The characterization and design of this study of new liquid crystals with a V shape compounds containing thiazolidine-2,4-dione and 1,3-phenylene as a core unite with mesophase properties were reported. Preparation and characterization of chloroacetic acid, water, and thiourea to produce thiazolidine-2,4-dione [I] in the presence of strong hydrochloric acid. The 4-hydreoxybenzaldehyde and n-alkyl bromide were reacted with potassium hydroxide to create the n-alkoxy benzaldehyde., then the compound [I] reacted with [II]n in presence of piperidine to produce compounds [III]n. Also, converted resorcinol to a corresponding compound [IV] by refluxing pyridine and DMF with two moles of chloracetyl chloride, after that interacted the compounds [III]n and compound [IV] with sodium acetate to form compounds [V]n. FT-IR and 1HNMR spectroscopy were really used to determine the structures of the produced substances. Using polarized optical microscopy, these mesogens' mesomorphic characteristics were studied (POM).The synthesized molecules exhibited enantiotropic liquid crystal phases, the substances [V]1-4 exhibited an only the enantiotropic nematic phase.
{"title":"Design of New V Shaped Thermotropic Liquid Crystals containing Heterocyclic","authors":"Athraa J. Ali, N. H. Karam","doi":"10.30526/36.2.3046","DOIUrl":"https://doi.org/10.30526/36.2.3046","url":null,"abstract":" The characterization and design of this study of new liquid crystals with a V\u0000 shape compounds containing thiazolidine-2,4-dione and 1,3-phenylene as a core unite with\u0000 mesophase properties were reported. Preparation and characterization of chloroacetic\u0000 acid, water, and thiourea to produce thiazolidine-2,4-dione [I] in the presence of\u0000 strong hydrochloric acid. The 4-hydreoxybenzaldehyde and n-alkyl bromide were reacted\u0000 with potassium hydroxide to create the n-alkoxy benzaldehyde., then the compound [I]\u0000 reacted with [II]n in presence of piperidine to produce compounds [III]n. Also,\u0000 converted resorcinol to a corresponding compound [IV] by refluxing pyridine and DMF\u0000 with two moles of chloracetyl chloride, after that interacted the compounds [III]n and\u0000 compound [IV] with sodium acetate to form compounds [V]n. FT-IR and 1HNMR spectroscopy\u0000 were really used to determine the structures of the produced substances. Using polarized\u0000 optical microscopy, these mesogens' mesomorphic characteristics were studied (POM).The\u0000 synthesized molecules exhibited enantiotropic liquid crystal phases, the substances\u0000 [V]1-4 exhibited an only the enantiotropic nematic phase.","PeriodicalId":13022,"journal":{"name":"Ibn AL- Haitham Journal For Pure and Applied Sciences","volume":"71 1","pages":""},"PeriodicalIF":0.0,"publicationDate":"2023-04-20","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"86077058","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Supra nanoparticles ( submicron ) of Chicken bones fibers were used ( before and after treatedwith citric acid solution) as additives to dental composite with the weight ratios ( 1% , 2% and 4%) .The main mechanical tests represented by hardness , wear resistance and compression strengthwas carried out on the improvement dental composites .The addition of treated supra nanoparticles Chicken thigh bones with particles size (300 nm) byweight ratio (1%) to ordinary dental composite resin , significantly improves all of its mechanicalproperties , in addition to the increase the value of the its glass transition temperature from 43C .The techniques X-ray diffraction (XRD) , Energy Dispersive Spectroscopy (EDS) and Electron microscope images (SEM) were used to interpretation all the results that are improvedmechanically and thermally.
{"title":"IMPROVEMENT ON DENTAL COMPOSITE RESIN USING Supra -Nano Chicken thigh bone fibers","authors":"Rand Alkarkhy, Widad H. Jassim","doi":"10.30526/36.2.2998","DOIUrl":"https://doi.org/10.30526/36.2.2998","url":null,"abstract":"Supra nanoparticles ( submicron ) of Chicken bones fibers were used ( before and\u0000 after treatedwith citric acid solution) as additives to dental composite with the weight\u0000 ratios ( 1% , 2% and 4%) .The main mechanical tests represented by hardness , wear\u0000 resistance and compression strengthwas carried out on the improvement dental composites\u0000 .The addition of treated supra nanoparticles Chicken thigh bones with particles size\u0000 (300 nm) byweight ratio (1%) to ordinary dental composite resin , significantly improves\u0000 all of its mechanicalproperties , in addition to the increase the value of the its glass\u0000 transition temperature from 43C .The techniques X-ray diffraction (XRD) , Energy\u0000 Dispersive Spectroscopy (EDS) and Electron microscope images (SEM) were used to\u0000 interpretation all the results that are improvedmechanically and thermally.","PeriodicalId":13022,"journal":{"name":"Ibn AL- Haitham Journal For Pure and Applied Sciences","volume":"1857 1","pages":""},"PeriodicalIF":0.0,"publicationDate":"2023-04-20","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"86528624","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
This paper is concerned with the quaternary nonlinear hyperbolic boundary value problem (QNLHBVP) studding constraints quaternary optimal classical continuous control vector (CQOCCCV), the cost function (CF), and the equality and inequality quaternary state and control constraints vector (EIQSCCV). The existence of a CQOCCCV dominating by the QNLHBVP is stated and demonstrated using the Aubin compactness theorem (ACTH) under appropriate hypotheses (HYPs). Furthermore, mathematical formulation of the quaternary adjoint equations (QAEs) related to the quaternary state equations (QSE) are discovere so as its weak form (WF) . The directional derivative (DD) of the Hamiltonian (Ham) is calculated. The necessary and sufficient conditions for optimality (NCSO) theorems for the proposed problem are stated and proved.
{"title":"Constraints Optimal Classical Continuous Control Vector Problem for Quaternary\u0000 Nonlinear Hyperbolic System","authors":"Jamil Amir Al-hawasy, Mayeada Abd Alsatar Hassan","doi":"10.30526/36.2.2992","DOIUrl":"https://doi.org/10.30526/36.2.2992","url":null,"abstract":"This paper is concerned with the quaternary nonlinear hyperbolic boundary value\u0000 problem (QNLHBVP) studding constraints quaternary optimal classical continuous control\u0000 vector (CQOCCCV), the cost function (CF), and the equality and inequality quaternary\u0000 state and control constraints vector (EIQSCCV). The existence of a CQOCCCV dominating by\u0000 the QNLHBVP is stated and demonstrated using the Aubin compactness theorem (ACTH) under\u0000 appropriate hypotheses (HYPs). Furthermore, mathematical formulation of the quaternary\u0000 adjoint equations (QAEs) related to the quaternary state equations (QSE) are discovere \u0000 so as its weak form (WF) . The directional derivative (DD) of the Hamiltonian (Ham) is\u0000 calculated. The necessary and sufficient conditions for optimality (NCSO) theorems for\u0000 the proposed problem are stated and proved.","PeriodicalId":13022,"journal":{"name":"Ibn AL- Haitham Journal For Pure and Applied Sciences","volume":"8 1","pages":""},"PeriodicalIF":0.0,"publicationDate":"2023-04-20","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"77153639","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}