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Removal of methyl orange from synthetic wastewater using analcime-C, MCM-41 and γ-Al2O3 composite membranes 氨肟- c、MCM-41和γ-Al2O3复合膜去除合成废水中的甲基橙
IF 0.6 Q4 ENGINEERING, ENVIRONMENTAL Pub Date : 2018-01-01 DOI: 10.1504/ijetm.2018.10019111
R. Kumar, K. Pakshirajan, G. Pugazhenthi
The present study describes the fabrication of analcime-C, MCM-41 and γ-Al2O3 composite membranes and their potential in removal of anionic dye from aqueous solution. The hydrothermal crystallisation technique was employed to deposit the charged inorganic oxides such as analcime-C, MCM-41 and γ-Al2O3 on the low cost ceramic support. The formation and purity of analcime-C, MCM-41 and γ-Al2O3 powders were verified by XRD analysis. The porosity, average pore size and water permeability of analcime-C composite membrane were calculated as 24% (23% and 29% for MCM-41 and γ-Al2O3 composite membrane), 0.155 μm (0.173 and 0.970 μm for MCM-41 and γ-Al2O3 composite membrane) and 4.53 × 10−8 m3/m2s.kPa (6.05 × 10−8 and 8.23 × 10−6 m3/m2s.kPa for MCM-41 and γ-Al2O3 composite membrane), respectively. To identify the effectiveness of the prepared composite membranes, applied pressure of the filtration process and initial dye concentration was varied to study their influence on the permeate flux and percentage of dye removal. The results showed that the percentage of dye removal is found to be reduced while increasing applied pressure for all the membranes. The maximum percentage of methyl orange removal was exhibited as 67% for analcime-C, 44% for MCM-41 and 56% for γ-Al2O3 membrane.
本文介绍了氨酰- c、MCM-41和γ-Al2O3复合膜的制备及其去除水溶液中阴离子染料的潜力。采用水热结晶技术在低成本的陶瓷载体上沉积了带电的无机氧化物(如:c、MCM-41和γ-Al2O3)。通过XRD分析验证了c、MCM-41和γ-Al2O3粉末的形成和纯度。结果表明,复合膜的孔隙率、平均孔径和透水性分别为24% (MCM-41和γ-Al2O3复合膜分别为23%和29%)、0.155 μm (MCM-41和γ-Al2O3复合膜分别为0.173和0.970 μm)和4.53 × 10−8 m3/m2s。kPa (6.05 × 10−8和8.23 × 10−6 m3/m2s)。MCM-41和γ-Al2O3复合膜分别为kPa)。为了验证所制备复合膜的有效性,通过改变过滤过程的施加压力和初始染料浓度来研究它们对渗透通量和染料去除率的影响。结果表明,当增加所有膜的施加压力时,染料去除率降低。对甲基橙的最大去除率分别为:analim - c 67%, MCM-41 44%, γ-Al2O3 56%。
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引用次数: 2
Designing a sustainable municipal solid waste management system in Pathum Thani, Thailand 在泰国巴吞他尼设计可持续的城市固体废物管理系统
IF 0.6 Q4 ENGINEERING, ENVIRONMENTAL Pub Date : 2017-09-13 DOI: 10.1504/IJETM.2017.10007527
S. Olapiriyakul
In most developing countries, the disposal and treatment of solid waste in urban areas has proved to be a problem for the social acceptance of local residents and long-term sustainable development. This study proposes a multi-objective optimisation methodology to investigate sustainable network designs for solid waste management system. A case of Pathum Thani province, Thailand, is used to illustrate the application of the methodology. The social impact, defined as the number of people affected by the unpleasant sanitary conditions of nearby solid waste management facilities, is estimated by using GIS tools. The sustainability performances are normalised to a satisfaction scale, allowing decision makers to select network design solutions based on their sustainability target preferences. The results suggest that the facility location can significantly alter the sustainability performances, and it is shown that the locations of waste management facilities can be arranged to simultaneously improve all of the aspects of sustainability.
在大多数发展中国家,城市地区固体废物的处置和处理已被证明是当地居民社会接受和长期可持续发展的一个问题。本研究提出了一种多目标优化方法来研究固体废物管理系统的可持续网络设计。以泰国巴吞他尼省为例说明了该方法的应用。社会影响是指受附近固体废物管理设施恶劣卫生条件影响的人数,通过使用GIS工具进行估计。可持续性表现被标准化为满意度,使决策者能够根据其可持续性目标偏好选择网络设计解决方案。结果表明,设施的位置可以显著改变可持续性绩效,并且表明废物管理设施的位置安排可以同时提高可持续性的各个方面。
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引用次数: 11
Ammonia removal from poultry manure leachate via struvite precipitation: a strategy for more efficient anaerobic digestion 通过鸟粪石沉淀去除禽粪渗滤液中的氨:一种更有效的厌氧消化策略
IF 0.6 Q4 ENGINEERING, ENVIRONMENTAL Pub Date : 2017-09-13 DOI: 10.1504/IJETM.2017.10007532
C. Farrow, A. Crolla, C. Kinsley, E. McBean
To improve poultry waste management, the feasibility of enabling efficient anaerobic digestion of poultry manure through reduction of ammonia accumulation is examined. This study employs struvite precipitation to control ammonia accumulation, and focuses on the efficacy of ammonia removal under neutral reaction conditions (pH = 7). The impacts of phosphate and magnesium additives, pH, temperature and the N:Mg:P molar ratio are quantified. Magnesium chloride (MgCl2 • 6H2O) and monopotassium phosphate (KH2PO4) are shown to be the most efficient combination of additives for total ammoniacal nitrogen (TAN) reduction of poultry manure leachate under neutral reaction conditions (pH = 7), demonstrating a TAN reduction of 90.3%. Modification of molar ratios (NH4:Mg:PO4) evidenced no significant benefit with regard to TAN reduction. However, increasing the fraction of supplementary magnesium resulted in a statistically significant (p < 0.05) decrease in phosphate concentration within the leachate. This study demonstrates the advantages of struvite precipitation, as a method of ammonia control, to improve anaerobic digestion and hence management of poultry manure. Although an effective means of TAN control, struvite precipitation from poultry manure is an ineffective means of obtaining pure struvite due to the formation of co-precipitates.
为了改善家禽废物管理,研究了通过减少氨积累实现家禽粪便高效厌氧消化的可行性。本研究采用鸟粪石沉淀法控制氨积累,重点考察了中性反应条件(pH = 7)下的氨去除效果,量化了磷酸盐和镁添加剂、pH、温度和N:Mg:P摩尔比的影响。在中性反应条件下(pH = 7),氯化镁(MgCl2•6H2O)和磷酸一钾(KH2PO4)是禽粪渗滤液中还原总氨态氮(TAN)最有效的添加剂组合,TAN还原率为90.3%。修正摩尔比(NH4:Mg:PO4)对TAN还原没有显著的好处。然而,增加补充镁的比例导致渗滤液中磷酸盐浓度降低,具有统计学意义(p < 0.05)。本研究表明鸟粪石沉淀作为一种控制氨的方法,在改善厌氧消化和家禽粪便管理方面具有优势。虽然鸟粪粪中鸟粪石的析出是一种有效的控制TAN的手段,但由于形成共沉淀物,从鸟粪中析出鸟粪石是一种无效的获得纯鸟粪石的手段。
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引用次数: 6
Effects of cadmium on growth, short-term photosynthetic acclimation and metal accumulation in radish plants (Raphanus sativus L.) 镉对萝卜生长、短期光合驯化及金属积累的影响
IF 0.6 Q4 ENGINEERING, ENVIRONMENTAL Pub Date : 2017-09-13 DOI: 10.1504/IJETM.2017.10007530
Austin H. Nguyen, C. Hoying, Theresa M. Urbina, P. Drennan
Plants displaying heavy metal hyper-accumulation and high biomass could be used in phytoextraction. The present study utilises photosynthetic acclimation rates and morphological measurements to gauge cadmium toxicity in radish plants raised on nutrient solutions containing 0, 5, 10 and 20 µM CdCl2. Growth rates displayed a dose-dependent decline with cadmium exposure. Photosynthetic acclimation was significantly reduced compared to controls in all cadmium treatments. Inductively coupled plasma mass spectrometry was used to determine cadmium accumulation. In both the roots and shoots of the plant, cadmium levels were significantly higher than the controls in 10 and 20 µM treatments. Significantly more cadmium was distributed into the roots compared to shoots. A moderate tolerance for and reasonable accumulation of cadmium makes the radish a candidate for phytoremediation in marginally contaminated environments. Furthermore, the sensitivity of photosynthetic acclimation rates to cadmium exposure serves as a potential bioindicator of cadmium contamination.
重金属超积累和高生物量的植物可用于植物提取。本研究利用光合适应速率和形态测量来测量含有0、5、10和20µM CdCl2的营养液对萝卜的镉毒性。随着镉暴露,生长速率呈剂量依赖性下降。与对照相比,所有镉处理的光合驯化均显著降低。采用电感耦合等离子体质谱法测定镉的累积量。在10µM和20µM处理下,根和芽的镉含量均显著高于对照。根中的镉含量明显高于茎。萝卜对镉的适度耐受性和合理的积累使其成为轻度污染环境中植物修复的候选植物。此外,光合适应速率对镉暴露的敏感性可以作为镉污染的潜在生物指标。
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引用次数: 2
Analysis of polychlorinated biphenyls treatment present in transformers oils 变压器油中多氯联苯处理分析
IF 0.6 Q4 ENGINEERING, ENVIRONMENTAL Pub Date : 2017-09-13 DOI: 10.1504/IJETM.2017.10007524
K. Dumorné, Margie Zorrilla Velazco, Petra G. Velazco Pedroso
In this research, we demonstrated the effectiveness of potassium polyethylene plycolate method (KPEG) in the removal of polychlorinated biphenyls (PCBs) from transformer oil. A commercially available transformer oil composed of a mixture of PCBs (Aroclor 1254) was treated by polyethylene glycol 400 (PEG 400), with potassium hydroxide (KOH). The relative efficiency of the different treatments was assessed in terms of the destruction and removal efficiency (DRE, %) by means of gas chromatography at different reaction times. Our results revealed that the DRE average, with a value of 95.0%, was obtained under the experimental conditions: mol ratio KOH/PEG = 2:1 and KPEG/oil = 30:1 for 3 h 30 min of reaction at 90°C. Additionally, the influence of time demonstrated effect on the dechlorination of PCBs.
在这项研究中,我们证明了聚乳酸钾法(KPEG)去除变压器油中多氯联苯(pcb)的有效性。用聚乙二醇400 (PEG 400)和氢氧化钾(KOH)处理由多氯联苯混合物(Aroclor 1254)组成的市售变压器油。通过气相色谱法测定不同处理在不同反应时间下的破坏和去除效率(DRE, %),评价不同处理的相对效率。结果表明,在KOH/PEG = 2:1, KPEG/oil = 30:1的条件下,在90℃下反应3 h 30 min, DRE平均值为95.0%。此外,时间对多氯联苯的脱氯也有影响。
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引用次数: 1
Assessment of heavy metal contamination zones of biota of Western Uttar Pradesh Terrain, India using atomic absorption spectroscopy 使用原子吸收光谱法评估印度北方邦西部地区生物区系的重金属污染区
IF 0.6 Q4 ENGINEERING, ENVIRONMENTAL Pub Date : 2017-09-13 DOI: 10.1504/IJETM.2017.10007523
Nazia Tarannum, R. Agrawal, R. Yadav, A. Yadav, R. Soni
In the present work, heavy metal contamination of water and soil in western Uttar Pradesh terrain, India was assessed. About 16 boreholes and tap water samples and ten soil samples were studied using atomic absorption spectrophotometer (AAS) for arsenic (As) and lead (Pb) content, and the levels were compared with World Health Organization (WHO) specified maximum contaminant level (MCL). According to WHO, the MCL for As and Pb is 0.01 mg/L. From the results obtained, about 75% of biota samples analysed contained As and Pb in concentrations above MCL. The subject of health concern is the increasing concentration of As in Modinagar and Meerut residential area. The effluents from industries, pesticides used in agriculture land and improper waste management are the reasons responsible for heavy metal toxicity in this belt. The deep bore water samples of Muradnagar, Modinagar, Meerut and Mawana showed high concentrations of As.
在本工作中,对印度北方邦西部地区的水和土壤的重金属污染进行了评估。使用原子吸收分光光度计(AAS)对约16个钻孔、自来水样品和10个土壤样品的砷(As)和铅(Pb)含量进行了研究,并将其与世界卫生组织(世界卫生组织)规定的最大污染物水平(MCL)进行了比较。根据世界卫生组织,As和Pb的MCL为0.01 mg/L。从所获得的结果来看,所分析的生物群样品中约75%含有浓度高于MCL的As和Pb。健康问题的主题是As越来越集中在Modinagar和Meerut居民区。工业废水、农田中使用的杀虫剂和不当的废物管理是造成该带重金属毒性的原因。Muradnagar、Modinagar、Meerut和Mawana的深水样品显示出高浓度的As。
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引用次数: 1
Analysis of emission models integrated with traffic models for freight transportation study in urban areas 城市货运研究中排放模型与交通模型的结合分析
IF 0.6 Q4 ENGINEERING, ENVIRONMENTAL Pub Date : 2017-09-13 DOI: 10.1504/IJETM.2017.10007529
H. L. F. Dias, B. V. Bertoncini, M. L. Oliveira, F. S. Cavalcante, Ed Pinheiro Lima
In the present work, two dynamic emission models integrated to traffic simulators were analysed: Panis et al. and EnViver integrated to traffic simulators AIMSUN and VISSIM, respectively. These models were selected due to their capacity to execute emission estimations of particulate matter (PM), a pollutant found in the incomplete combustion in diesel cycle engines and extremely harmful to human health and because of their negative impact was the study object of this paper. Estimated data were confronted with collected data emission in the field through a collecting procedure built by Dias et al. (2015) from a typical urban service vehicle of Fortaleza City - CE, aiming to verify the model that estimated particulate matter data emission closer to the reality of vehicles studied in this research. The selected models can estimate the main rates of particulate matter or originated in urban freight transport. However, the model proposed by Panis et al. was considered more appropriate in the representation of this phenomenon.
本文分析了两种集成在交通模拟器中的动态排放模型:Panis等和集成在交通模拟器AIMSUN和VISSIM中的EnViver。选择这些模型是因为它们能够执行颗粒物(PM)的排放估算,PM是柴油循环发动机中不完全燃烧中发现的对人体健康极其有害的污染物,并且它们的负面影响是本文的研究对象。通过Dias et al.(2015)构建的以福塔莱萨市典型城市服务车辆为样本的数据采集流程,将估算数据与现场采集的数据排放进行对比,验证估算的颗粒物数据排放模型更接近本研究所研究车辆的实际情况。所选择的模型可以估计主要的颗粒物率或源自城市货运。然而,Panis等人提出的模型被认为更适合于表示这一现象。
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引用次数: 6
Assessing treatment of lead (Pb II) from industrial wastewater on dried bulbs of water hyacinth: adsorption capacity, isotherm and kinetic study 工业废水中铅(PbII)在水葫芦干球茎上的吸附性能、等温线和动力学研究
IF 0.6 Q4 ENGINEERING, ENVIRONMENTAL Pub Date : 2017-09-13 DOI: 10.1504/IJETM.2017.10007533
Tiyasha Kanjilal, C. Bhattacharjee, S. Datta
Remediation through aquatic macrophytes treatment system for the removal of noxious contaminants from wastewater is an emerging environmental protection technique. The dried and acid-alkali treated bulbs of water hyacinth (WHB) having high porosity and O2-filled functional groups were utilised to treat Pb(II) from industrial wastewater. Characterisation of WHB with FESEM, XRD and FTIR exhibited the presence of several carboxyls, hydroxyl, ketonic, aldehydes and other O2-filled functional groups showing WHB adsorption with highest monolayer capacity of (Qm) 38.614 mg/g. WHB adsorption directed towards the pseudo-second order kinetics and Langmuir isotherm mechanism. The study also emphasised effective regeneration of WHB using HNO3, NaOH and vacuum dry. The bio-sorption mechanism was observed to be endothermic spontaneous reaction process, with ΔG decreased from -0.71 to -8.53 with increasing temperature. With optimised and controlled process conditions, only 5.0 g L−1 of WHB bio-sorbent could significantly treat about 85.3% of 100 mg L−1 of Pb(II) within 120 minutes at pH 7.0 and 30°C. Also a comparative optimisation study of ANN and RSM were used to predict the WHB bio-sorption bioprocess. Therefore, WHB have efficient potential to be commercially applicable as an environmental-friendly and economical bio-sorbent for treatment of Pb(II) from solutions and effluent from paint industry.
通过水生植物处理系统去除废水中的有害污染物是一种新兴的环境保护技术。利用干燥和酸碱处理的具有高孔隙率和充氧官能团的水葫芦球茎(WHB)处理工业废水中的Pb(II)。用FESEM、XRD和FTIR对WHB的表征显示出几种羧基、羟基、酮基、醛和其他O2填充的官能团的存在,显示出WHB吸附的最高单层容量为(Qm)38.614mg/g。WHB吸附趋向于拟二阶动力学和Langmuir等温线机制。该研究还强调了使用HNO3、NaOH和真空干燥对WHB进行有效再生。生物吸附机理为吸热自发反应过程,随着温度的升高,ΔG从-0.71降至-8.53。在优化和受控的工艺条件下,在pH 7.0和30°C下,只有5.0 g L−1的WHB生物吸附剂可以在120分钟内显著处理约85.3%的100 mg L−1 Pb(II)。此外,还使用ANN和RSM的比较优化研究来预测WHB生物吸附生物过程。因此,WHB作为一种环境友好、经济的生物吸附剂,具有有效的商业应用潜力,可用于处理涂料工业溶液和废水中的Pb(II)。
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引用次数: 2
Application of combined emergent plants in floating bed for phytoremediation of landscape pond in South China 浮床组合挺水植物在华南景观塘植物修复中的应用
IF 0.6 Q4 ENGINEERING, ENVIRONMENTAL Pub Date : 2017-09-13 DOI: 10.1504/IJETM.2017.10007525
P. Huang, Dan J. Zhang, S. Bai, Song-yan Qin
Plants support fauna richness and can be aesthetically pleasing. They also play an invaluable role in the assimilation and removal of nutrients. Canna indica L, Iris tectorums, Lythrum salicaria L., Cyperus alternifolius were found to be highly effective in remediating high nutrient levels in an aquatic environment. In this paper, the four plants were planted in floating beds in a park pond-Fuzhuang, Hefei city. The nearby pond-Lianfang as control was unplanted. The results suggested that combination of four species emergent plants performed well in nutrients removal; the removal efficiencies for suspended solids (SS), turbidity, total nitrogen (TN), total phosphorus (TP) were 82.5%, 87.5%, 75%, 82.9% respectively, compared with the control. At the end of the test, it successfully transformed from V grade water-body to III grade water-body. Different periods of flowering could maintain longer landscape effect. This paper demonstrated that combination of emergent plants could form pleasant scenery as well as restore eutrophic landscape pond.
植物支持动物群的丰富性,并且可以在美学上令人愉悦。它们在吸收和去除营养物质方面也发挥着宝贵的作用。美人蕉(Canna indica L)、鸢尾(Iris tectorums)、柳柳(Lythrum salicaria L.)、互花米草(Cyperus alternifolius)被发现在修复水生环境中的高营养水平方面非常有效。本文在合肥市傅庄公园池塘的浮床上种植了这四种植物。附近的池塘连坊作为控制区,没有得到控制。结果表明,四种不同类型的挺水植物组合对养分去除效果较好;对悬浮物(SS)、浊度、总氮(TN)、总磷(TP)的去除率分别为82.5%、87.5%、75%、82.9%。试验结束时,它成功地从V级水体转变为III级水体。不同的花期可以保持较长的景观效果。该文论证了在恢复富营养化景观塘的同时,将新兴植物组合在一起可以形成怡人的景观。
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引用次数: 4
Actinobacteria are better bioremediating agents for removal of toxic heavy metals: an overview 放线菌是去除有毒重金属的较好生物修复剂
IF 0.6 Q4 ENGINEERING, ENVIRONMENTAL Pub Date : 2017-01-01 DOI: 10.1504/IJETM.2017.10010678
K. Kannabiran
Accumulation of high concentrations of heavy metals in soil and environment affects both humans and microorganisms. Heavy metals get accumulated within the tissues of the organism and at various levels of the ecological chain; leads to decrease in the biomass and biological diversity by affecting the growth, morphology, and activity of the organism. Removal of hazardous heavy metals and radionuclide-contamination through biological means is of current importance. Bioremediation using microorganisms is considered as safe and more efficient. Actinobacteria, the most important groups of microbes, are responsible for degradation and transformation of organic and metal substrates and also possess significant bioremediation potential. It can degrade high doses of pesticides, chemical complexes, and heavy metals. Actinomycetes utilise toxins as carbon sources and in turn synthesise commercially viable antibiotics, enzymes and proteins. In this review, the efficacy of actinomycetes in bioremediation of heavy metals such as copper, chromium, mercury, lead, zinc, and cadmium was discussed.
高浓度重金属在土壤和环境中的积累对人类和微生物都有影响。重金属在生物体的组织内和生态链的各个层次上积累;通过影响生物的生长、形态和活动导致生物量和生物多样性的减少。目前,通过生物手段清除有害重金属和放射性核素污染具有重要意义。利用微生物进行生物修复被认为是安全有效的。放线菌是最重要的微生物类群,负责有机和金属底物的降解和转化,也具有显著的生物修复潜力。它可以降解大剂量的农药、化学复合物和重金属。放线菌利用毒素作为碳源,进而合成商业上可行的抗生素、酶和蛋白质。本文综述了放线菌对铜、铬、汞、铅、锌、镉等重金属的生物修复效果。
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引用次数: 10
期刊
International Journal of Environmental Technology and Management
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