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Exploration of Lipid Content in Sargassum binderi Algae from the North Coast of Manokwari West Papua 探索西巴布亚马诺夸里北海岸马尾藻中的脂质含量
Pub Date : 2024-03-01 DOI: 10.24114/ijcst.v7i1.56442
Jamius Bin Stepanus, D. Kolibongso
The aim of this research is to determine the potential of biodiesel from the algae Sargassum binderi from the North Coast of Manokwari by determining the lipid components contained in the algae. Lipid extraction was carried out using the soxhletation method with n-hexane solvent. Lipid percentage was determined via GCMS analysis. The research results obtained 4 lipid components consisting of hexadecanoic acid (palmitic acid), 9,12-hexadecadienoic acid, 9-octadecenoic acid (Z) (oleic acid) and octadecanoic acid (stearic acid) with a percentage of 18.12%, 4.75%, 19.4% and 4.29% respectively. The total percentage of lipid components extracted was 46.56%, almost half of the total extract.
本研究的目的是通过测定马诺夸里北海岸马尾藻所含的脂质成分,确定从马尾藻中提取生物柴油的潜力。脂质提取采用正己烷溶剂索氏提取法。通过 GCMS 分析确定脂质百分比。研究结果得出了 4 种脂质成分,包括十六烷酸(棕榈酸)、9,12-十六碳二烯酸、9-十八烯酸(Z)(油酸)和十八烷酸(硬脂酸),所占百分比分别为 18.12%、4.75%、19.4% 和 4.29%。提取的脂质成分总比例为 46.56%,几乎占总提取物的一半。
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引用次数: 0
Type Design of Continuous Stirred Tank Reactors (CSTRs) for Bath Bomb Lavender Production 用于生产浴缸薰衣草的连续搅拌罐反应器(CSTR)的类型设计
Pub Date : 2024-03-01 DOI: 10.24114/ijcst.v7i1.56441
R. Namira, Atha Nissa
One of the most widely used complimentary bath products is lavender bath bomb, which has a pleasant scent, a foamy feel, and a relaxing effect. This is a chance to expand the production of bath bombs. The manufacture of lavender bath bombs on a large scale (industry) can be done using a continuous stirred tank reactors (CSTRs). This research aims to design a reactor to react the raw materials of lavender bath bomb through mixing reaction. The method used is by conducting computational analysis and calculation of the reactor and its stirrer and mass balance as the basis for calculation using Microsoft Excel. According to the computation results, the examined reactor needs one stirrer with a power of 141 horsepower and a total volume of 7.2334 ft3 with a height of 27.1045 in. These computational and analytical results can describe the production system using the reactor as a learning tool.
薰衣草浴霸是使用最广泛的免费沐浴产品之一,它气味宜人,泡沫丰富,具有放松身心的效果。这是一个扩大浴霸生产的机会。使用连续搅拌罐反应器(CSTR)可以大规模(工业化)生产薰衣草浴霸。本研究旨在设计一种反应器,通过混合反应对薰衣草浴霸的原材料进行反应。采用的方法是使用 Microsoft Excel 对反应器及其搅拌器进行计算分析和计算,并以质量平衡作为计算基础。根据计算结果,所研究的反应器需要一个功率为 141 马力的搅拌器,总容积为 7.2334 立方英尺,高度为 27.1045 英寸。这些计算和分析结果可以描述将反应器作为学习工具的生产系统。
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引用次数: 0
Formulation dan Phyical Stability Test Of Turi Leaf Extract (Sesbania grandiflora L.) Silver Nanoparticle Soap 都里叶(Sesbania grandiflora L.)提取物银纳米粒子皂的配制和植物稳定性测试
Pub Date : 2024-03-01 DOI: 10.24114/ijcst.v7i1.56444
Astri Aulia Savitri, Wilda Amananti, Joko Santoso
One metal that is widely researched is silver (Ag) which can be used as an antibacterial and antifungal. The method that is widely developed is the biological method, also called biosynthesis. Biosynthesis is a synthesis method using media from plant extracts. This research was conducted to determine the best formulation of Ag nanoparticle soap from turi (sesbania grandiflora) leaf extract based on its stability test. To obtain turi leaf extraction using the infusion method, a flavonoid compound test was carried out to determine the flavonoid compound content. After knowing the existence of flavonoid compounds, the wavelength was determined using UV-Vis Spectrophotometry. In the nanoparticle soap formula, a nanoparticle soap preparation was made which was then tested for the physical quality of Ag nanoparticle soap from turi leaf extract (Sesbania Grandiflora L). The gel-shaped preparation has a characteristic oleum rosae odor and a yellow to blackish soap color. Test the homogeneity to see if there are coarse grains on the surface of the soap. The specific gravity test results of all soap formulations meet the criteria for good soap. The high foam value in soap preparations is between 6.1 – 12.5 mM. The results of measuring the absorption values for concentrations of 1 mM, 2 mM, and 3 mM show that the optimum absorption results in liquid soap preparations are a concentration of 3 mM with a wavelength of 300 nm with an absorbance value of 1.105. The research results showed that turi leaf extract (sesbania grandiflora L) had an effect on the physical stability of Ag nanoparticle soap and met the standards set by SNI. Among formulation 1 with a concentration of 0.03, formulation II with a concentration of 0.06 and formulation III with a concentration of 0.09, the turi leaf extract soap preparation showed the best physical properties in formulation 1 with a concentration of 0.03 in the pH stability test.
银(Ag)是一种被广泛研究的金属,可用作抗菌剂和抗真菌剂。目前广泛开发的方法是生物法,也称为生物合成法。生物合成法是一种利用植物提取物的培养基进行合成的方法。本研究的目的是根据其稳定性测试,确定从土里(sesbania grandiflora)叶提取物中提取银纳米粒子皂的最佳配方。在使用浸泡法获得土里叶提取物时,进行了黄酮化合物测试,以确定黄酮化合物的含量。在确定黄酮类化合物的存在后,使用紫外可见分光光度法测定其波长。在纳米微粒皂配方中,制备了纳米微粒皂制剂,然后测试了从土里叶(Sesbania Grandiflora L)提取物中提取的银纳米微粒皂的物理质量。凝胶状制剂具有油橄榄特有的气味,皂色为黄色至黑色。测试均匀性,看肥皂表面是否有粗颗粒。所有肥皂配方的比重测试结果都符合优质肥皂的标准。肥皂制剂的高泡沫值在 6.1 - 12.5 毫摩尔之间。对 1 毫摩尔、2 毫摩尔和 3 毫摩尔浓度的吸收值进行测量的结果表明,液体肥皂制剂的最佳吸收值为 3 毫摩尔浓度,波长为 300 纳米,吸收值为 1.105。研究结果表明,土里叶提取物(sesbania grandiflora L)对纳米银皂的物理稳定性有影响,达到了 SNI 规定的标准。在浓度为 0.03 的配方 1、浓度为 0.06 的配方 II 和浓度为 0.09 的配方 III 中,浓度为 0.03 的配方 1 在 pH 稳定性测试中显示出最好的物理性质。
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引用次数: 0
Antioxidant Activity Test of Barangan Banana Peel (Musa Acuminata Linn) Etanol Extract With DPPH Method DPPH法测定巴兰干香蕉皮乙醇提取物抗氧化活性
Pub Date : 2023-07-31 DOI: 10.24114/ijcst.v6i2.49373
Nurul Arista, R. Siregar
Barangan banana (Musa acuminata linn) is also called Medan banana which is often found in North Sumatra. Banana peels are known to contain phenolic compounds that have potential as antioxidants. This study aims to determine the antioxidant activity of raw and ripe banana peel extract of Barangan banana (Musa acuminata linn) using the DPPH (1,1-diphenyl-2-pikrihidrazil) method. The data obtained was calculated to determine the antioxidant activity. The results showed that the antioxidant activity of the ethanol extract of Barangan raw banana peel IC50 = 32,52 μg/mL, the ethanol extract of Barangan ripe banana peel IC50 = 83,60 μg/mL, and the vitamin C comparator obtained an IC50 value of 5,00. Raw banana peel extract has higher antioxidant activity than ripe banana peel extract.
巴兰干香蕉(Musa acuminata linn)也被称为棉兰香蕉,通常在北苏门答腊岛发现。众所周知,香蕉皮含有酚类化合物,具有抗氧化剂的潜力。本研究旨在采用DPPH(1,1-二苯基-2-吡krihidrazil)法测定Barangan banana (Musa acuminata linn)生香蕉皮和熟香蕉皮提取物的抗氧化活性。计算所得数据以测定其抗氧化活性。结果表明,巴兰干生香蕉皮乙醇提取物的抗氧化活性IC50 = 32、52 μg/mL,巴兰干熟香蕉皮乙醇提取物的抗氧化活性IC50 = 83、60 μg/mL,维生素C比较物的IC50值为5000。生香蕉皮提取物比熟香蕉皮提取物具有更高的抗氧化活性。
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引用次数: 0
Characterization of Silica Nanoparticles from Pumice as an Aerogel Adsorbent 浮石二氧化硅纳米颗粒作为气凝胶吸附剂的表征
Pub Date : 2023-07-31 DOI: 10.24114/ijcst.v6i2.49368
Rahma Hidayah, D. Kurniawati, Alizar Alizar
Pumice is often found around the banks of rivers, this stone is a type of igneous rock formed from volcanic eruptions. One of the compounds contained in pumice is silica. Therefore, the synthesis of silica nanoparticles from pumice using the sol gel method was used because it is simpler and more efficient in terms of cost and processing time. the initial step was by reacting pumice powder and NaOH at 70°C - 80°C then synthesized by adding 2M HCI to form a gel or white precipitate, soaking in ethanol, teos, hexane solutions was then synthesized to become an aerogel. Silica synthesis results into silica aerogels were characterized by FTIR and XRF. From FTIR silanol and siloxane functional groups were found, and the SiO2 composition increased to 93,299% after synthesis.
浮石经常在河岸周围发现,这种石头是一种由火山喷发形成的火成岩。浮石中含有的一种化合物是二氧化硅。因此,采用溶胶-凝胶法从浮石中合成二氧化硅纳米颗粒,因为它在成本和处理时间方面更简单,效率更高。初始步骤是浮石粉与NaOH在70℃- 80℃下反应,然后加入2M HCI合成,形成凝胶或白色沉淀,在乙醇、正己烷溶液中浸泡,然后合成成气凝胶。用FTIR和XRF对二氧化硅气凝胶的合成结果进行了表征。从红外光谱中发现了硅醇和硅氧烷官能团,合成后SiO2含量提高到93,299%。
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引用次数: 0
Adsorption Of Soluble Ammoniac Using A Porous Polymer Composite Cu-(TAC) And Activated Carbon Empty Fruit Palm Oil 多孔聚合物复合Cu-(TAC)与活性炭空果棕榈油吸附可溶性氨
Pub Date : 2023-07-31 DOI: 10.24114/ijcst.v6i2.49375
Rissah Maulina, R. Selly, H. Nasution, Jasmidi Jasmidi, M. Zubir, Siti Rahmah, P. Faradilla
This study aims to determine the stages in the process of making activated carbon, synthesis of porous polymer composites Cu(TAC) and activated carbon composites (KA-Cu(TAC) for adsorption of dissolved ammonia (NH4OH). To know the characterization results of activated carbon and KA- Cu(TAC), as well as knowing the optimum mass, concentration, and contact time of activated carbon KA-Cu(TAC) for the adsorption of dissolved ammonia. The research stages started from Empty Oil Palm Bunches (EFB) used as biosorbents for carbon production at 500oC. The resulting product was activated with H3PO4, then modified with porous polymer Cu(TAC) to make a composite. The KA-Cu(TAC) composite was synthesized by reflux method. Then MOFs, activated carbon and KACu(TAC) composite were characterized by BET. The BET characterization results showed that the successfully synthesized KA-Cu(TAC) composite experienced an increase in surface area.In the NH4OH adsorption process the optimum mass efficiency on activated carbon still increased at 8 grams while the KA-Cu(TAC) composite obtained an efficiency of 36, 6% and optimally at a mass of 4 g. At variations in concentration, the efficiency of the two samples still decreased. And the optimum time efficiency obtained in the NH4OH adsorption process with activated carbon was 70% and the KA-Cu(TAC) composite was 86.6%, both samples were equally optimal at 75 minutes.
本研究旨在确定活性炭制备过程中的各个阶段,合成多孔聚合物复合材料Cu(TAC)和吸附溶解氨(NH4OH)的活性炭复合材料KA-Cu(TAC)。了解活性炭和KA-Cu(TAC)的表征结果,了解活性炭KA-Cu(TAC)吸附溶解氨的最佳质量、浓度和接触时间。研究阶段从空油棕束(EFB)作为生物吸附剂在500℃下生产碳开始。将所得产物用H3PO4活化,再用多孔聚合物Cu(TAC)进行改性制备复合材料。采用回流法制备了KA-Cu(TAC)复合材料。然后用BET对MOFs、活性炭和KACu(TAC)复合材料进行表征。BET表征结果表明,成功合成的KA-Cu(TAC)复合材料的表面积有所增加。活性炭吸附NH4OH的最佳质量效率在8 g时仍有提高,而KA-Cu(TAC)复合材料吸附NH4OH的最佳质量效率在4 g时达到36.6%。在浓度变化时,两种样品的效率仍然下降。活性炭吸附NH4OH的最佳时间效率为70%,KA-Cu(TAC)复合材料吸附NH4OH的最佳时间效率为86.6%,两种样品在75 min时同样最佳。
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引用次数: 0
Synthesis of Cu-(TAC) Composite with Oil Palm Empty Fruit Bunch Waste Activated Carbon Through the Adsorption Mechanism of βCarotene 油棕空果串废活性炭吸附β -胡萝卜素合成Cu- TAC复合材料
Pub Date : 2023-07-31 DOI: 10.24114/ijcst.v6i2.49371
Lidia Mutia Sari, Jasmidi Jasmidi, H. Nasution, M. Zubir, Siti Rahmah, R. Selly, P. Faradilla
This study aims to determine the adsorption and desorption abilities of activated carbon and Cu-(TAC) composites in the β-carotene adsorption process on Crude Palm Oil (CPO). Oil Palm Empty Fruit Bunches (EFB) are used as activated carbon and modified with MOFs Cu-(TAC). Activated carbon and Cu-(TAC) composites were characterized by XRD, SEM-EDX, and BET. The concentration of β-carotene absorbed during the adsorption process was analyzed using a UV-Vis spectrophotometer. The variations used to determine the optimum conditions for absorption of β-carotene were the mass variation of the adsorbent and the variation in the contact time between the adsorbent and adsorbate. The results of the characterization of activated carbon showed a sharp absorption in the presence of O-H, C-H and C-O groups indicating the presence of cellulose. Activated carbon is amorphous and the Cu-(TAC) composite has a crystal structure and its pore size is mesoporous. The optimum conditions for the use of activated carbon for β-carotene adsorption were the mass variation of 8 grams with 0.495 ppm of β-carotene and contact time at 120 minutes with 2.605 ppm of β-carotene. The optimum condition of the Cu-(TAC) composite in the β-carotene adsorption process was at 4 gram mass variation with 1.026 ppm β-carotene content and optimum contact time at 60 minutes with 6.384 ppm β-carotene content. The ability of desorption can be seen from the percentage of desorption showing activated carbon in the 150th minute with 96.252% while in the Cu-(TAC) composite in the 30th minute with 88.188%.
本研究旨在确定活性炭和Cu-(TAC)复合材料对粗棕榈油(CPO)中β-胡萝卜素的吸附和解吸能力。以油棕空果束(EFB)为活性炭,用MOFs Cu-(TAC)改性。采用XRD、SEM-EDX和BET对活性炭和Cu- TAC复合材料进行了表征。用紫外-可见分光光度计测定吸附过程中β-胡萝卜素的浓度。确定β-胡萝卜素吸附最佳条件的变量是吸附剂质量的变化和吸附剂与吸附物接触时间的变化。表征结果表明,在O-H、C-H和C-O基团存在时,活性炭有明显的吸收,表明纤维素的存在。活性炭是无定形的,Cu-(TAC)复合材料具有晶体结构,孔径为介孔。活性炭吸附β-胡萝卜素的最佳条件为:当β-胡萝卜素浓度为0.495 ppm时,质量变化量为8 g;当β-胡萝卜素浓度为2.605 ppm时,接触时间为120 min。Cu-(TAC)复合材料吸附β-胡萝卜素的最佳条件为质量变化4 g, β-胡萝卜素含量为1.026 ppm;最佳接触时间为60 min, β-胡萝卜素含量为6.384 ppm。从150分钟活性炭的解吸率为96.252%,30分钟Cu-(TAC)复合材料的解吸率为88.188%可以看出其解吸能力。
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引用次数: 0
The Jasmine Plant Growth Effect Supplemented with Liquid Organic Fertilizer from Banana Peels 添加香蕉皮液态有机肥对茉莉植株生长的影响
Pub Date : 2023-07-31 DOI: 10.24114/ijcst.v6i2.49362
R. Selly, Angel Shylvia Panjaitan, Dinda Natalisa Br. Gurusinga,, Dira Khairunissa, Santa Maria Manalu, Siti Rahmah
Liquid organic fertilizer (LOF) is a solution resulting from the decomposition of organic matter originating from plant residues, agro-industrial waste, animal waste, and human waste containing more than one nutrient. LOF can be made from liquid organic matter (liquid organic waste), by composting and providing composting activators so that a LOF that is stable and contains complete nutrients can be produced. The use of LOF has the advantage that although it is often used it does not damage the soil and plants, the use of organic waste as fertilizer can help improve soil structure and quality, because it contains nutrients and other organic matter. The process of adding different fertilizers to the plants for 10 days showed that there were different height changes for each plant. With only water, the plants only reach 0.1 cm difference in 7 days. The plants that were given LOF and NPK (Chemical Fertilizer) gained height in only 4 days with heights 15.6 cm and 16 cm respectively. The growth percentage between LOF and NPK showed a significant difference in 4 days with 0.6% and 3.2 % respectively.
液态有机肥(LOF)是一种由植物残留物、农业工业废物、动物废物和人类废物中含有一种以上营养物质的有机物分解产生的溶液。LOF可以由液态有机物(液态有机废物)制成,通过堆肥和提供堆肥活化剂,从而产生稳定且含有完整营养的LOF。使用LOF的优点是,虽然它经常被使用,但它不会损害土壤和植物,使用有机废物作为肥料可以帮助改善土壤结构和质量,因为它含有营养物质和其他有机物。在施用不同肥料10 d的过程中,每株植物的高度变化不同。在只浇水的情况下,植株在7天内只差0.1厘米。施用LOF和氮磷钾的植株在4 d内长高,分别为15.6 cm和16 cm。LOF和NPK在4 d内的生长率差异显著,分别为0.6%和3.2%。
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引用次数: 0
Comparison between Transesterification Reaction with Microwave Heating and Conventional Heating for Biodiesel Production from Coconut Oil with Alkaline Catalyst 微波加热与常规加热反应制备椰子油碱性生物柴油的比较
Pub Date : 2023-07-31 DOI: 10.24114/ijcst.v6i2.49364
Srunika Boangmanalu, E. Ginting
Biodiesel is a biofuel made from vegetable oil through an esterification-transesterification process. The process of making biodiesel is carried out by conventional heating methods and microwave heating. The reaction process was carried out according to the specified variables, with a concentration of 0.1% of the volume of methanol and a variable microwave power of 135, 225 and 315 watts with time variations of 5, 3 and 1 minute, as well as conventional heating at 60°C for 1 hour. The best result is the one using microwave heating with a power of 315 watts for 1 minute. The best biodiesel yield is 88.879%, with water content of 0.01%, an acid number of 0.56 Kg-KOH/g, a density of 0.892 g/mL and a viscosity of 2.617 cSt. The best result of biodiesel oil in comparison of is using the microwave heating method.
生物柴油是一种由植物油通过酯化-酯交换过程制成的生物燃料。生物柴油的制备过程采用常规加热和微波加热两种方式进行。反应过程按规定的变量进行,浓度为甲醇体积的0.1%,微波功率为135、225和315瓦,时间变化为5、3和1分钟,60℃常规加热1小时。效果最好的是用315瓦的微波加热1分钟。最佳生物柴油产率为88.879%,水含量为0.01%,酸数为0.56 Kg-KOH/g,密度为0.892 g/mL,粘度为2.617 cSt。生物柴油的微波加热效果最好。
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引用次数: 0
Synthesis and Characterization of Activated Carbon/Alginate/Nanocellulose-Cu Composites 活性炭/海藻酸盐/纳米纤维素- cu复合材料的合成与表征
Pub Date : 2023-07-31 DOI: 10.24114/ijcst.v6i2.49369
Atikah Nur Syahirah, Jasmidi Jasmidi, Z. Muchtar, Siti Rahmah, A. Pulungan, M. Zubir, R. Selly, P. Faradilla
OPEFB is one source of natural fiber-based composites which have the potential to become activated carbon and nanocellulose. This study aims to synthesize and characterize the activated carbon/alginate/nanocellulose-Cu composite. The characterization used in this study is FTIR and PSA. The synthesis of activated carbon/alginate/nanocellulose-Cu composites began with a process of carbonization and activation with H3PO4 to produce Activated Carbon. Followed by a bleaching process with NaClO2 and a delignification process with Na2SO3 and NaOH to produce Nanocellulose. Alginate using commercial alginate. Furthermore, the three ingredients were mixed until homogeneous and put into a 0.1M CuSO4 solution to produce beads. The results of the characterization of characterization of PSA Nanocellulose obtained a particle size of 41.05 nm and the result of FTIR characterization on the activated carbon/alginate/nanocellulose-Cu composite contained the functional group OH group, triple C bond from stretching alkyne, C=C aromatic group, C-H alkane group, C-O group, the P=O stretching vibration of the P-O-C group and the alcohol OH group expressing the active carbon; there are functional groups of hydroxyl (OH), carboxyl, carbonyl, and C-O-C and –COOH bonds which represent alginate and there are OH functional groups, stretching C-H bonds, C-O stretching, stretching C-C, and β- glucosidic bonds between glucose units which indicate nanocellulose.
OPEFB是天然纤维基复合材料的一种来源,具有成为活性炭和纳米纤维素的潜力。本研究旨在合成活性炭/海藻酸盐/纳米纤维素-铜复合材料并对其进行表征。本研究使用的表征是FTIR和PSA。活性炭/海藻酸盐/纳米纤维素- cu复合材料的合成首先采用炭化和H3PO4活化法制备活性炭。然后用NaClO2进行漂白,再用Na2SO3和NaOH进行脱木质素处理,得到纳米纤维素。使用商业海藻酸盐。将三种成分混合均匀后,放入0.1M的CuSO4溶液中制珠。表征结果表明,表征的PSA纳米纤维素粒径为41.05 nm, FTIR表征结果表明,活性炭/海藻酸盐/纳米纤维素- cu复合材料含有官能团OH基团、三C键由拉伸炔、C=C芳香基团、C- h烷烃基团、C-O基团、P=O伸缩振动的P-O-C基团和表达活性炭的醇OH基团;羟基(OH)、羧基、羰基、C-O- c和- cooh键代表海藻酸盐,羟基官能团、伸展的C-H键、伸展的C-O键、伸展的C-C键和葡萄糖单元之间的β-糖苷键表示纳米纤维素。
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引用次数: 0
期刊
Indonesian Journal of Chemical Science and Technology (IJCST)
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