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Degradation of thiophanate-methyl fungicide by photo-Fenton process using lab-scale annular and solar tubular reactors 环形反应器和太阳能管式反应器光fenton法降解硫代甲基杀菌剂
IF 0.6 Q4 ENGINEERING, ENVIRONMENTAL Pub Date : 2019-09-04 DOI: 10.1504/ijetm.2019.10023674
T. Borges, O. Chiavone-Filho, A. C. Teixeira, E. Foletto, G. Dotto, C. Nascimento
In this work, thiophanate-methyl fungicide was degraded by the homogeneous photo-Fenton process using lab-scale annular and solar tubular reactors. A UV light was used as artificial irradiation source in the lab-scale reactor. The influence of hydrogen peroxide (H2O2) dosage and initial pollutant concentration on the process efficiency was investigated. Degradation efficiency of thiophanate-methyl fungicide was monitored by measuring the total organic carbon (TOC). The results revealed that the variable H2O2 dosage showed remarkable effect on the process efficiency, whereas the fungicide concentration showed little influence. Both reactors showed similar efficiencies, reaching a fungicide mineralisation of 80% at 120 min of reaction time. Therefore, both reactors demonstrate to be effective on the thiophanate-methyl degradation from aqueous solution.
在本研究中,利用实验室规模的环形反应器和太阳能管式反应器,采用均匀光fenton法降解硫代甲基杀菌剂。在实验室规模的反应器中,采用紫外光作为人工照射源。考察了过氧化氢(H2O2)投加量和初始污染物浓度对工艺效率的影响。通过测定总有机碳(TOC)来监测硫磷-甲基杀菌剂的降解效率。结果表明,不同H2O2用量对工艺效率有显著影响,而杀菌剂浓度对工艺效率影响不大。两个反应器显示出相似的效率,在120分钟的反应时间内达到80%的杀菌剂矿化。因此,两种反应器都能有效地从水溶液中降解硫代甲基。
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引用次数: 1
Evaluating the effects of elevated concentrations of urea, phosphogypsum and paper mill sludge on soil chemical, microbial and exoenzyme dynamics 评估尿素、磷石膏和造纸厂污泥浓度升高对土壤化学、微生物和外酶动力学的影响
IF 0.6 Q4 ENGINEERING, ENVIRONMENTAL Pub Date : 2019-09-04 DOI: 10.1504/ijetm.2019.10023679
S. Samal, C. Mishra, S. Sahoo
Urea, phosphogypsum (PG) and paper mill sludge (PMS) are commonly used to address soil nutrient deficiency. In this study, these chemicals were used at recommended agricultural dose (RAD) along with low and high concentrations to assess their effects on soil chemical and biological quality. Urea was applied at 0.5, 1.0, 1.5 g/kg soil, PG at 50, 100, 150 g/kg soil and PMS at 5, 10, 15 g/kg soil. Significant variation in soil pH, electrical conductivity and organic carbon (OC) were noticed in response to chemical concentration and treatment types. The percent OC reduction was high in PG and PMS treated soils. Percent nitrogen and phosphorous in soil increased with the concentrations of urea and PG. Invariably, lower bacterial and fungal population were observed in treated soils relative to control. Activities of amylase, cellulase, invertase, dehydrogenase and protease were inhibited at high concentration of all test chemicals with minor deviations. The study indicated that bacterial population and exoenzymes could be useful markers to evaluate soil toxicity due to hyper concentrations of urea, PG and PMS in soil.
尿素、磷石膏(PG)和造纸厂污泥(PMS)通常用于解决土壤养分缺乏问题。在这项研究中,这些化学物质以推荐的农业剂量(RAD)以及低浓度和高浓度使用,以评估它们对土壤化学和生物质量的影响。尿素施用量为0.5、1.0、1.5 g/kg土壤,PG施用量为50、100、150 g/kg土壤,PMS施用量为5、10、15 g/kg土壤。土壤pH、电导率和有机碳(OC)随化学浓度和处理类型的变化而显著。PG和PMS处理的土壤中OC的减少百分比较高。土壤中氮和磷的百分比随着尿素和PG的浓度而增加。与对照相比,处理土壤中的细菌和真菌数量始终较低。淀粉酶、纤维素酶、转化酶、脱氢酶和蛋白酶的活性在高浓度下均受到抑制,但偏差较小。研究表明,由于土壤中尿素、PG和PMS浓度过高,细菌种群和外酶可能是评估土壤毒性的有用标记。
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引用次数: 2
Numerical simulation of pollutant dispersion in an urban street canyon - effects of elevated metro rail track 城市街道峡谷中污染物扩散的数值模拟——高架地铁轨道的影响
IF 0.6 Q4 ENGINEERING, ENVIRONMENTAL Pub Date : 2019-09-04 DOI: 10.1504/ijetm.2019.10023672
A. Singh, P. Bhatia
Urban air pollution is one of the unsettled issues in urban development and planning process. Urban street canyons are one of the main focused areas of investigation due to the heavy emission of the pollutants from vehicles. In the present study, the effects of elevated metro rail track (EMRT) on pollutant dispersion phenomena have been studied using computational fluid dynamics (CFD) technique. As a practical application of a CFD model, k-e turbulence model was applied for airflow modelling. Species transport model was applied for pollutant dispersion modelling. Geometrical configuration of urban street canyon of aspect ratio 'one', with elevated metro rail track, has been considered. Numerical simulations were carried out for perpendicular wind flow. Pollutant concentrations, at various locations of the street canyon, were largely affected by the introduction of elevated metro rail track. These results were compared with the street canyon without elevated metro rail track. It has been observed that the pollutant concentration increased at lower region and decreased at the upper region of the street canyon. Variations were not uniformly distributed in street canyon volume. Contours and pollutant concentrations have been compared and discussed for different sampled locations in the street canyon.
城市大气污染是城市发展和规划过程中未解决的问题之一。城市街道峡谷因其大量排放的污染物而成为研究的重点领域之一。本文采用计算流体力学(CFD)技术研究了高架轨道对污染物扩散现象的影响。作为CFD模型的实际应用,采用k-e湍流模型对气流进行建模。污染物扩散模型采用物种迁移模型。考虑了高架地铁轨道纵横比为“1”的城市街道峡谷几何形态。对垂直气流进行了数值模拟。街道峡谷不同位置的污染物浓度受高架轨道的影响较大。这些结果与无高架地铁轨道的街道峡谷进行了比较。结果表明,街道峡谷下部污染物浓度呈上升趋势,上部污染物浓度呈下降趋势。变化在街道峡谷体积中分布不均匀。对街道峡谷不同采样点的等高线和污染物浓度进行了比较和讨论。
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引用次数: 1
Optimisation of crystal violet removal onto raw kaolin using response surface methodology 用响应面法优化高岭土对结晶紫的去除
IF 0.6 Q4 ENGINEERING, ENVIRONMENTAL Pub Date : 2019-09-04 DOI: 10.1504/ijetm.2019.10023671
Natiela Caponi, G. C. Collazzo, Julia S. Salla, S. L. Jahn, G. Dotto, E. Foletto
This work aimed to investigate the removal of crystal violet (CV) dye from coloured wastewater using natural kaolin as an adsorbent. In order to investigate the effects of independent variables and to determine the optimum conditions on the dye removal, a 23 central composite design combined with a response surface methodology was employed. Experiments were carried out as a function of agitation rate (80 to 150 rpm), initial dye concentration (50 to 150 mg L-1) and adsorbent dosage (0.5 to 1.0 g L-1). The accuracy of the model was evaluated by employing the analysis of variance (ANOVA). The results revealed a good agreement between the model predicted and the experimental values. Under the optimal experimental conditions, the CV removal efficiency was 71% and the maximum adsorption capacity was 48.8 mg g-1. These results indicated that the kaolin can be successfully applied as a potential low-cost adsorbent for the removal of dyes from coloured wastewaters.
本工作旨在研究以天然高岭土为吸附剂去除有色废水中的结晶紫(CV)染料。为了研究自变量的影响并确定染料去除的最佳条件,采用了23中心复合材料设计与响应面方法相结合。实验是作为搅拌速率(80至150rpm)、初始染料浓度(50至150mg L-1)和吸附剂剂量(0.5至1.0g L-1的函数进行的。采用方差分析(ANOVA)对模型的准确性进行评估。结果表明,模型预测值与实验值吻合较好。在最佳实验条件下,CV的去除率为71%,最大吸附量为48.8mg-1。这些结果表明,高岭土可以成功地作为一种潜在的低成本吸附剂从有色废水中去除染料。
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引用次数: 3
Desilication of calcined pulverised fly ash and use of silicate solution to prepare a mesoporous silica adsorbent for heavy metals in acid mine drainage 粉煤灰煅烧粉的脱硅及硅酸盐溶液对酸性矿山废水中重金属的吸附性能研究
IF 0.6 Q4 ENGINEERING, ENVIRONMENTAL Pub Date : 2019-09-04 DOI: 10.1504/ijetm.2019.10023676
T. Falayi, F. Ntuli, F. Okonta
Mesoporous silica (MCM41) adsorbent was prepared from silicate solution produced from silica leaching of calcined pulverised fly ash. MCM41 was used for the removal of heavy metals and neutralisation of acid mine drainage. Silica leaching was optimised using two level full factorial and 13 run central composite rotable uniform design with five centre points. A pH of 7 produced the most pure MCM41 with an external surface area of 98,000 m2m-3. A 4% m/v solid loading of MCM41 could remove 95.5%, 97.3% and 99.6% of Ni, Cu and Fe respectively. The adsorption process was found to fit the Langmuir isotherm and pseudo second order kinetics. The Gibbs free energy of adsorption for all metals was below-20 kJ/mol for all metals. The enthalpy for Fe, Cu and Ni removal were 19.97 kJ/mol, 21.40 kJ/mol and 16.44 kJ/mol respectively and thus endothermic. The significance of the research was that silica could be leached from calcined pulverised fly ash and MCM41 can be used as an adsorbent for heavy metals in acid mine drainage treatment.
以煅烧粉煤灰经二氧化硅浸出得到的硅酸盐溶液为原料,制备了中孔二氧化硅(MCM41)吸附剂。MCM41用于去除重金属和中和酸性矿井排水。二氧化硅浸出采用两级全因子和具有五个中心点的13次中心复合旋转均匀设计进行优化。pH为7产生了最纯的MCM41,其外表面积为98000 m2m-3。固体负载量为4%m/v的MCM41可分别去除95.5%、97.3%和99.6%的Ni、Cu和Fe。吸附过程符合Langmuir等温线和拟二阶动力学。所有金属的吸附吉布斯自由能均低于-20kJ/mol。Fe、Cu和Ni的去除焓分别为19.97kJ/mol、21.40kJ/mol和16.44kJ/mol,因此是吸热的。研究的意义在于,煅烧粉煤灰可以浸出二氧化硅,MCM41可以作为酸性矿山排水处理中重金属的吸附剂。
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引用次数: 2
Forecasting air pollution rates in industrial centres: a case study for Kocaeli-Turkey 预测工业中心的空气污染率:以土耳其科卡埃利为例
IF 0.6 Q4 ENGINEERING, ENVIRONMENTAL Pub Date : 2019-09-04 DOI: 10.1504/ijetm.2019.10023677
Aliye Atay, Y. Akdi, Y. Okkaoğlu, Faruk Çelikkanat
Around the world, air pollution is a leading social problem despite all the precautions. Of all the reasons for this, human-induced ones are at the top of the list. These can be prevented or at least reduced by some measures. Thus, forecasting air pollution is an important issue for all related agencies. In this paper, in order to forecast future values of air pollution rates, two different model approaches were considered. The first one is the Box-Jenkins time series model and the second one is a trigonometric Yt = μ + Acos(wkt) + Bsin(wkt) + et time series model. As a main air pollution measurement index, monthly average amounts of particulate matter, PM10 were used. Kocaeli was selected as a representative city because it is the most important industrial city in Turkey. Hence, data were collected monthly from different air monitoring stations in the city of Kocaeli between 2007 and 2018 and averaged to produce a single time series. Both models yielded high forecast values of PM10.
在世界各地,尽管采取了各种预防措施,空气污染仍是一个主要的社会问题。在所有的原因中,人为因素是最重要的。这些都可以通过一些措施来预防或至少减少。因此,预测空气污染是所有相关机构的一个重要问题。在本文中,为了预测未来的空气污染率,考虑了两种不同的模型方法。第一个是Box-Jenkins时间序列模型,第二个是三角函数Yt = μ + Acos(wkt) + Bsin(wkt) + et时间序列模型。空气污染的主要测量指标是月平均颗粒物PM10。科恰埃利被选为代表城市,因为它是土耳其最重要的工业城市。因此,在2007年至2018年期间,每月从科卡埃利市的不同空气监测站收集数据,并进行平均以产生单个时间序列。两种模式的PM10预测值均较高。
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引用次数: 0
Modelling and simulation of batch adsorption of malachite green using groundnut shell waste-based activated carbon 花生壳废弃物活性炭分批吸附孔雀石绿的模拟研究
IF 0.6 Q4 ENGINEERING, ENVIRONMENTAL Pub Date : 2019-08-05 DOI: 10.1504/IJETM.2019.10022951
I. Dahlan, K. Kit
Modelling and simulation of batch adsorption in malachite green dye removal using activated carbon prepared from groundnut shell waste was studied. Mathematical model was developed based on a two-resistance model which included external mass transfer coefficient and pore diffusion coefficient that controls the mass transfer process in batch adsorption. MATLAB program was written to solve ordinary differential equation from the model and to estimate mass transfer parameters by matching the simulation data with the experimental data from literature. From the results, it was found that the external mass transfer coefficient kf and pore diffusion coefficient Dp were estimated to be 6.2054 × 10−2 m/s and 2.2660 × 10−10 m2/s, respectively. Using the estimated parameters, simulation results showed that the model provided good correlation with the experimental data based on different initial concentrations. The estimated parameters were used to study the adsorption of dye under different variables such as initial dye concentration, volume of dye solution, adsorbent particle size and mass of adsorbent. It was concluded that the dye removal efficiency was higher for lower initial dye concentration, higher mass of adsorbent, lower volume of dye solution and smaller adsorbent particle size.
利用花生壳废料制备的活性炭对孔雀石绿染料的分批吸附过程进行了模拟研究。数学模型建立在包含外部传质系数和孔扩散系数的双阻力模型的基础上,该模型控制了间歇吸附中的传质过程。编写了MATLAB程序,从模型中求解常微分方程,并通过将模拟数据与文献中的实验数据相匹配来估计传质参数。结果表明,外传质系数kf和孔扩散系数Dp分别为6.2054×10−2 m/s和2.2660×10−10 m2/s。利用估算的参数,模拟结果表明,该模型与不同初始浓度下的实验数据具有良好的相关性。利用估算的参数研究了染料在初始浓度、染料溶液体积、吸附剂粒度和吸附剂质量等不同变量下的吸附性能。结果表明,染料初始浓度越低、吸附剂质量越高、染料溶液体积越小、吸附剂粒径越小,染料去除率越高。
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引用次数: 1
Removal of Cr(VI) and Cu(II) from wastewater by an Argopecten irradians shell powder adsorbent 荧光镜贝壳粉吸附剂去除废水中的Cr(VI)和Cu(II)
IF 0.6 Q4 ENGINEERING, ENVIRONMENTAL Pub Date : 2019-08-02 DOI: 10.1504/IJETM.2019.101391
Yanhong Xu, Guangrong Huang
The ability of the shell powder of Argopecten irradians to remove Cr(VI) and Cu(II) ions from aquatic systems was evaluated. The adsorption efficiency was very high for Cu(II), at approximately 99.04%, while for Cr(VI), it was not higher than 24.03%. The adsorption rate of Cr(VI) was affected by the pH, feeding amount, stirring time, calcination temperature and initial Cr(VI) ion concentration. The experimental results indicate that the optimal Cr(VI) absorption rate was 32.86% of Cr(VI) within 1.5 h at a pH of 3 and a 200 mg/L initial Cr(VI) concentration on shell powder acidifie, using hydrochloric acid and calcination at 300°C to promote adsorption. Langmuir and Freundlich models were used to analyse the isotherm data of Cr(VI) and Cu(II). The Freundlich model was suited to Cr(VI) adsorption, while the Langmuir model fit Cu(II) adsorption.
评价了扇贝壳粉对水体中Cr(VI)和Cu(II)离子的去除能力。对Cu(II)的吸附效率很高,约为99.04%,而对Cr(VI)的吸附率不高于24.03%。Cr(VI。实验结果表明,在pH为3、初始Cr(VI)浓度为200mg/L的壳粉酸化条件下,用盐酸和300°C煅烧以促进吸附,在1.5小时内Cr(Ⅵ)的最佳吸收率为32.86%。采用Langmuir和Freundlich模型对Cr(VI)和Cu(II)的等温线数据进行了分析。Freundlich模型适用于Cr(VI)吸附,Langmuir模型适用于Cu(II)吸附。
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引用次数: 1
Wind-assist marine demonstration for ferries: prospects for saving diesel fuel with wind power 渡轮的风力辅助海上示范:利用风力节省柴油的前景
IF 0.6 Q4 ENGINEERING, ENVIRONMENTAL Pub Date : 2019-08-02 DOI: 10.1504/IJETM.2019.10022837
T. Lipman, J. Lidicker
These sailing vessel testing, data collection and analysis project examined the real world potential for a novel carbon-fibre 'wingsail' technology to reduce fuel use in potential passenger ferryboat applications. The project involved building a carbon fibre, computer-controlled wingsail that was then mounted on a 14-metre trimaran test vessel with a complete instrumentation package. The vessel was then operated on the San Francisco Bay over a three-month period. The test results were conclusive that, for a test vessel travelling at seven knots though water on a particular ferry route, up to 25% to 40% of the fuel burned can be saved through the use of the wingsail, depending on wind speed, with a corresponding reduction in greenhouse gases, toxic and criteria pollutant emissions and fuel costs. The estimated fuel efficiency gains will not necessarily translate directly to those at actual ferryboat service speeds (at 17 or more knots) but are encouraging pending further investigations.
这些帆船测试、数据收集和分析项目考察了一种新型碳纤维“翼帆”技术在现实世界中的潜力,以减少潜在客运渡轮应用中的燃料使用。该项目涉及建造一个碳纤维、计算机控制的翼帆,然后安装在一艘14米长的三体船试验船上,并配有完整的仪器包。该船随后在旧金山湾运营了三个月。测试结果是决定性的,对于在特定航线上以7节/小时的速度在水中行驶的测试船来说,根据风速的不同,通过使用翼帆可以节省高达25%至40%的燃料消耗,并相应减少温室气体、有毒和标准污染物排放以及燃料成本。估计的燃油效率收益不一定会直接转化为实际渡轮服务速度(17节或更多节)下的收益,但在进一步调查之前,这是令人鼓舞的。
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引用次数: 2
Correlations between on-site screening methods and laboratory analyses of oil-contaminated fuelling station sites 受石油污染加油站现场筛选方法与实验室分析之间的相关性
IF 0.6 Q4 ENGINEERING, ENVIRONMENTAL Pub Date : 2019-08-02 DOI: 10.1504/IJETM.2019.10022880
Tsung-Nan Weng, Chen‐Wuing Liu, Wen Liu
In order to assess the potential of soil contamination from petroleum-based products and determine the soil samples required for laboratory analysis, investigators generally use portable instruments such as photo ionisation detectors (PIDs) or flame ionisation detectors (FIDs) for on-site screening. In this study, PIDs, FIDs, and turbidimetric test kits were integratively used to screen 47 soil samples from 28 fuelling station sites suspected of total petroleum hydrocarbon (TPH) contamination. The PIDs and FIDs achieved high accuracy in screening sites contaminated by gasoline (TPHC6-C9); the test kits yielded high accuracy in screening those contaminated by diesel fuel (TPHC10-C40), as well as high correlation with laboratory analysis. Regression analyses showed high coefficients of determination (R2), reaching up to 0.819 (PIDs versus TPHC6-C9), 0.788 (FIDs versus TPHC6-C9), and 0.653 (test kits versus TPHC10-C40). The integration of PIDs, FIDs, and test kits with laboratory analysis can significantly increase the efficiency and accuracy of soil contamination investigations. We suggest that the application of turbidimetric test kits to screen potential oil-contaminated fuelling station sites can produce accurate assessment results.
为了评估石油产品对土壤污染的可能性,并确定实验室分析所需的土壤样本,调查人员通常使用便携式仪器,如光电电离探测器(PID)或火焰电离探测器(FID)进行现场筛查。在本研究中,PID、FID和浊度测试试剂盒被综合用于筛选28个加油站站点的47个疑似总石油烃(TPH)污染的土壤样本。PID和FID在汽油污染场地(TPHC6-C9)的筛选中实现了高精度;该检测试剂盒在筛选被柴油污染的物质(TPHC10-C40)方面具有较高的准确性,并且与实验室分析具有较高的相关性。回归分析显示,决定系数(R2)很高,达到0.819(PID与TPHC6-C9)、0.788(FID与TPHC6-C9)和0.653(检测试剂盒与TPHC10-C40)。PID、FID和测试试剂盒与实验室分析的集成可以显著提高土壤污染调查的效率和准确性。我们建议,应用浊度测试试剂盒来筛选潜在的受石油污染的加油站站点,可以产生准确的评估结果。
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引用次数: 0
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International Journal of Environmental Technology and Management
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