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Study of the thermal behaviour of a derivative based on a zirconium agent (modified montmorillonite) and determination of the physical characteristics 锆衍生物(改性蒙脱土)的热行为研究及物理特性测定
IF 0.5 4区 工程技术 Q4 CHEMISTRY, APPLIED Pub Date : 2023-01-01 DOI: 10.56042/ijct.v30i2.64537
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引用次数: 0
Equilibrium, kinetic and thermodynamic study for the efficient removal of malachite green dye onto untreated Morus nigra L. (mulberry tree) leaves powder and its biochar 桑树叶粉及其生物炭高效脱除孔雀石绿染料的平衡、动力学和热力学研究
IF 0.5 4区 工程技术 Q4 CHEMISTRY, APPLIED Pub Date : 2023-01-01 DOI: 10.56042/ijct.v30i2.66355
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引用次数: 0
Ultrasonication pretreatment of real-field pulping wastewater from bagasse-based paper mill 蔗渣造纸厂现场制浆废水的超声预处理
IF 0.5 4区 工程技术 Q4 CHEMISTRY, APPLIED Pub Date : 2023-01-01 DOI: 10.56042/ijct.v30i2.66923
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引用次数: 0
Mn3O4 and Ag2MnO4 nanoparticles loaded on g-C3N4 as magnetically catalysts for sonodegradation of dyes g-C3N4负载纳米Mn3O4和Ag2MnO4作为染料超声降解的磁性催化剂
4区 工程技术 Q4 CHEMISTRY, APPLIED Pub Date : 2023-01-01 DOI: 10.56042/ijct.v30i5.5210
New magnetic Mn3O4/g-C3N4 and Ag2MnO4/g-C3N4 nanocomposites have been synthesized based on Mn(II) Schiff base complex and used for sonodegradation of methylene blue (MB) and methyl orange (MO) dyes in aqueous solution. Ag2MnO4 nanoparticles (NPs) have been synthesized from Mn3O4 NPs and AgNO3 under ultrasonic irradiation for the first time. The results indicate that the sonodegradation method of dyes in the presence of Mn3O4/g-C3N4 and Ag2MnO4/g-C3N4 nanocomposites is better than solar degradation processes. The better photodegradation rates for MB and MO dyes observed in the presence of Ag2MnO4/g-C3N4 (k= 0.0916 min-1) and Mn3O4/g-C3N4 (k= 0.0381 min-1), as compared to pure Mn3O4 and Ag2MnO4 compounds The synthesized nanocomposites are good fluorescent materials.
以Mn(II)席夫碱配合物为基料,合成了新型磁性Mn3O4/g-C3N4和Ag2MnO4/g-C3N4纳米复合材料,并用于水溶液中亚甲基蓝(MB)和甲基橙(MO)染料的超声降解。本文首次在超声辐照下,以mn3o4nps和AgNO3为原料合成了Ag2MnO4纳米颗粒。结果表明,在Mn3O4/g-C3N4和Ag2MnO4/g-C3N4纳米复合材料存在下,超声降解染料的方法优于太阳降解方法。Ag2MnO4/g-C3N4 (k= 0.0916 min-1)和Mn3O4/g-C3N4 (k= 0.0381 min-1)对MB和MO染料的光降解率均优于纯Mn3O4和Ag2MnO4,所合成的纳米复合材料是良好的荧光材料。
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引用次数: 0
Thermal and mechanical properties of nanofilled poly(methyl methacrylate) nanocomposites produced by two ultrasonic methods 两种超声法制备纳米填充聚甲基丙烯酸甲酯纳米复合材料的热力学性能
4区 工程技术 Q4 CHEMISTRY, APPLIED Pub Date : 2023-01-01 DOI: 10.56042/ijct.v30i5.5216
PPMANC1 and PMMANC2 nanocomposites have been fabricated using two reactive clays by two methods and characterized in order to estimate the impact of the different dispersion states on the mechanical properties. A simple and economical process of polymerisation is adopted to develop PMMANC nanocomposites using an Algerian clay, trying to optimize the distribution of PMMA in the clay layers. Two distinct types of organic clays have been mined, labelled as (i) benzyltrimethyl ammonium chloride (BTBA-Mag (1CEC)) and (ii) hexadecyltrimethylammonium bromide (HDTAB-MagCTA (2.5CEC)). Evaluation of the properties of the PMMANC1 and PMMANC2 nanocomposites are carried out using different physicochemical techniques. The results obtained by XRD, transmission electron microscopy reveal that the modified maghnite are well dispersed in the matrix and significant improvements in thermal properties are observed from thermal analysis. The Young module, impact resistance and tensile strength of the nanocomposites incorporating 5% organoargile are the most effective compared to the two synthesis processes.
以两种活性粘土为原料,采用两种方法制备了PPMANC1和PMMANC2纳米复合材料,并对其进行了表征,以评估不同分散状态对其力学性能的影响。采用一种简单而经济的聚合工艺,利用阿尔及利亚粘土制备PMMANC纳米复合材料,试图优化PMMA在粘土层中的分布。已经开采出两种不同类型的有机粘土,标记为(i)苄基三甲基氯化铵(BTBA-Mag (1CEC))和(ii)十六烷基三甲基溴化铵(HDTAB-MagCTA (2.5CEC))。采用不同的物理化学技术对PMMANC1和PMMANC2纳米复合材料的性能进行了评价。XRD、透射电镜分析结果表明,改性后的磁铁矿在基体中分散良好,热性能有明显改善。与两种合成工艺相比,Young模块、含5%有机凝胶的纳米复合材料的抗冲击性和抗拉强度是最有效的。
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引用次数: 0
Entropy generation on chemically reactive hydromagnetic oscillating flow of third grade nanofluid in a porous channel with Cattaneo-Christov heat flux 具有Cattaneo-Christov热流通量的三级纳米流体在多孔通道中化学反应性磁振荡流动的熵生成
IF 0.5 4区 工程技术 Q4 CHEMISTRY, APPLIED Pub Date : 2023-01-01 DOI: 10.56042/ijct.v30i1.68837
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引用次数: 0
Voltammetric investigations of functional dyspepsia drug acotiamide at pencil graphite electrode: An eco-friendly and cost effective stripping detection method 铅笔石墨电极上对功能性消化不良药物阿哥替胺的伏安法研究:一种环保、经济的溶出检测方法
IF 0.5 4区 工程技术 Q4 CHEMISTRY, APPLIED Pub Date : 2023-01-01 DOI: 10.56042/ijct.v30i1.58991
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引用次数: 2
Comparison study of COD adsorption on bentonite-based nanocomposite materials in landfill leachate treatment: Characterization, Isotherms, Kinetics and Regeneration 膨润土基纳米复合材料处理垃圾渗滤液中COD吸附的比较研究:表征、等温线、动力学和再生
IF 0.5 4区 工程技术 Q4 CHEMISTRY, APPLIED Pub Date : 2023-01-01 DOI: 10.56042/ijct.v30i3.68031
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引用次数: 0
Hydrothermal synthesis of mesoporous TiO2 nanoparticles for enhanced photocatalytic degradation of organic dye 水热合成介孔TiO2纳米颗粒增强光催化降解有机染料
IF 0.5 4区 工程技术 Q4 CHEMISTRY, APPLIED Pub Date : 2023-01-01 DOI: 10.56042/ijct.v30i3.61561
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引用次数: 0
Hydrogels based on mucilage of underutilized cereals: Synthesis and characterization 基于未充分利用的谷物粘液的水凝胶:合成和表征
IF 0.5 4区 工程技术 Q4 CHEMISTRY, APPLIED Pub Date : 2023-01-01 DOI: 10.56042/ijct.v30i4.70238
Ritu Sharma, Rajinder K. Gupta, A. Rani
Mucilage is a natural polysaccharide with a variety of physicochemical and structural properties. Plant-derived mucilage has a wide range of applications, such as binding agent, stabilizer, emulsifying agent, thickening agent, and gelling agent. This study investigated the potential of underutilized cereals’ mucilage and further explored their application by synthesizing mucilage-based hydrogels. For this purpose, we have explored four new sources of mucilage, namely adzuki beans (A b ), amaranth (A m ), proso millet (P r ), and little millet (L m ). The underutilized cereals’ mucilage application has been examined by developing hydrogels through the free radical co-polymerization technique. Mucilages are confirmed to be a natural thickening and a substitute for synthetic polymers after being evaluated physically and phytochemically. Structural analysis of mucilages and their hydrogels (A b H, A m H, P r H & L m H) were characterized by using FTIR-ATR, XRD, 1 H & 13 C NMR techniques. It confirms that all four mucilages are rich in polysaccharide residues and grafting of sodium acrylate has been successfully done on mucilages. Thermal gravimetric analyses represent the better thermal stability of the synthesized hydrogels than their respective mucilages. SEM confirms the porous structure of the mucilages and their hydrogels. All of these studies demonstrated that the underutilized mucilage from cereals might be a good feedstock for a hydrogel-forming agent, which can be explored in the food, cosmetics, and pharmaceutical industries.
粘液是一种天然多糖,具有多种物理化学和结构特性。植物源性粘液具有广泛的用途,如粘合剂、稳定剂、乳化剂、增稠剂、胶凝剂等。本研究探讨了未充分利用的谷物粘液的潜力,并通过合成粘液基水凝胶进一步探索其应用。为此,我们探索了四种新的粘液来源,即小豆(A b)、苋菜(A m)、小小米(P r)和小小米(L m)。利用自由基共聚合技术制备水凝胶,考察了未充分利用的谷物的黏液应用。经过物理和植物化学评价,胶浆是一种天然增稠剂和合成聚合物的替代品。采用FTIR-ATR、XRD、1h和13c NMR等技术对胶浆及其水凝胶(A b H、A m H、P r H和L m H)进行结构表征。证实了四种胶浆均含有丰富的多糖残基,并成功地在胶浆上接枝丙烯酸钠。热重分析表明,合成的水凝胶的热稳定性优于它们各自的黏液。扫描电镜证实了黏液及其水凝胶的多孔结构。所有这些研究都表明,未充分利用的谷物粘液可能是水凝胶形成剂的良好原料,可以在食品,化妆品和制药工业中进行探索。
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引用次数: 1
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Indian Journal of Chemical Technology
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