The Feidong Complex, located on the northeastern margin of the Yangtze Craton, exposes Precambrian basement rocks and is the subject of debate regarding its tectonic affinity. In this study, we conducted in situ U–Pb dating and Hf isotope analyses of zircons from basement rocks within the Feidong Complex. The results reveal crystallisation ages of ca. 2.45, 2.0 and 0.8 Ga for the granitic gneiss, amphibole biotite plagiogneiss and mylonitised monzonitic granite, respectively. The basement rocks with ages of ca. 2.45 and 2.0 Ga exhibit negative zircon εHf(t) values (−10.48 to −0.13) and older two-stage model ages (TDM2 = 2974 to 3296 Ma). We compared the zircon U–Pb ages and Hf isotopic characteristics of the basement rocks from the Feidong Complex with those of the southern margin of the North China Craton and the northern margin of the Yangtze Craton. Additionally, we also compared the metamorphic grades of rocks between the Feidong Complex and Susong Complex of the Dabie orogenic belt. We found that the Feidong Complex and the northern margin of Yangtze Craton share comparable zircon U–Pb ages and Hf isotopic characteristics. However, the metamorphic grades of the Feidong Complex were distinct from those of the Susong Complex. In particular, the basement rocks with an age of ca. 2.45 Ga formed within a subduction setting; those with an age of ca. 2.0 Ga formed during the subduction and collision associated with the assembly of the Columbia supercontinent; and those with an age of ca. 0.8 Ga experienced extensional processes before the breakup of the Rodinia supercontinent.
{"title":"Tectonic affinity and geological significance of the Feidong Complex in the northeastern margin of the Yangtze Craton: Evidence from zircon U–Pb and Lu–Hf isotopes of the basement rocks","authors":"Shouwen Chen, Jiahao Li, Feng Yuan, Yufeng Deng, Chuanzhong Song, Gang Zhang","doi":"10.1002/gj.5018","DOIUrl":"10.1002/gj.5018","url":null,"abstract":"<p>The Feidong Complex, located on the northeastern margin of the Yangtze Craton, exposes Precambrian basement rocks and is the subject of debate regarding its tectonic affinity. In this study, we conducted in situ U–Pb dating and Hf isotope analyses of zircons from basement rocks within the Feidong Complex. The results reveal crystallisation ages of ca. 2.45, 2.0 and 0.8 Ga for the granitic gneiss, amphibole biotite plagiogneiss and mylonitised monzonitic granite, respectively. The basement rocks with ages of ca. 2.45 and 2.0 Ga exhibit negative zircon ε<sub>Hf</sub>(t) values (−10.48 to −0.13) and older two-stage model ages (T<sub>DM2</sub> = 2974 to 3296 Ma). We compared the zircon U–Pb ages and Hf isotopic characteristics of the basement rocks from the Feidong Complex with those of the southern margin of the North China Craton and the northern margin of the Yangtze Craton. Additionally, we also compared the metamorphic grades of rocks between the Feidong Complex and Susong Complex of the Dabie orogenic belt. We found that the Feidong Complex and the northern margin of Yangtze Craton share comparable zircon U–Pb ages and Hf isotopic characteristics. However, the metamorphic grades of the Feidong Complex were distinct from those of the Susong Complex. In particular, the basement rocks with an age of ca. 2.45 Ga formed within a subduction setting; those with an age of ca. 2.0 Ga formed during the subduction and collision associated with the assembly of the Columbia supercontinent; and those with an age of ca. 0.8 Ga experienced extensional processes before the breakup of the Rodinia supercontinent.</p>","PeriodicalId":12784,"journal":{"name":"Geological Journal","volume":"59 8","pages":"2319-2335"},"PeriodicalIF":1.4,"publicationDate":"2024-06-27","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"141506352","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"地球科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Tunnel waste constitutes a prevalent by-product of highway construction in high-altitude mountainous and hilly regions. Sulphide minerals exhibit a unique distribution pattern within the alpine hills. Consequently, tunnel excavation can disrupt the stability of these sulphide minerals, rendering the tunnel waste susceptible to generating secondary environmental hazards during stockpiling. This research delves into the migration and transformation dynamics of potential environmental pollutants in tunnel waste through geoenvironmental simulation techniques. Controlled variables were employed to simulate various conditions, including surface illumination, internal anaerobiosis, water content and aerobic environments. The study's findings indicate that the presence of pyrite in the waste stream primarily drives the secondary contamination of the tunnel waste. Pyrite within the slag tends to react and form sulphuric acid in the stockpile environment, thus creating an acidic milieu that exacerbates the release of existing contaminants. The emergence of an anaerobic environment and a photocatalytic system composed of Fe/Ti substances in the waste stream serves to further accelerate pollutant release. This study thoroughly investigates the primary causes of environmental pollution during the stockpiling of tunnel slag and assesses the potential environmental impact scenarios. The outcomes of this research offer substantial theoretical and empirical support for the management of slag generated during the tunnel construction process.
{"title":"Synergistic mechanism of physical chemistry and acid bacteria: Product evolution of sulphides during tunnel mining","authors":"Minjie He, Yuanchuan Ren, Guangfei Qu, Junyan Li, Caiyue Jin, Ye Liu, Linrui Kuang","doi":"10.1002/gj.5016","DOIUrl":"10.1002/gj.5016","url":null,"abstract":"<p>Tunnel waste constitutes a prevalent by-product of highway construction in high-altitude mountainous and hilly regions. Sulphide minerals exhibit a unique distribution pattern within the alpine hills. Consequently, tunnel excavation can disrupt the stability of these sulphide minerals, rendering the tunnel waste susceptible to generating secondary environmental hazards during stockpiling. This research delves into the migration and transformation dynamics of potential environmental pollutants in tunnel waste through geoenvironmental simulation techniques. Controlled variables were employed to simulate various conditions, including surface illumination, internal anaerobiosis, water content and aerobic environments. The study's findings indicate that the presence of pyrite in the waste stream primarily drives the secondary contamination of the tunnel waste. Pyrite within the slag tends to react and form sulphuric acid in the stockpile environment, thus creating an acidic milieu that exacerbates the release of existing contaminants. The emergence of an anaerobic environment and a photocatalytic system composed of Fe/Ti substances in the waste stream serves to further accelerate pollutant release. This study thoroughly investigates the primary causes of environmental pollution during the stockpiling of tunnel slag and assesses the potential environmental impact scenarios. The outcomes of this research offer substantial theoretical and empirical support for the management of slag generated during the tunnel construction process.</p>","PeriodicalId":12784,"journal":{"name":"Geological Journal","volume":"59 8","pages":"2304-2318"},"PeriodicalIF":1.4,"publicationDate":"2024-06-26","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"141506321","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"地球科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
The coal-bearing series of the Eocene Pinghu Formation is one of the focused reservoir exploration in the Xihu Sag. This study conducted a cyclostratigraphy time series analysis using natural gamma-ray (GR) logging data from four boreholes of the Xihu Sag. The spectral analysis shows a good match with the La2004 orbital solution. The sedimentation duration calculated by the astronomical age models spans at least 4.31–5.94 Myr, with an average sedimentation rate of 13.47–18.57 cm/kyr. The Pinghu Formation is subdivided into 1 second-order, 3 third-order and 14 fourth-order sequences within seismic, well logging and 405 kyr-long cycles constraints. Based on available age-control data, the Pinghu Formation is corresponding to the middle-late Eocene. The floating astronomical timescale of XH-3 borehole now provides a new age constraint for the Pinghu Formation. There are four shorter-term (<2 Myr) regional sea-level cycles in the Pinghu Formation, which are similar to the calibrated global sea-level fluctuations. Inconsistencies between reconstructed sea-level curve by sedimentary noise modelling and true sea level inferred from lithology and sequence reveal various sources of noise in the sedimentary record. Variations in the distribution and thickness of coal seams in the Pinghu Formation appear to be a stratigraphic response to astronomical and non-astronomical forcing such as regional tectonicssm and facies changes.
{"title":"Astronomical forcing in Eocene coal-bearing series: A case study from the Pinghu Formation in Xihu Sag, East China Sea Shelf Basin","authors":"Tianchang Zhang, Lanzhi Qin, Longyi Shao, Shilong Kang, Shuxia Li, Xingyu Dang, Wenchao Shen, Qianyu Zhou","doi":"10.1002/gj.5006","DOIUrl":"10.1002/gj.5006","url":null,"abstract":"<p>The coal-bearing series of the Eocene Pinghu Formation is one of the focused reservoir exploration in the Xihu Sag. This study conducted a cyclostratigraphy time series analysis using natural gamma-ray (GR) logging data from four boreholes of the Xihu Sag. The spectral analysis shows a good match with the La2004 orbital solution. The sedimentation duration calculated by the astronomical age models spans at least 4.31–5.94 Myr, with an average sedimentation rate of 13.47–18.57 cm/kyr. The Pinghu Formation is subdivided into 1 second-order, 3 third-order and 14 fourth-order sequences within seismic, well logging and 405 kyr-long cycles constraints. Based on available age-control data, the Pinghu Formation is corresponding to the middle-late Eocene. The floating astronomical timescale of XH-3 borehole now provides a new age constraint for the Pinghu Formation. There are four shorter-term (<2 Myr) regional sea-level cycles in the Pinghu Formation, which are similar to the calibrated global sea-level fluctuations. Inconsistencies between reconstructed sea-level curve by sedimentary noise modelling and true sea level inferred from lithology and sequence reveal various sources of noise in the sedimentary record. Variations in the distribution and thickness of coal seams in the Pinghu Formation appear to be a stratigraphic response to astronomical and non-astronomical forcing such as regional tectonicssm and facies changes.</p>","PeriodicalId":12784,"journal":{"name":"Geological Journal","volume":"60 2","pages":"240-252"},"PeriodicalIF":1.4,"publicationDate":"2024-06-26","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"141514227","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"地球科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Based on pressure test data, well logging data and geological conditions, the distribution and cause of overpressure in the western Qaidam Basin are analysed. The contribution of different overpressure causes is quantified, and the main controlling factors of overpressure at different evolution stages are further divided. This is useful for analysing the pressure state in different geological historical periods and indicating the direction of oil and gas migration. The research results show that the formation pressure coefficient in the western part of the Qaidam Basin is mainly in the range of 0.5–2.1, and the pressure coefficient generally decreases from the depression to the edge. According to the stress variation characteristics and logging response of overpressure, two models of acoustic travel time-vertical effective stress and electrical resistivity-vertical effective stress are established to identify and quantify the cause of overpressure for loading and unloading. Through the analysis of logging curves, acoustic velocity-density cross-plot and geological conditions, the causes of overpressure in western Qaidam Basin was clarified. The overpressure calculation results of different origins show that the main controlling factors of overpressure in the Kunbei fault stage are disequilibrium compaction and tectonic extrusion, with contribution rates of 38% and 52%, respectively. The overpressure in Mangya depression is caused by disequilibrium compaction, tectonic extrusion and hydrocarbon generation, with overpressure ratios of 30%, 32% and 38% respectively. The overpressure of the Dafengshan uplift can contribute up to 53% of the disequilibrium compaction, and the contributions of tectonic extrusion and hydrocarbon generation are 28% and 19%, respectively. Finally, the evolution of residual pressure in the upper segment of the Xiaganchaigou Formation () in western Qaidam Basin can be divided into four evolution stages: undercompaction stage (42.8–40.5 MPa), normal compaction stage (40.5–12.0 MPa), hydrocarbon generation pressurization stage (12.0–2.8 Ma) and pressure release stage (2.8 Ma-present).
{"title":"Distribution, origin and evolution of overpressure in the Paleogene and Neogene in the Western Qaidam Basin, northwestern China","authors":"Taozheng Yang, Chenglin Liu, Pei Li, Jixian Tian, Rizwan Sarwar Awan, Haipeng Li, Dehao Feng, Yuping Wu, Guoxiong Li, Qibiao Zang","doi":"10.1002/gj.5009","DOIUrl":"10.1002/gj.5009","url":null,"abstract":"<p>Based on pressure test data, well logging data and geological conditions, the distribution and cause of overpressure in the western Qaidam Basin are analysed. The contribution of different overpressure causes is quantified, and the main controlling factors of overpressure at different evolution stages are further divided. This is useful for analysing the pressure state in different geological historical periods and indicating the direction of oil and gas migration. The research results show that the formation pressure coefficient in the western part of the Qaidam Basin is mainly in the range of 0.5–2.1, and the pressure coefficient generally decreases from the depression to the edge. According to the stress variation characteristics and logging response of overpressure, two models of acoustic travel time-vertical effective stress and electrical resistivity-vertical effective stress are established to identify and quantify the cause of overpressure for loading and unloading. Through the analysis of logging curves, acoustic velocity-density cross-plot and geological conditions, the causes of overpressure in western Qaidam Basin was clarified. The overpressure calculation results of different origins show that the main controlling factors of overpressure in the Kunbei fault stage are disequilibrium compaction and tectonic extrusion, with contribution rates of 38% and 52%, respectively. The overpressure in Mangya depression is caused by disequilibrium compaction, tectonic extrusion and hydrocarbon generation, with overpressure ratios of 30%, 32% and 38% respectively. The overpressure of the Dafengshan uplift can contribute up to 53% of the disequilibrium compaction, and the contributions of tectonic extrusion and hydrocarbon generation are 28% and 19%, respectively. Finally, the evolution of residual pressure in the upper segment of the Xiaganchaigou Formation (<span></span><math>\u0000 <mrow>\u0000 <msup>\u0000 <msub>\u0000 <mi>E</mi>\u0000 <mn>3</mn>\u0000 </msub>\u0000 <mn>2</mn>\u0000 </msup>\u0000 </mrow></math>) in western Qaidam Basin can be divided into four evolution stages: undercompaction stage (42.8–40.5 MPa), normal compaction stage (40.5–12.0 MPa), hydrocarbon generation pressurization stage (12.0–2.8 Ma) and pressure release stage (2.8 Ma-present).</p>","PeriodicalId":12784,"journal":{"name":"Geological Journal","volume":"59 8","pages":"2225-2242"},"PeriodicalIF":1.4,"publicationDate":"2024-06-26","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"141514228","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"地球科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
A flare-up of granitoids occurred at 465–445 Ma in the South Altyn Tagh, synchronously with the exhumation of subducted continental crust. Nevertheless, it remains enigmatic whether a petrogenetic connection exists between them. Here, we report a 454–451 Ma monzogranite pluton, which is characterized by abundant inherited zircons, located in the northern margin of the South Altyn Tagh high-pressure (HP)—ultrahigh-pressure (UHP) metamorphic terrane. U–Pb ages and Hf–O isotopic compositions of inherited and synmagmatic zircons are investigated to trace the source rocks and petrogenesis of this pluton. The inherited zircons (zircons that predate the magmatism) exhibit a wide range of ages from 2618 to 484 Ma, displaying three major peaks at 1800–1100 Ma, 1000–800 Ma and 500 Ma. By comparing these inheritance age patterns with zircon spectra of main (meta-)sedimentary sequences and the widespread Early Neoproterozoic granites (presently as granitic gneisses) in South Altyn Tagh, along with zircon εHf(t) and whole-rock Nd isotopic composition, we argue that the main source rocks of the studied monzogranite are Early Neoproterozoic granitic gneisses and Late Mesoproterozoic paragneisses from the South Altyn Tagh HP–UHP metamorphic terrane. The ca. 500 Ma inherited zircons have a metamorphic origin, which is simultaneous with the peak metamorphic ages of HP–UHP metamorphic rocks in the Altyn Tagh Complex. These observations indicate that the source rocks of the monzogranite pluton are the subducted continental crust, which underwent metamorphism at ca. 500 Ma and followed by partial melting at 454–451 Ma. In addition, synmagmatic zircons exhibit variable δ18O and εHf(t) values ranging from 5.4 to 11.7‰ and from −19 to +10.3, respectively, indicating a minor contribution of mantle-derived melts in the formation of the monzogranite. Given the studied pluton and contemporaneous extensive granitoids (465–445 Ma), characterized by similar geochemistry and source rocks, are synchronous with the final exhumation of subducted South Altyn Tagh continental crust, we propose that the reworking of exhumed continental crust at middle to lower crustal depths is their main petrogenesis.
南阿尔廷塔格地区花岗岩的爆发发生在465-445Ma,与俯冲大陆地壳的掘起同步。然而,它们之间是否存在岩石成因上的联系仍然是个谜。在此,我们报告了位于南阿尔金山高压(HP)-超高压(UHP)变质岩阶北缘的454-451 Ma单晶质岩,其特征是含有大量的继承锆石。对继承锆石和同步锆石的U-Pb年龄和Hf-O同位素组成进行了研究,以追溯该构造的源岩和成岩过程。继承锆石(岩浆活动之前的锆石)的年龄范围很广,从2618到484Ma,在1800-1100Ma、1000-800Ma和500Ma处有三个主要峰值。通过将这些继承年龄模式与南阿尔金山主要(元)沉积序列和广泛分布的早新元古代花岗岩(现为花岗片麻岩)的锆石谱进行比较,以及锆石εH和锆石εE的年龄模式,可以发现锆石εH和锆石εE的年龄范围在2618-484Ma之间、结合锆石εHf(t)和全岩钕同位素组成,我们认为所研究的单斜岩的主要源岩是南阿尔廷塔格 HP-UHP 变质地层中的早新元古代花岗片麻岩和晚中元古代片麻岩。约约 500 Ma 的继承锆石具有变质起源,与 Altyn Tagh 复合体中 HP-UHP 变质岩的变质峰值年龄同步。这些观察结果表明,单斜花岗岩柱的源岩是俯冲的大陆地壳,在大约 500 Ma 时经历了变质作用,随后在大约 500 Ma 时部分熔融。500 Ma时发生变质作用,随后在454-451 Ma时部分熔化。此外,同步锆石的δ18O和εHf(t)值各不相同,分别为5.4至11.7‰和-19至+10.3,表明地幔源熔体在形成单斜花岗岩过程中的作用较小。鉴于所研究的柱状花岗岩和同时代的大面积花岗岩(465-445 Ma)具有相似的地球化学特征和源岩,与南阿尔廷塔格大陆俯冲地壳的最终排挤同步,我们认为在地壳中下部深度对排挤出的大陆地壳进行再加工是它们的主要成岩过程。
{"title":"Middle to Late Ordovician flare-up of granitoids, South Altyn Tagh: Reworking of exhumed continental crust","authors":"Ningchao Zhou, Guochun Zhao, Jinlong Yao, Qian Liu, Yigui Han, Huishan Zhang, Guangli Ren","doi":"10.1002/gj.5003","DOIUrl":"10.1002/gj.5003","url":null,"abstract":"<p>A flare-up of granitoids occurred at 465–445 Ma in the South Altyn Tagh, synchronously with the exhumation of subducted continental crust. Nevertheless, it remains enigmatic whether a petrogenetic connection exists between them. Here, we report a 454–451 Ma monzogranite pluton, which is characterized by abundant inherited zircons, located in the northern margin of the South Altyn Tagh high-pressure (HP)—ultrahigh-pressure (UHP) metamorphic terrane. U–Pb ages and Hf–O isotopic compositions of inherited and synmagmatic zircons are investigated to trace the source rocks and petrogenesis of this pluton. The inherited zircons (zircons that predate the magmatism) exhibit a wide range of ages from 2618 to 484 Ma, displaying three major peaks at 1800–1100 Ma, 1000–800 Ma and 500 Ma. By comparing these inheritance age patterns with zircon spectra of main (meta-)sedimentary sequences and the widespread Early Neoproterozoic granites (presently as granitic gneisses) in South Altyn Tagh, along with zircon εHf(t) and whole-rock Nd isotopic composition, we argue that the main source rocks of the studied monzogranite are Early Neoproterozoic granitic gneisses and Late Mesoproterozoic paragneisses from the South Altyn Tagh HP–UHP metamorphic terrane. The ca. 500 Ma inherited zircons have a metamorphic origin, which is simultaneous with the peak metamorphic ages of HP–UHP metamorphic rocks in the Altyn Tagh Complex. These observations indicate that the source rocks of the monzogranite pluton are the subducted continental crust, which underwent metamorphism at ca. 500 Ma and followed by partial melting at 454–451 Ma. In addition, synmagmatic zircons exhibit variable δ<sup>18</sup>O and εHf(t) values ranging from 5.4 to 11.7‰ and from −19 to +10.3, respectively, indicating a minor contribution of mantle-derived melts in the formation of the monzogranite. Given the studied pluton and contemporaneous extensive granitoids (465–445 Ma), characterized by similar geochemistry and source rocks, are synchronous with the final exhumation of subducted South Altyn Tagh continental crust, we propose that the reworking of exhumed continental crust at middle to lower crustal depths is their main petrogenesis.</p>","PeriodicalId":12784,"journal":{"name":"Geological Journal","volume":"59 8","pages":"2190-2207"},"PeriodicalIF":1.4,"publicationDate":"2024-06-26","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://onlinelibrary.wiley.com/doi/epdf/10.1002/gj.5003","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"141506322","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"地球科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Faizan Ahmad Khan, Gurumurthy GP, Tripti Muguli, Mahboob Alam, Anupam Sharma
Iron speciation has emerged as a robust proxy for discerning oceanic redox conditions; nonetheless, it is subject to certain limitations. Specifically, the applicability of the degree of pyritization is contingent upon the presence of unequivocal evidence of an anoxic water column and its discriminatory capacity is limited to distinguish between ferruginous (anoxic) and euxinic conditions. This study highlights that through the integration of redox-sensitive trace metal enrichment data with Fe-speciation data, the depositional redox conditions for marine sediments can be established with greater certainty. Recently, a set of dedicated geological reference materials (BHW and WHIT) have been developed for validating the Fe-speciation analytical results for redox reconstruction studies; however, to the best of our knowledge, these reference materials are not characterized for trace and rare earth elements (REEs). In this connection, the BHW (oxic) and WHIT (anoxic) reference materials are measured for major, trace and REEs. After careful statistical considerations for these reference standards, a complete set of trace and REEs is reported. Furthermore, considering BHW and WHIT as oxic and anoxic end-members, respectively, the utility of trace metal enrichment and Fe-speciation data in combination has been discussed. The trace and REE concentrations of BHW and WHIT reported in this study will enhance their applicability as a reference material to understand ocean chemistry and the oxidation state of the ancient oceans.
{"title":"The depositional redox conditions of Fe-speciation reference materials (BHW and WHIT) using redox-sensitive trace metal enrichment","authors":"Faizan Ahmad Khan, Gurumurthy GP, Tripti Muguli, Mahboob Alam, Anupam Sharma","doi":"10.1002/gj.5014","DOIUrl":"10.1002/gj.5014","url":null,"abstract":"<p>Iron speciation has emerged as a robust proxy for discerning oceanic redox conditions; nonetheless, it is subject to certain limitations. Specifically, the applicability of the degree of pyritization is contingent upon the presence of unequivocal evidence of an anoxic water column and its discriminatory capacity is limited to distinguish between ferruginous (anoxic) and euxinic conditions. This study highlights that through the integration of redox-sensitive trace metal enrichment data with Fe-speciation data, the depositional redox conditions for marine sediments can be established with greater certainty. Recently, a set of dedicated geological reference materials (BHW and WHIT) have been developed for validating the Fe-speciation analytical results for redox reconstruction studies; however, to the best of our knowledge, these reference materials are not characterized for trace and rare earth elements (REEs). In this connection, the BHW (oxic) and WHIT (anoxic) reference materials are measured for major, trace and REEs. After careful statistical considerations for these reference standards, a complete set of trace and REEs is reported. Furthermore, considering BHW and WHIT as oxic and anoxic end-members, respectively, the utility of trace metal enrichment and Fe-speciation data in combination has been discussed. The trace and REE concentrations of BHW and WHIT reported in this study will enhance their applicability as a reference material to understand ocean chemistry and the oxidation state of the ancient oceans.</p>","PeriodicalId":12784,"journal":{"name":"Geological Journal","volume":"59 8","pages":"2266-2276"},"PeriodicalIF":1.4,"publicationDate":"2024-06-24","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"141514229","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"地球科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Junxing Zhao, Kezhang Qin, Noreen J. Evans, Tong Pan, Changtong He, Sushmita Bhandari, Tao Wang
Spodumene-bearing pegmatite dyke swarms have recently been discovered in the Chaqiabeishan area, at the northeastern margin of the Qinghai-Tibet Plateau in northwest China. In order to elucidate the connection between the Chaqiabeishan lithium pegmatites and Triassic magmatism and mineralization within the West Kunlun – Songpan -Garzê rare-metal belt, this study presents new columbite-group mineral and monazite U–Pb dating results, mineral chemistry, monazite in situ Nd isotope analyses and gamma-ray spectrometric measurements. Magmatism and mineralization at Chaqiabeishan mainly occurred ca. 216 Ma, and the mineralized pegmatites (Mn-rich columbite-group minerals, highly evolved monazite compositions and high effective uranium contents in the gamma-ray survey) were generated from the high degree of the fractional crystallization in a volatile-rich granitic magma. The source material of the Chaqiabeishan lithium pegmatites (εNd(t) values from −14.4 to −12.8) was more enriched than that of other pegmatite-type lithium deposits (Jiajika and Bailongshan) in the West Kunlun – Songpan – Garzê rare-metal belt and is ascribed to melting of ancient crustal materials in the basement. These late-Triassic mineralizing events were closely related to the collision-related tectonic setting at the northeastern margin of the Tibetan-Qinghai Plateau, a product of Paleo-Tethys Ocean closure.
{"title":"Late Triassic lithium pegmatites in Northwest China: A response to continental collision during Paleo-Tethys Ocean closure","authors":"Junxing Zhao, Kezhang Qin, Noreen J. Evans, Tong Pan, Changtong He, Sushmita Bhandari, Tao Wang","doi":"10.1002/gj.5005","DOIUrl":"10.1002/gj.5005","url":null,"abstract":"<p>Spodumene-bearing pegmatite dyke swarms have recently been discovered in the Chaqiabeishan area, at the northeastern margin of the Qinghai-Tibet Plateau in northwest China. In order to elucidate the connection between the Chaqiabeishan lithium pegmatites and Triassic magmatism and mineralization within the West Kunlun – Songpan -Garzê rare-metal belt, this study presents new columbite-group mineral and monazite U–Pb dating results, mineral chemistry, monazite in situ Nd isotope analyses and gamma-ray spectrometric measurements. Magmatism and mineralization at Chaqiabeishan mainly occurred ca. 216 Ma, and the mineralized pegmatites (Mn-rich columbite-group minerals, highly evolved monazite compositions and high effective uranium contents in the gamma-ray survey) were generated from the high degree of the fractional crystallization in a volatile-rich granitic magma. The source material of the Chaqiabeishan lithium pegmatites (ε<sub>Nd(t)</sub> values from −14.4 to −12.8) was more enriched than that of other pegmatite-type lithium deposits (Jiajika and Bailongshan) in the West Kunlun – Songpan – Garzê rare-metal belt and is ascribed to melting of ancient crustal materials in the basement. These late-Triassic mineralizing events were closely related to the collision-related tectonic setting at the northeastern margin of the Tibetan-Qinghai Plateau, a product of Paleo-Tethys Ocean closure.</p>","PeriodicalId":12784,"journal":{"name":"Geological Journal","volume":"59 8","pages":"2208-2224"},"PeriodicalIF":1.4,"publicationDate":"2024-06-23","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"141506323","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"地球科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Han Meng, Gang Mei, Xiaoyu Qi, Nengxiong Xu, Jianbing Peng
Tunnels stand as indispensable pillars of transportation infrastructure, assuming a central and transformative role in fostering the sustainable evolution of urban. The excavation process of tunnels presents a spectrum of geological challenges, encompassing the potential for instability and collapse. Ensuring the stability of the tunnel is a top priority in tunnel construction. The destabilization leading to collapse in certain tunnels is intricately connected to the structural planes of the rock mass. Accurately obtaining the distribution of structural planes within the rock mass is the necessary basis for maintaining the stability of the tunnel. The conventional Monte Carlo method generates each parameter of stochastic structural planes separately without considering the correlations between the parameters. To address this limitation, we propose a stochastic structural plane generation method based on deep generative model (DGM). The model takes the measured factual structural plane data as input, and the neural network realizes the generation of structural plane data with automatic learning of the distribution law of structural planes and the correlations between each parameters without assuming the probability distribution of stochastic structural planes in advance. This method has been used for stochastic structural plane generation of the rock mass in the Yuelongmen tunnel located in Mianyang City, Sichuan Province. The validation results show that the proposed DGM-based method automatically captures the correlation between structural plane parameters while ensuring the greater accuracy of the generated structural planes.
{"title":"Deep generative model-based generation method of stochastic structural planes of rock masses in tunnels","authors":"Han Meng, Gang Mei, Xiaoyu Qi, Nengxiong Xu, Jianbing Peng","doi":"10.1002/gj.5000","DOIUrl":"10.1002/gj.5000","url":null,"abstract":"<p>Tunnels stand as indispensable pillars of transportation infrastructure, assuming a central and transformative role in fostering the sustainable evolution of urban. The excavation process of tunnels presents a spectrum of geological challenges, encompassing the potential for instability and collapse. Ensuring the stability of the tunnel is a top priority in tunnel construction. The destabilization leading to collapse in certain tunnels is intricately connected to the structural planes of the rock mass. Accurately obtaining the distribution of structural planes within the rock mass is the necessary basis for maintaining the stability of the tunnel. The conventional Monte Carlo method generates each parameter of stochastic structural planes separately without considering the correlations between the parameters. To address this limitation, we propose a stochastic structural plane generation method based on deep generative model (DGM). The model takes the measured factual structural plane data as input, and the neural network realizes the generation of structural plane data with automatic learning of the distribution law of structural planes and the correlations between each parameters without assuming the probability distribution of stochastic structural planes in advance. This method has been used for stochastic structural plane generation of the rock mass in the Yuelongmen tunnel located in Mianyang City, Sichuan Province. The validation results show that the proposed DGM-based method automatically captures the correlation between structural plane parameters while ensuring the greater accuracy of the generated structural planes.</p>","PeriodicalId":12784,"journal":{"name":"Geological Journal","volume":"59 9","pages":"2566-2583"},"PeriodicalIF":1.4,"publicationDate":"2024-06-23","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"141514230","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"地球科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Fouzi Mancer, Alaoua Bouaicha, Marcin Chwała, Abdelhak Mabrouki
Skirted foundations are critical components in offshore applications where combined loads are common in deep-water environments. Their ultimate capacity under VH (vertical-horizontal) combined loading is traditionally determined using VH failure envelopes, which are primarily constructed using numerical methods. These methodologies, however, frequently ignore the spatial variability inherent in seabed soils due to geological formations. This paper investigates the effect of spatial variability of undrained shear strength and embedment ratio impact on the capacity of skirted foundations subjected to VH combined loading. For this, OptumG2 software is used to perform Monte Carlo simulation combined with random finite element limit analysis. This paper investigates the stochastic analysis of bearing capacity and failure envelopes, with a particular emphasis on understanding the effect of spatial correlation on undrained shear strength. The study focuses on the horizontal scale of fluctuation and the soil strength heterogeneity index, shedding insight on previously undiscovered areas. Novel findings highlight how a rigid base affects VH failure envelopes and offer insights into evaluating the vertical bearing capacity of skirted foundations. [Correction added on 8 July 2024, after first online publication: The above statement has been updated in this version.]
{"title":"Probabilistic assessment of bearing capacity of skirted foundation under combined loadings with a rigid base","authors":"Fouzi Mancer, Alaoua Bouaicha, Marcin Chwała, Abdelhak Mabrouki","doi":"10.1002/gj.5008","DOIUrl":"10.1002/gj.5008","url":null,"abstract":"<p>Skirted foundations are critical components in offshore applications where combined loads are common in deep-water environments. Their ultimate capacity under <i>VH</i> (vertical-horizontal) combined loading is traditionally determined using <i>VH</i> failure envelopes, which are primarily constructed using numerical methods. These methodologies, however, frequently ignore the spatial variability inherent in seabed soils due to geological formations. This paper investigates the effect of spatial variability of undrained shear strength and embedment ratio impact on the capacity of skirted foundations subjected to <i>VH</i> combined loading. For this, <i>OptumG2</i> software is used to perform Monte Carlo simulation combined with random finite element limit analysis. This paper investigates the stochastic analysis of bearing capacity and failure envelopes, with a particular emphasis on understanding the effect of spatial correlation on undrained shear strength. The study focuses on the horizontal scale of fluctuation and the soil strength heterogeneity index, shedding insight on previously undiscovered areas. Novel findings highlight how a rigid base affects <i>VH</i> failure envelopes and offer insights into evaluating the vertical bearing capacity of skirted foundations. [Correction added on 8 July 2024, after first online publication: The above statement has been updated in this version.]</p>","PeriodicalId":12784,"journal":{"name":"Geological Journal","volume":"59 9","pages":"2609-2622"},"PeriodicalIF":1.4,"publicationDate":"2024-06-20","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"141514231","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"地球科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Shima Shomali, Mansour Ghorbani, Mohammad R. Ghassemi, Ehsan Moosavi, Jiri Slama
The Neotethyan Sanandaj–Sirjan Zone of western Iran has recorded major magmatic activities due to its continental arc tectonic setting during the Mesozoic. The Varcheh mafic intrusions were less-studied plutons in the northern Sanandaj–Sirjan Zone (SSZ). Field evidence, petrography, geochemistry and U–Pb geochronological data were used to determine petrographic composition, geochemical nature, crystallization age and also to suggest a conceptual tectonomagmatic model for their emplacement. Small plutonic bodies are dominantly composed of monzogabbro that have intruded into the Cretaceous sedimentary rocks. Based on U–Pb zircon datings, these rocks have crystallized at 125–118 Ma in late Early Cretaceous (Barremian–Aptian), and are older than the supposed ages reported on geological maps. Varcheh rocks are not just typical calc-alkaline rocks and some show alkaline affinity. Negative anomalies in Nb–Ta–Ti and enrichments in some large-ion lithophile elements on spider diagrams are consistent with a subduction-zone setting. Potential deep source for magma generation is partial melting of subcontinental lithospheric mantle wedge above a subducting slab of oceanic lithosphere. The spaces for the Varcheh mafic intrusions are accommodated by dominant dextral strike-slip movement in a continental arc experiencing extension during late Early Cretaceous subduction. According to the zircon U–Pb geochronology results in this paper and previous U–Pb ages in the northern part of the SSZ, the mid-Cretaceous magmatism reveals a significant NW-ward younging trend and migration of the magmatic arc from the Barremian–Aptian in south-east to the Albian–Cenomanian in the north-west.
由于中生代期间的大陆弧构造环境,伊朗西部新近纪的萨南达季-锡尔詹区曾发生过重大岩浆活动。瓦尔切岩浆侵入体是萨南达季-锡尔詹地区(SSZ)北部研究较少的岩浆侵入体。研究人员利用实地证据、岩相学、地球化学和铀-铅地质年代数据确定了岩相成分、地球化学性质、结晶年龄,并提出了关于其成因的构造地质学概念模型。小块岩体主要由侵入白垩纪沉积岩的单斜辉长岩组成。根据锆石 U-Pb 定期测定,这些岩石结晶于 125-118 Ma 早白垩世晚期(巴里米亚-安普顿),比地质图上报告的假定年龄要早。瓦尔切岩石不仅仅是典型的钙碱性岩石,其中一些还显示出碱性亲和性。蛛网图上的铌-钽-钛负异常和一些大离子亲岩元素的富集与俯冲带环境一致。岩浆生成的潜在深部来源是俯冲板块海洋岩石圈上方的次大陆岩石圈地幔楔的部分熔融。在早白垩世晚期的俯冲过程中,大陆弧经历了伸展,其主要的右旋走向滑动运动为瓦尔谢岩浆侵入体提供了空间。根据本文的锆石U-Pb地质年代结果和以往在SSZ北部地区的U-Pb年龄,白垩纪中期的岩浆活动显示出明显的向西北年轻化趋势,岩浆弧从东南部的巴里米安-中页纪迁移到西北部的阿尔比安-仙人掌纪。
{"title":"Petrography, U–Pb geochronology and geochemistry of Varcheh intrusions: Insight into younging trend of mid-Cretaceous subduction in the northern Sanandaj–Sirjan Zone, western Iran","authors":"Shima Shomali, Mansour Ghorbani, Mohammad R. Ghassemi, Ehsan Moosavi, Jiri Slama","doi":"10.1002/gj.5001","DOIUrl":"https://doi.org/10.1002/gj.5001","url":null,"abstract":"<p>The Neotethyan Sanandaj–Sirjan Zone of western Iran has recorded major magmatic activities due to its continental arc tectonic setting during the Mesozoic. The Varcheh mafic intrusions were less-studied plutons in the northern Sanandaj–Sirjan Zone (SSZ). Field evidence, petrography, geochemistry and U–Pb geochronological data were used to determine petrographic composition, geochemical nature, crystallization age and also to suggest a conceptual tectonomagmatic model for their emplacement. Small plutonic bodies are dominantly composed of monzogabbro that have intruded into the Cretaceous sedimentary rocks. Based on U–Pb zircon datings, these rocks have crystallized at 125–118 Ma in late Early Cretaceous (Barremian–Aptian), and are older than the supposed ages reported on geological maps. Varcheh rocks are not just typical calc-alkaline rocks and some show alkaline affinity. Negative anomalies in Nb–Ta–Ti and enrichments in some large-ion lithophile elements on spider diagrams are consistent with a subduction-zone setting. Potential deep source for magma generation is partial melting of subcontinental lithospheric mantle wedge above a subducting slab of oceanic lithosphere. The spaces for the Varcheh mafic intrusions are accommodated by dominant dextral strike-slip movement in a continental arc experiencing extension during late Early Cretaceous subduction. According to the zircon U–Pb geochronology results in this paper and previous U–Pb ages in the northern part of the SSZ, the mid-Cretaceous magmatism reveals a significant NW-ward younging trend and migration of the magmatic arc from the Barremian–Aptian in south-east to the Albian–Cenomanian in the north-west.</p>","PeriodicalId":12784,"journal":{"name":"Geological Journal","volume":"59 8","pages":"2156-2174"},"PeriodicalIF":1.4,"publicationDate":"2024-06-17","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"141967948","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"地球科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}