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Complexes of bipositive metal ions from vanadium (II) to copper (II) with the ligand tris (3,5-dimethyl-1-pyrazolylethyl)-amine 从钒(II)到铜(II)的双正电金属离子与三(3,5-二甲基-1-吡唑乙基)胺的配合物
Pub Date : 1981-01-01 DOI: 10.1016/0020-1650(81)80054-2
Fabrizio Mani
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引用次数: 0
Crystal structure of I3CZ2+SbCZ6− I3CZ2+SbCZ6−的晶体结构
Pub Date : 1981-01-01 DOI: 10.1016/0020-1650(81)80069-4
Niels Thorup, Jacob Shamir

Single crystal X-rays have shown that the I3SbCZ8 compound is of ionic structure, containing a centosymmetric I3CZ2+cation with a linear central part of tri-iodine atoms.

单晶x射线表明,I3SbCZ8化合物为离子结构,含有一个中心对称的I3CZ2+阳离子,其中心部分为三碘原子。
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引用次数: 4
New penta-, hexa- and hepta coordinated complexes of Zr(IV) with N-2 (2-pyridyl)salicylaldimine Zr(IV)与N-2(2-吡啶基)水杨醛二胺的新型五、六、七配位配合物
Pub Date : 1981-01-01 DOI: 10.1016/0020-1650(81)80078-5
Megh Singh, B.L. Mathur, K.S. Gharia, Rajendra Mehta
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引用次数: 3
Luminescence of BaSnSi3O9:Ti4+ compared to BaZrSi3O9:Ti4+
Pub Date : 1981-01-01 DOI: 10.1016/0020-1650(81)80058-X
W.L. Konijnendijk
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引用次数: 16
An XPS study of the valence levels of alpha plutonium α -钚的价级的XPS研究
Pub Date : 1981-01-01 DOI: 10.1016/0020-1650(81)80071-2
Lawrence E. Cox, John W. Ward

The X-ray photoelectron spectum of the valence levels (0–25eV binding energy) of α-Pu has been obtained. The 5f bandwidth (1.8eV) results from significant 5f-5f overlap in the monoclinic phase.

得到了α-Pu的价能级(0 ~ 25ev结合能)的x射线光电子能谱。5f带宽(1.8eV)是由于单斜相中显著的5f-5f重叠造成的。
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引用次数: 12
Effect of chelating anions on metal-crown interaction. Part III. X-ray structure of potassium picrate complex of benzo-15-crown-5 螯合阴离子对金属-冠相互作用的影响。第三部分。苯并-15-冠-5苦味酸钾配合物的x射线结构
Pub Date : 1981-01-01 DOI: 10.1016/0020-1650(81)80002-5
V.W. Bhagwat , H. Manohar, N.S. Poonia

The crystal structure of [potassium(benzo-15-crown-5)2](picrate) shows that in the complex the metal is sandwiched between two crowns and has no interaction with picrate.

[钾(苯并-15-冠-5)2](苦味酸)的晶体结构表明,在配合物中,金属夹在两个冠之间,与苦味酸没有相互作用。
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引用次数: 23
Superoxide dismuting activity of an iron porphyrin 铁卟啉的超氧化物异位活性
Pub Date : 1981-01-01 DOI: 10.1016/0020-1650(81)80035-9
Yael Ilan, Joseph Rabani ∗, Irwin Fridovich, Robert F. Pasternack ∗

The efficiency of tetrakis-(4-N-methylpyridyl)porphineiron(III) as a superoxide dismuting catalyst has been determined using a pulse radiolysis technique.

采用脉冲辐射分解技术测定了四烷基(4- n -甲基吡啶基)卟啉铁(III)作为超氧化物歧化剂的效率。
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引用次数: 23
Amino acids as cations: Tetrachlorocuprates (II) of glycine and β-alanine cations 作为阳离子的氨基酸:甘氨酸和β-丙氨酸阳离子的四氯乙酸
Pub Date : 1981-01-01 DOI: 10.1016/0020-1650(81)80053-0
L. Antolini, L. Menabue, M. Saladini, P. Morini

The effect of glycine and β-alanine, when act as counterions, on the coordination geometry of the tetrachlorocuprates has been investigated.

研究了甘氨酸和β-丙氨酸作为反离子时对四氯菊酯配位几何的影响。
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引用次数: 0
Electron impact induced fragmentation studies on some diorganotin complexes of s-containing schiff bases 含s-席夫碱二有机锡配合物的电子冲击破碎研究
Pub Date : 1981-01-01 DOI: 10.1016/0020-1650(81)80007-4
A.K. Saxena, J.K. Koacher, J.P. Tandon ∗

Complexes of the type Bu2SnL (where L is the anion having donor system ONNS such as Salicylaldehyde Thiosemicarbazone or salicylaldehyde-S-Benzyl dithio carbazate) have been synthesized. Fragmentation schemes upon electron impact have been constructed on the basis of measurements of metastable transitions and the isotopic contributions for the fragment ions containing the Sn atoms.

已经合成了Bu2SnL型配合物(其中L是具有供体系统ONNS的阴离子,如水杨醛硫代氨基脲或水杨醛- s -苄基双硫代氨基甲酸酯)。基于亚稳跃迁的测量和含有锡原子的碎片离子的同位素贡献,构建了电子碰撞的碎片方案。
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引用次数: 26
Halogeno salts of (π-cyclopentadienyl)(π-indenyl) oxinato zirconium(IV) chelate (π-环戊二烯基)(π-茚二基)氧合锆(IV)螯合物的卤代盐
Pub Date : 1981-01-01 DOI: 10.1016/0020-1650(81)80003-7
G.S. Sodhi, N.K. Kaushik ∗
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引用次数: 10
期刊
Inorganic and Nuclear Chemistry Letters
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