This work describes two efficient and useful methods for solving fractional pantograph delay equations (FPDEs) with initial and boundary conditions. These two methods depend mainly on orthogonal polynomials, which are the method of the operational matrix of fractional derivative that depends on Bernstein polynomials and the operational matrix of the fractional derivative with Shifted Legendre polynomials. The basic procedure of this method is to convert the pantograph delay equation to a system of linear equations and by using, the operational matrices we get rid of the integration and differentiation operations, which makes solving the problem easier. The concept of Caputo has been used to describe fractional derivatives. Finally, some numerical examples are identified to show the utility and capability of the two proposed approaches. Mathematica®12 program has been relied upon in the calculations.
{"title":"Fractional Pantograph Delay Equations Solving by the Meshless Methods","authors":"Shefaa M. N. Jasim, Ghada H. Ibraheem","doi":"10.30526/36.3.3076","DOIUrl":"https://doi.org/10.30526/36.3.3076","url":null,"abstract":"This work describes two efficient and useful methods for solving fractional pantograph delay equations (FPDEs) with initial and boundary conditions. These two methods depend mainly on orthogonal polynomials, which are the method of the operational matrix of fractional derivative that depends on Bernstein polynomials and the operational matrix of the fractional derivative with Shifted Legendre polynomials. The basic procedure of this method is to convert the pantograph delay equation to a system of linear equations and by using, the operational matrices we get rid of the integration and differentiation operations, which makes solving the problem easier. The concept of Caputo has been used to describe fractional derivatives. Finally, some numerical examples are identified to show the utility and capability of the two proposed approaches. Mathematica®12 program has been relied upon in the calculations.","PeriodicalId":13022,"journal":{"name":"Ibn AL- Haitham Journal For Pure and Applied Sciences","volume":"11 1","pages":""},"PeriodicalIF":0.0,"publicationDate":"2023-07-20","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"88609764","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Mohammed Kamal Saleh, Thair Abdulkareem, Khalil Al-Aish
Abstract: The power and the size of the final spot of the laser beam reaching the target are very important requirements in most of the laser applications and fields such as medical, military, and scientific, so studying laser propagation in the atmosphere is a very important topic. The propagation of the laser beam through the atmosphere is subject to several attenuation processes that deplete the power and expand the beam. Through the simulation results of the free electron laser within the visible region of the electromagnetic spectrum (400-700nm), it was found that the attenuation increases with decreasing wavelength. Laser propagation in the presence of rain and snow leads to a very large loss of power compared to propagation in normal weather conditions free of rain and snow. Atmosphere turbulence depends largely on changes in temperature, so the turbulence decreases with altitude from sea level, which makes laser work at high altitudes, such as the stratosphere, a good option with better results.
{"title":"Simulation and Analysis the Attenuation Effect of Atmospheric Layers on a Laser Beam Within the Visible Range","authors":"Mohammed Kamal Saleh, Thair Abdulkareem, Khalil Al-Aish","doi":"10.30526/36.3.3093","DOIUrl":"https://doi.org/10.30526/36.3.3093","url":null,"abstract":"Abstract: The power and the size of the final spot of the laser beam reaching the target are very important requirements in most of the laser applications and fields such as medical, military, and scientific, so studying laser propagation in the atmosphere is a very important topic. The propagation of the laser beam through the atmosphere is subject to several attenuation processes that deplete the power and expand the beam. Through the simulation results of the free electron laser within the visible region of the electromagnetic spectrum (400-700nm), it was found that the attenuation increases with decreasing wavelength. Laser propagation in the presence of rain and snow leads to a very large loss of power compared to propagation in normal weather conditions free of rain and snow. Atmosphere turbulence depends largely on changes in temperature, so the turbulence decreases with altitude from sea level, which makes laser work at high altitudes, such as the stratosphere, a good option with better results. \u0000 ","PeriodicalId":13022,"journal":{"name":"Ibn AL- Haitham Journal For Pure and Applied Sciences","volume":"2 1","pages":""},"PeriodicalIF":0.0,"publicationDate":"2023-07-20","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"86873831","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
The set of all (n×n) non-singular matrices over the field F. And this set forms a group under the operation of matrix multiplication. This group is called the general linear group of dimension over the field F, denoted by . The determinant of these matrices is a homomorphism from into F* and the kernel of this homomorphism was the special linear group and denoted by Thus is the subgroup of which contains all matrices of determinant one. The rationally valued characters of the rational representations are written as a linear combination of the induced characters for the groups discussed in this paper. We find the Artin indicator for this group after studying the rationally valued characters of the rational representations and the induced characters.
{"title":"Score for the Group SL(2,38)","authors":"N. Jasim, Mohammed Ibrahem Lfta, Ahmad Issa","doi":"10.30526/36.3.3017","DOIUrl":"https://doi.org/10.30526/36.3.3017","url":null,"abstract":" The set of all (n×n) non-singular matrices over the field F. And this set forms a group under the operation of matrix multiplication. This group is called the general linear group of dimension over the field F, denoted by . The determinant of these matrices is a homomorphism from into F* and the kernel of this homomorphism was the special linear group and denoted by Thus is the subgroup of which contains all matrices of determinant one.\u0000The rationally valued characters of the rational representations are written as a linear combination of the induced characters for the groups discussed in this paper. We find the Artin indicator for this group after studying the rationally valued characters of the rational representations and the induced characters.","PeriodicalId":13022,"journal":{"name":"Ibn AL- Haitham Journal For Pure and Applied Sciences","volume":"30 1","pages":""},"PeriodicalIF":0.0,"publicationDate":"2023-07-20","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"90714175","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Ali Moazzam, Ayza Anjum, Nimra Saleem, Emad A. Kuffi
A new technique to study the telegraph equation, mostly familiar as damped wave equation is introduced in this study. This phenomenon is mostly rising in electromagnetic influences and production of electric signals. The proposed technique called as He-Fractional Laplace technique with help of Homotopy perturbation is utilized to found the exact and nearly approximated results of differential model and numerical example of telegraph equation or damped wave equation in this article. The most unique term of this technique is that, there is no worry to find the next iteration by integration in recurrence relation. As fractional Laplace integral transformation has some limitations in non-linear terms, to get the result of nonlinear term in this differential mode, He polynomials via homotopy techniques of iteration is proposed to find the result of the computation assignment. The obtained result by this proposed technique directed that this technique is quite ease to apply and convergent rapidly to exact solutions. Numerous examples are described to determine the stability and accuracy of the proposed technique with the graphical explanation.
{"title":"Study of Telegraph Equation via He-Fractional Laplace Homotopy Perturbation Technique","authors":"Ali Moazzam, Ayza Anjum, Nimra Saleem, Emad A. Kuffi","doi":"10.30526/36.3.3239","DOIUrl":"https://doi.org/10.30526/36.3.3239","url":null,"abstract":"A new technique to study the telegraph equation, mostly familiar as damped wave equation is introduced in this study. This phenomenon is mostly rising in electromagnetic influences and production of electric signals. The proposed technique called as He-Fractional Laplace technique with help of Homotopy perturbation is utilized to found the exact and nearly approximated results of differential model and numerical example of telegraph equation or damped wave equation in this article. The most unique term of this technique is that, there is no worry to find the next iteration by integration in recurrence relation. As fractional Laplace integral transformation has some limitations in non-linear terms, to get the result of nonlinear term in this differential mode, He polynomials via homotopy techniques of iteration is proposed to find the result of the computation assignment. The obtained result by this proposed technique directed that this technique is quite ease to apply and convergent rapidly to exact solutions. Numerous examples are described to determine the stability and accuracy of the proposed technique with the graphical explanation. ","PeriodicalId":13022,"journal":{"name":"Ibn AL- Haitham Journal For Pure and Applied Sciences","volume":"59 1","pages":""},"PeriodicalIF":0.0,"publicationDate":"2023-07-20","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"81726045","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Vitamins are a type of essential and important nutrient in the human body. It also plays an essential role in the health and protection of the human body. They share physiological functions with many chemicals, and their deficiency or increase endangers human health. Therefore, it is required to evolve and use modern methods to estimate the concentration of vitamins, even if their concentration is very low, and these include the vitamin E group tocopherols, tocotrienols, isomers, esters, and derivatives. They disagree not in their ability as anti-cancer agents but rather in their physiological as well as chemical relations, unlike vitamin A and vitamin D. The richest source of vitamin E is vegetable oil. Vitamin E, classified as a vitamin, dissolves in fat. It is pointed out in different types of foods involving vegetable oils, meat, eggs, cereals, and poultry, in addition to fruits. Some of the vital signs and symptoms of a vitamin E deficiency include neurological defects such as dysfunction of the brain, nerves, spinal cord, and muscles; muscle pain and weakness; muscle deterioration, including cardiomyopathy or weak heart muscle; low birth weight; difficulty moving the eyes up and down; poor vision at night; loss or lack of sense of vibration; and a feeling of numbness or tingling.
{"title":"Review: - Determination of vitamin E concentration in different samples","authors":"E. N. Mezaal, M. A. Mohammed, K. A. Sadiq","doi":"10.30526/36.3.3113","DOIUrl":"https://doi.org/10.30526/36.3.3113","url":null,"abstract":"Vitamins are a type of essential and important nutrient in the human body. It also plays an essential role in the health and protection of the human body. They share physiological functions with many chemicals, and their deficiency or increase endangers human health. Therefore, it is required to evolve and use modern methods to estimate the concentration of vitamins, even if their concentration is very low, and these include the vitamin E group tocopherols, tocotrienols, isomers, esters, and derivatives. They disagree not in their ability as anti-cancer agents but rather in their physiological as well as chemical relations, unlike vitamin A and vitamin D. The richest source of vitamin E is vegetable oil. Vitamin E, classified as a vitamin, dissolves in fat. It is pointed out in different types of foods involving vegetable oils, meat, eggs, cereals, and poultry, in addition to fruits. Some of the vital signs and symptoms of a vitamin E deficiency include neurological defects such as dysfunction of the brain, nerves, spinal cord, and muscles; muscle pain and weakness; muscle deterioration, including cardiomyopathy or weak heart muscle; low birth weight; difficulty moving the eyes up and down; poor vision at night; loss or lack of sense of vibration; and a feeling of numbness or tingling.","PeriodicalId":13022,"journal":{"name":"Ibn AL- Haitham Journal For Pure and Applied Sciences","volume":"1 1","pages":""},"PeriodicalIF":0.0,"publicationDate":"2023-07-20","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"88521196","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
In the current work, Punica granatum L. peel, Artemisia herba-alba Asso., Matricaria chamomilla L., and Camellia sinensis extracts were used to prepare manganese dioxide (MnO2) nanoparticles utilizing a green method. Energy-dispersive X-ray (EDX) analysis, Fourier Transform Infrared Spectroscopy (FTIR) analysis, and Filed emission-scanning electron microscopy (FE-SEM) analysis were used to evaluate the produced MnO2 NPs. FE-SEM pictures demonstrated how agglomerated nanoparticles formed. According to FE-SEM calculations, the particle size ranged from 18.7-91.5 nm. FTIR spectra show that pure Mn-O is formed, while EDX results show that Mn and O are present. The ability to suppress biofilm growth in the produced MnO2 NPs was examined. The outcomes showed that both bacterial and fungal biofilms were effectively inhibited by the MnO2 NPs produced.
{"title":"Synthesis of Manganese Dioxide Nanoparticles by Plant Extract Mediated and their Effect on Biofilm Formation","authors":"Sabeha Sabeha, Zainab J. Shanan","doi":"10.30526/36.3.3061","DOIUrl":"https://doi.org/10.30526/36.3.3061","url":null,"abstract":"In the current work, Punica granatum L. peel, Artemisia herba-alba Asso., Matricaria chamomilla L., and Camellia sinensis extracts were used to prepare manganese dioxide (MnO2) nanoparticles utilizing a green method. Energy-dispersive X-ray (EDX) analysis, Fourier Transform Infrared Spectroscopy (FTIR) analysis, and Filed emission-scanning electron microscopy (FE-SEM) analysis were used to evaluate the produced MnO2 NPs. FE-SEM pictures demonstrated how agglomerated nanoparticles formed. According to FE-SEM calculations, the particle size ranged from 18.7-91.5 nm. FTIR spectra show that pure Mn-O is formed, while EDX results show that Mn and O are present. The ability to suppress biofilm growth in the produced MnO2 NPs was examined. The outcomes showed that both bacterial and fungal biofilms were effectively inhibited by the MnO2 NPs produced.","PeriodicalId":13022,"journal":{"name":"Ibn AL- Haitham Journal For Pure and Applied Sciences","volume":"26 1","pages":""},"PeriodicalIF":0.0,"publicationDate":"2023-07-20","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"75886273","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
In this study, SnO2 nanoparticles were prepared from cost-low tin chloride (SnCl2.2H2O) and ethanol by adding ammonia solution by the sol-gel method, which is one of the lowest-cost and simplest techniques. The SnO2 nanoparticles were dried in a drying oven at a temperature of 70°C for 7 hours. After that, it burned in an oven at a temperature of 200°C for 24 hours. The structure, material, morphological, and optical properties of the synthesized SnO2 in nanoparticle sizes are studied utilizing X-ray diffraction. The Scherrer expression was used to compute nanoparticle sizes according to X-ray diffraction, and the results needed to be scrutinized more closely. The micro-strain indicates the broadening of diffraction peaks for nanoparticles that are not ideal crystals. The extra broadening of the diffraction peak may lead to a miscalculation of the nanoparticle size. We use the Williamson-Hall method to directly compute and discuss the particle size and micro-strain of SnO2 nanoparticles and compare them with results obtained using the Scherrer method. In conclusion, the straight line has been derived due to Williamson–Hall methods demonstrating the nanoparticles' uniformity.
{"title":"Study the Effect of Manganese Ion Doping on the Size- Strain of SnO2 nanoparticles Using X-Ray Diffraction Data","authors":"Tagreed M. Al-Saadi, Zahraa A. Kamil","doi":"10.30526/36.3.3052","DOIUrl":"https://doi.org/10.30526/36.3.3052","url":null,"abstract":"In this study, SnO2 nanoparticles were prepared from cost-low tin chloride (SnCl2.2H2O) and ethanol by adding ammonia solution by the sol-gel method, which is one of the lowest-cost and simplest techniques. The SnO2 nanoparticles were dried in a drying oven at a temperature of 70°C for 7 hours. After that, it burned in an oven at a temperature of 200°C for 24 hours. The structure, material, morphological, and optical properties of the synthesized SnO2 in nanoparticle sizes are studied utilizing X-ray diffraction. The Scherrer expression was used to compute nanoparticle sizes according to X-ray diffraction, and the results needed to be scrutinized more closely. The micro-strain indicates the broadening of diffraction peaks for nanoparticles that are not ideal crystals. The extra broadening of the diffraction peak may lead to a miscalculation of the nanoparticle size. We use the Williamson-Hall method to directly compute and discuss the particle size and micro-strain of SnO2 nanoparticles and compare them with results obtained using the Scherrer method. In conclusion, the straight line has been derived due to Williamson–Hall methods demonstrating the nanoparticles' uniformity.","PeriodicalId":13022,"journal":{"name":"Ibn AL- Haitham Journal For Pure and Applied Sciences","volume":"234 1","pages":""},"PeriodicalIF":0.0,"publicationDate":"2023-07-20","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"74480290","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
In previous our research, the concepts of visible submodules and fully visible modules were introduced, and then these two concepts were fuzzified to fuzzy visible submodules and fully fuzzy. The main goal of this paper is to study the relationships between fully fuzzy visible modules and some types of fuzzy modules such as semiprime, prime, quasi, divisible, F-regular, quasi injective, and duo fuzzy modules, where under certain conditions it has been proven that each fully fuzzy visible module is fuzzy duo. In addition, there are many various properties and important results obtained through this research, which have been illustrated. Also, fuzzy Artinian modules and fuzzy fully stable modules have been introduced, and we study the relationships between these kinds of modules and fully fuzzy visible modules. Many other intersecting results we found.
{"title":"Fully Fuzzy Visible Modules With Other Related Concepts","authors":"Sajda Kadhum Mohammed, B. N. Shihab","doi":"10.30526/36.3.3092","DOIUrl":"https://doi.org/10.30526/36.3.3092","url":null,"abstract":"In previous our research, the concepts of visible submodules and fully visible modules were introduced, and then these two concepts were fuzzified to fuzzy visible submodules and fully fuzzy. The main goal of this paper is to study the relationships between fully fuzzy visible modules and some types of fuzzy modules such as semiprime, prime, quasi, divisible, F-regular, quasi injective, and duo fuzzy modules, where under certain conditions it has been proven that each fully fuzzy visible module is fuzzy duo. In addition, there are many various properties and important results obtained through this research, which have been illustrated. Also, fuzzy Artinian modules and fuzzy fully stable modules have been introduced, and we study the relationships between these kinds of modules and fully fuzzy visible modules. Many other intersecting results we found.","PeriodicalId":13022,"journal":{"name":"Ibn AL- Haitham Journal For Pure and Applied Sciences","volume":"54 9","pages":""},"PeriodicalIF":0.0,"publicationDate":"2023-07-20","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"72395312","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
For many years, reading rate as word correct per minute (WCPM) has been investigated by many researchers as an indicator of learners’ level of oral reading speed, accuracy, and comprehension. The aim of the study is to predict the levels of WCPM using three machine learning algorithms which are Ensemble Classifier (EC), Decision Tree (DT), and K- Nearest Neighbor (KNN). The data of this study were collected from 100 Kurdish EFL students in the 2nd-year, English language department, at the University of Duhok in 2021. The outcomes showed that the ensemble classifier (EC) obtained the highest accuracy of testing results with a value of 94%. Also, EC recorded the highest precision, recall, and F1 scores with values of 0.92 for the three performance measures. The Receiver Operating Character curve (ROC curve) also got the highest results than other classification algorithms. Accordingly, it can be concluded that the ensemble classifier is the best and most accurate model for predicting reading rate (accuracy) WCPM.
多年来，许多研究者将阅读率作为每分钟正确单词数(WCPM)作为学习者口语阅读速度、准确性和理解水平的指标进行了研究。该研究的目的是使用三种机器学习算法来预测WCPM的水平，这三种算法是集成分类器(EC)、决策树(DT)和K-最近邻(KNN)。本研究的数据是在2021年从杜胡克大学英语系二年级的100名库尔德语学生中收集的。结果表明，集成分类器(EC)的检测结果准确率最高，达到94%。此外，EC在三个绩效指标上的准确率、召回率和F1得分最高，为0.92。受试者工作特征曲线(Receiver Operating Character curve, ROC曲线)的分类效果也优于其他分类算法。综上所述，集成分类器是预测阅读率(准确率)WCPM的最佳和最准确的模型。
{"title":"Applying Ensemble Classifier, K-Nearest Neighbor and Decision Tree for Predicting Oral Reading Rate Levels","authors":"Jwan Abdulkhaliq Mohammed","doi":"10.30526/36.3.3102","DOIUrl":"https://doi.org/10.30526/36.3.3102","url":null,"abstract":"For many years, reading rate as word correct per minute (WCPM) has been investigated by many researchers as an indicator of learners’ level of oral reading speed, accuracy, and comprehension. The aim of the study is to predict the levels of WCPM using three machine learning algorithms which are Ensemble Classifier (EC), Decision Tree (DT), and K- Nearest Neighbor (KNN). The data of this study were collected from 100 Kurdish EFL students in the 2nd-year, English language department, at the University of Duhok in 2021. The outcomes showed that the ensemble classifier (EC) obtained the highest accuracy of testing results with a value of 94%. Also, EC recorded the highest precision, recall, and F1 scores with values of 0.92 for the three performance measures. The Receiver Operating Character curve (ROC curve) also got the highest results than other classification algorithms. Accordingly, it can be concluded that the ensemble classifier is the best and most accurate model for predicting reading rate (accuracy) WCPM. ","PeriodicalId":13022,"journal":{"name":"Ibn AL- Haitham Journal For Pure and Applied Sciences","volume":"62 1","pages":""},"PeriodicalIF":0.0,"publicationDate":"2023-07-20","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"72834079","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Azo-ligand-(HL)([4-((2-hydroxyquinolin-3-yl)diazenyl)-N-(5-methylisoxazol-3-yl)benzenesulfonamide] ) , (2- hydroxy quinolin derivative),reacts with the next metal ions (Cr (III), Fe (III),Co (II) and Cu(II)) forming stable complexes with unique geometries such as(tetrahedral for bothCo (II) and Cu (II), octahedral for both Cr (III) and Fe (III)). The creation of such complexes was detected by employing spectroscopic means involving ultraviolet-visible which proved the obtained geometries, Fourier transfer proved the involvement of coordinated water molecule in all complexes besides the pyrolysis (TGA & DSC) studies proved the coordination of water residues with metal ions inside the coordination sphere as well as chlorine atoms. Moreover element-micro-analysis and AAS that gave corresponding outcome with theoretically counting outcome. Magnetic quantification scan also indicates the unique geometries of complexes. The degradation of reactive oxygen entities for the compounds were estimated toward (DPPH-radical then matched to the standard-natural antioxidant, Gallic acid. The incomes display good radical degradations-activities.The lower IC50 value, the higher antioxidant activity. Depending on this conception, the order of our compounds besides Azo-species-HL is as follows: (G_A<[Co(L)(H2O)Cl]> [Cr(L)(H2O)Cl]> [Fe(L)(H2O)2Cl2]> [Cu(L)(H2O)Cl]).
{"title":"Cr (III), Fe (III), Co (II) and Cu(II)Metal ions complexes with azo compound derived from 2-hydroxy quinolin synthesis, characterization, thermal study and antioxidant activity","authors":"Adhraa Ghazi Abdulrazzaq, A. A. Al-Hamdani","doi":"10.30526/36.3.3068","DOIUrl":"https://doi.org/10.30526/36.3.3068","url":null,"abstract":"Azo-ligand-(HL)([4-((2-hydroxyquinolin-3-yl)diazenyl)-N-(5-methylisoxazol-3-yl)benzenesulfonamide] ) , (2- hydroxy quinolin derivative),reacts with the next metal ions (Cr (III), Fe (III),Co (II) and Cu(II)) forming stable complexes with unique geometries such as(tetrahedral for bothCo (II) and Cu (II), octahedral for both Cr (III) and Fe (III)). The creation of such complexes was detected by employing spectroscopic means involving ultraviolet-visible which proved the obtained geometries, Fourier transfer proved the involvement of coordinated water molecule in all complexes besides the pyrolysis (TGA & DSC) studies proved the coordination of water residues with metal ions inside the coordination sphere as well as chlorine atoms. Moreover element-micro-analysis and AAS that gave corresponding outcome with theoretically counting outcome. Magnetic quantification scan also indicates the unique geometries of complexes. The degradation of reactive oxygen entities for the compounds were estimated toward (DPPH-radical then matched to the standard-natural antioxidant, Gallic acid. The incomes display good radical degradations-activities.The lower IC50 value, the higher antioxidant activity. Depending on this conception, the order of our compounds besides Azo-species-HL is as follows: (G_A<[Co(L)(H2O)Cl]> [Cr(L)(H2O)Cl]> [Fe(L)(H2O)2Cl2]> [Cu(L)(H2O)Cl]).","PeriodicalId":13022,"journal":{"name":"Ibn AL- Haitham Journal For Pure and Applied Sciences","volume":"47 1","pages":""},"PeriodicalIF":0.0,"publicationDate":"2023-07-20","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"89044596","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
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