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Design of New V Shaped Thermotropic Liquid Crystals containing Heterocyclic 新型含杂环V型热致液晶的设计
Pub Date : 2023-04-20 DOI: 10.30526/36.2.3046
Athraa J. Ali, N. H. Karam
    The characterization and design of this study of new liquid crystals with a V shape compounds containing thiazolidine-2,4-dione and 1,3-phenylene as a core unite with mesophase properties were reported. Preparation  and characterization of chloroacetic acid, water, and thiourea to produce thiazolidine-2,4-dione [I] in the presence of strong hydrochloric acid. The 4-hydreoxybenzaldehyde and n-alkyl bromide were reacted with potassium hydroxide to create the n-alkoxy benzaldehyde., then the compound [I] reacted with [II]n in presence of piperidine to produce compounds [III]n. Also, converted resorcinol to a corresponding  compound [IV] by refluxing pyridine and DMF with two moles of chloracetyl chloride, after that interacted the compounds [III]n and compound [IV] with sodium acetate to form compounds [V]n. FT-IR and 1HNMR spectroscopy were really used to determine the structures of the produced substances. Using polarized optical microscopy, these mesogens' mesomorphic characteristics were studied (POM).The synthesized molecules exhibited enantiotropic liquid crystal phases, the substances [V]1-4 exhibited an only the enantiotropic nematic phase.
本文报道了以噻唑烷-2,4-二酮和1,3-苯基为核心单元,具有中间相性质的新型V型液晶的表征和设计。氯乙酸、水和硫脲在强盐酸存在下生产噻唑烷-2,4-二酮[I]的制备及表征。将4-羟基苯甲醛和正烷基溴与氢氧化钾反应生成正烷氧基苯甲醛。,然后化合物[I]与[II]n在哌啶存在下反应生成化合物[III]n。用两摩尔氯乙酰氯将吡啶和DMF回流,将间苯二酚转化为相应的化合物[IV],然后将化合物[III]n和化合物[IV]与乙酸钠相互作用,形成化合物[V]n。FT-IR和1HNMR光谱被用来确定生产物质的结构。利用偏光显微镜研究了这些介胚的介胚特征(POM)。合成的分子表现为对映性液晶相,而物质[V]1-4只表现为对映性向列相。
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引用次数: 0
IMPROVEMENT ON DENTAL COMPOSITE RESIN USING Supra -Nano Chicken thigh bone fibers 超纳米鸡大腿骨纤维对牙科复合树脂的改进
Pub Date : 2023-04-20 DOI: 10.30526/36.2.2998
Rand Alkarkhy, Widad H. Jassim
Supra nanoparticles ( submicron ) of Chicken bones fibers were used ( before and after treatedwith citric acid solution) as additives to dental composite with the weight ratios ( 1% , 2% and 4%) .The main mechanical tests represented by hardness , wear resistance and compression strengthwas carried out on the improvement dental composites .The addition of treated supra nanoparticles Chicken thigh bones with particles size (300 nm) byweight ratio (1%) to ordinary dental composite resin , significantly improves all of its mechanicalproperties , in addition to the increase the value of the its glass transition temperature from 43C .The techniques X-ray diffraction (XRD) , Energy Dispersive Spectroscopy (EDS) and Electron microscope images (SEM) were used to interpretation all the results that are improvedmechanically and thermally.
将经柠檬酸溶液处理前后的鸡骨纤维超细纳米颗粒(亚微米)分别添加到重量比为1%、2%和4%的牙科复合材料中,对改进后的牙科复合材料进行了硬度、耐磨性和抗压强度等主要力学性能试验。在普通牙科复合树脂中添加重量比为1%、粒径为300 nm的经处理的鸡大腿骨超细纳米颗粒,通过x射线衍射仪(XRD)、能谱仪(EDS)和电子显微镜(SEM)等技术对其力学性能和热性能的改善进行了分析。
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引用次数: 0
Constraints Optimal Classical Continuous Control Vector Problem for Quaternary Nonlinear Hyperbolic System 第四系非线性双曲型系统的约束最优经典连续控制向量问题
Pub Date : 2023-04-20 DOI: 10.30526/36.2.2992
Jamil Amir Al-hawasy, Mayeada Abd Alsatar Hassan
This paper is concerned with the quaternary nonlinear hyperbolic boundary value problem (QNLHBVP) studding constraints quaternary optimal classical continuous control vector (CQOCCCV), the cost function (CF), and the equality and inequality quaternary state and control constraints vector (EIQSCCV). The existence of a CQOCCCV dominating by the QNLHBVP is stated and demonstrated using the Aubin compactness theorem (ACTH) under appropriate hypotheses (HYPs). Furthermore, mathematical formulation of the quaternary adjoint equations (QAEs) related to the quaternary state equations (QSE) are discovere  so as its weak form (WF) . The directional derivative (DD) of the Hamiltonian (Ham) is calculated. The necessary and sufficient conditions for optimality (NCSO) theorems for the proposed problem are stated and proved.
本文研究了四元非线性双曲边值问题(QNLHBVP),研究了约束四元最优经典连续控制向量(CQOCCCV)、代价函数(CF)以及等价和不等式四元状态和控制约束向量(EIQSCCV)。在适当的假设条件下,利用Aubin紧性定理证明了由QNLHBVP支配的CQOCCCV的存在性。此外,还发现了与四元态方程(QSE)相关的四元伴随方程(qes)的数学表达式及其弱形式(WF)。计算哈密顿量(Ham)的方向导数(DD)。给出并证明了该问题的最优性定理的充要条件。
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引用次数: 0
Morphological Characterization and Conservation Status for the Herbarium Specimens of Orchidaceae in Kurdistan Iraq 伊拉克库尔德斯坦兰科植物标本馆标本形态特征及保存现状
Pub Date : 2023-04-20 DOI: 10.30526/36.2.3031
Saman Abdulrahman Ahmad, R. M.Salih, Sakar Y. Hama Yaseen Hama
This study was contacted on Orchidaceae, it is a second largest family in flowering plants, comes after Asteraceae, and approximately has 25,000–30,000 species in 750–800 genera in the world. This study included 10 genera, Anacamptis (five species), Androrchis (two species), Cephalanthera (one species), Dactylorhiza (three species), Epipactis (two species), Himantoglossum (two species), Limodorum (one species), Neotinea (one species), Ophrys (seven species ), and Orchis (four species). The name abbreviation of authors of plant names follows the International Plant Name Index (IPNI) (https://www.ipni.org/). Images of type collections of most species were checked on virtual herbaria (https://herbarium.univie.ac.at/database/search.php) and JSTOR Global Plants (https://plants.jstor.org/). The taxonomic status, geographical distribution, and the conservation status for all taxa were provided.
兰科是开花植物中仅次于菊科的第二大科,在世界上有750-800属,约有25000 - 30000种。共纳入10个属,分别为Anacamptis(5种)、Androrchis(2种)、Cephalanthera(1种)、Dactylorhiza(3种)、Epipactis(2种)、Himantoglossum(2种)、Limodorum(1种)、Neotinea(1种)、Ophrys(7种)和Orchis(4种)。植物名称作者的名称缩写遵循国际植物名称索引(IPNI) (https://www.ipni.org/)。在虚拟植物标本馆(https://herbarium.univie.ac.at/database/search.php)和JSTOR Global Plants (https://plants.jstor.org/)上查询了大多数物种的类型集合图像。介绍了各分类群的分类学现状、地理分布和保护现状。
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引用次数: 0
Extend Nearly Pseudo Quasi-2-Absorbing Submodules (II) 扩展近伪拟2吸收子模块(II)
Pub Date : 2023-04-20 DOI: 10.30526/36.2.3045
O. Abdullah, Haibat Karim Mohammadali
The concept of the Extend Nearly Pseudo Quasi-2-Absorbing submodules was recently introduced by Omar A. Abdullah and Haibat K. Mohammadali in 2022, where he studies this concept and it is relationship to previous generalizationsm especially  2-Absorbing submodule and Quasi-2-Absorbing submodule, in addition to studying the most important Propositions, charactarizations and Examples. Now in this research, which is considered a continuation of the definition that was presented earlier, which is the Extend Nearly Pseudo Quasi-2-Absorbing submodules, we have completed the study of this concept in multiplication modules. And the relationship between the Extend Nearly Pseudo Quasi-2-Absorbing submodule and Extend Nearly Pseudo Quasi-2-Absorbing ideal. We also studied more result of Extend Nearly Pseudo Quasi-2-Absorbing submodule in multiplication module. In the end, we obtained new Propositions and distinguished results in studying this concept.
Omar A. Abdullah和Haibat K. Mohammadali在2022年提出了扩展近伪拟2吸收子模的概念,除了研究了最重要的命题、表征和例子外,他们还研究了这一概念及其与以往推广理论的关系,特别是2吸收子模和拟2吸收子模。现在,在本研究中,我们将先前提出的扩展近拟2吸收子模的定义作为延续,完成了乘法模中这一概念的研究。并讨论了扩展近伪拟2吸收子模与扩展近伪拟2吸收理想的关系。我们还研究了乘法模中扩展近拟2吸收子模的更多结果。最后,我们对这一概念的研究得到了新的命题和显著的成果。
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引用次数: 0
Polypropylene/Pt Nanocomposite: Synthesis, Characterization and Study the Cytotoxic Effects 聚丙烯/铂纳米复合材料的合成、表征及细胞毒性研究
Pub Date : 2023-04-20 DOI: 10.30526/36.2.2989
M. Abdulwahid, Nada M. Abbass
     This paper presents the synthesis of a polypropylene nanocomposite. The  nanocomposites were characterized using different techniques: atomic electron microscopy (AFM), surface shape was evaluated by (SEM),(EDS),(XRD) and (FTIR). The study showed that the platinum nanocomposite had a fatal effect on both strains of bacteria used, as well as on the growth of fungi. The compound tested showed antioxidant properties moderate activity was found. The mentioned material were evaluated in normal cell line HdFn (Human Dermal Fibroblasts, neonatal)  and breast cancer MCF-7 cancer cell line , by MTT assay for study cytotoxic effects, morphological changes, all experiments were conducted on cell lines by using the materials alone. The results of the MTT assay showed that the material [PP/ Pt] had a toxic effect on the cell lines, and the toxicity of the materials was concentration-dependent manner where that have higher toxicity on the MCF-7  cell lines than HdFn. The toxic effects of material alone were reflected on cell morphology by appearance irreversible cytopathic changes in the treated cells, which ability to cause cellular death and DNA damage. When there appeared a significant increase in the concentration of  nanocomposite , [PP/Pt]  nanocomposite have an inhibitory effect on both breast cancer and normal cell lines. Conclude both materials have genotoxic effects on normal and cancer cell lines.
本文介绍了聚丙烯纳米复合材料的合成。采用原子电子显微镜(AFM)、扫描电镜(SEM)、能谱仪(EDS)、x射线衍射仪(XRD)和红外光谱(FTIR)对纳米复合材料进行了表征。该研究表明,铂纳米复合材料对所使用的两种细菌菌株以及真菌的生长都有致命的影响。该化合物抗氧化性能良好,活性适中。在正常细胞系HdFn (Human真皮成纤维细胞,新生儿)和乳腺癌MCF-7细胞系中,采用MTT法研究其细胞毒作用和形态学变化,所有实验均单独使用该材料进行。MTT试验结果表明,材料[PP/ Pt]对MCF-7细胞系具有一定的毒性作用,且毒性呈浓度依赖性,对MCF-7细胞系的毒性高于HdFn。物质单独的毒性作用反映在细胞形态上,在处理的细胞中出现不可逆的细胞病变,这种病变能够引起细胞死亡和DNA损伤。当纳米复合材料浓度出现显著增加时,[PP/Pt]纳米复合材料对乳腺癌和正常细胞系均有抑制作用。结论:两种物质对正常细胞和癌细胞均有遗传毒性作用。
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引用次数: 0
Radical Polymerization Kinetics of Hexyl Methacrylate in Dimethylsulfoxide Solution 甲基丙烯酸己酯在二甲亚砜溶液中的自由基聚合动力学
Pub Date : 2023-04-20 DOI: 10.30526/36.2.2985
Hala Rahman Noormohamad, Ameen Hadi
In this study, we conducted a series of polymerization studies of hexyl methacrylate in dimethyl sulfoxide with (0.1 - 0.4) mol dm-3 of monomer and (1 10-3 – 4 10-3) mol dm-3 of benzoyl peroxide as initiators at 70 °C. Using the well-known conversion vs. time technique, the effects of initiator and monomer concentration on the rate of polymerization (Rp) were studied. An initiator of order 0.35 was obtained in accordance with theory and a divergence from normal kinetics was detected with an order of 1.53 with respect to monomer concentration. The activation energy was determined to be (72.90) kJ mol-1, which does not correspond to the value of most thermally initiated monomers. The observed value of activation energy suggests that propagation and termination reactions have equal activation energy and the difference between them is nearly zero. The average degree of polymerization (DPn) decreased as benzoyl peroxide concentration increase whereas an increase in solvent polarity has slightly increased rate of polymerization value.
在本研究中,我们以(0.1 - 0.4)mol dm-3单体和(1 10-3 - 4 10-3)mol dm-3过氧化苯甲酰为引发剂,在70℃下进行了一系列甲基丙烯酸己酯在二甲亚砜中的聚合研究。采用著名的转化率-时间法,研究了引发剂和单体浓度对聚合速率的影响。根据理论得到了0.35阶的引发剂,并检测到单体浓度与正常动力学的差异,其阶数为1.53。测定的活化能为(72.90)kJ mol-1,不符合大多数热引发单体的值。活化能的观测值表明,传播反应和终止反应具有相等的活化能,两者之间的差值几乎为零。平均聚合度(DPn)随过氧化苯甲酰浓度的增加而降低,而溶剂极性的增加使聚合速率值略有增加。
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引用次数: 0
Solution of Population Growth Rate Linear Differential Model via Two Parametric SEE Transformation 人口增长率线性微分模型的双参数SEE变换解
Pub Date : 2023-04-20 DOI: 10.30526/36.2.3251
Ali Moazzam, Hira M. Aslam, N. Tabassum, Emad A. Kuffi
The integral transformations is a complicated function from a function space into a simple function in transformed space. Where the function being characterized easily and manipulated through integration in transformed function space. The two parametric form of SEE transformation and its basic characteristics have been demonstrated in this study. The transformed function of a few fundamental functions along with its time derivative rule is shown. It has been demonstrated how two parametric SEE transformations can be used to solve linear differential equations. This research provides a solution to population growth rate equation. One can contrast these outcomes with different Laplace type transformations
积分变换是将一个复杂的函数从函数空间转化为变换空间中的一个简单函数。通过变换后的函数空间中的积分可以很容易地对函数进行表征和操作。本文论证了SEE变换的两参数形式及其基本特征。给出了几种基本函数的变换函数及其时间导数规律。它已经证明了如何两个参数SEE变换可以用来解决线性微分方程。本研究提供了一个人口增长率方程的解。我们可以用不同的拉普拉斯变换来对比这些结果
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引用次数: 1
Influence Annealing on the Physical Properties of Silver Selenide Thin Film at Different Temperatures by Thermal Evaporation 热蒸发退火对不同温度下硒化银薄膜物理性能的影响
Pub Date : 2023-04-20 DOI: 10.30526/36.2.2990
Hiba Mumtaz
This survey investigates the thermal evaporation of Ag2Se on glass substrates at various thermalannealing temperatures (300, 348, 398, and 448) °K. To ascertain the effect of annealingtemperature on the structural, surface morphology, and optical properties of Ag2Se films,investigations and research were carried out. The crystal structure of the film was described by Xraydiffractionandothermethods.ThephysicalstructureandcharacteristicsoftheAg2Sethinfilms wereexaminedusingX-rayandatomicforcemicroscopy(AFM)basedtechniques.TheAg2Se films surface morphology was examined by AFM techniques; the investigation gave averagediameter, surface roughness, and grain size mutation values with increasing annealing temperature(75.74 nm–96.36 nm). Additionally, With various variations to the nominal values, the absorbanceand transmittance spectra are further studied and reported in accordance with the wavelength rangeof (400-1100) nm. The findings indicate that the sample highest absorbance value was attained ata temperature treatment of 448 K, whereas the sample highest transmittance was at a temperaturetreatment of 300 K. According to the results, direct transitions were permitted in the under-reviewthin films at optical energies of (2.15, 1.85, 1.75, and 1.7) eV, respectively
本研究研究了Ag2Se在不同热退火温度(300、348、398和448)K下在玻璃基板上的热蒸发。为了确定退火温度对Ag2Se薄膜结构、表面形貌和光学性能的影响,进行了调查和研究。用x射线衍射和其他方法描述了薄膜的晶体结构。ThephysicalstructureandcharacteristicsoftheAg2Sethinfilms wereexaminedusingX-rayandatomicforcemicroscopy basedtechniques (AFM)。采用原子力显微镜(AFM)技术对ag2se薄膜表面形貌进行了检测;研究得到了平均直径、表面粗糙度和晶粒尺寸随退火温度升高的变异值(75.74 nm ~ 96.36 nm)。此外,根据标称值的不同变化,进一步研究并报道了在(400-1100)nm波长范围内的吸收光谱和透射光谱。结果表明,样品在448 K时吸光度最高,而在300 K时透射率最高。结果表明,在光能分别为(2.15,1.85,1.75和1.7)eV的情况下,薄膜可以发生直接跃迁
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引用次数: 1
A Brief Review: Some Interesting Methods of Synthesis Chromene Derivatives as Bioactive Molecules 铬烯类生物活性分子的合成方法综述
Pub Date : 2023-04-20 DOI: 10.30526/36.2.3180
Zainab Sallal Abdulsahib, R. M. Shakir
Chromene is considered a fused pyran ring with a benzene ring, which is found in many plants and is part of many important compounds such as anthocyanidins, anthocyanins, catechins, and flavanones. These compounds are included under the headings "flavonoids" and "iso-flavonoids." These compounds are well known as bioactive molecules with wide medicinal uses. According to these pharmacokinetic characteristics, many researchers are giving more attention to this type of compound and its derivatives. Many chromene derivatives have been synthesized to study their biological effects for the treatment of many diseases. Furthermore, the researcher displayed wide interest in finding new methods for synthesizing chromene derivatives. These methods depend on utilizing a new catalyst to increase the yield of this reaction or reduce the time of the reaction. On the other hand, new methods were found by using a new reactant and a new substrate. This review will present the most recent important methods for the synthesis of chromene derivatives as well as an examination of their biological activity. 
铬被认为是一个与苯环融合的吡喃环,它存在于许多植物中,是许多重要化合物的一部分,如花青素、花青素、儿茶素和黄酮。这些化合物包括在“类黄酮”和“异类黄酮”的标题下。这些化合物是众所周知的生物活性分子,具有广泛的药用价值。根据这些药动学特征,这类化合物及其衍生物受到了许多研究者的关注。人们已经合成了许多铬衍生物,并对其治疗多种疾病的生物学效应进行了研究。此外,研究人员对寻找合成铬衍生物的新方法表现出广泛的兴趣。这些方法依赖于使用一种新的催化剂来提高该反应的产率或缩短反应时间。另一方面,通过使用新的反应物和新的底物,发现了新的方法。本文综述了近年来合成铬烯衍生物的重要方法,并对其生物活性进行了研究。
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引用次数: 1
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Ibn AL- Haitham Journal For Pure and Applied Sciences
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