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Interacting cationic rhodium(1) and anionic iridium(1) complexes in the solid state 固态阳离子铑(1)和阴离子铱(1)的相互作用配合物
Pub Date : 1980-01-01 DOI: 10.1016/0020-1650(80)80081-X
Philip N.A. Seth, Allan E. Underhill, David M. Watkins
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引用次数: 2
Studies on Th(IV) and Zr(IV) complexes of oxygen donor ligands-IV oxozirconium(IV) complexes of tetramethylene sulphoxide 氧给体Th(IV)和Zr(IV)配合物的研究——四亚甲基亚砜氧锆(IV)配合物
Pub Date : 1980-01-01 DOI: 10.1016/0020-1650(80)80067-5
R.K. Agarwal, A.K. Srivastava, T.N. Srivastava
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引用次数: 5
Reduction potentials of beta-substituted free base porphyrins 取代游离基卟啉的还原电位
Pub Date : 1980-01-01 DOI: 10.1016/0020-1650(80)80024-9
P. Worthington, P. Hambright ∗, R.F.X. Williams ∗, M.R. Feldman, K.M. Smith, K.C. Langry

Reduction potentials for twenty-three beta-substituted free base porphyrins are reported, along with substituent partial potentials and correlations are made with porphyrin basicity and reactivity.

报道了23种β -取代游离基卟啉的还原电位,以及取代基部分电位,并与卟啉的碱度和反应性进行了相关性分析。
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引用次数: 20
Search for 7Be and 32Si as products of ternary fission of 235U by thermal neutrons 寻找7Be和32Si作为235U的热中子三重裂变的产物
Pub Date : 1980-01-01 DOI: 10.1016/0020-1650(80)80116-4
D.C. Aumann, H. Zeising

The yields of 53.3-d 7Be and 280-yr 32Si from the thermal-neutron fission of 235U have been investigated. Upper limits of 2 · 10−10% and 1.2 · 10−10% have been set for the fission yields of 7Be and 32Si, respectively. The yields of these isotopes are lower by 4 to 5 orders of magnitude than indicated from results of instrumental measurements.

研究了235U的热中子裂变生成53.3-d 7Be和280-yr 32Si。7Be和32Si的裂变产率分别为2·10−10%和1.2·10−10%。这些同位素的产率比仪器测量结果显示的要低4到5个数量级。
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引用次数: 0
Complexes of lanthanide perchlorates with two new “ O,N,O ” ligands derived from antipyraldehyde and acetic and benzoic acid hydrazides 高氯酸镧系与两种新型“O,N,O”配体的配合物,这些配体由抗乙醛和乙酸及苯甲酸肼衍生
Pub Date : 1980-01-01 DOI: 10.1016/0020-1650(80)80014-6
R. Jagannathan, S. Soundararajan
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引用次数: 4
Chromium(III) and ethylenediamine-N,N′ diacetic acid complexes 铬(III)与乙二胺-N,N '二乙酸配合物
Pub Date : 1980-01-01 DOI: 10.1016/0020-1650(80)80123-1
D.S. Veselinović, D.J. Radanović, S.A. Grujić
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引用次数: 0
Metal complexation and rotational isomerism of simple carboxylic acids-V molybdate-thiomalic acid complexes in neutral solution studied by 1H NMR 用1H NMR研究了简单羧酸-钼酸钒-硫柳酸配合物在中性溶液中的金属络合和旋转异构
Pub Date : 1980-01-01 DOI: 10.1016/0020-1650(80)80096-1
Victor M.S. Gil, M.Madalena Caldeira, M.Emília T.L. Saraiva
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引用次数: 2
Preparative and structural studies of triphenylphosphonium salts 三苯基膦盐的制备及结构研究
Pub Date : 1980-01-01 DOI: 10.1016/0020-1650(80)80104-8
Masood Khan, Colin Oldham , Michael J. Taylor , Dennis G. Tuck

The electrochemical oxidation of gallium or cobalt in the presence of CH3CN + (C6H5)3P + HX (X  Cl, Br, I) yields, in a single step, the (C6H5)3PH+ salts of Ga2X62− (X  Cl, Br, I) or CoCl42− in good crystalline form. X-ray crystallogrpahic studies gave the bond lengths and angles of the cation, and confirmed the presence of the Ga2X62− anion for XCl or I. Vibrational spectra provide diagnostic criteria for distinguishing (C6H5)3PH+ from ligated (C6H5)3P.

在CH3CN + (C6H5)3P + HX (XCl, Br, I)的存在下,镓或钴的电化学氧化在一个步骤中得到(C6H5)3PH+ Ga2X62−(XCl, Br, I)或CoCl42−的良好结晶。X射线晶体学研究给出了阳离子的键长和角度,并证实了XCl或i的Ga2X62−阴离子的存在。振动谱提供了区分(C6H5)3PH+和结合(C6H5)3P的诊断标准。
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引用次数: 15
Intercalation of decamethylferrocene in iron oxide chloride — orientation of the ferrocene molecule in the host lattice 十甲基二茂铁在氯化铁中的插层作用——二茂铁分子在主晶格中的取向
Pub Date : 1980-01-01 DOI: 10.1016/0020-1650(80)80059-6
H. Stahl
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引用次数: 14
Thorium dibutyl phosphate complexes 二丁基磷酸钍配合物
Pub Date : 1980-01-01 DOI: 10.1016/0020-1650(80)80102-4
O.K. Tallent, J.C. Mailen, K.E. Dodson
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引用次数: 1
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Inorganic and Nuclear Chemistry Letters
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