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Geochemical Appraisal of the Depositional Environment and Source Organic Matter of Crude Oils from Some Oil Fields in Bayelsa State, Nigeria 尼日利亚巴耶尔萨州部分油田原油沉积环境及源有机质地球化学评价
Pub Date : 2020-07-01 DOI: 10.22050/IJOGST.2020.221306.1538
Charles Ikenna Oraegbunam, L. Osuji, M. Onojake, S. Abrakasa
The organic geochemical characterization of crude oil samples from the oil fields of the Niger delta was carried out using gas chromatography–-mass spectrometry (GC–-MS) to genetically characterize the oil samples in terms of their biomarker composition. Geochemical characteristics such as depositional environments, kerogen type, and source of organic matter were analyzed using aliphatic biomarkers as a supporting tool. Five samples were randomly collected from Tebidaba, Clough Creek and Azuzuama fields in Bayelsa State, Nigeria. The saturated hydrocarbons were analyzed using GC–MS. The n-alkanes, isoprenoids, biomarkers hopanes, and steranes fingerprints were extracted from chromatogram for m/z 57, 191, 217 values respectively. The results revealed that the five studied samples were characterized by C29 sterane predominance and the presence of oleanane, depicting organic matter with vascular land plant material inputs and a deltaic contribution. Ternary plots showed that the oils were deposited in an estuarine environment. The pristane (Pr) /nC17 versus phytane (Ph)/nC18 showed that TEB 08 and WELL 2 are in the anoxic environment inferring kerogen II and a mixture of types I and II respectively. TEB 12, CCST, and AZU ST has kerogen type III deposited in an oxic environment.
采用气相色谱-质谱法(GC -MS)对尼日尔三角洲油田原油样品进行了有机地球化学表征,根据其生物标志物组成对石油样品进行了遗传表征。以脂肪族生物标志物为辅助工具,分析了沉积环境、干酪根类型、有机质来源等地球化学特征。从尼日利亚巴耶尔萨州的Tebidaba、Clough Creek和Azuzuama油田随机采集了5个样本。采用气相色谱-质谱法分析饱和烃。正构烷烃、类异戊二烯、生物标志物藿烷和甾烷指纹图谱分别为m/z值57、191、217。结果表明,5个样品均以C29甾烷为主,齐墩烷的存在为特征,表明有机质具有维管陆生植物物质输入和三角洲贡献。三元图显示油类沉积于河口环境。原烷(Pr) /nC17与植烷(Ph)/nC18对比表明,TEB 08和WELL 2分别处于缺氧环境,推断为干酪根II型和I型和II型的混合物。teb12、CCST和AZU ST为III型干酪根沉积于氧环境中。
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引用次数: 0
Identifying Gas-bearing Carbonate Reservoir Using Extended Elastic Impedance 扩展弹性阻抗法识别含气碳酸盐岩储层
Pub Date : 2020-07-01 DOI: 10.22050/IJOGST.2020.218837.1535
Hessam MansouriSiahgoli, M. Riahi, B. Heidari, R. Mohebian
It is difficult to identify the carbonate reservoirs by using conventional seismic reflection data, especially in cases where the reflection coefficient of the gas-bearing zone is close to that of the carbonate background. In such cases, the extended elastic impedance (EEI) as a seismic reconnaissance attribute with the ability to predict fluids and lithology can be used. It allows for a better distinction between seismic anomaly caused by lithology and the one caused by the fluid content. The EEI attribute extends the available reflection angles and applies different weights to the intercept and gradient values so as to extract the petrophysical properties of the rock at a specific incident angle. Using the EEI attribute, we can estimate the elastic parameters such as shear impedance; the ratio of the compressional velocity to shear velocity; Poisson’s ratio; and bulk, Lame, and shear moduli, and petrophysical properties, including porosity, clay content, and water saturation. The known reservoirs in the study area are three oil-bearing formations namely, Surmeh (Arab), Gadvan (Buwaib), and Dariyan (Shuaiba), and three gas-bearing formations, including Kangan, Dalan, and Faraghan. The Dehram group is composed of Kangan (Triassic), Dalan, and Faraghan (Permian) formations. Permian carbonates of Kangan–Dalan and its equivalent Khuff have regionally been developed as a thick carbonate sequence in the southern Persian Gulf region. In this paper, parameters 𝜆𝑝 and 𝜇𝜌 extracted from the EEI method are used to characterize a carbonate reservoir. Our results show that the EEI can highlight the difference between the reservoir and non-reservoir formation to identify the gas-bearing areas.
常规地震反射资料难以识别碳酸盐岩储层,特别是在含气带反射系数接近碳酸盐岩背景反射系数的情况下。在这种情况下,可以使用扩展弹性阻抗(EEI)作为地震侦察属性,具有预测流体和岩性的能力。它可以更好地区分岩性引起的地震异常和流体含量引起的地震异常。EEI属性扩展了可用的反射角,并对截距和梯度值应用不同的权重,从而提取特定入射角下岩石的物性。利用EEI属性,可以估计剪切阻抗等弹性参数;压缩速度与剪切速度之比;泊松比;体积、剪切模量和剪切模量,以及岩石物性,包括孔隙度、粘土含量和含水饱和度。研究区已知储层为Surmeh (Arab)、Gadvan (Buwaib)、Dariyan (Shuaiba) 3个含油组和Kangan、Dalan、Faraghan 3个含气组。Dehram组由Kangan组(三叠纪)、Dalan组和Faraghan组(二叠纪)组成。坎干—达兰二叠系及其对应的胡夫二叠系碳酸盐岩在波斯湾南部地区是一层较厚的碳酸盐岩层序。本文利用EEI方法提取的参数𝑝和𝜌对某碳酸盐岩储层进行了表征。结果表明,EEI可以突出储层与非储层的差异,从而识别含气区。
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引用次数: 1
Analyzing Single- and Two-parameter Models for Describing Oil Recovery in Imbibition from Fractured Reservoirs 裂缝性油藏渗吸采收率单参数和双参数模型分析
Pub Date : 2020-07-01 DOI: 10.22050/IJOGST.2020.207829.1524
M. Ghaedi, S. Ahmadpour
The imbibition process is known as one of the main production mechanisms in fractured reservoirs where oil/gas-filled matrix blocks are surrounded by water-filled fractures. Different forces such as gravity and capillary play a role in production from a fractured reservoir during imbibition and complicate the imbibition process. In previous works, single-parameter models such as the Aronofsky model and Lambert W function were presented to model imbibition recovery from matrix blocks. The Aronofsky model underestimates early time recovery and overestimates late time recovery, and Lambert W function is suitable for water wet cases. In this work, a data bank of different experimental and numerical imbibition recovery curves at various rock and fluid properties were collected. Then, a rigorous analysis was performed on the models utilized to describe oil/gas recovery during the imbibition process. In addition to investigating the single-parameter models, two-parameter models used for dose-response modeling, including Weibull, beta-Poisson, and Logit models were examined. The results of this work demonstrate that using two-parameter models can improve the prediction of imbibition behavior. Moreover, among the two-parameter models, the Weibull has the capability to describe the imbibition process better. The Aronofsky model underestimates early time recovery and overestimates late time recovery, and Lambert W function is suitable for water wet cases. In this work, a data bank of different experimental and numerical imbibition recovery curves at various rock and fluid properties were collected. Then, a rigorous analysis was performed on the models utilized to describe oil/gas recovery during the imbibition process. In addition to investigating the single-parameter models, two-parameter models used for dose-response modeling, including Weibull, beta-Poisson, and Logit models were examined. The results of this work demonstrate that using two-parameter models can improve the prediction of imbibition behavior. Moreover, among the two-parameter models, the Weibull has the capability to describe the imbibition process better.
渗吸过程是裂缝性储层的主要生产机制之一,在裂缝性储层中,充满油气的基质块被充满水的裂缝包围。裂缝性储层在吸胀过程中受重力、毛管等不同作用力的影响,使吸胀过程复杂化。在以前的工作中,采用了单参数模型,如Aronofsky模型和Lambert W函数来模拟基质区块的渗吸采收率。Aronofsky模型低估了早期恢复,高估了后期恢复,Lambert W函数适用于水湿情况。本文收集了不同岩石和流体性质下不同的实验和数值吸胀采收率曲线数据库。然后,对用于描述吸胀过程中油气采收率的模型进行了严格的分析。除了研究单参数模型外,还研究了用于剂量-反应建模的双参数模型,包括Weibull, beta-Poisson和Logit模型。研究结果表明,采用双参数模型可以更好地预测吸胀行为。此外,在两参数模型中,威布尔模型更能描述吸胀过程。Aronofsky模型低估了早期恢复,高估了后期恢复,Lambert W函数适用于水湿情况。本文收集了不同岩石和流体性质下不同的实验和数值吸胀采收率曲线数据库。然后,对用于描述吸胀过程中油气采收率的模型进行了严格的分析。除了研究单参数模型外,还研究了用于剂量-反应建模的双参数模型,包括Weibull, beta-Poisson和Logit模型。研究结果表明,采用双参数模型可以更好地预测吸胀行为。此外,在两参数模型中,威布尔模型更能描述吸胀过程。
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引用次数: 1
Experimental Measurement of Equilibrium Surface Tension of an Aqueous Solution of Polyethylene Glycol and a Surfactant 聚乙二醇和表面活性剂水溶液平衡表面张力的实验测量
Pub Date : 2020-07-01 DOI: 10.22050/IJOGST.2020.198631.1519
F. Beiranvand, S. H. Najibi, B. H. Shahraki
A device is designed and constructed for measuring the equilibrium surface tension of water and a number of other solutions. The measured equilibrium surface tension of water, as a reference fluid, has good consistency with literature data. Moreover, the equilibrium surface tension of the aqueous solutions of surfactants and polymer composed of sodium dodecyl sulphate (SDS), Triton CG-110, dimethyl di-dodecyl-ammonium bromide (DDAB), and polyethylene glycol (PEG) with different molecular weights of 200, 300, 400, and 600, as well as that of the ternary solutions of SDS/PEG/water, Triton CG-110/PEG/water, and DDAB/PEG/water at 293.15 K and atmospheric pressure are measured. The equilibrium surface tension of the aqueous solutions of PEG 600 are measured at 296.15 K because PEG 600 is solid at 293.15 K. The measured data are compared with the predictions of thermodynamic models, and the results show that Redlich-Kister (RK) model has the lowest error in predicting the experimental data.
设计并制造了一种测量水和许多其他溶液的平衡表面张力的装置。作为参考流体的水的平衡表面张力测量值与文献数据有较好的一致性。此外,测定了由十二烷基硫酸钠(SDS)、Triton CG-110、二甲基二十二烷基溴化铵(DDAB)和聚乙二醇(PEG)组成的分子量为200、300、400和600的表面活性剂和聚合物的水溶液,以及SDS/PEG/水、Triton CG-110/PEG/水和DDAB/PEG/水三元溶液在293.15 K和常压下的平衡表面张力。PEG 600水溶液的平衡表面张力在296.15 K时测得,因为PEG 600在293.15 K时为固体。将实测数据与热力学模型的预测结果进行了比较,结果表明Redlich-Kister (RK)模型对实验数据的预测误差最小。
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引用次数: 1
Mass Transfer Modeling of CO2 Absorption into Blended Aqueous MDEA–PZ Solution 混合MDEA-PZ水溶液中CO2吸收的传质模型
Pub Date : 2020-07-01 DOI: 10.22050/IJOGST.2020.222615.1540
Fahimeh Mirzaei, A. Ghaemi
In this research, the rate of CO2 absorption into methyl diethanolamine–piperazine (MDEA–PZ) solution was investigated. To model the mass transfer flux in the reactive absorption processes, the dimensionless parameters of the process were obtained using the Buckingham Pi theorem and considering the effective parameters in mass transfer. The CO2 mass transfer flux in the reactive absorption process depends on the mass transfer parameters of both the liquid and gas phases. Based on the dimensionless parameters obtained, a correlation is proposed to calculate the mass transfer flux of acidic gases in MDEA–PZ solutions. The mass transfer flux in the reactive absorption process is modeled based on the four laws of chemical equilibrium, phase equilibrium, mass balance, and charge balance. Experimental data from the literature were used to determine the constants of the derived correlation as a function of dimensionless parameters. In the provided correlation, the effects of dimensionless parameters including film parameter, CO2 loading, ratio of diffusion coefficients in the gas–liquid phase, CO2 partial to total pressure, and film thickness ratio as well as factors such as temperature, the number of free amines in the solution, the partial pressure of CO2, on the CO2 mass transfer flux were investigated. According to the results, the absorption rate decreases with increasing CO2 loading and film parameter, and the mean absolute deviation is about 3.6%, which indicates the high accuracy of the correlation.
本研究考察了甲基二乙醇胺-哌嗪(MDEA-PZ)溶液对CO2的吸收率。为了模拟反应吸收过程的传质通量,利用Buckingham Pi定理,考虑传质过程中的有效参数,得到了反应吸收过程的无因次参数。反应吸收过程中的CO2传质通量取决于液相和气相的传质参数。基于得到的无量纲参数,提出了一种关系式来计算MDEA-PZ溶液中酸性气体的传质通量。根据化学平衡、相平衡、质量平衡和电荷平衡四定律对反应吸收过程的传质通量进行了建模。利用文献中的实验数据来确定作为无量纲参数函数的导出相关性的常数。在此关系式中,考察了膜参数、CO2载荷、气液相扩散系数比、CO2分压与总压、膜厚比等无量纲参数以及温度、溶液中游离胺数、CO2分压等因素对CO2传质通量的影响。结果表明,吸收率随CO2负荷和膜参数的增加而降低,平均绝对偏差约为3.6%,相关性较高。
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引用次数: 2
Managed Pressure Drilling Using Integrated Process Control 采用集成过程控制的控压钻井
Pub Date : 2020-04-01 DOI: 10.22050/IJOGST.2020.177554.1499
Mahdi Imanian, M. Karbasian, A. Ghassemi
Control of wellbore pressure during drilling operations has always been important in the oil industry as this can prevent the possibility of well blowout. The present research employs a combination of automatic process control and statistical process control for the first time for the identification, monitoring, and control of both random and special causes in drilling operations. To this end, by using automatic process control, control charts are applied to the output of the controlled process; subsequently, the points which are outside the predefined control limits are identified. This method is capable of using controllable input variables not used in automatic process control, such as changes in the mud weight, to fully control the process. Due to the dynamic nature of the process, adaptive model-based controllers have replaced feedback methods in automatic process control. Control charts have also been used to compare the performance of different automatic process control approaches. Based on this new criterion, the fuzzy adaptive approach is shown to have good performance in automatic process control. The results indicate that this approach can improve the limits of the automatic process control method by using statistical process control for controlling the bit pressure in an acceptable range.
在石油工业中,钻井作业过程中的井筒压力控制一直很重要,因为这可以防止井喷的发生。本研究首次将自动过程控制与统计过程控制相结合,对钻井作业中的随机和特殊原因进行识别、监测和控制。为此,采用自动过程控制,将控制图应用于被控过程的输出;随后,确定超出预定义控制范围的点。该方法能够使用自动过程控制中不使用的可控输入变量,例如泥浆比重的变化,来完全控制过程。由于过程的动态性,基于自适应模型的控制器已经取代了自动过程控制中的反馈方法。控制图也被用来比较不同的自动过程控制方法的性能。在此基础上,模糊自适应方法在自动过程控制中具有良好的性能。结果表明,该方法可以改善自动过程控制方法的局限性,通过统计过程控制将钻头压力控制在可接受的范围内。
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引用次数: 0
Implementing Direct and Indirect Wireline Methods in Determination of Total Organic Carbon: A Case Study from a West African Hydrocarbon Field 采用直接和间接电缆法测定总有机碳:以西非某油气田为例
Pub Date : 2020-04-01 DOI: 10.22050/IJOGST.2020.193179.1512
Amir Gharavi, Mohamed Hassan, H. Ghoochaninejad, J. Fianu, Michael Kenomore, A. Shah, J. Buick
Since the development bloom in unconventional reservoirs in North America, total organic carbon (TOC) has become a more essential parameter, as the indicator of the efficiency of these reservoirs. In this paper, by using conventional well logs and NMR log data, the TOC content of an unconventional reservoir in West Africa is estimated. Passy’s, Issler’s, and Schmoker’s methods were used as indirect wireline methods to estimate TOC content, along the well paths. Afterward, NMR log data, as a direct method, was used to provide more precise calculations of TOC. Both methods showed almost similar trends, with the NMR method indicating lower values for the TOC. Then, an adjusted Schmoker equation was proposed, which showed the best fit between NMR and conventional well logs results. By using the equation, the TOC content was calculated in three other wells, where NMR data were unavailable. The results were then used to prepare a 3D model of the TOC distribution, within the reservoir.
自北美非常规油藏开发热潮以来,总有机碳(TOC)作为储层开发效率的指标,已成为一个更为重要的参数。利用常规测井资料和核磁共振测井资料,对西非某非常规储层的TOC含量进行了估算。Passy、Issler和Schmoker的方法被用作沿井径估算TOC含量的间接电缆方法。随后,利用核磁共振测井数据作为一种直接方法,提供了更精确的TOC计算。两种方法显示出几乎相似的趋势,核磁共振法表明TOC值较低。在此基础上,提出了调整后的Schmoker方程,证明了核磁共振测井结果与常规测井结果的最佳拟合。通过使用该方程,计算了另外三口井的TOC含量,这些井没有核磁共振数据。然后将结果用于制备储层内TOC分布的3D模型。
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引用次数: 1
Application of Decline Curve Analysis for Estimating Different Properties of Closed Fractured Reservoirs for Vertical Wells 递减曲线分析在直井封闭裂缝性储层物性评价中的应用
Pub Date : 2020-04-01 DOI: 10.22050/IJOGST.2017.30498.1275
Amin Daryasafar, Mohammad Fathinasab, G. D. Prat, R. Kharrat
In this paper, decline curve analysis is used for estimating different parameters of bounded naturally fractured reservoirs. This analysis technique is based on rate transient technique, and it is shown that if production rate is plotted against time on a semi-log graph, straight lines are obtained that can be used to determine important parameters of the closed fractured reservoirs. The equations are based on Warren and Root model. The comparison between the results of this technique and those of the conventional methods confirms its high proficiency in transient well testing. It should be noted that in conventional decline curve methods, parameters such as interporosity flow parameter and storage capacity ratio must be first obtained by previous methods like the build-up analysis, but in the proposed method all the main reservoir parameters can be calculated directly, which is one of the advantages of this method. This paper focuses on the interpretation of rate tests, and the starting points and slopes of straight lines are utilized with proper equations to solve directly for various properties. The main important aspect of the presented method is its accuracy since analytical solutions are used for calculating reservoir parameters.
本文采用递减曲线分析方法估计有界天然裂缝性储层的不同参数。该分析技术基于速率瞬变分析技术,结果表明,在半对数图上绘制产量随时间变化的曲线,可以得到直线,从而确定封闭裂缝性储层的重要参数。方程基于Warren和Root模型。通过与常规方法的对比,验证了该技术在暂态试井中的适用性。需要注意的是,在传统的递减曲线方法中,孔隙间流动参数、储层容量比等参数必须先通过堆积分析等方法得到,而本文方法可以直接计算出储层的所有主要参数,这是该方法的优点之一。本文着重于速率试验的解释,并利用直线的起点和斜率与适当的方程直接求解各种性质。该方法的主要重要方面是其精度,因为解析解用于计算储层参数。
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引用次数: 0
A New Methodology to Define Net Pay Zone in Gas Reservoirs 确定气藏净产层的新方法
Pub Date : 2020-04-01 DOI: 10.22050/IJOGST.2020.196320.1516
M. Qassamipour, E. Khodapanah, S. Tabatabaei‐Nezhad
Net pay thickness is defined as that portion of a reservoir which contains economically producible hydrocarbons with today’s technology, prices, and costs. This thickness is a key parameter of the volumetric calculation of in-place hydrocarbons, well test interpretation, and reservoir characterization. A reservoir interval is considered as net pay when it contains hydrocarbons that can flow at an economic rate. Therefore, to define net pay, cutoffs of hydrocarbon storage properties besides flow properties of reservoir rock are necessary. Frequently, petrophysical log-derived rock storage properties like porosity and water saturation are linked to core measured properties like permeability to find a relation between them. Then, by use of a fixed limiting value for permeability, log-derived properties cutoffs are determined. The basic problem of these methods is related to permeability cutoff, since in most cases there is no knowledge about it, and the permeability cutoff can differ from field to field or even well to well. A new methodology has been developed to find a logical permeability cutoff for gas reservoirs which can differ for different wells and/or fields. This technique is based on gas flow through porous media in tight rocks. Accordingly, a relationship between porosity and permeability is derived as a cutoff value at reservoir pressure and temperature, which is considered as a discriminator plot. Then, the core data of the specified reservoir are added to this plot and the data points reflecting net pay zone are identified. This technique has been applied to four real gas reservoirs in Iran and indicated acceptable results confirmed by the drill stem test (DST) and production data. The results show that the proposed procedure is less dependent on experts’ experiences and acts as a straightforward and powerful tool for the refinement of net pays. In addition, the cutoff values calculated from this method contain a scientific base supporting the main procedure.
净产层厚度被定义为在当前技术、价格和成本条件下,储层中含有具有经济产出能力的油气的部分。该厚度是原位油气体积计算、试井解释和储层表征的关键参数。当储层中含有能够以经济速度流动的碳氢化合物时,该储层被认为是净产层。因此,为了确定净产层,除了需要确定储层岩石的流动特性外,还需要确定储层的储集特性。通常,岩石物理测井衍生的岩石存储属性(如孔隙度和含水饱和度)与岩心测量的属性(如渗透率)相关联,以找到它们之间的关系。然后,利用渗透率的固定限制值,确定测井导出的性质截止值。这些方法的基本问题与渗透率切断有关,因为在大多数情况下,人们对渗透率切断一无所知,并且渗透率切断可能因油田甚至井而异。目前已经开发出一种新的方法来寻找气藏的合理渗透率截止值,该截止值可能因井和/或油田的不同而不同。该技术基于致密岩石中气体通过多孔介质的流动。据此,导出了储集层压力和温度下孔隙度和渗透率的临界值,并将其视为判别图。然后,将指定储层的岩心数据添加到该图中,识别出反映净产层的数据点。该技术已应用于伊朗的四个实际气藏,并通过钻杆测试(DST)和生产数据证实了可接受的结果。结果表明,所提出的程序较少依赖于专家的经验,并作为一个简单而有力的工具,为细化净支付。此外,该方法计算出的截止值具有科学依据,支持了主要程序。
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引用次数: 1
A Robust Method to Predict Equilibrium and Kinetics of Sulfur and Nitrogen Compounds Adsorption from Liquid Fuel on Mesoporous Material 介孔材料对液体燃料中硫化物和氮化物吸附平衡和动力学的稳健预测方法
Pub Date : 2020-04-01 DOI: 10.22050/IJOGST.2019.147638.1477
M. Khosravi-Nikou, A. Shariati, M. Mohammadian, A. Barati, Adel Najafi‐Marghmaleki
This study presents a robust and rigorous method based on intelligent models, namely radial basis function networks optimized by particle swarm optimization (PSO-RBF), multilayer perceptron neural networks (MLP-NNs), and adaptive neuro-fuzzy inference system optimized by particle swarm optimization methods (PSO-ANFIS), for predicting the equilibrium and kinetics of the adsorption of sulfur and nitrogen containing compounds from a liquid hydrocarbon model fuel on mesoporous materials. All the models were evaluated by the statistical and graphical methods. The predictions of the models were also compared with different kinetics and equilibrium models. The results showed that although all the models lead to accurate results, the PSO-ANFIS model represented the most reliable and dependable predictions with the correlation coefficient (R2) of 0.99992 and average absolute relative deviation (AARD) of 0.039%. The developed models are also able to predict the experimental data with better precision and reliability compared to literature models.
本研究提出了一种基于智能模型的稳健、严格的方法,即基于粒子群优化的径向基函数网络(PSO-RBF)、多层感知器神经网络(MLP-NNs)和基于粒子群优化方法优化的自适应神经模糊推理系统(PSO-ANFIS),用于预测液态烃模型燃料中含硫和含氮化合物在介孔材料上的吸附平衡和动力学。采用统计和图解方法对模型进行评价。并与不同的动力学和平衡模型进行了比较。结果表明,虽然所有模型的预测结果都很准确,但PSO-ANFIS模型的预测结果最可靠,相关系数(R2)为0.99992,平均绝对相对偏差(AARD)为0.039%。与文献模型相比,所建立的模型对实验数据的预测精度和可靠性都有所提高。
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引用次数: 3
期刊
Iranian Journal of Oil and Gas Science and Technology
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