Pub Date : 2024-05-05DOI: 10.1007/s00531-024-02408-8
Wolfgang Ruebsam, Lorenz Schwark
The Toarcian Oceanic Anoxic Event (T-OAE, Early Jurassic) is marked by widespread marine deoxygenation and deposition of organic carbon (OC)-rich strata. The genesis of the T-OAE is thought to be associated with environmental changes caused by the emission of 12C-enriched greenhouse gasses (CO2, CH4), manifested in a negative Toarcian carbon isotope excursion (nT-CIE). The nT-CIE is commonly used to stratigraphically define the T-OAE, and despite the complex interrelationship of the different environmental phenomena, both terms (nT-CIE and T-OAE) are commonly used interchangeable. We here demonstrate that occurrence of OC-rich strata is diachronous and not restricted to the nT-CIE, reflecting the interaction of global- and regional-scale processes. Thus, the interchangeable use of T-OAE and nT-CIE should be discarded. The nT-CIE, however, hosts the T-OAE climax, marked by the widest extent of OC-rich strata. Early Toarcian environmental changes, particularly sea level rise and rising temperatures, may have made marine areas more susceptible to develop oxygen deficient conditions, favoring OC-accumulation.
{"title":"Disparity between Toarcian Oceanic Anoxic Event and Toarcian carbon isotope excursion","authors":"Wolfgang Ruebsam, Lorenz Schwark","doi":"10.1007/s00531-024-02408-8","DOIUrl":"https://doi.org/10.1007/s00531-024-02408-8","url":null,"abstract":"<p>The Toarcian Oceanic Anoxic Event (T-OAE, Early Jurassic) is marked by widespread marine deoxygenation and deposition of organic carbon (OC)-rich strata. The genesis of the T-OAE is thought to be associated with environmental changes caused by the emission of <sup>12</sup>C-enriched greenhouse gasses (CO<sub>2</sub>, CH<sub>4</sub>), manifested in a negative Toarcian carbon isotope excursion (nT-CIE). The nT-CIE is commonly used to stratigraphically define the T-OAE, and despite the complex interrelationship of the different environmental phenomena, both terms (nT-CIE and T-OAE) are commonly used interchangeable. We here demonstrate that occurrence of OC-rich strata is diachronous and not restricted to the nT-CIE, reflecting the interaction of global- and regional-scale processes. Thus, the interchangeable use of T-OAE and nT-CIE should be discarded. The nT-CIE, however, hosts the T-OAE climax, marked by the widest extent of OC-rich strata. Early Toarcian environmental changes, particularly sea level rise and rising temperatures, may have made marine areas more susceptible to develop oxygen deficient conditions, favoring OC-accumulation.</p><h3 data-test=\"abstract-sub-heading\">Graphical abstract</h3>","PeriodicalId":13845,"journal":{"name":"International Journal of Earth Sciences","volume":"19 1","pages":""},"PeriodicalIF":2.3,"publicationDate":"2024-05-05","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"140888534","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"地球科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2024-05-05DOI: 10.1007/s00531-024-02411-z
Jasemin Ayse Ölmez, Benjamin Busch, Christoph Hilgers
The Upper Cretaceous limestones unconformably overlie Upper Carboniferous coal-bearing lithologies and are studied to assess their effect on rising mine-water levels in the Ruhr mining district. Upper Cretaceous sedimentary rocks from the Münsterland Cretaceous Basin have previously been studied regarding their sedimentary structures and fossil content. However, understanding the petrophysical and petrographic heterogeneity in regard to sedimentary properties and their effect on fluid migration pathways is yet missing. Utilizing He-pycnometry, Klinkenberg-corrected air permeabilities, p-wave velocities, transmitted and reflected light analyses, point-counting and cathodoluminescence, we assess the petrophysical, geomechanical and mineralogical properties. Porosity ranges from 1.0 to 18.7% and permeability ranges from < 0.0001 to 0.2 mD, while p-wave velocity ranges between 2089 and 5843 m/s. Mechanical compaction leads to grain rearrangement, deformation of calcispheres, foraminifera and ductile clay mineral laminae. Above and below clay laminae, compaction bands of deformed calcispheres develop. Early diagenetic mineral precipitation of ferroan calcite in inter- and intragranular pores reduces porosity and permeability and influences geomechanical properties. An underestimated aspect of limestone petrography is the relationship of the original primary compactable depositional volume and the influence of compaction, deformation and cementation during early and late diagenesis on reservoir properties. The detrital dominated limestones show an originally high compactable depositional volume (CDV). Overall, reservoir qualities are poor and indicate the sealing potential of the studied lithologies. The Upper Cretaceous (Campanian) limestones thus may act as a barrier for increasing mine-water levels from dismantled, post-mining subsurface hard coal mines in the region.