性构造增强了灰岩储层的岩石物性特征,控制了油气进入储层的电荷通道。影响Abiod储层的裂缝大部分平行于大断裂,运动方向相同,而其他裂缝则接近于大断裂垂直,呈共轭族分布,运动方向互补。地质因素和测井参数综合分析表明,构造遗产和构造反转对盖层的构造和含油气系统的演化起着重要作用,使该白垩系成为突尼斯东部最重要的油藏之一。最后,开发的三维结构模型指出了研究区域内高潜力区域的有利位置,并为储层开发提供了见解。
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引用次数: 0
Multi-Criteria Decision Analysis Framework for Landslide Susceptibility Mapping With Analytical Hierarchy Process in Parts of Assam–Arakan Fold Belt, India 基于层次分析法的阿萨姆-阿拉干褶皱带部分地区滑坡易感性制图多准则决策分析框架
IF 2.2 4区 地球科学 Q3 GEOSCIENCES, MULTIDISCIPLINARY Pub Date : 2025-05-12 DOI: 10.1002/gj.5229
Debasish Mazumder, Ratan Das, Sourav Das

Landslide is one of the most sought-after research areas in the current multidisciplinary geoscience studies. In this study, a landslide susceptibility map was developed using a Multi-Criteria Decision Analysis (MCDM) framework with the Analytical Hierarchy Process (AHP) in the Dima Hasao district of Assam, India. The region is located in the western extent of the Assam–Arakan fold belt. It is characterised by extensively folded and faulted mountainous terrain. The region is highly susceptible to landslide hazard due to several factors including climatic factors, weak lithologic conditions, anthropogenic activity and so forth. This study utilised a GIS-based approach of mapping landslide susceptibility zones; geoprocessing of 12 landslide causative factors was considered, namely slope, rainfall, elevation, geology, distance from fault, drainage density, distance from drainage, curvature (Cu), distance from road, Land Use/Land Cover, Topographic Wetness Index and aspect were utilised by the AHP algorithm. Weightage criteria are assigned to all the 12 factors on a scale of 1–5 based on the significance of landslide occurrence. The AHP algorithm classified four landslide susceptible zones of different hazard, that is, low, moderate, high and very high susceptible zones. The obtained landslide susceptibility model was validated using the area under the curve (AUC) of the receiver operating characteristics (ROC) with an accuracy of 0.864, which confirmed its reliability.

滑坡是当前多学科地球科学研究中最受欢迎的研究领域之一。在这项研究中,使用多标准决策分析(MCDM)框架和层次分析法(AHP)在印度阿萨姆邦的Dima Hasao地区绘制了滑坡易感性图。该地区位于阿萨姆-阿拉干褶皱带的西部。它的特点是广泛的褶皱和断裂的山地地形。该地区受气候因素、岩性条件薄弱、人为活动等因素的影响,极易发生滑坡灾害。本研究采用基于gis的方法绘制滑坡易感区;利用AHP算法对边坡、降雨、高程、地质、离断层距离、排水密度、离排水距离、曲率(Cu)、离道路距离、土地利用/土地覆盖、地形湿度指数和坡向等12个滑坡成因进行地质处理。根据滑坡发生的显著性,将12个因素按1-5的等级分配权重标准。AHP算法将不同危险性的滑坡易感区分为低、中、高、高4个易感区。利用receiver operating characteristic (ROC)曲线下面积(area under The curve, AUC)对得到的滑坡敏感性模型进行了验证,精度为0.864,验证了模型的可靠性。
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引用次数: 0
The Geophysical and Seismotectonic Implications of the Partial Subduction of the Ogasarawa Plateau on the Southern Izu-Bonin Arc-Trench System 南伊豆-波宁弧-海沟系小笠川高原部分俯冲的地球物理和地震构造意义
IF 2.2 4区 地球科学 Q3 GEOSCIENCES, MULTIDISCIPLINARY Pub Date : 2025-05-12 DOI: 10.1002/gj.5212
Peter Sangana, Qin Gao, Zilong Li

The present-day structure of the southern Izu-Bonin arc-trench system appears to have been influenced by the partial subduction of the Ogasawara Plateau beneath the Philippine Sea Plate, which has significant tectonic consequences. Unfortunately, there is insufficient information regarding the effects of the Ogasawara Plateau collision on the geophysical and seismic characteristics of the region. Therefore, we employ the geophysical and seismic analysis on the gravity and bathymetry datasets, seismic events and earthquake moment tensors to examine the geophysical and seismic patterns of the southern Izu-Bonin subduction zone, thereby uncovering the effects of the Ogasawara Plateau subduction. The results show that the Ogasawara Plateau forms uplift/upthrusts and large fractures/faults in the outer rise region at its subduction area. Several uplifted tectonic features are observed along the southern Izu-Bonin Trench axis at the area of the Ogasawara Plateau collision, where also the bathymetry is approximately 3 km elevated compared to other sections of the trench. Several conspicuous seamounts, uplifts, depressions and ridges are visible in the outer forearc region affected by the collision of the Ogasawara Plateau. Moreover, abnormal low Bouguer gravity anomalies are detected in both the outer and inner forearc regions around the area associated with the Ogasawara Plateau subduction. An area with a scarcity of earthquakes is observed to the west of the Ogasawara Plateau, suggesting a density contrast within the subducting Pacific Plate beneath this region. A seismic gap (moderate to great magnitude [Mw > 4]) is observed in the subducting Pacific Plate at depths ranging from 200 to 500 km around the Ogasawara Plateau subduction area. This study shows that the Ogasawara Plateau subduction influences geophysical properties, seismic activity and faulting in the southern Izu-Bonin subduction system. It also improves understanding of subduction dynamics and the seismic effects associated with the subduction of large bathymetric highs.

南伊豆-波宁弧-海沟体系的现今结构似乎受到菲律宾海板块下小笠原高原部分俯冲的影响,这具有重要的构造后果。不幸的是,关于小笠原高原碰撞对该地区地球物理和地震特征的影响的信息不足。为此,我们利用重力、测深数据、地震事件和地震矩张量等地球物理和地震分析方法,研究了伊豆-小原俯冲带南部的地球物理和地震模式,从而揭示了小笠原高原俯冲的影响。结果表明:小笠原高原在其俯冲区外隆起区形成隆升/逆冲和大断裂/断裂;在Ogasawara高原碰撞区域,沿着Izu-Bonin海沟轴线南部观察到几个隆起的构造特征,与海沟的其他部分相比,那里的测深也高出约3公里。在受小笠原高原碰撞影响的外前弧区域,可以看到几个明显的海山、隆起、洼地和山脊。此外,在与小笠原高原俯冲有关的外、内前弧区域均发现了异常的低布格重力异常。在小笠原高原以西观察到一个地震稀少的地区,这表明在该地区下方俯冲的太平洋板块内部存在密度对比。在小笠原高原俯冲区周围200 ~ 500 km深度处,观测到太平洋板块俯冲形成中~大震隙[Mw >; 4]。研究表明,小笠原高原俯冲作用影响了伊豆-波宁俯冲系统南部的地球物理性质、地震活动和断裂。它还提高了对俯冲动力学和与大水深高点俯冲有关的地震效应的理解。
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引用次数: 0
The Role of the Blue Economy, Renewable Energy, and Energy Intensity in Mitigating CO2 Emissions: Evidence From China Using MMQREG Analysis 蓝色经济、可再生能源和能源强度在减少二氧化碳排放中的作用:来自中国的MMQREG分析证据
IF 2.2 4区 地球科学 Q3 GEOSCIENCES, MULTIDISCIPLINARY Pub Date : 2025-05-12 DOI: 10.1002/gj.5224
Muhammad Iatzaz Ul Hassan, Mengyun Wu, Yasir Rasool, Jan Muhammad Sohu, Shoaib Ali

China's rapid industrialization and economic development have significantly contributed to rising CO2 emissions, posing a direct challenge to sustainable development objectives. This study investigates the relationship between aquaculture production, renewable energy consumption, energy intensity, and CO2 emissions in China, with a particular focus on the role of aquaculture production and renewable energy consumption in shaping emission patterns. Employing the Method of Moments Quantile Regression (MMQREG) and Bootstrap Quantile Regression (BSQREG) approaches, the analysis explores the nonlinear dynamics across various quantiles of CO2 emissions. The findings reveal that renewable energy consumption and energy intensity exert varying effects on CO2 emissions across different emission levels, with the most pronounced impact observed in the lower quantiles. The study underscores the necessity of considering regional and sectoral disparities when formulating emission mitigation policies. It highlights the importance of China's ongoing transition toward renewable energy, enhanced efficiency, and region-specific policy interventions, particularly in high-emission areas. These insights contribute to the discourse on sustainable development in emerging economies, offering practical implications for policymakers and avenues for future research, particularly in regional variations and economic determinants of CO2 emissions.

中国快速的工业化和经济发展极大地促进了二氧化碳排放量的上升,对可持续发展目标构成了直接挑战。本研究探讨了中国水产养殖生产、可再生能源消费、能源强度和二氧化碳排放之间的关系,重点研究了水产养殖生产和可再生能源消费在形成排放格局中的作用。采用矩量分位数回归(MMQREG)和自举分位数回归(BSQREG)方法,分析了二氧化碳排放各分位数之间的非线性动态。研究结果表明,可再生能源消费和能源强度对不同排放水平的二氧化碳排放产生不同的影响,在较低的分位数中观察到的影响最为明显。该研究强调,在制定减缓排放政策时,必须考虑到区域和部门差异。报告强调了中国正在进行的向可再生能源转型、提高能效以及针对特定地区的政策干预的重要性,特别是在高排放地区。这些见解有助于新兴经济体可持续发展的论述,为政策制定者提供了实际意义,并为未来的研究提供了途径,特别是在二氧化碳排放的区域差异和经济决定因素方面。
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引用次数: 0
Early Cretaceous–Late Miocene Basin–Mountains Pattern in the Northeastern Margin of the Tibetan Plateau, NW China: Evidence From Detrital Zircon Chronology in the Lanzhou Basin 青藏高原东北缘早白垩世-晚中新世盆山格局:兰州盆地碎屑锆石年代学证据
IF 2.2 4区 地球科学 Q3 GEOSCIENCES, MULTIDISCIPLINARY Pub Date : 2025-05-11 DOI: 10.1002/gj.5219
Hang Liu, Hu–jun Gong, Fen–hong Luo, Rui Zhang

The basin-mountain tectonic system along the northeastern margin of the Tibetan Plateau represents a structural signature formed through Cenozoic collision between the Indian and Eurasian plates and subsequent tectonic adjustments, though the mechanisms controlling its tectonic deformation and uplift remain subjects of ongoing scientific debate. The Cenozoic sedimentary sequences preserved in the Lanzhou Basin provide critical archives documenting both provenance variations and tectonic evolution of adjacent orogenic belts. In this study, we employed detrital zircon U–Pb geochronology combined with bulk sediment geochemical analysis (major and trace elements) to reconstruct source-to-sink relationships. Quantitative provenance discrimination was achieved through DZmix and DZstats modelling to determine relative contributions from potential source terrains. Analysis of the modelling results showed that During the Early Cretaceous and Late Palaeocene, the Indo-Eurasian collision affected the West Qinling (50.3% contribution) and North Qilian (34.6%) orogen belts. A significant provenance shift occurred during the Eocene when large-scale planation surfaces developed across the northeastern Tibetan Plateau margin, resulting in complete cessation of West Qinling-derived sediments (3% contribution) to the Lanzhou Basin. Subsequent Early Oligocene stratigraphic records indicate resurgent West Qinling input (31%), marking its secondary uplift phase. Multiphase uplift-denudation cycles characterised both Qilian and West Qinling domains throughout the Early Cretaceous to Late Miocene. Notably, spatiotemporal disparities emerged between North and South Qilian uplift histories, with differential exhumation timing and sediment routing generating distinct provenance signatures in basin fills.

青藏高原东北缘的盆山构造系统代表了新生代印度板块与欧亚板块碰撞及随后的构造调整形成的构造特征,尽管其构造变形和隆升的控制机制仍是科学界争论的主题。兰州盆地保存的新生代沉积层序为记录邻近造山带的物源变化和构造演化提供了重要的档案。在本研究中,我们采用碎屑锆石U-Pb年代学方法结合大块沉积物地球化学分析(主要元素和微量元素)重建源-汇关系。通过DZmix和DZstats建模来确定潜在源区的相对贡献,实现了定量的物源判别。模拟结果分析表明,早白垩世至晚古新世,印-欧亚碰撞对西秦岭造山带和北祁连造山带分别产生了50.3%和34.6%的影响。始新世青藏高原东北缘大规模夷平面发育,导致西秦岭源沉积物对兰州盆地的贡献(3%)完全停止。随后的早渐新世地层记录表明西秦岭输入再次出现(31%),标志着其次生隆升阶段。早白垩世至晚中新世,祁连域和西秦岭域均具有多期隆升-剥蚀旋回特征。值得注意的是,祁连南北隆升历史存在时空差异,不同的挖掘时间和沉积物路径在盆地充填中产生了不同的物源特征。
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引用次数: 0
Recovery of Rare Earth Elements (REEs) From Different Sources of E-Waste and Their Potential Applications: A Focused Review 从不同来源的电子垃圾中回收稀土元素及其潜在应用综述
IF 2.2 4区 地球科学 Q3 GEOSCIENCES, MULTIDISCIPLINARY Pub Date : 2025-05-11 DOI: 10.1002/gj.5207
Rohit Kumar Dev, Shiv Narayan Yadav, Nisha Magar, Srijana Ghimire, Mahima Koirala, Rijan Giri, Ashok Kumar Das, Sujit Kumar Shah, Ramesh L. Gardas, Ajaya Bhattarai

The rapid use of electrical and electronic devices due to their wide applications in various fields produces a large amount of e-waste (electronic waste) in the modern world. To overcome this problem, there is a need to recycle the used product into useful products from e-waste. Therefore, this approach is essential for the development of advanced technologies for the recovery and separation of REEs (rare earth elements) from e-waste. Here, REEs are sometimes referred to as the “vitamins” of the modern industry. E-waste can contribute significantly to REE pollution since it is frequently handled hazardously and contains high amounts of REEs. Apart from the harmful effects on the environment, these wastes also destroy precious materials such as gold, silver, copper, platinum, palladium, and rare earth elements. Every year, 50 million tons of e-waste is generated worldwide. A large amount of e-waste goes to waste as only 20% of it is handled properly worldwide. The various approaches, including bioleaching, biosorption, siderophores, pyrometallurgical, and hydrometallurgical processes, have been reported in numerous studies on the recovery and separation of rare earth elements (REEs) from electronic waste. This review paper provides an overview of the introduction, characteristics, sources, and applications of clean and green energy technologies. The current pathways for REEs production and recovery point out significant deficiencies in methods currently in use and emphasise areas where multidisciplinary research may lead to more practical solutions. A summary also provides the impact of e-waste on health and the environment. The challenges, research gap, and future directions and suggestions are reported at the end of this review paper.

电子电气设备由于其在各个领域的广泛应用而迅速使用,在现代世界产生了大量的电子废物(电子废物)。为了克服这个问题,有必要从电子废物中回收使用过的产品,使其成为有用的产品。因此,这种方法对于开发从电子垃圾中回收和分离稀土元素的先进技术至关重要。在这里,稀土元素有时被称为现代工业的“维生素”。电子垃圾会对稀土污染产生重大影响,因为它经常被危险地处理,并且含有大量的稀土元素。除了对环境造成有害影响外,这些废物还破坏了金、银、铜、铂、钯和稀土元素等珍贵材料。全球每年产生5000万吨电子垃圾。全球只有20%的电子垃圾得到妥善处理,因此大量的电子垃圾被浪费。从电子废物中回收和分离稀土元素的各种方法,包括生物浸出、生物吸附、铁载体、火法冶金和湿法冶金等,已经在许多研究中得到了报道。本文综述了清洁和绿色能源技术的介绍、特点、来源和应用。目前稀土生产和回收的途径指出了目前使用的方法的重大缺陷,并强调了多学科研究可能导致更实际解决方案的领域。摘要还提供了电子废物对健康和环境的影响。本文最后提出了面临的挑战、研究差距以及未来的发展方向和建议。
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引用次数: 0
In-Depth Analysis of the Effects of Temperature–Pressure and Degree of Hydration on the Mechanical Properties of Montmorillonite: Insights From Molecular Dynamics Simulations 温度-压力和水化程度对蒙脱土力学性能影响的深入分析:来自分子动力学模拟的见解
IF 2.2 4区 地球科学 Q3 GEOSCIENCES, MULTIDISCIPLINARY Pub Date : 2025-05-08 DOI: 10.1002/gj.5204
Xiaobin Yang, Junqing Chen, Yuying Wang, Hong Pang, Kanyuan Shi, Bingyao Li, Xungang Huo

Shale oil and gas, as an essential type of unconventional oil and gas resources, and compressibility is one of the most critical aspects of shale oil and gas exploration and development. Elastic parameters have a significant impact on the compressibility of shale. Montmorillonite is one of the typical clay minerals in shale, and its microstructure has unique characteristics. When encountering water underground, it is effortless to expand. Therefore, the study of the mechanical properties of montmorillonite is crucial. This study is based on molecular dynamics simulation to establish Na-montmorillonite with different hydration degrees, change its temperature and pressure, conduct comprehensive research and comparison by combining the elasticity parameter of montmorillonite with different hydration degrees, and explain the micro mechanism of its impact. Simulation results display that the mechanical properties of hydrated montmorillonite are negatively correlated with temperature. There is a positive correlation with pressure. As the degree of hydration increases, the mechanical properties of montmorillonite decrease. The mechanical properties of montmorillonite are anisotropic. The factors that play a leading role in the stage of temperature, pressure and hydration degree under micro and macro conditions are studied. This research achievement has guiding significance for the comprehensive understanding of montmorillonite and the elastic parameters of shale at the micro level.

页岩油气作为非常规油气资源的重要类型,其可压缩性是页岩油气勘探开发的关键环节之一。弹性参数对页岩的可压缩性影响较大。蒙脱石是页岩中典型的粘土矿物之一,其微观结构具有独特的特点。遇到地下有水,就毫不费力地膨胀起来。因此,研究蒙脱土的力学性能至关重要。本研究基于分子动力学模拟,建立不同水化程度的na -蒙脱土,改变其温度和压力,结合不同水化程度蒙脱土的弹性参数进行综合研究和比较,并解释其影响的微观机理。模拟结果表明,水合蒙脱土的力学性能与温度呈负相关。与压力呈正相关。随着水化程度的增加,蒙脱土的力学性能降低。蒙脱土的力学性能具有各向异性。研究了微观和宏观条件下温度、压力和水化程度阶段起主导作用的因素。该研究成果对全面认识蒙脱石和页岩微观弹性参数具有指导意义。
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引用次数: 0
Constraining the Origin of Primary Magma in Barren Island and Narcondam of Andaman Subduction Zone, NE Indian Ocean Using Arc Basalt Simulator 5 (ABS5) 利用Arc玄武岩模拟器5 (ABS5)约束印度洋东北部安达曼俯冲带贫岛和纳尔康达原生岩浆的成因
IF 2.2 4区 地球科学 Q3 GEOSCIENCES, MULTIDISCIPLINARY Pub Date : 2025-05-06 DOI: 10.1002/gj.5223
Bhagyashree Doley, Abhishek Saha

This review presents new insights on the origin of primary arc magma and its geochemical signatures in the Barren Island and Narcondam using Arc Basalt Simulator 5 (ABS5). Barren Island rocks are basalt to basaltic andesite showing tholeiitic composition, while Narcondam is mostly andesite showing calc-alkaline composition. ABS5 indicates that slab dehydration and P–T conditions were similar, and slab liquid uptake was highest from the altered oceanic crust, followed by sediment and mantle wedge coupled to slab top. Unlike trace elements, the 87Sr/86Sr–143Nd/144Nd ratios of the slab liquid show a depleted signature in Barren Island compared with Narcondam, due to R% (reactivity between solid and liquid in the slab). The initial mantle composition in the Barren Island and Narcondam indicates prior melt extraction of < 0.5%–1.5%. Barren Island shows lower β% (fraction of slab liquid in the partial melt) than Narcondam. The H2O content in slab liquid was slightly higher in Barren Island (7.3–8.6 wt%) than Narcondam (5.5–6.8 wt%). Accordingly, the degree of partial melting (F = 10.9%–20.20% in Barren Island, F = 5.3%–10.5% in Narcondam) and total melt productivity (%) were higher in Barren Island compared with Narcondam. ABS5 indicates that the slab liquid contributed LILE, LREE, Th, U and 87Sr/86Sr-143Nd/144Nd, while the mantle melts contributed HFSE, MREE, HREE, Y143Nd/144Nd in Barren Island and Narcondam. ABS5 indicates that the total melt production (%), H2O content in slab liquid and mantle wedge were higher in post-caldera than in pre-caldera rocks.

本文利用arc玄武岩模拟器5 (ABS5)对巴伦岛和纳尔康丹地区原生弧岩浆的成因及其地球化学特征进行了新的认识。荒岛岩主要为玄武岩-玄武岩安山岩,表现为拉斑岩成分;纳尔康达岩主要为钙碱性安山岩成分。ABS5表明,陆块脱水和P-T条件相似,陆块吸收量最大的是蚀变洋壳,其次是与陆块顶部耦合的沉积物和地幔楔。与微量元素不同的是,由于R%(板岩中固液反应活性)的影响,巴伦岛的板岩液87Sr/ 86Sr-143Nd /144Nd的比值明显低于纳尔康达姆。巴伦岛和纳尔康丹的初始地幔成分表明,先前的熔融萃取为<; 0.5%-1.5%。不毛岛的β%(部分熔体中板状液体的比例)比那康达低。在巴仑岛,平板液中H2O的含量(7.3-8.6 wt%)略高于那康当(5.5-6.8 wt%)。因此,barrenisland的部分熔化程度(F = 10.9% ~ 20.20%)和Narcondam的总熔体生产率(%)均高于Narcondam。ABS5表明,在Barren Island和Narcondam地区,板块液体贡献了LILE、LREE、Th、U和87Sr/86Sr-143Nd/144Nd,而地幔熔体贡献了HFSE、MREE、HREE和Y143Nd/144Nd。ABS5表明,破火山口后岩石的总熔体产量(%)、板液和地幔楔中的H2O含量均高于破火山口前岩石。
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引用次数: 0
Characteristics and Mechanisms of Hydrocarbon Accumulation in Tight Oil Reservoirs of the Carboniferous Kalagang Formation, Malang Sag, Santanghu Basin, China 三塘湖盆马郎凹陷石炭系卡拉岗组致密油成藏特征及成藏机制
IF 2.2 4区 地球科学 Q3 GEOSCIENCES, MULTIDISCIPLINARY Pub Date : 2025-05-06 DOI: 10.1002/gj.5225
Weiming Wang, Tingting Li, Bin Yang, Xiongfei Xu, Zhichao Zhou, Shuxia Zhang, Changsheng Miao

As hydrocarbon exploration progresses in the Santanghu Basin, tight oil reservoirs in Carboniferous volcanic rocks have become a focal point for exploration and development efforts. This study aims to account for significant industrial oil flow from the tight tuff layers of the Kalagang Formation in well blocks Ma 71 to 33 in the Malang Sag within the basin. Through experiments including organic carbon analysis, rock pyrolysis, and nuclear magnetic resonance (NMR), this study systematically investigated the principal characteristics and determinants of the tight oil reservoirs, culminating in the development of hydrocarbon modes, thus providing a reference for tight oil exploration and production in the study area. The results indicate that the Kalagang Formation is composed predominantly of tuff, especially vitric tuff. The storage spaces of this formation include dissolution pores, tectonic fractures, and dissolution fractures, with devitrification pores less common. Compaction plays a crucial role in rendering the tuff reservoirs tight. Nevertheless, differentiated diagenetic alterations have improved the microscopic storage spaces and their interconnectivity. Well blocks Ma 3301 and Ma 33, having undergone significant weathering (leaching), exhibit superior reservoir physical properties and connectivity compared to well blocks Ma 71 and Ma 73. In contrast, well blocks Ma 71 and Ma 73 experienced more significant alterations due to organic acid dissolution and devitrification under the influence of source rock types and hydrocarbon generation. The comprehensive analysis indicates that tight oil reservoirs in the Malang Sag were formed due to the close superimposition of source rocks and reservoirs, along with the effective connection of source rock-rooted faults. This results in the formation of two sets of proximal tight tuff reservoirs with the ‘lower-source rock and upper-reservoir’ and ‘self-sourced reservoir’ modes.

随着三塘湖盆地油气勘探的深入,石炭系火山岩致密油已成为勘探开发的重点。本研究旨在解释盆地内马郎凹陷马71 ~马33井区卡拉冈组致密凝灰岩层的重要工业油流。通过有机碳分析、岩石热解、核磁共振等实验,系统研究了致密油储集层的主要特征和决定因素,最终得出了烃成藏模式的发展规律,为研究区致密油勘探开发提供了参考依据。结果表明,喀拉岗组以凝灰岩为主,以玻璃凝灰岩为主。储层空间包括溶蚀孔隙、构造裂缝和溶蚀裂缝,脱硝孔隙较少。压实作用对凝灰岩储层致密化起着至关重要的作用。然而,分化的成岩改变改善了微观储集空间和它们之间的连通性。与Ma 71和Ma 73井区块相比,Ma 3301和Ma 33井区块经历了明显的风化(淋溶),表现出更优越的储层物性和连通性。在烃源岩类型和生烃作用的影响下,马71和马73井区由于有机酸溶解和脱硝作用而发生了更为显著的变化。综合分析认为,麻郎凹陷致密油储层是烃源岩与储层紧密叠加,烃源岩断裂有效连接的结果。形成了“下源上储”和“自源”两套近端致密凝灰岩储层。
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引用次数: 0
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Geological Journal
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