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Review of experimental methods for studying the hydrodynamics of gas-solid fluidized beds 气固流化床流体力学实验研究方法综述
Pub Date : 1986-04-01 DOI: 10.1021/I200033A001
N. Cheremisinoff
A state-of-the-art review of experimental methods for studying the hydrodynamics of gas-solids fluidization is presented. Techniques applied by various investigators to obtain statistically representative properties of bubble behavior and particle mixing in the dense region and particle dynamics in the region above the bed surface are described. Measurement principles, descriptions of the experimental setups, and accuracy of the measurements are presented. Guidelines for measurement system selection are given.
介绍了气固流化流体力学实验方法的最新进展。本文描述了各种研究人员用于获得具有统计代表性的气泡行为和致密区域的颗粒混合特性以及床面以上区域的颗粒动力学的技术。介绍了测量原理、实验装置的描述和测量的精度。给出了测量系统选择的指导原则。
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引用次数: 68
Improved graphical-analytical method for the design of reverse-osmosis plants 反渗透装置设计的改进图解分析法
Pub Date : 1986-04-01 DOI: 10.1021/I200033A005
F. Evangelista
Methode de Mc Cabe et Thiele de calcul des unites d'osmose inverse avec des rejets entre 80 et 100%. Lorsque l'on fixe le facteur de concentration total et que l'on connait les conditions operatoires et les caracteristiques des membranes, cette methode permet de connaitre le nombre de lignes de modules en parallele, le nombre de modules en serie dans chaque ligne, le debit du permeat et la concentration moyenne du permeat, par de simples equations explicites
Mc Cabe和Thiele的反渗透装置的计算方法在80 - 100%之间。当固定因子浓度和总要知道膜的发展条件和特点,这种方法可以了解许多线路平行单元,单元数》系列中的每一行,借方permeat permeat日平均浓度,并明确由简单的方程
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引用次数: 36
Gas holdup and mass-transfer characteristics in a three-phase bubble column 三相气泡塔的气含率和传质特性
Pub Date : 1986-04-01 DOI: 10.1021/I200033A020
E. Sada, H. Kumazawa, Choulho Lee, Takahisa Iguchi
En utilisant des solutions aqueuses de sucrose on compare l'influence de la vitesse superficielle du gaz et des proprietes physiques du liquide sur la retenue de gaz et sur le coefficient de transfert volumetrique du liquide dans une colonne a bulle a deux phases, avec des resultats precedents. Etude quantitative de l'influence de particules en suspension, au moyen de diverses sortes de particules mouillables
用蔗糖水溶液比较了气体表面速度和液体物理性质对两相气泡柱中气体保留和液体体积传递系数的影响,并与上述结果进行了比较。利用各种可湿颗粒对悬浮颗粒影响的定量研究
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引用次数: 35
Suppression of sulfur trioxide formation in a monolithic catalytic converter for cars due to oscillating reaction conditions 振荡反应条件对整体式汽车催化转化器中三氧化硫生成的抑制作用
Pub Date : 1986-04-01 DOI: 10.1021/I200033A031
P. Olsson, N. Schoeoen
The net formation of sulfur trioxide in the presence of an excess of carbon monoxide with respect to sulfur dioxide was studied under different reaction conditions in a single element of a commercial monolithic Pt, Rh converter. Conditions giving rise to self-oscillations were found to result in a complete oxidation of carbon monoxide and in only a 10% net conversion of sulfur dioxide.
在商业单片Pt, Rh转炉的不同反应条件下,研究了在一氧化碳相对于二氧化硫过量的情况下,三氧化硫的净形成。发现引起自振荡的条件导致一氧化碳完全氧化,而二氧化硫的净转化率仅为10%。
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引用次数: 3
KINETIC-STUDIES OF AMINATION OF 11-BROMOUNDECANOIC ACID 11-溴癸酸胺化反应动力学研究
Pub Date : 1986-04-01 DOI: 10.1021/I200033A003
Shrikant B. Gudadhe, D. Ramkumar, A. P. Kudchadker
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引用次数: 2
Novel process for direct conversion of free energy of mixing into electric power 将混合自由能直接转化为电能的新方法
Pub Date : 1986-04-01 DOI: 10.1021/I200033A016
J. Jagur-grodzinski, R. Kramer
Direct conversion of salinity gradients into electric power as well as production of an acid and a base, simultaneous to generation of electricity, was investigated. Devices that combined features of an electrodialytic pile with those of fuel cells or of electrochemical half cells were designed. Electrodes of the electrochemical half cells were restored to their initial condition by simple reversal of the flow pattern. Fuel cells in the investigated system used water as the fuel and air as the oxidant. Energy extracted from salinity gradients at power density of up to 1 W/m/sup 2/ of the membrane yields up to 0.6 MW of electric power per m/sup 3//s of river or brackish water. Sodium hydroxide is obtained in an amount which corresponds to the number of coulombs of electricity generated in the process. Part of the produced HCI is, however, lost.
研究了将盐度梯度直接转化为电能以及在发电的同时生产酸和碱的方法。设计了结合了电渗析堆与燃料电池或电化学半电池特性的装置。通过简单的反流,使电化学半电池的电极恢复到初始状态。所研究系统中的燃料电池使用水作为燃料,空气作为氧化剂。从盐度梯度中提取的能量在膜的功率密度高达1 W/m/sup 2/ s时,每m/sup 3/ s的河水或微咸水可产生高达0.6 MW的电力。得到的氢氧化钠的量与该过程中产生的库仑电的数量相对应。然而,部分产生的HCI丢失了。
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引用次数: 89
Methanol synthesis reactions: calculations of equilibrium conversions using equations of state 甲醇合成反应:用状态方程计算平衡转化
Pub Date : 1986-04-01 DOI: 10.1021/I200033A021
Te Chang, R. W. Rousseau, P. K. Kilpatrick
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引用次数: 56
Catalyst performance in continuous hydrotreating of Rundle shale oil Rundle页岩油连续加氢处理催化剂性能研究
Pub Date : 1986-04-01 DOI: 10.1021/I200033A029
T. G. Harvey, T. Matheson, K. Pratt, M. Stanborough
The 100-400C fraction of Rundle shale oil has been processed over three commercial sulfide hydrotreating catalysts at 400C, 13.8-MPa hydrogen pressure, and 1.0-h/sup -1/ LHSV. Ni-W/SiO/sub 2/-Al/sub 2/O/sub 3/ deactivated rapidly, Co-Mo/Al/sub 2/O/sub 3/ was effective, and Ni-Mo/Al/sub 2/O/sub 3/ was most effective. The Ni-Mo should allow production of a good substitute crude oil but not single-step production of finished middle-distillate fuels. Hydroprocessing under the above conditions did not alter the boiling range of the oil much, but all the catalysts brought about hydrogenation of diaromatic material, a concomitant increase in hydroaromatics, and some cracking of polyaromatics. All the catalysts except the Ni-W completely deoxygenated phenolic components. Residual nitrogen compounds were predominantly nonbasic benzo- and dibenzopyrroles.
Rundle页岩油100-400C馏分在400C、13.8 mpa氢气压力、1.0 h/sup -1/ LHSV条件下,使用三种商用硫化物加氢处理催化剂进行处理。Ni-W/SiO/sub 2/-Al/sub 2/O/sub 3/快速失活,Co-Mo/Al/sub 2/O/sub 3/有效,Ni-Mo/Al/sub 2/O/sub 3/最有效。镍钼应允许生产一种良好的替代原油,但不能单步生产成品中间馏分燃料。在上述条件下加氢处理对油的沸点范围没有太大的影响,但所有催化剂都引起了二芳类物质的加氢,伴随的是氢芳烃的增加,以及多芳烃的一些裂解。除Ni-W外,其余催化剂均能完全脱氧酚类成分。残留氮化合物主要是非碱性苯并吡咯和二苯并吡咯。
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引用次数: 8
Internal Model Control: multiloop design 内模控制:多回路设计
Pub Date : 1986-04-01 DOI: 10.1021/I200033A011
C. Economou, M. Morari
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引用次数: 61
Recovery of sulfuric acid with multicompartment electrodialysis 多室电渗析法回收硫酸
Pub Date : 1986-04-01 DOI: 10.1021/I200033A033
Ting-chia Huang, R. Juang
Etude theorique; vitesse du transfert de masse dans l'electrodialyse du systeme H 2 SO 4 -glucose-xylose; application au calcul de la densite de courant limite et au choix du domaine de concentration optimale pour un electrodialyseur a compartiments multiples
1.2研究;h2so4 -葡萄糖-木糖系统电透析的传质速率;应用于多室电渗析器极限电流密度的计算和最佳浓度范围的选择
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引用次数: 25
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Industrial & Engineering Chemistry Process Design and Development
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