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Black shale deposition during the Paleocene–Eocene thermal maximum: shale-gas potential of the Patala Formation, Himalayan fold-and-thrust belt, Pakistan (eastern Tethys) 古新世-始新世热量最高时期的黑色页岩沉积:巴基斯坦(特提斯东部)喜马拉雅褶皱推覆带帕塔拉地层的页岩气潜力
IF 2.3 3区 地球科学 Q3 GEOSCIENCES, MULTIDISCIPLINARY Pub Date : 2024-06-23 DOI: 10.1007/s00531-024-02436-4
Nasar Khan, Ralf Littke, Gert Jan Weltje, Rudy Swennen

This study focuses on the implications of a global hyperthermal event, the Paleocene–Eocene Thermal Maximum (PETM) for the origin, preservation and maturation of organic matter (OM) in the Late Paleocene Patala Formation, Himalayan fold-and-thrust belt, Pakistan. The OM present in the full array of lithofacies of the Patala Formation is characterized by petrographic (vitrinite reflectance) and geochemical techniques (total organic carbon (TOC), total organic nitrogen (TON), Rock-Eval pyrolysis and stable C and N isotopes). These analyses record deposition of the formation in a Late Paleocene shallow marine shelf environment. The organic geochemical proxies indicate the presence of Type III mixed with subordinate Type II kerogen as well as thermally immature to early mature source rocks. OM is derived both from terrestrial and marine sources. Rather high TOC (> 2 wt.%) and a negative carbon isotope excursion (CIE) reveal that the prevalence of anoxic conditions, at least for short periods, enhanced OM preservation. The quantity and quality of OM, as well as the thickness and thermal maturity of the Patala Formation, make it a potential target for shale-gas exploration. During PETM, the extensive biological activity and addition of organic carbon into shallow marine eastern Tethyan settings provided precursor materials for hydrocarbon source rocks and shale-gas generation within the Patala Formation. The high organic influx and suboxic to anoxic conditions during PETM also facilitated OM preservation within the formation. Thus, the transient global warming PETM event significantly contributed to the OM accumulation and its preservation, which implies the suitability of such source rocks for shale-gas exploration within the Potwar Basin (Pakistan) and similar basins in neighboring areas.

Graphical abstract

本研究的重点是全球高热事件--古新世-始新世热极盛(PETM)--对巴基斯坦喜马拉雅褶皱推覆带晚古新世帕塔拉地层有机质(OM)的起源、保存和成熟的影响。通过岩石学(玻璃光泽反射率)和地球化学技术(总有机碳(TOC)、总有机氮(TON)、Rock-Eval 热解以及稳定的碳和氮同位素)对帕塔拉地层所有岩相中的有机质进行了表征。这些分析记录了该地层在晚古新世浅海陆架环境中的沉积情况。有机地球化学代用指标表明,这里存在第三类混合第二类角质以及热未成熟至早期成熟的源岩。有机质来源于陆地和海洋。相当高的总有机碳含量(> 2 wt.%)和负碳同位素偏移(CIE)表明,缺氧条件的普遍存在(至少在短时间内)增强了 OM 的保存。帕塔拉地层的 OM 数量和质量以及厚度和热成熟度使其成为页岩气勘探的潜在目标。在 PETM 期间,广泛的生物活动和有机碳的加入为帕塔拉地层内的烃源岩和页岩气的生成提供了前体材料。在 PETM 期间,大量有机物涌入和亚缺氧至缺氧条件也促进了有机质在地层中的保存。因此,瞬时全球变暖的 PETM 事件极大地促进了 OM 的积累和保存,这意味着此类源岩适合在 Potwar 盆地(巴基斯坦)和邻近地区的类似盆地进行页岩气勘探。
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引用次数: 0
Permian thermally-induced shear of the Cossato-Mergozzo-Brissago shear zone in the W-Southalpine basement, Italy: new petrological, geochemical and U–Pb geochronological constraints from the amphibolite-facies units of the Strona Ceneri Border Zone 意大利西南阿尔卑斯基底 Cossato-Mergozzo-Brissago 剪切带的二叠纪热诱导剪切:来自 Strona Ceneri 边界区闪长岩岩相单元的新岩石学、地球化学和铀-铅地质年代制约因素
IF 2.3 3区 地球科学 Q3 GEOSCIENCES, MULTIDISCIPLINARY Pub Date : 2024-06-21 DOI: 10.1007/s00531-024-02435-5
F. Arboit, A. Decarlis, S. Ferrando, A. Maffeis, S. De Bernardi, A. Ceriani

The onset of the Cossato-Mergozzo-Brissago shear zone within the Strona Ceneri Border Zone in the W-Southalpine basement (Italy) and its role in the collapse of the Variscan crust have been the subject of considerable controversy. A set of new petrographic, geochemical and geochronological data from a suite of syn-kinematic migmatitic paragneiss and amphibolites in between the upper and lower crustal sections of the W-Southalpine basement provide new evidence on the thermo-mechanical role played by the middle crust in the evolution of the Permian Southalpine basement. The petrological investigation of these amphibolite-facies rocks and U–Pb ages from monazite crystals, occurring in distinct microstructural positions, provide new P–T-t constraints on the late-Paleozoic tectono-thermal evolution of the Variscan middle crust. The SCBZ units recorded tectonic events from a possible Early Silurian Cenerian (ca. 440 Ma) overprint onto the proto-sedimentary units of the Southalpine basement to the Mid-Permian (ca. 285 Ma) syn-kinematic partial melting event developed close to the CMB shear zone. Phase equilibria modeling is used to constrain the metamorphic conditions recorded by this section of the Variscan basement. Pressure–temperature (P–T) isochemical phase diagrams show that, after the ca. 330 Ma Variscan metamorphic peak at P ≅ 4 kbar and T < 630 °C, the SCBZ paragneiss experienced isobaric heating up to 700–720 °C at ca. 285 Ma, which led to the formation of a syn-kinematic partial melting event coeval to the emplacement of the Mafic Complex in the lower Ivrea-Verbano Zone. These new geochronological and petrological constraints on the SCBZ paragneiss seem to corroborate the hypothesis that the transition from the stage of mature Variscan orogen to the stage of its collapse developed in the Permian, at ca. 285 Ma. Thus, we argue that the orogenic collapse was probably driven by the rheological weakening of the mid-crustal SCBZ units induced by their syn-tectonic partial melting and, ultimately, by the coeval thermal perturbation of the crust due to the intrusion of the mafic igneous suite at the crust-mantle boundary.

Graphical abstract

意大利南阿尔卑斯山西部基底 Strona Ceneri 边界区内的 Cossato-Mergozzo-Brissago 剪切带的形成及其在瓦里斯山地壳塌陷中的作用一直存在很大争议。来自 W-Southalpine 基底上、下地壳剖面之间的一套同脉偏斜辉长岩和闪长岩的一组新的岩石学、地球化学和地质年代数据,为中地壳在二叠纪 Southalpine 基底演化过程中所起的热机械作用提供了新的证据。对这些闪长岩成因岩石的岩石学研究和出现在不同微结构位置的独居石晶体的U-Pb年龄,为瓦里斯坎中地壳晚古生代构造-热演化提供了新的P-T-t约束。SCBZ单元记录了从可能的早志留纪新生代(约440Ma)对南阿尔卑斯山基底原沉积单元的叠印,到二叠纪中期(约285Ma)在CMB剪切带附近发展的同步局部熔融等构造事件。相平衡模型用于约束瓦里坎基底这一段记录的变质条件。在 P ≅ 4 千巴和 T < 630 °C 的 330 Ma Variscan 变质峰值之后,SCBZ 副基性岩在大约 285 Ma 时经历了等压加热,温度升至 700-720 °C,这导致了与下 Ivrea-Verbano 区 Mafic 复合体的形成同时发生的同步脉动部分熔融事件。SCBZ 副片麻岩的这些新的地质年代和岩石学约束似乎证实了这样一个假设,即从成熟的瓦里斯山造山带阶段向其坍塌阶段的过渡是在二叠纪,即大约 285 Ma。因此,我们认为,造山运动的塌陷可能是由地壳中层SCBZ单元的同步构造部分熔融所引起的流变性减弱所驱动的,最终是由地壳-地幔边界的黑云母火成岩组的侵入所引起的地壳的同期热扰动所驱动的。
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引用次数: 0
Kinematic reconstruction of the Alpine Tethys and surrounding Mesozoic rifted margins 阿尔卑斯特提斯山脉及周边中生代裂谷边缘的运动学重建
IF 2.3 3区 地球科学 Q3 GEOSCIENCES, MULTIDISCIPLINARY Pub Date : 2024-06-20 DOI: 10.1007/s00531-024-02407-9
Gianluca Frasca, Gianreto Manatschal, Pauline Chenin

In plate kinematic reconstructions, the restoration of rifted margins and their fossil equivalents exposed in orogens remains challenging. Tight fit reconstructions rely on the mapping of margins rift domains, their restoration to their pre-rift crustal thickness, and the removal of the oceanic and exhumed mantle domains. At present-day margins, high-resolution wide-angle seismic imaging allows mapping and measurement of rift domains; however, restoring fossil margins is trickier because they are largely overprinted and partially lost during convergence. Here, we present a new kinematic model for the Mesozoic rifting along the Tethys–Atlantic junction, which relies on two assumptions: (1) the width of the fossil Alpine Tethys rift domains was comparable to that of their present-day analogs, and (2) the necking zones of the former tectonic plates can be mapped, dated and used as kinematic markers. This reproducible workflow allows us, for the first time, to restore the rifted margins of the Alpine Tethys. Our reconstruction shows: (1) a westward propagation of extension through the Ionian, Alpine Tethys and Pyrenean rift systems from the Triassic to the Cretaceous, (2) the segmentation of the Mesozoic Tethyan rifted margins by strike-slip corridors, (3) the opening of an oceanic gateway at 165 Ma as mantle was exhumed along the entire Alpine Tethys and (4) the subdivision of the Mesozoic oceanic domain into compartments that were later consumed during subduction. This new model is supported by published data from the Alps, the Ionian Sea, the Pyrenees and the southern North Atlantic.

Graphical abstract

在板块运动学重建中,恢复断裂边缘及其在造山运动中暴露的化石等同物仍然具有挑战性。严密拟合重建依赖于对边缘裂谷域的测绘,将其恢复到裂谷前的地壳厚度,并去除大洋域和出露的地幔域。在现今的边缘地带,高分辨率的广角地震成像可以对裂谷域进行测绘和测量;然而,恢复化石边缘地带则更为棘手,因为它们在汇聚过程中大部分被覆盖,部分消失了。在这里,我们为特提斯-大西洋交界处的中生代断裂提出了一个新的运动学模型,该模型依赖于两个假设:(1)化石阿尔卑斯特提斯断裂带的宽度与现今类似断裂带的宽度相当;(2)前构造板块的颈状带可以被测绘、测定年代并用作运动学标记。这种可重现的工作流程使我们首次恢复了阿尔卑斯特提斯断裂边缘。我们的重建显示(1)从三叠纪到白垩纪,通过爱奥尼亚、阿尔卑斯特提斯和比利牛斯裂谷系统向西延伸,(2)中生代特提斯裂谷边缘被走向滑动走廊分割,(3)随着地幔沿整个阿尔卑斯特提斯地区被吐出,在165Ma处打开了一个大洋门户,(4)中生代大洋域被细分为多个区块,这些区块后来在俯冲过程中被消耗掉。来自阿尔卑斯山、爱奥尼亚海、比利牛斯山和北大西洋南部的已发表数据为这一新模型提供了支持。
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引用次数: 0
Slope-specific lateritization of garnet–sillimanite–gneiss cuestas in Matale area, Sri Lanka 斯里兰卡马塔勒地区榴辉岩-闪长岩-片麻岩辉长岩的特定斜坡红土化现象
IF 2.3 3区 地球科学 Q3 GEOSCIENCES, MULTIDISCIPLINARY Pub Date : 2024-05-31 DOI: 10.1007/s00531-024-02421-x
W. K. G. V. Weligepola, D. M. S. N. Dissanayake, M. M. M. G. P. G. Mantilaka, H. M. T. G. A. Pitawala

This study investigates the uncommon formation of laterite from garnet–sillimanite–gneiss (grt-sil-gn) in the Matale area, a hilly region of Sri Lanka. Geographically, laterites typically form in lowland wet zone of the country, but this research explores their genesis in a unique, less-studied hilly environment. Employing a comprehensive approach combining field observations, petrographic studies, and chemical mapping, we elucidate the contrasting mechanisms of lateritization on the dip slope and scarp slope of a cuesta landform. Our findings reveal a significant influence of weathering conditions and supergene processes on laterite formation. Dip slopes experience intense supergene activity due to deeper groundwater, promoting downward fluid flow and mineral dissolution. Conversely, scarp slopes exhibit isovolumetric leaching with reduced infiltration and enhanced fluid interaction, leading to lateritization along fractures in partially weathered grt-sil-gn. Intense supergene processes on the dip slopes involve downward fluid migration and mineral dissolution, aided by a deep groundwater table. In contrast, scarp slopes exhibit laterite formation through isovolumetric leaching in areas with reduced water infiltration and heightened fluid interaction. Evidence of lateritization includes the formation of gibbsite, hematite, or goethite, attributed to fluctuating oxic and anoxic conditions caused by fluid variations. Additionally, kaolinite patches emerged on the exterior of fully altered garnet, resulting from the weathering products and leachates of quartz, sillimanite, and feldspar. This research emphasizes the critical role of external factors, such as weathering and supergene processes, alongside parent rock composition, in influencing laterite formation. It significantly advances our understanding of lateritization in grt-sil-gn, particularly in hilly areas with lower rainfall compared to usual laterite formation zones.

Graphical Abstract

本研究调查了斯里兰卡丘陵地区马塔勒地区石榴石-矽线石-片麻岩(grt-sil-gn)形成红土的罕见现象。从地理位置上看,红土通常形成于该国的低地湿润地带,但本研究探讨了红土在独特的、研究较少的丘陵环境中的成因。我们采用实地观察、岩相学研究和化学绘图相结合的综合方法,阐明了红土在奎斯特地貌的倾坡和陡坡上形成的截然不同的机制。我们的研究结果揭示了风化条件和超生过程对红土形成的重要影响。由于地下水较深,倾斜斜坡经历了强烈的超生活动,促进了流体向下流动和矿物溶解。相反,陡坡则表现出等体积沥滤作用,渗透减少,流体相互作用增强,导致部分风化的 grt-sil-gn 中的红土沿裂缝形成。在深层地下水的帮助下,倾角斜坡上强烈的超生过程包括流体向下迁移和矿物溶解。与此相反,陡坡上的红土则是在渗水量减少和流体相互作用增强的地区通过等体积沥滤形成的。红土化的证据包括由于流体变化造成的缺氧和缺氧条件波动而形成的辉锑矿、赤铁矿或鹅铁矿。此外,在完全蚀变的石榴石外部出现了高岭石斑块,这是石英、矽线石和长石的风化产物和浸出物造成的。这项研究强调了风化和超生过程等外部因素以及母岩成分在影响红土形成中的关键作用。它极大地推动了我们对grt-sil-gn地区红土化的理解,尤其是在与通常的红土形成区相比降雨量较少的丘陵地区。
{"title":"Slope-specific lateritization of garnet–sillimanite–gneiss cuestas in Matale area, Sri Lanka","authors":"W. K. G. V. Weligepola, D. M. S. N. Dissanayake, M. M. M. G. P. G. Mantilaka, H. M. T. G. A. Pitawala","doi":"10.1007/s00531-024-02421-x","DOIUrl":"https://doi.org/10.1007/s00531-024-02421-x","url":null,"abstract":"<p>This study investigates the uncommon formation of laterite from garnet–sillimanite–gneiss (grt-sil-gn) in the Matale area, a hilly region of Sri Lanka. Geographically, laterites typically form in lowland wet zone of the country, but this research explores their genesis in a unique, less-studied hilly environment. Employing a comprehensive approach combining field observations, petrographic studies, and chemical mapping, we elucidate the contrasting mechanisms of lateritization on the dip slope and scarp slope of a cuesta landform. Our findings reveal a significant influence of weathering conditions and supergene processes on laterite formation. Dip slopes experience intense supergene activity due to deeper groundwater, promoting downward fluid flow and mineral dissolution. Conversely, scarp slopes exhibit isovolumetric leaching with reduced infiltration and enhanced fluid interaction, leading to lateritization along fractures in partially weathered grt-sil-gn. Intense supergene processes on the dip slopes involve downward fluid migration and mineral dissolution, aided by a deep groundwater table. In contrast, scarp slopes exhibit laterite formation through isovolumetric leaching in areas with reduced water infiltration and heightened fluid interaction. Evidence of lateritization includes the formation of gibbsite, hematite, or goethite, attributed to fluctuating oxic and anoxic conditions caused by fluid variations. Additionally, kaolinite patches emerged on the exterior of fully altered garnet, resulting from the weathering products and leachates of quartz, sillimanite, and feldspar. This research emphasizes the critical role of external factors, such as weathering and supergene processes, alongside parent rock composition, in influencing laterite formation. It significantly advances our understanding of lateritization in grt-sil-gn, particularly in hilly areas with lower rainfall compared to usual laterite formation zones.</p><h3 data-test=\"abstract-sub-heading\">Graphical Abstract</h3>\u0000","PeriodicalId":13845,"journal":{"name":"International Journal of Earth Sciences","volume":"89 1","pages":""},"PeriodicalIF":2.3,"publicationDate":"2024-05-31","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"141193403","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"地球科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Initiation of the Unazuki Belt, Southwest Japan, during the Carboniferous as an island arc system along the North China Craton 日本西南部宇奈月带(Unazuki Belt)在石炭纪时期作为华北克拉通沿岸的岛弧系统开始形成
IF 2.3 3区 地球科学 Q3 GEOSCIENCES, MULTIDISCIPLINARY Pub Date : 2024-05-13 DOI: 10.1007/s00531-024-02422-w
Chang Whan Oh, Kenta Kawaguchi, Bo Young Lee, Seung Hwan Lee, Takeshi Imayama

The Unazuki Belt, Southwest Japan, is a part of the Hida Belt, which is characterized as a plutono-metamorphic complex with a continental affinity formed between the late Paleozoic and early Mesozoic. The Unazuki Belt is known to be an important tectonic unit for the tectonic correlation between the proto-Japan and East Asian continents as it records Permo–Triassic tectono-thermal events, however, comprehensive chronology of the Unazuki Belt including the timing of the initiation of this Belt is yet unclear. The present study reveals certain Carboniferous magmatic and sedimentation events from the Unazuki Belt and their tectonic implications for the first time as follows. Zircon U–Pb age dating results and whole-rock geochemical compositions show that the protoliths of metagranite and metatrachyandesite in the Unazuki Belt formed at 328.2 ± 4.4 Ma and 332.8 ± 2.2 Ma, respectively, in an arc tectonic setting. Most metasedimentary rocks of the Unazuki Belt have the youngest detrital zircon grains of ~ 300 Ma with the Carboniferous single cluster at ~ 340–300 Ma without any Pre-360 Ma detrital zircon grains. However, one metasedimentary rock with Precambrian detrital zircons (~ 20%) has the youngest detrital zircon age of ~ 252 Ma, and ~ 66% of detrital zircons show a Permian age. Most of the εHf(t) values of zircon grains from all the studied Unazuki Belt samples, including the metasedimentary and metaigneous rocks with Carboniferous ages (~ 360–300 Ma) are positive (+ 6– + 18), whereas those of the zircon grains with Permian ages (~ 280–260 Ma) show wide variations between + 16 and -23. The whole-rock geochemical compositions of the ~ 300 Ma metasedimentary rocks of the Unazuki Belt show an island arc tectonic setting, whereas those of ~ 252 Ma metasedimentary rock have a continental arc affinity. These new data suggest that (1) igneous and sedimentary rocks in the Unazuki Belt formed in the island arc tectonic setting separated from the margin of continental crust during the Carboniferous but shifted to the continental arc tectonic setting during the latest Permian, (2) the collision between the island arc and continental arc may have caused the intermediate-P/T metamorphism during the Permian in the Unazuki Belt. The Carboniferous island arc tectonic setting in the Unazuki Belt indicates that the Hida Belt, including the Unazuki Belt, formed not at the margin of the South China Craton where Carboniferous subduction is absent but on the continuous subduction zone located along the eastern margin of the North China Craton, including the eastern margin of the northern Korean Peninsula where Carboniferous subduction occurred.

Graphical Abstract

日本西南部的宇奈月带(Unazuki Belt)是飞驒带(Hida Belt)的一部分,飞驒带的特征是在古生代晚期和中生代早期之间形成的具有大陆亲缘关系的增生变质复合带。宇奈月带记录了二叠三叠世构造热事件,是原日本大陆和东亚大陆构造关联的重要构造单元,但宇奈月带的全面年代学,包括该带的起始时间尚不清楚。本研究首次揭示了宇奈月带的某些石炭纪岩浆和沉积事件及其构造影响,具体如下。锆石U-Pb年龄测定结果和全岩地球化学成分显示,宇奈月带的偏闪长岩和偏闪长岩的原岩分别形成于328.2±4.4Ma和332.8±2.2Ma的弧构造环境中。宇奈月带大多数变质岩最年轻的锆英石碎屑约为300 Ma,石炭纪单个岩群的锆英石碎屑约为340-300 Ma,没有任何360 Ma以前的锆英石碎屑。然而,一块含有前寒武纪锆石的变质岩(约20%)的最年轻锆石年龄为约252 Ma,约66%的锆石显示为二叠纪年龄。在所有研究的宇奈月带样品中,包括石炭纪(约 360-300 Ma)的变质岩和元成岩的锆石颗粒的εHf(t)值大多为正值(+ 6- + 18),而二叠纪(约 280-260 Ma)的锆石颗粒的εHf(t)值则在 + 16 和 -23 之间变化很大。宇奈月带〜300Ma变质岩的全岩地球化学成分显示了岛弧构造背景,而〜252Ma变质岩的全岩地球化学成分则与大陆弧有亲缘关系。这些新数据表明:(1)宇奈月带的火成岩和沉积岩在石炭纪形成于与大陆地壳边缘分离的岛弧构造环境中,但在二叠纪晚期转变为大陆弧构造环境;(2)岛弧与大陆弧的碰撞可能导致了宇奈月带二叠纪中期的P/T变质作用。宇奈月带的石炭纪岛弧构造背景表明,包括宇奈月带在内的飞驒带不是形成于没有石炭纪俯冲的华南克拉通边缘,而是形成于华北克拉通东缘的连续俯冲带,包括发生石炭纪俯冲的朝鲜半岛北部东缘。
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引用次数: 0
Gondwana sedimentary rocks of Andigama Basin, Sri Lanka: unraveling weathering dynamics, tectonic setting, and paleoclimate 斯里兰卡安迪伽马盆地的冈瓦纳沉积岩:揭示风化动力学、构造背景和古气候
IF 2.3 3区 地球科学 Q3 GEOSCIENCES, MULTIDISCIPLINARY Pub Date : 2024-05-11 DOI: 10.1007/s00531-024-02423-9
B. M. Gunathilake, D. T. Jayawardana, A. S. Ratnayake, A. M. N. M. Adikaram

The Andigama Basin is a pre-rift Gondwana sedimentary basin containing Late Jurassic to Early Cretaceous calcareous sandstones and carbonaceous shales of varying thickness. This study aims to reconstruct the weathering, tectonic setting, and paleoenvironment of East Gondwanaland using a 90 m deep drill core. Whole-rock geochemistry and elemental analysis were carried out using X-ray fluorescence spectrometry and CHNS/O elemental analyzer, respectively. Lithological changes in the borehole core reflect diverse hydrodynamic conditions. X-ray diffraction patterns indicate a significantly high content of quartz and kaolinite peaks. Scanning electron microscope images suggest that quartz, carbonate, and aluminosilicate dominant detrital particles and chemical residues enhanced the cementation by reducing the porosity and permeability of sealing interfaces. Major oxide and trace element concentrations are approximately similar to the Upper Continental Crust values. High Chemical Index of Alteration, Plagioclase Index of Alteration, Index of Compositional Variability, and high content of kaolinite peaks reflect intense chemical weathering, suggesting a hot and humid climate during the Late Jurassic–Early Cretaceous periods. The calculated paleo-land surface temperature (24.7 ± 5 °C) and mean annual precipitation (1120 mm) values are also consistent with the interpretation of weathering indices and global oxygen isotopic studies. Provenance and tectonic setting discrimination diagrams suggest the deposition of quartzose and mafic igneous sources under the passive margin stage. In addition, elemental analysis indicates a nutrient-rich (average total organic carbon = 4.67 ± 1.04 wt. % and total nitrogen = 3.13 ± 3.39 wt. %) and oxic to oxygen-poor reducing (average total sulfur = 2.13 ± 1.43 wt. %) swamp environment. Consequently, the Late Jurassic–Early Cretaceous climate was simulated as a prominent deglaciation/hot and humid climate in the Gondwana supercontinent, based on calculated paleo-land surface temperatures and mean annual precipitation.

Graphical abstract

安迪伽马盆地是冈瓦纳大断裂前的沉积盆地,包含厚度不等的晚侏罗世至早白垩世钙质砂岩和碳质页岩。这项研究旨在利用 90 米深的钻探岩芯重建东冈瓦纳的风化、构造环境和古环境。研究分别采用 X 射线荧光光谱仪和 CHNS/O 元素分析仪进行了全岩地球化学和元素分析。钻孔岩心的岩性变化反映了不同的水动力条件。X 射线衍射图样显示,石英和高岭石峰的含量很高。扫描电子显微镜图像表明,以石英、碳酸盐和铝硅酸盐为主的碎屑颗粒和化学残留物通过降低密封界面的孔隙度和渗透性增强了胶结作用。主要氧化物和微量元素浓度与上大陆壳的值大致相似。高化学蚀变指数、斜长石蚀变指数、成分变异指数和高岭石峰值含量反映了强烈的化学风化作用,表明晚侏罗世-早白垩世时期气候炎热潮湿。计算得出的古地表温度(24.7 ± 5 °C)和年平均降水量(1120 毫米)值也与风化指数和全球氧同位素研究的解释一致。成因和构造环境判别图表明,在被动边缘阶段,石英质火成岩和岩浆火成岩来源沉积。此外,元素分析表明这是一个营养丰富(平均总有机碳 = 4.67 ± 1.04 重量%,总氮 = 3.13 ± 3.39 重量%)、缺氧至缺氧还原(平均总硫 = 2.13 ± 1.43 重量%)的沼泽环境。因此,根据计算的古地表温度和年平均降水量,模拟出晚侏罗世-早白垩世的气候为冈瓦纳超大陆突出的脱冰/炎热潮湿气候。
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引用次数: 0
Magma recharge in persistently active basaltic–andesite systems and its geohazards implications: the case of Villarrica volcano, Chile 持续活跃的玄武安山岩系统中的岩浆补给及其地质灾害影响:智利比利亚里卡火山的案例
IF 2.3 3区 地球科学 Q3 GEOSCIENCES, MULTIDISCIPLINARY Pub Date : 2024-05-10 DOI: 10.1007/s00531-024-02414-w
J. A. Cortés, R. Gertisser, E. S. Calder

We report whole-rock chemistry, mineral chemistry, and volatile content from Villarrica volcano’s major recent paroxysms and background activity. Composition of the volcanic products are basalt to basaltic andesite with whole-rock SiO2 content between 50 and 56 wt%, and a mineralogy dominated by olivine (Fo71-80), clinopyroxene (Mg# ~ 50) and plagioclase (An60–80). Volatile contents in melt inclusions are up to 1.5 wt% H2O, 500 ppm CO2, 1230 ppm sulfur and 580 ppm chlorine. Regardless of the type of activity, there are no substantial variations in whole-rock composition or the volatile content when the activity switches from background activity to a major paroxysm, strongly suggesting that this shift does not just depend on the arrival of new magma in the shallow magmatic system. Geothermobarometry constrains crystallization of the major mineral phases at various depths between 3 and 12.7 km, suggesting that degassing of a volatile-rich recharge magma occurs deeper than 12 km, producing efficient mixing throughout the whole system, and sustaining the lava lake activity in Villarrica’s summit crater. The occurrence of a permanent lava lake also suggests that the magma recharge must be close to continuous and therefore sudden changes between background and paroxysmal volcanic activity are likely controlled by relatively small changes in the rate of recharge and/or the volatile release rate in the magmatic system. This has important implications for the understanding of eruption triggers and the forecasting of volcanic eruptions.

Graphical abstract

我们报告了比利亚里卡火山近期主要阵发和背景活动的全岩化学、矿物化学和挥发物含量。火山产物的成分为玄武岩至玄武安山岩,整块岩石的二氧化硅含量在 50 至 56 wt%之间,矿物成分主要为橄榄石(Fo71-80)、倩辉石(Mg# ~ 50)和斜长石(An60-80)。熔融包裹体中的挥发物含量高达 1.5 wt% H2O、500 ppm CO2、1230 ppm 硫和 580 ppm 氯。无论岩浆活动的类型如何,当岩浆活动从本底活动转为大阵发活动时,整个岩石的成分或挥发物含量都没有实质性的变化,这有力地表明这种转变并不仅仅取决于浅层岩浆系统中新岩浆的到来。地热测量法确定了主要矿物相在 3 至 12.7 千米不同深度的结晶情况,这表明富含挥发性物质的补给岩浆的脱气发生在 12 千米以上的深度,从而在整个系统中产生了有效的混合,并维持了比利亚里卡山顶火山口的熔岩湖活动。永久性熔岩湖的出现还表明,岩浆补给必须接近连续,因此背景火山活动和阵发性火山活动之间的突然变化很可能是由岩浆系统中补给率和/或挥发性释放率的相对较小变化所控制的。这对了解火山爆发的触发因素和预报火山爆发具有重要意义。
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引用次数: 0
Climate cyclicity-controlled recurrent bottom-water ventilation events in the aftermath of the Toarcian Oceanic Anoxic Event: the Jenkyns Event 托阿尔西元大洋缺氧事件后气候周期性控制的周期性底水通风事件:詹金斯事件
IF 2.3 3区 地球科学 Q3 GEOSCIENCES, MULTIDISCIPLINARY Pub Date : 2024-05-09 DOI: 10.1007/s00531-024-02417-7
Lorenz Schwark, Wolfgang Ruebsam

Environmental perturbations of the Toarcian Anoxic Event and its associated carbon isotope excursion (CIE) occurred in a cyclic fashion indicating an orbital control mechanism. Sedimentary strata of the E. elegantulum ammonite subzone in the Lorraine Sub-basin, Luxembourg, exhibit eight sedimentary cycles, most of which postdate the CIE, implying that its termination did not coincide with a full recovery from environmental stress. Sea-level and temperature fluctuations of the Toarcian crisis were linked to a cryosphere demise in the Northern Hemisphere, which modulated stadial versus interstadial phases on the orbital 100 ka eccentricity frequency band. Upon stadial phases, enhanced wind strength in combination with lowered sea level disrupted stratified shelf waters and shifted the storm wave base close to the sea floor. Ventilation of bottom waters interrupted accumulation of laminated and organic-rich black shales, but formed organic-lean and non-laminated gray claystones enriched in terrigenous wax lipids and spores provided via aeolian transport from the hinterland due to the enhanced wind strength. Wind systems are assumed to have been driven by high pressure differences between the cryosphere in the North of the Tethyan shelf and the warmer costal lowland. This distinguishes the atmospheric turbulences after the CIE from the postulated intensification of the cyclones that accompanied the rapid warming at the beginning of the CIE. The deep-water ventilation event following the CIE in the Lorraine Sub-basin was accompanied by a parallel evolution in the SW German Basin, indicating a supraregional driving mechanism in paleobathymetric sub-basins susceptible to lowering of storm wave base. In sub-basins with greater water depth on the NW-Tethyan shelf, post-CIE orbitally driven atmospheric turbulences had a minor or no effect on water column stratification and deposition of organic-rich laminated black shales persisted.

Graphical abstract

托阿克缺氧事件的环境扰动及其相关的碳同位素偏移(CIE)以周期性的方式发生,表明存在一种轨道控制机制。卢森堡洛林次盆地的雅罗姆E. ammonite亚区沉积地层显示了八个沉积周期,其中大部分都在CIE之后,这意味着CIE的结束与环境压力的完全恢复并不一致。托阿希安危机的海平面和温度波动与北半球冰冻圈的消亡有关,冰冻圈的消亡调节了轨道 100 ka 偏心率频带上的恒星期与间冰期。在恒星阶段,风力增强加上海平面降低,破坏了分层的陆架水域,并使风暴潮基底靠近海底。底层水的通风中断了层状和富含有机质的黑色页岩的堆积,但形成了有机质稀薄的非层状灰色粘土岩,其中富含陆生蜡脂和孢子,这些都是由于风力增强而从腹地通过风化搬运提供的。据推测,风系统是由泰提安大陆架北部低温层与较温暖的沿海低地之间的高压差驱动的。这就将大陆架界限会议之后的大气湍流与假定的伴随大陆架界限会议初期快速变暖的气旋加强区分开来。CIE 之后洛林次盆地的深水通风事件伴随着德国西南部盆地的平行演变,这表明在易受风暴潮基底降低影响的古测深次盆地中存在一种超区域驱动机制。在西北-泰坦大陆架水深较大的次盆地,CIE 后轨道驱动的大气湍流对水柱分层的影响较小或没有影响,富含有机质的层状黑页岩沉积持续存在。
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引用次数: 0
Zircon trace element fingerprint of changing tectonic regimes in Permian rhyolites from the Central European Lowlands 中欧低地二叠纪流纹岩构造体系变化的锆石痕量元素指纹
IF 2.3 3区 地球科学 Q3 GEOSCIENCES, MULTIDISCIPLINARY Pub Date : 2024-05-08 DOI: 10.1007/s00531-024-02419-5
Słodczyk Elżbieta, Pietranik Anna, Repstock Alexander, Przybyło Arkadiusz, Glynn Sarah, Lukács Réka

The late Carboniferous/early Permian post-collisional rhyolites (305–285 Ma) that formed in Central Europe have generally similar whole rock compositions to that of older Late-Variscan rhyolites (330–310 Ma). However, data compilation combining zircon age with the chemical composition of rhyolites from 20 units shows a trend of increasing zircon saturation temperature with decreasing age. This trend is particularly well identified in rhyolites from the Central European Lowlands (CEL)—consisting of the NE German and NW Polish Basin—and also correlates their location with the zircon saturation temperature increasing from SE to NW from 750°C to 850°C. We infer that these higher temperatures of zircon saturation reflect a contemporaneous change in the tectonic setting from collisional to divergent, reflecting the onset of the Central European continental rifting. This interpretation is further corroborated by the trace element compositions of the CEL zircons, which resembles zircon crystallized in a divergent setting. Interestingly, the zircon formed globally in this type of setting is chemically diverse, especially considering uranium concentration. For example, zircon from locations dominated by mafic magma fractionation, such as rhyolites from Iceland, have low U concentrations and low U/Yb ratios. On the other hand, zircon formed in rhyolites in rifted margins, like western North America, tends to have much higher U and U/Yb ratios. Such high concentrations are not observed in zircon from the CEL, suggesting that the mantle input could be higher and residence times within continental crust shorter than those for rhyolites from the Cenozoic western USA. This may, in turn, suggest that the region might have been affected by a hot spot, similar to that responsible for rhyolite formation of the Snake River Plain.

Graphical abstract

形成于中欧的石炭纪晚期/二叠纪早期碰撞后流纹岩(305-285Ma)的整岩成分与晚期瓦利斯坎流纹岩(330-310Ma)的整岩成分基本相似。然而,将 20 个单元的流纹岩的锆石年龄与化学成分相结合的数据汇编显示,随着年龄的降低,锆石饱和温度呈上升趋势。这种趋势在中欧低地(CEL)--包括德国东北部和波兰西北部盆地--的流纹岩中表现得尤为明显,而且与这些流纹岩的位置相关,锆石饱和温度从东南向西北从750°C上升到850°C。我们推断,这些较高的锆石饱和温度反映了同时代的构造环境从碰撞型向发散型的转变,反映了中欧大陆裂解的开始。CEL锆石的微量元素组成进一步证实了这一解释,它类似于在分异环境中结晶的锆石。有趣的是,全球在这种环境下形成的锆石化学成分多种多样,特别是考虑到铀的浓度。例如,冰岛流纹岩等以岩浆分馏为主的地区的锆石铀浓度低,U/Yb比值也低。另一方面,在北美洲西部等断裂边缘地区的流纹岩中形成的锆石,其铀浓度和U/Yb比值往往要高得多。在 CEL 的锆石中没有观察到如此高的浓度,这表明地幔输入可能比美国西部新生代流纹岩的地幔输入更高,在大陆地壳中的停留时间更短。这可能反过来表明,该地区可能受到了一个热点的影响,类似于导致蛇河平原流纹岩形成的热点。
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引用次数: 0
Crustal dynamics prediction and characterization for the Yishu fault zone based on slip susceptibility analysis 基于滑动敏感性分析的沂沭断层带地壳动力学预测与特征分析
IF 2.3 3区 地球科学 Q3 GEOSCIENCES, MULTIDISCIPLINARY Pub Date : 2024-05-06 DOI: 10.1007/s00531-024-02424-8
Guiyun Gao, Pu Wang, Chenghu Wang, Chengwei Yang

We estimate the slip susceptibility of faults in the Yishu fault zone using a slip tendency analysis based on coupled tectonic stress profiles. Studying in situ stress data and focal mechanism solution data collected in this area over more than 30 years, we construct the stress profiles of the study area using the coupling analysis method for deep and shallow stress data. Subsequently, the susceptibility of faults to slip is comprehensively evaluated based on various stress indicators and other related factors. Our results show that the frictional characteristic index μm is low in the deep and shallow crust of the Yishu fault zone, indicating a low degree of overall stress accumulation. A comprehensive evaluation of the susceptibility of faults to slip based on five typical factors (μm, horizontal-to-vertical stress ratio K, angle between the P axis and fault plane θ, S-wave velocity, and seismic density) indicates that the overall seismic risk in the central part of the Yishu fault zone is low, while the northwestern Yishu fault zone exhibits high seismic risk. Furthermore, the southeastern part of the Yishu fault zone reflects the transition from medium- to low-seismic risk. These results provide geomechanical and fault mechanics evidence for evaluating the regional crustal dynamics of the Yishu fault zone.

Graphical abstract

我们利用基于构造应力耦合剖面的滑动倾向分析,估算了沂沭断裂带断层的滑动敏感性。通过对该地区 30 多年来收集的原地应力数据和焦点机制解算数据的研究,采用深浅应力数据耦合分析方法构建了研究区的应力剖面。随后,根据各种应力指标和其他相关因素,对断层的易滑性进行了综合评价。结果表明,沂沭断裂带深浅地壳摩擦特征指数μm较低,表明整体应力堆积程度较低。基于五个典型因子(μm、水平垂直应力比 K、P 轴与断层面夹角θ、S 波速度和地震密度)对断层滑动敏感性的综合评价表明,沂沭断裂带中部的整体地震风险较低,而沂沭断裂带西北部的地震风险较高。此外,沂沭断裂带的东南部反映了从中震风险向低震风险的过渡。这些结果为评价沂沭断裂带的区域地壳动力学提供了地质力学和断层力学证据。 图文摘要
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引用次数: 0
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International Journal of Earth Sciences
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