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Selective detection of picolinic acid by molecularly imprinted polymer based electrochemical sensor 分子印迹聚合物电化学传感器对吡啶酸的选择性检测
IF 0.8 4区 材料科学 Q4 METALLURGY & METALLURGICAL ENGINEERING Pub Date : 2023-08-29 DOI: 10.1557/s43578-023-01136-0
Nur Asyiqin Zulkefli, F. S. Mehamod, A. Jani, Nur Habibah Safiyyah Jusoh, F. Suah
Picolinic acid (PIC) is a key metabolite found in the amino acid tryptophan. While it has been well-studied for its significant role in mental health disorders, there has been little research into developing a rapid sensor to detect PIC. In this preliminary work, we sought to develop a molecularly imprinted polymers (MIPs)-based electrochemical sensor that could rapidly and selectively detect PIC. The electrochemical sensor performance was evaluated using differential pulse voltammetry (DPV) in a linear range between 1 and 5 mM, with a limit of detection of 0.6 mM (S/N = 3) and a limit of quantification of 1.7 mM (S/N = 10). The interference analysis was also conducted on the MIPs sensor to evaluate its ability to selectively detect PIC in the presence of other interfering molecules. Overall, the results demonstrate that this sensor has significant potential for use in the rapid and selective detection of PIC by electrochemical analysis.
吡啶酸(PIC)是氨基酸色氨酸中的关键代谢物。虽然它在精神健康障碍中的重要作用已经得到了充分的研究,但很少有研究开发一种快速检测PIC的传感器。在这项初步工作中,我们试图开发一种基于分子印迹聚合物(MIPs)的电化学传感器,可以快速和选择性地检测PIC。采用差分脉冲伏安法(DPV)在1 ~ 5 mM的线性范围内评价电化学传感器的性能,检测限为0.6 mM (S/N = 3),定量限为1.7 mM (S/N = 10)。我们还对MIPs传感器进行了干扰分析,以评估其在存在其他干扰分子的情况下选择性检测PIC的能力。总的来说,结果表明该传感器在电化学分析中快速和选择性检测PIC方面具有重要的潜力。
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引用次数: 0
Preparation of lightweight, high hardness multi-component systems induced by partial oxidation and hard intermetallic phase formation 由部分氧化和金属间相形成诱发的轻质、高硬度多组分体系的制备
IF 0.8 4区 材料科学 Q4 METALLURGY & METALLURGICAL ENGINEERING Pub Date : 2023-08-29 DOI: 10.1557/s43578-023-01137-z
S. Lee, C. Chokradjaroen, Yasuyuki Sawada, N. Saito
The ternary Mg–Al–Ti and quaternary Mg–Al–Ti–Cu systems were prepared by mechanical alloying in oxygen-lean atmosphere followed by spark plasma sintering. The ternary Mg–Al–Ti and quaternary Mg–Al–Ti–Cu systems which were sintered at 750 °C after 16 h milling showed the highest hardness of 509 and 947 HV with low densities of 2.9 and 3.9 g/cm3, respectively. The decrease in particle size and uniform dispersion of elements through optimization of the MA process induced the formation of uniform composite microstructure after SPS. Moreover, the addition of the fourth element, Cu, showed a significant impact on the improvement in hardness. This result was explained from the perspective of the microstructure and the electronic nature of elements. Our results provide a facile method for synthesizing oxide/metal composites from elemental powders without a separate oxidation process.
采用机械合金化的方法,在贫氧气氛下制备了三元Mg-Al-Ti和季相Mg-Al-Ti - cu体系,并进行了放电等离子烧结。在750℃下烧结16 h的三元Mg-Al-Ti和季相Mg-Al-Ti - cu体系的最高硬度分别为509和947 HV,低密度分别为2.9和3.9 g/cm3。通过优化MA工艺,使颗粒尺寸减小,元素分散均匀,SPS后形成了均匀的复合组织。此外,第四元素Cu的加入对硬度的提高有显著的影响。从微观结构和元素的电子性质两方面解释了这一结果。我们的研究结果提供了一种简便的方法来合成氧化物/金属复合材料从元素粉末没有单独的氧化过程。
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引用次数: 0
Effect of particle size and distribution of hollow spheres on the compressive behavior of aluminum matrix syntactic foams 中空球体粒径及分布对铝基复合泡沫压缩性能的影响
IF 0.8 4区 材料科学 Q4 METALLURGY & METALLURGICAL ENGINEERING Pub Date : 2023-08-29 DOI: 10.1557/s43578-023-01153-z
Yong Mei, Chao Fu, Ying Fu, E. Wang, Quanzhan Yang, Yong Ding
Aluminum matrix syntactic foams (AMSFs) reinforced by Al2O3 hollow sphere (HS) with three different distributions of the particles were successfully produced by a self-developed counter-gravity infiltration casting technique. The effects of the size and distribution of particles on the quasi-static compressive behavior and failure mechanisms of the AMSFs was investigated. Microstructural images showed a clear interface between the fillers and matrix and no obvious shrinkage cavity was detected. The quasi-static compressive stress–strain curve of the AMSFs underwent three stages, namely linear-elastic, plateau, and then densification stages. The long plateau stage indicated that the AMSFs have excellent energy absorption capacity. The compressive strength and specific energy absorption capacity of the syntactic foam was lower when smaller particles were used and the compressive strength of bimodal AMSFs was much lower than that of monomodal AMSFs. The deformation of the AMSFs under compressive load, indicates that the distribution of the particles has an important influence on the failure mechanism of the AMSFs.
采用自主研发的反重力渗铸技术,成功制备了三种不同颗粒分布的Al2O3空心球增强铝基复合泡沫(amsf)。研究了颗粒尺寸和颗粒分布对amsf准静态压缩行为和破坏机制的影响。显微结构图像显示填料与基体界面清晰,无明显缩孔。准静态压缩应力-应变曲线经历了线弹性、平台化和致密化三个阶段。长期的高原期表明,amsf具有良好的能量吸收能力。粒径越小,复合泡沫的抗压强度和比能吸收能力越低,双峰复合泡沫的抗压强度远低于单峰复合泡沫。压缩载荷作用下amsf的变形表明,颗粒的分布对amsf的破坏机制有重要影响。
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引用次数: 0
Thermodynamic modeling of the Sb–Te system supported by DSC measurement and ab initio calculations 由DSC测量和从头计算支持的Sb-Te体系热力学模型
IF 0.8 4区 材料科学 Q4 METALLURGY & METALLURGICAL ENGINEERING Pub Date : 2023-08-29 DOI: 10.1557/s43578-023-01140-4
Cheng-Yu Liu, Yu-Yun Liu, Su-Hua Chen, Sinn-Wen Chen, A. Dębski, W. Gasior, W. Gierlotka
Nowadays, thermoelectric materials became important sources of renewable energy. Among various materials that show this property, the Sb2Te3 attracts attention due to its excellent properties. Recent experimental information revealed a new phase equilibrium data; therefore, it is reasonable to elaborate a state-of-art thermodynamic model of the binary Sb–Te system. In this work, a new thermodynamic description is proposed based on the available experimental data. In addition, a new DSC measurement of heat and temperature of fusion of Sb2Te3 as well as ab initio calculation of Sb2Te3 were included in the experimental dataset. The homogeneity range of Sb2Te3 was modeled according to the stability of defects obtained from first-principle calculations. The morphology of the optimized phase diagram follows the latest findings, which means that the Ksi phase has replaced the delta and gamma phases. The elaborated thermodynamic parameters allow for a good reproduction of experimental data as well as for future modeling of higher-ordered systems.
目前,热电材料已成为可再生能源的重要来源。在各种表现出这种特性的材料中,Sb2Te3因其优异的性能而备受关注。最近的实验资料揭示了一个新的相平衡数据;因此,建立一个目前最先进的Sb-Te二元体系热力学模型是合理的。在此工作中,基于现有的实验数据,提出了一种新的热力学描述。此外,实验数据集还包括了Sb2Te3的热和聚变温度的DSC测量以及Sb2Te3的从头计算。根据第一性原理计算得到的缺陷稳定性对Sb2Te3的均匀性范围进行了建模。优化后的相图形貌遵循最新的发现,这意味着Ksi相已经取代了delta相和gamma相。详细阐述的热力学参数可以很好地再现实验数据以及将来对高阶系统的建模。
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引用次数: 0
DGM – Deutsche Gesellschaft für Materialkunde (德国情报协会
4区 材料科学 Q4 METALLURGY & METALLURGICAL ENGINEERING Pub Date : 2023-08-25 DOI: 10.1515/ijmr-2023-2009
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引用次数: 0
Correction: In vitro evaluation of pH-sensitive liposomes loaded with d-limonene in targeting human malignant glioma cells 更正:在体外评估负载d-柠檬烯的ph敏感脂质体靶向人类恶性胶质瘤细胞
IF 0.8 4区 材料科学 Q4 METALLURGY & METALLURGICAL ENGINEERING Pub Date : 2023-08-25 DOI: 10.1557/s43578-023-01131-5
Vinitha Rani, J. Venkatesan, A. Prabhu
This article was updated to correct Fig. 7. The correct Fig. 7 is also reproduced here. Correction: In vitro evaluation of pH‐sensitive liposomes loaded with d‐limonene in targeting human malignant glioma cells Vinitha Rani1, Jayachandran Venkatesan1, Ashwini Prabhu1,a) 1 Yenepoya Research Centre, Yenepoya (Deemed to be University), Deralakatte, Mangalore, Karnataka 575018, India a) Address all correspondence to this author. e-mail: ashwiniprabhu@yenepoya.edu.in
本文已更新以更正图7。此处也复制了正确的图7。更正:负载d - limonene的pH敏感脂粒靶向人类恶性胶质瘤细胞的体外评估Vinitha ran1, Jayachandran Venkatesan1, Ashwini Prabhu1,a) 1 Yenepoya研究中心,Yenepoya(被认为是大学),Deralakatte, Mangalore, Karnataka 575018,印度a)请将所有通信发送给本文作者。电子邮件:ashwiniprabhu@yenepoya.edu.in
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引用次数: 0
Automated classification of granular bainite and polygonal ferrite by electron backscatter diffraction verified through local structural and mechanical analyses 通过局部结构和力学分析,验证了电子背散射衍射对粒状贝氏体和多边形铁素体的自动分类
IF 0.8 4区 材料科学 Q4 METALLURGY & METALLURGICAL ENGINEERING Pub Date : 2023-08-24 DOI: 10.1557/s43578-023-01113-7
R. Jentner, S. Tsai, A. Welle, K. Srivastava, S. Scholl, J. Best, C. Kirchlechner, G. Dehm
Differentiation of granular bainite and polygonal ferrite in high-strength low-alloy (HSLA) steels possesses a significant challenge, where both nanoindentation and chemical analyses do not achieve an adequate phase classification due to the similar mechanical and chemical properties of both constituents. Here, the kernel average misorientation from electron backscatter diffraction (EBSD) was implemented into a Matlab code to differentiate and quantify the microstructural constituents. Correlative electron channeling contrast imaging (ECCI) validated the automated phase classification results and was further employed to investigate the effect of the grain tolerance angle on classification. Moreover, ECCI investigations highlighted that the grain structure of HSLA steels can be subdivided into four grain categories. Each category contained a different nanohardness or substructure size that precluded a nanoindentation-based phase classification. Consequently, the automated EBSD classification approach based on local misorientation achieved a reliable result using a grain tolerance angle of 5°.
在高强度低合金(HSLA)钢中,颗粒贝氏体和多边形铁素体的区分具有重大的挑战,其中纳米压痕和化学分析都无法获得足够的相分类,因为这两种成分的机械和化学性质相似。在此,将电子背散射衍射(EBSD)的核平均取向偏差实现到Matlab代码中,以区分和量化微结构成分。相关电子通道对比成像(ECCI)验证了自动相位分类结果,并进一步研究了晶粒公差角对分类的影响。此外,ECCI研究强调,HSLA钢的晶粒结构可以细分为四种晶粒类型。每个类别包含不同的纳米硬度或亚结构尺寸,这排除了基于纳米压痕的相分类。因此,基于局部取向误差的EBSD自动分类方法在5°晶粒公差角下获得了可靠的分类结果。
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引用次数: 3
Correction: Effects of annealing on bonding strengthening mechanism of Ti/Al composite sheets by twin‑roll casting with roller vibration 修正:退火对双辊振动铸造Ti/Al复合薄板结合强化机制的影响
IF 0.8 4区 材料科学 Q4 METALLURGY & METALLURGICAL ENGINEERING Pub Date : 2023-08-22 DOI: 10.1557/s43578-023-01051-4
Li Li, Fengshan Du
Correction: Effects of annealing on bonding strengthening mechanism of Ti/Al composite sheets by twin‐roll casting with roller vibration Li Li1,2, Fengshan Du1,2,a) 1 National Engineering Research Center for Equipment and Technology of Cold Strip Rolling, Yanshan University, Qinhuangdao 066004, Hebei, People’s Republic of China 2 College of Mechanical Engineering, Yanshan University, Qinhuangdao 066004, Hebei, People’s Republic of China a) Address all correspondence to this author. e-mail: fsdu@ysu.edu.cn
李莉1,2,杜凤山1,2,a) 1燕山大学冷连轧装备与技术国家工程技术研究中心,河北秦皇岛066004;2燕山大学机械工程学院,河北秦皇岛066004;a)所有通信请与作者联系。电子邮件:fsdu@ysu.edu.cn
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引用次数: 0
Ultraviolet-B radiation from Gd (III) doped hardystonite Gd (III)掺杂硬石的紫外- b辐射
IF 0.8 4区 材料科学 Q4 METALLURGY & METALLURGICAL ENGINEERING Pub Date : 2023-08-18 DOI: 10.1515/ijmr-2022-0289
Vijay P. Singh, Ch.B. Annapurna Devi, A. Rao, J. Joo
Abstract Trivalent gadolinium (Gd3+)-doped calcium zinc silicate (Ca2ZnSi2O7/hardystonite) with a molar composition of Ca2−x ZnSi2O7:xGd3+ (x = 0.09 mol) was produced using a sol–gel system. The hardystonite was characterized using X-ray diffraction and Fourier transform infrared spectroscopy. The X-ray diffraction study revealed that the prepared sample contained a tetragonal phase of Ca2ZnSi2O7. The vibrational structures of the sample were studied using Fourier transform infrared spectroscopy measurements. The photoluminescence emission spectrum of the Ca1.91ZnSi2O7:0.09Gd3+ phosphor narrow band was optimized at 312 nm in the Ultraviolet-B region under excitation at 273 nm wavelength. Electron paramagnetic resonance study authenticates the presence of gadolinium (Gd) ions within the trivalent state in the Ca1.91ZnSi2O7:0.09Gd3+ host.
摘要采用溶胶-凝胶法制备了三价钆(Gd3+)掺杂的钙锌硅酸钙(Ca2ZnSi2O7/硬石岩),其摩尔组成为Ca2−x ZnSi2O7:xGd3+ (x = 0.09 mol)。利用x射线衍射和傅里叶变换红外光谱对硬石岩进行了表征。x射线衍射研究表明,制备的样品含有Ca2ZnSi2O7的四方相。利用傅里叶变换红外光谱对样品的振动结构进行了研究。在273 nm激发下,Ca1.91ZnSi2O7:0.09Gd3+荧光粉窄带的光致发光发射光谱在312 nm处得到优化。电子顺磁共振研究证实了Ca1.91ZnSi2O7:0.09Gd3+基体中存在三价态钆离子。
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引用次数: 0
Bacterial cellulose: A smart biomaterial for biomedical applications 细菌纤维素:用于生物医学应用的智能生物材料
IF 0.8 4区 材料科学 Q4 METALLURGY & METALLURGICAL ENGINEERING Pub Date : 2023-08-17 DOI: 10.1557/s43578-023-01116-4
Ashutosh Pandey, M. Singh, Annika Singh
The escalating curiosity in bacterial cellulose (BC) due to exceptional attributes such as purity, biodegradability, non-toxicity, porous fibrillar structure, and high water retention potential expand its applications to tissue engineering, controlled drug delivery, and cosmetics. BC has proved highly prospective to be used to manufacture innovative wound care solutions, drug carriers and delivering complexes. The drug-carrying BC found enormous applications in dental therapies, wound care, and scare-free wound management. Various degradation techniques of BC under antibiotic environments and physiological conditions offer different advantages in drug design. The drug loading capacity of BC can be increased by in situ modifications of its fibrillar network. The BC-based scaffolds compounded with other materials such as nanopolymers have explored new frontiers for BC applications in auspicious biomedicinal product developments. BC can accommodate different nanoparticles, biomaterials, synthetic materials, carbon materials, and plant extracts, which allows using BC in various biomedical and cosmetic products. Graphical abstract
细菌纤维素(BC)由于其纯度、可生物降解性、无毒性、多孔纤维结构和高保水潜力等特殊特性,使其在组织工程、药物输送控制和化妆品等领域的应用不断扩大。BC已被证明具有很高的前景,用于制造创新的伤口护理解决方案,药物载体和输送复合物。携带药物的BC在牙科治疗、伤口护理和无惊吓伤口管理方面有巨大的应用。各种抗生素环境和生理条件下BC的降解技术在药物设计中具有不同的优势。BC的载药能力可以通过原位修饰其纤维网络来增加。BC基支架与其他材料如纳米聚合物复合,为BC在吉祥生物医药产品开发中的应用开辟了新的领域。BC可以容纳不同的纳米颗粒、生物材料、合成材料、碳材料和植物提取物,这使得BC可以在各种生物医学和化妆品中使用。图形抽象
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引用次数: 0
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