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Complexes of oxamic acid with Pt(II) and Pd(II) 肟酸与Pt(II)、Pd(II)配合物的研究
Inorganic and Nuclear Chemistry Letters
Pub Date : 1981-01-01 DOI: 10.1016/0020-1650(81)80052-9
J.M. Tsangaris, P. Veltsistas
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引用次数: 17
Tetrahydropyran complexes with some 3d metal perchlorates 四氢吡喃配合物与一些三维金属高氯酸盐
Inorganic and Nuclear Chemistry Letters
Pub Date : 1981-01-01 DOI: 10.1016/0020-1650(81)80014-1
Nicholas M. Karayannis , Chester M. Mikulski
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引用次数: 6
Activity coefficients of bis(2-ethylhexyl) phosphoric acid in n-dodecane 二(2-乙基己基)磷酸在正十二烷中的活度系数
Inorganic and Nuclear Chemistry Letters
Pub Date : 1981-01-01 DOI: 10.1016/0020-1650(81)80039-6
P.R. Danesi, G.F. Vandegrift

The activity coefficients of bis(2-ethylhexyl) phosphoric acid, HDEHP, in n-dodecane in the concentration range 1 × 10−3 − 1 F have been evaluated from liquid-liquid distribution studies of Eu+3, Tm+3 and Ca2+. The deviations from ideality have been interpreted in terms of solute-solute weak interactions, where the interacting solute species is the HDEHP dimer.

通过对Eu+3、Tm+3和Ca2+的液液分布研究，计算了正十二烷中2-乙基己基磷酸(HDEHP)在1 × 10−3−1 F浓度范围内的活度系数。从溶质-溶质弱相互作用的角度解释了理想的偏差，其中相互作用的溶质物种是HDEHP二聚体。
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引用次数: 45
A procedure for a fast separation of berkelium and cerium 一种快速分离锫和铈的方法
Inorganic and Nuclear Chemistry Letters
Pub Date : 1981-01-01 DOI: 10.1016/0020-1650(81)80013-X
Yuan-fang Liu , Cheng Luo , Hans R. von Gunten , Glenn T. Seaborg
{"title":"A procedure for a fast separation of berkelium and cerium","authors":"Yuan-fang Liu ,&nbsp;Cheng Luo ,&nbsp;Hans R. von Gunten ,&nbsp;Glenn T. Seaborg","doi":"10.1016/0020-1650(81)80013-X","DOIUrl":"10.1016/0020-1650(81)80013-X","url":null,"abstract":"","PeriodicalId":13630,"journal":{"name":"Inorganic and Nuclear Chemistry Letters","volume":null,"pages":null},"PeriodicalIF":0.0,"publicationDate":"1981-01-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://sci-hub-pdf.com/10.1016/0020-1650(81)80013-X","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"78771226","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 4
The reactivity of orgoanophosphorus cobalt hydride-complexes with carbon dioxide 有机磷钴氢化配合物与二氧化碳的反应性
Inorganic and Nuclear Chemistry Letters
Pub Date : 1981-01-01 DOI: 10.1016/0020-1650(81)80030-X
V.D. Bianco, S. Doronzo, N. Gallo
{"title":"The reactivity of orgoanophosphorus cobalt hydride-complexes with carbon dioxide","authors":"V.D. Bianco,&nbsp;S. Doronzo,&nbsp;N. Gallo","doi":"10.1016/0020-1650(81)80030-X","DOIUrl":"10.1016/0020-1650(81)80030-X","url":null,"abstract":"","PeriodicalId":13630,"journal":{"name":"Inorganic and Nuclear Chemistry Letters","volume":null,"pages":null},"PeriodicalIF":0.0,"publicationDate":"1981-01-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://sci-hub-pdf.com/10.1016/0020-1650(81)80030-X","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"77980340","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 8
Some di- and triphosphines containing PF2-groups 一些含有pf2基团的二膦和三膦
Inorganic and Nuclear Chemistry Letters
Pub Date : 1981-01-01 DOI: 10.1016/0020-1650(81)80048-7
E.A.V. Ebsworth, D.J. Hutchison, E.K. Macdonald, D.W.H. Rankin

A number of di- and triphosphines containing PF2 groups have been prepared by exchange reactions between PF2Br and phosphines containing SiP or SnP bonds. N.m.r. parameters are reported.

通过PF2Br和含有SiP或SnP键的膦之间的交换反应，制备了许多含PF2基团的二膦和三膦。报告新核磁共振参数。
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引用次数: 2
Nonelectrolytic dicyanonitrosyl complexes of vanadium 钒的非电解二氰硝基配合物
Inorganic and Nuclear Chemistry Letters
Pub Date : 1981-01-01 DOI: 10.1016/0020-1650(81)80049-9
Rishiji Srivastava, Sabayasachi Sarkar

The preparation and characterization of new nonelectrolytic hepta-coordinated cyanonitrosyl complexes of vanadium(I) are reported.

报道了新型钒(I)非电解七配位氰硝基配合物的制备和表征。
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引用次数: 1
Complexes containing indium-gallium bonds 含有铟镓键的配合物
Inorganic and Nuclear Chemistry Letters
Pub Date : 1981-01-01 DOI: 10.1016/0020-1650(81)80075-X
I. Sinclair, I.J. Worrall

The mixed metal compounds InGaX4·2L (X = Cl, Br; L = pyridine, piperidine, piperazine, 1,4-dioxan, tetrahydropyran, tetrahydrofuran) have been prepared and also the salts [(n-Bu)4N]2 InGaX6, (X = Cl, Br). Their Raman spectra have been recorded in the solid state and indicate that the compounds contain InGa bonds.

混合金属化合物InGaX4·2L (X = Cl, Br;L =吡啶，哌啶，哌嗪，1,4-二恶烷，四氢吡喃，四氢呋喃)和盐[(n-Bu)4N]2 InGaX6， (X = Cl, Br)。在固体状态下记录了它们的拉曼光谱，表明化合物含有inGa键。
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引用次数: 5
Ionisation potentials of one-electron atoms 单电子原子的电离势
Inorganic and Nuclear Chemistry Letters
Pub Date : 1981-01-01 DOI: 10.1016/0020-1650(81)80050-5
Peter F. Lang, Barry C. Smith

Ionisation potentials of the hydrogen atom and one-electron ions are calculated from the equation: I = (R∞hcZ2 μme)[1 + e4Z(Z−1)16ϵ02h2c2]

氢原子和单电子离子的电离势由公式计算:I = (R∞hcZ2 μme)[1 + e4Z(Z−1)16ϵ02h2c2]
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引用次数: 4
Spin-exchange interactions in the cubane-like cluster dimers [NEt4]3[Fe6M2S8(SPh)6(OMe)3] (M Mo or W) 类古巴烷簇二聚体[NEt4]3[Fe6M2S8(SPh)6(OMe)3] (M、Mo或W)的自旋交换作用
Inorganic and Nuclear Chemistry Letters
Pub Date : 1981-01-01 DOI: 10.1016/0020-1650(81)80060-8
George Christou , David Collison , C. David Garner , Frank E. Mabbs *

Average magnetic moments, μ¯m¯, versus temperature in the range 300−1.8K, and the variation of μ¯m¯ with applied magnetic field, from 0.125 to 2.0T, are reported for [NEt4]3[Fe6M2S8(SPh)6(OMe)3] (M Mo or W). These data have been interpreted in terms of antiferromagnetic spin coupling between the iron atoms within the separate {Fe3MS4} cubane-like clusters of the anions.

报道了[NEt4]3[Fe6M2S8(SPh)6(OMe)3] (m Mo或W)的平均磁矩μ¯m¯随温度在300 ~ 1.8K范围内的变化，以及μ¯m¯随外加磁场的变化，从0.125 t到2.0T。这些数据已被解释为在独立的{Fe3MS4}类立方体阴离子簇内的铁原子之间的反铁磁自旋耦合。
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引用次数: 3
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