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Deformation and Strength Properties of a Gamma-Irradiated Plasticized Binder Based on Low-Molecular-Weight Polydiene Urethane Rubbers 基于低分子量聚氨基甲酸乙酯橡胶的γ辐照增塑剂的变形和强度特性
IF 0.7 4区 化学 Q4 CHEMISTRY, PHYSICAL Pub Date : 2023-11-30 DOI: 10.1134/s0018143923060127
E. Nurullaev, V. D. Oniskiv, L. L. Himenko, E. M. Ibragimova

Abstract

The effect of gamma-radiation doses of 50, 100, and 150 kGy on the deformation and strength properties of a plasticized binder based on low-molecular-weight polydiene urethane rubbers of the PDI-3B brand has been studied. To assess changes in the strength of the plasticized binder depending on the dose of gamma irradiation, the fracture energies were calculated at temperatures of 223, 295, and 323 K. At these test temperatures, the conditional stress increased and deformation slightly decreased depending on the dose of gamma irradiation compared with those of the original sample. Sharp changes in the deformation and strength characteristics occurred at a test temperature of 223 K; the strength of the irradiated samples increased by a factor of more than 4, and the deformation decreased slightly compared to that of the original sample. This trend persisted with an increase in the test temperature, but the difference was almost halved. Such an effect of gamma irradiation on the test material can be explained by the prevalence of crosslinking over degradation.

摘要研究了50kgy、100kgy和150kgy γ辐射剂量对PDI-3B牌低分子量聚氨酯橡胶增塑剂变形和强度性能的影响。为了评估塑化粘合剂强度随辐照剂量的变化,在223、295和323 K的温度下计算了断裂能。在这些测试温度下,与原始样品相比,随辐照剂量的增加,条件应力增加,变形略有减少。在223 K测试温度下,变形和强度特性发生了剧烈变化;辐照后试样的强度比原试样提高了4倍以上,变形比原试样略有减小。这种趋势随着测试温度的升高而持续,但差异几乎减半。伽马辐照对测试材料的这种影响可以用交联在降解过程中的普遍性来解释。
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引用次数: 0
A Study on the Effect of Gamma-Radiation on the Molecular Structure and Hydrophobic Properties of Telomeric Coatings on Glass Fabric γ辐射对玻璃织物端粒膜分子结构和疏水性影响的研究
4区 化学 Q4 CHEMISTRY, PHYSICAL Pub Date : 2023-09-29 DOI: 10.1134/s0018143923050041
G. A. Kichigina, P. P. Kushch, D. P. Kiryukhin, E. N. Kabachkov, Yu. M. Shulga
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引用次数: 0
Effect of Ionizing Radiation on Electrical Conductivity of a Tetrafluoroethylene–Ethylene Copolymer Containing Single-Wall Carbon Nanotubes 电离辐射对含单壁碳纳米管的四氟乙烯-乙烯共聚物电导率的影响
4区 化学 Q4 CHEMISTRY, PHYSICAL Pub Date : 2023-09-29 DOI: 10.1134/s0018143923050120
V. P. Selkin, S. V. Kopylov
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引用次数: 0
Effect of Protonation on the Spectral–Luminescent and Photochemical Properties of a Bis(styrylbenzoquinoline) Dyad with the Naphthylene Framework and of Corresponding Dibenzoquinolylcyclobutane 质子化作用对萘骨架双(苯基苯并喹啉)和相应的二苯并喹啉环丁烷的光谱发光和光化学性质的影响
4区 化学 Q4 CHEMISTRY, PHYSICAL Pub Date : 2023-09-29 DOI: 10.1134/s0018143923050028
M. F. Budyka, V. M. Li, N. I. Potashova, T. N. Gavrishova, V. I. Kozlovskii, I. V. Sulimenkov
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引用次数: 0
Single- and Double-Pulse Laser Kinetic Spectroscopy of Indoline Spiropyran 吲哚类螺吡喃的单、双脉冲激光动力学光谱研究
4区 化学 Q4 CHEMISTRY, PHYSICAL Pub Date : 2023-09-29 DOI: 10.1134/s0018143923050016
L. S. Atabekyan, A. K. Chibisov, T. A. Svyatoslavskaya, N. L. Svyatoslavskii, V. P. Markelov
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引用次数: 0
Thickness of the Modified Polymer Layer Formed by Low-Temperature Plasma Treatment 低温等离子体处理形成的改性聚合物层厚度
4区 化学 Q4 CHEMISTRY, PHYSICAL Pub Date : 2023-09-29 DOI: 10.1134/s001814392305003x
A. B. Gilman, M. S. Piskarev, A. A. Kuznetsov
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引用次数: 0
Quantum-Chemical Study of Synthesized Ultrafine Bi2O3–B2O3–BaO Glasses 合成超细Bi2O3-B2O3-BaO玻璃的量子化学研究
4区 化学 Q4 CHEMISTRY, PHYSICAL Pub Date : 2023-09-29 DOI: 10.1134/s0018143923050107
S. D. Plekhovich, A. D. Plekhovich, A. M. Kut’in, A. V. Budruev
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引用次数: 0
Radiolytic Inactivation of Ponceau 4R Mutagenicity in Aqueous Solution 水溶液中Ponceau 4R致突变性的放射性失活研究
4区 化学 Q4 CHEMISTRY, PHYSICAL Pub Date : 2023-09-29 DOI: 10.1134/s0018143923050119
A. V. Ponomarev, E. M. Kholodkova, I. V. Zotova, A. R. Shumega, E. I. Stepchenkova
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引用次数: 0
Photochemical Properties of Polyfluoroalkylated Chlorin in a Perfluorocarbon Nanoemulsion 全氟碳纳米乳液中多氟烷基化氯的光化学性质
4区 化学 Q4 CHEMISTRY, PHYSICAL Pub Date : 2023-09-29 DOI: 10.1134/s0018143923050077
M. T. Nguyen, I. D. Burtsev, A. E. Egorov, A. A. Markova, E. A. Zevakin, V. A. Kuzmin
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引用次数: 0
Radiation-Chemical Transformations of Ethylene Glycol and Its Deuterated Derivative in Deaerated Aqueous Solutions 乙二醇及其氘化衍生物在脱氧水溶液中的辐射化学转化
4区 化学 Q4 CHEMISTRY, PHYSICAL Pub Date : 2023-09-29 DOI: 10.1134/s0018143923050132
O. V. Urbanovich, A. I. Davydenko, R. L. Sverdlov, A. V. Bekish, S. B. Lastovskii, E. V. Tochilin
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引用次数: 0
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High Energy Chemistry
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