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Friction Stir Welding of 1.4 GPa-Grade Tempered Martensitic Steel 1.4 GPa 级回火马氏体钢的搅拌摩擦焊
IF 1.8 4区 材料科学 Q2 METALLURGY & METALLURGICAL ENGINEERING Pub Date : 2024-08-26 DOI: 10.2355/isijinternational.isijint-2024-175
Yasuyuki Miyano, Hiroki Washiya, Hiromu Sato, Yoshihiro Aoki, Mitsuhiko Kimura, Kohsaku Ushioda, Hidetoshi Fujii

Thermal hysteresis in fusion welding causes significant weld deterioration in medium- and high-carbon steels. Therefore, the development of an effective alternative welding process is required. Friction stir welding (FSW) is a solid-state welding process performed in an atmosphere that reduces the risks associated with melting and solidification of metals, making it an effective alternative method. Furthermore, it facilitates a flexible in-process control of heat input, which can be achieved by controlling the welding parameters. Considering these, the authors conducted a series of studies to elucidate the characteristics of FSW for medium- and high-carbon steels, including high-strength tempered steels.

This paper presents the results of applying FSW to 1.4 GPa-grade tempered JIS-S55C steel plates. Five distinct weld types were created by varying the welding parameters, including tool rotation and welding speed. The temperature of the interface between the tool and in-process material was measured using a thermal imaging camera. The microstructure of the welds was evaluated using optical microscopy and field-emission scanning electron microscopy (FE-SEM) with an electron-backscatter diffraction (EBSD) measurement system. The mechanical properties of the welds were evaluated through Vickers hardness and tensile tests. Digital image correlation analysis was employed to analyze the local deformation during the tensile test.

熔化焊接中的热滞后会导致中碳钢和高碳钢的焊缝严重劣化。因此,需要开发一种有效的替代焊接工艺。搅拌摩擦焊(FSW)是一种在大气中进行的固态焊接工艺,可降低金属熔化和凝固带来的风险,是一种有效的替代方法。此外,它还可以通过控制焊接参数,灵活地对输入热量进行过程控制。有鉴于此,作者进行了一系列研究,以阐明中碳钢和高碳钢(包括高强度回火钢)的 FSW 特性。本文介绍了将 FSW 应用于 1.4 GPa 级回火 JIS-S55C 钢板的结果。通过改变焊接参数,包括工具旋转和焊接速度,形成了五种不同的焊接类型。使用热像仪测量了工具和加工中材料之间的界面温度。使用光学显微镜和带有电子背散射衍射(EBSD)测量系统的场发射扫描电子显微镜(FE-SEM)对焊缝的微观结构进行了评估。通过维氏硬度和拉伸试验评估了焊缝的机械性能。数字图像相关分析被用来分析拉伸试验过程中的局部变形。
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引用次数: 0
Effect of intercritical annealing on microstructure and toughness of medium-Mn steel with elongated prior-austenite grains formed via two-step hot rolling process 临界退火对通过两步热轧工艺形成的具有细长先奥氏体晶粒的中锰钢显微组织和韧性的影响
IF 1.8 4区 材料科学 Q2 METALLURGY & METALLURGICAL ENGINEERING Pub Date : 2024-08-22 DOI: 10.2355/isijinternational.isijint-2024-180
Kyosuke Matsuda, Takuro Masumura, Toshihiro Tsuchiyama, Misa Takanashi, Takuya Maeda, Shuichi Nakamura, Ryuji Uemori

Fe-9 mass%Ni alloy is widely used as a cryogenic steel owing to its excellent low-temperature strength and toughness. However, Ni is an expensive element, with medium-Mn steel considered an inexpensive alternative. Considering the Fe-10%Mn-0.1%C alloy is brittle at low temperatures, the application of intercritical annealing with two-step hot rolling could lead to toughening. Herein, the effect of intercritical annealing on the toughness of a Fe-10%Mn-0.1%C alloy with elongated prior-austenite grains (PAGs) formed via a two-step hot-rolling process was investigated. Intercritical annealing was performed on the specimens with and without two-step hot rolling. For both specimens, intercritical annealing resulted in softening of α'-martensite and an increase in the amount of retained austenite. In the specimen not subjected to the two-step hot rolling process, the fracture morphology transitioned from ductile to intergranular with a decrease in the temperature. Intercritical annealing improved the toughness when ductile fracture occurred. In the case of intergranular fracture, the effect of intercritical annealing on the toughness was negligible. In the two-step hot-rolled specimen with elongated PAGs, the fracture morphology transitioned from ductile to separation fracture with ductile fracture, and intercritical annealing improved the toughness at all temperature ranges. The improvement in toughness during separation fracture is attributed to the expansion of the plastic zone owing to ductile crack progression and the formation of sub-cracks, which promote the strain-induced transformation of retained austenite and ε-martensite.

Fe-9 mass%Ni 合金因其出色的低温强度和韧性而被广泛用作低温钢。然而,镍是一种昂贵的元素,中锰钢被认为是一种廉价的替代品。考虑到Fe-10%Mn-0.1%C合金在低温下较脆,采用两步热轧的间临界退火可导致韧化。本文研究了间临界退火对通过两步热轧工艺形成的具有细长先奥氏体晶粒(PAGs)的 Fe-10%Mn-0.1%C 合金韧性的影响。对经过和未经过两步热轧的试样进行了临界退火。对于两种试样,临界退火都导致了 α'-马氏体的软化和残余奥氏体量的增加。在未经过两步热轧工艺的试样中,随着温度的降低,断口形态从韧性转变为晶间腐蚀。临界退火改善了发生韧性断裂时的韧性。在晶间断裂的情况下,临界退火对韧性的影响可以忽略不计。在带有细长 PAG 的两步热轧试样中,断口形态从韧性断口过渡到韧性断口的分离断口,临界退火提高了所有温度范围内的韧性。分离断裂过程中韧性的改善归因于韧性裂纹发展和子裂纹形成导致的塑性区扩展,这促进了残余奥氏体和ε-马氏体的应变诱导转变。
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引用次数: 0
Effect of Cu addition on localized corrosion originating from MnS inclusions for low-alloy steel in a 3% NaCl solution 添加铜对低合金钢在 3% 氯化钠溶液中因 MnS 包裹体引起的局部腐蚀的影响
IF 1.8 4区 材料科学 Q2 METALLURGY & METALLURGICAL ENGINEERING Pub Date : 2024-08-22 DOI: 10.2355/isijinternational.isijint-2024-184
Takuya Hara, Hiroyuki Fuji

The effect of MnS inclusions on the localized corrosion of low-alloy steel in a 0.5 mol/kg (3 %) NaCl solution was investigated to propose countermeasures for inhibiting localized corrosion initiated by MnS inclusions. Low alloy steels without MnS inclusions did not corrode in a 0.5 mol/kg (3 %) NaCl solution, regardless of the addition of Cu. That is, no matrix improvement effect due to solute Cu was confirmed. Slight corrosion occurred in the Cu containing steel with MnS inclusions; however, the MnS inclusions remained. Cu7.2S4 precipitated on the MnS in contact with a 0.5 mol/kg (3 %) NaCl solution. Therefore, Cu7.2S4 precipitates on the MnS inclusions during immersion, which could suppress the localized corrosion initiated by the MnS inclusions because Cu sulfide is not dissolved based on potential-pH diagram. The addition of Cu in a 0.5 mol/kg (3 %) NaCl solution does not improve the corrosion resistance of the matrix due to solute Cu but does suppress localized corrosion initiating from MnS by precipitating Cu sulfide on MnS.

研究了MnS夹杂物对低合金钢在0.5 mol/kg (3 %) NaCl溶液中局部腐蚀的影响,以提出抑制由MnS夹杂物引发的局部腐蚀的对策。不含 MnS夹杂物的低合金钢在 0.5 mol/kg (3 %) NaCl 溶液中不会发生腐蚀,无论是否添加铜。也就是说,没有证实溶质 Cu 对基体有改善作用。含有 MnS夹杂物的含铜钢发生了轻微腐蚀,但 MnS夹杂物依然存在。在与 0.5 mol/kg (3 %) NaCl 溶液接触时,MnS 上析出了 Cu7.2S4。因此,在浸泡过程中,Cu7.2S4 在 MnS 包裹体上析出,这可能会抑制由 MnS 包裹体引发的局部腐蚀,因为根据电位-pH 图,硫化铜不会溶解。在 0.5 mol/kg (3 %) NaCl 溶液中加入 Cu 不会因为溶质 Cu 而提高基体的耐腐蚀性,但会通过在 MnS 上析出硫化铜而抑制由 MnS 引发的局部腐蚀。
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引用次数: 0
Analysis of Generation Mechanism of Unimodal and Bimodal Waveform Detection Signals of a Whole Roll Flatness Meter 全辊平面度测量仪的单模态和双模态波形检测信号生成机制分析
IF 1.8 4区 材料科学 Q2 METALLURGY & METALLURGICAL ENGINEERING Pub Date : 2024-08-09 DOI: 10.2355/isijinternational.isijint-2024-169
Tongyuan Zhang, Shuang Liao, Juntao Gao, Wenkai Hao, Hongmin Liu

Under certain conditions, the whole roll flatness meter outputs a bimodal waveform signal, which is clearly different from the conventional unimodal waveform signal. Since detection relies on the extraction of crest values and the values of the two waveforms do not have the same linearity, the presence of the two waveforms of different channels will clearly give rise to errors in the calculated flatness distribution. To develop an effective extraction method, it is necessary to accurately analyze the evolution of the waveforms. In this paper, the finite element method is used to calculate the load of the sensor, the stress distribution of each analysis surface and the deformation of the sensor mounting hole during the real-time detection to analyze the mechanism of the waveforms. The results show that unimodal and bimodal waveforms are produced under different strip tension and wrap angle conditions. In addition, the radial stress of the roll surface always presents two stress wave distributions. With increasing strip tension or wrap angle, the phase difference between the two waves increases. The stress distribution will change the deformation trend of the mounting hole and affect the stress distribution state of the sensor. When the phase difference of the stress waves exceeds the covering range of the sensor, the output signal changes from a unimodal waveform to a bimodal waveform. Finally, by setting up an experimental platform with variable tension and wrap angle, the relationship between the output waveforms and the working conditions in the simulation is reproduced.

在某些条件下,整辊平整度仪会输出双峰波形信号,这与传统的单峰波形信号明显不同。由于检测依赖于波峰值的提取,而两种波形的值不具有相同的线性,因此不同通道的两种波形的存在显然会导致计算出的平整度分布出现误差。要开发有效的提取方法,就必须准确分析波形的演变过程。本文采用有限元法计算实时检测过程中传感器的载荷、各分析面的应力分布以及传感器安装孔的变形,分析波形的机理。结果表明,在不同的带材张力和包角条件下会产生单模态和双模态波形。此外,轧辊表面的径向应力始终呈现两种应力波分布。随着板带张力或包角的增大,两波之间的相位差会增大。应力分布会改变安装孔的变形趋势,并影响传感器的应力分布状态。当应力波的相位差超过传感器的覆盖范围时,输出信号就会从单模态波形变为双模态波形。最后,通过建立一个具有可变张力和包角的实验平台,再现了输出波形与模拟工作条件之间的关系。
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引用次数: 0
Effect of MgO/CaO ratio on viscosity and phase structure of chromium-containing high-titanium blast furnace slag 氧化镁/氧化钙比例对含铬高钛高炉渣粘度和相结构的影响
IF 1.8 4区 材料科学 Q2 METALLURGY & METALLURGICAL ENGINEERING Pub Date : 2024-08-09 DOI: 10.2355/isijinternational.isijint-2024-148
Jiawen Chen, Weichao Zheng, Liangbin Chen, Ying Deng, Jiachang Hao, Zhenyun Tian, Guibao Qiu

The effect of MgO/CaO ratio on the viscosity and free running temperature of chromium-containing high-titanium blast furnace slag (CaO-SiO2-Al2O3-MgO-TiO2-Cr2O3) was investigated by a rotating crucible viscometer. When the ternary basicity with a fixed (CaO+MgO)/SiO2 ratio of 1.41 and the temperature was fixed, the MgO/CaO ratio had an obvious influence on the viscosity of slags. Increasing MgO/CaO ratio from 0.34 to 0.44 caused a slight decrease in the viscosity of the slag, and had an opposite effect when MgO/CaO ratio was more than 0.44. The XRD measurements showed that the technology of ‘‘replacing CaO with MgO'' has an effect on the precipitation temperature of perovskite phase and spinel phase. Accroding to the Raman spectroscopy results, with the increase of MgO/CaO ratio from 0.34 to 0.44, the DOP decreased, and then increased as the MgO/CaO ratio increased from 0.44 to 0.56.

通过旋转坩埚粘度计研究了 MgO/CaO 比对含铬高钛高炉渣(CaO-SiO2-Al2O3-MgO-TiO2-Cr2O3)粘度和自由流动温度的影响。当三元碱度(CaO+MgO)/SiO2 比为 1.41 且温度固定时,MgO/CaO 比对炉渣粘度有明显影响。将 MgO/CaO 比从 0.34 提高到 0.44 会使炉渣粘度略有下降,而当 MgO/CaO 比大于 0.44 时,则会产生相反的效果。XRD 测量结果表明,"用 MgO 替代 CaO "技术对包晶相和尖晶石相的析出温度有影响。根据拉曼光谱结果,随着氧化镁/氧化钙比率从 0.34 增加到 0.44,DOP 下降,然后随着氧化镁/氧化钙比率从 0.44 增加到 0.56,DOP 上升。
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引用次数: 0
Modification of Copper Slag Composite with Water-Quenched Silicon-Manganese Slag 用水淬硅锰渣改性铜渣复合材料
IF 1.8 4区 材料科学 Q2 METALLURGY & METALLURGICAL ENGINEERING Pub Date : 2024-07-31 DOI: 10.2355/isijinternational.isijint-2023-471
Bin Zheng, Liang Jiang, Fenglan Han, Hui Su, Pengxiang Li, Xinwei Gong

Metallurgical industries often discharge slag containing valuable elements that are poorly utilized when producing copper alloys and silicon-manganese alloys. To improve the utilization rate, in this study, a method to mix copper slag with water-quenched silicon-manganese slag and CaO for roasting and modification was proposed. In this work, FactSage 8.0, DSC-TG, and XRD were used to examine the phase change during the modification process and investigate the impacts of the CaO content, roasting temperature, and holding time on the modification effect. The results showed that the addition of water-quenched silicon-manganese slag and CaO could effectively promote the transformation of fayalite to (Mn, Mg, Fe)Fe2O4, with the highest conversion rate occurring at a 10% CaO content. An increase in the temperature and prolongation of the time facilitated fayalite transformation, but excessive temperature or time could result in iron loss. The optimal recovery rate and iron grade were achieved with roasting at 1400 °C for 60 min. This method can provide a concentrate suitable for producing copper-containing antibacterial stainless steel and wear-resistant cast iron, and the tailings can be used to produce ceramic materials.

冶金工业在生产铜合金和硅锰合金时,经常会排放含有宝贵元素的炉渣,而这些元素的利用率却很低。为了提高利用率,本研究提出了一种将铜渣与水淬硅锰渣和 CaO 混合进行焙烧和改性的方法。本研究采用 FactSage 8.0、DSC-TG 和 XRD 来检测改性过程中的相变,并研究 CaO 含量、焙烧温度和保温时间对改性效果的影响。结果表明,添加水淬硅锰渣和 CaO 能有效地促进辉绿岩向(锰、镁、铁)Fe2O4 的转化,其中 CaO 含量为 10%时转化率最高。温度的升高和时间的延长有利于辉绿岩的转化,但过高的温度或过长的时间会导致铁的损失。在 1400 °C 下焙烧 60 分钟可达到最佳回收率和铁品位。该方法可提供适用于生产含铜抗菌不锈钢和耐磨铸铁的精矿,尾矿可用于生产陶瓷材料。
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引用次数: 0
Lattice Defects Present beneath Crack Initiation, Propagation, and Final Fracture Regions on the Same Hydrogen Embrittlement Fracture Surface of Martensitic Steel 马氏体钢同一氢脆断裂表面上裂纹起始、扩展和最终断裂区域下方的晶格缺陷
IF 1.8 4区 材料科学 Q2 METALLURGY & METALLURGICAL ENGINEERING Pub Date : 2024-07-27 DOI: 10.2355/isijinternational.isijint-2024-147
Takahiro Chiba, Kenichi Takai

Atomic-scale lattice defects beneath various hydrogen embrittlement fracture process regions, i.e., different fracture modes, were compared for martensitic steel. The crack initiation region containing quasi-cleavage (QC) and intergranular (IG) fracture, the crack propagation region mostly consisting of IG fracture, and the final fracture region completely composed of microvoid coalescence (MVC) were extracted from the same fracture surface and analyzed by low-temperature thermal desorption spectroscopy (L-TDS). The relative shapes of the L-TDS curves were different at the sampling positions, demonstrating at the atomic-scale that the types and numbers of lattice defects formed vary depending on the fracture process and fracture mode.

比较了马氏体钢各种氢脆断裂过程区域(即不同断裂模式)下的原子尺度晶格缺陷。从同一断裂表面提取了包含准脆化(QC)和晶间(IG)断裂的裂纹起始区、主要由 IG 断裂组成的裂纹扩展区以及完全由微空洞凝聚(MVC)组成的最终断裂区,并通过低温热解吸光谱(L-TDS)进行了分析。在不同的取样位置,L-TDS 曲线的相对形状各不相同,这从原子尺度上证明了所形成的晶格缺陷的类型和数量随断裂过程和断裂模式的不同而变化。
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引用次数: 0
Comparison of the viscoelastic properties and viscosity of suspensions determined by oscillation and creep testing 通过振荡试验和蠕变试验测定的悬浮液粘弹性能和粘度的比较
IF 1.8 4区 材料科学 Q2 METALLURGY & METALLURGICAL ENGINEERING Pub Date : 2024-07-27 DOI: 10.2355/isijinternational.isijint-2024-078
Kento Nakanishi, Takehiro Sumita, Noritaka Saito, Kunihiko Nakashima

Knowledge of the viscoelastic properties of suspensions is essential for many industrial processes. Although oscillation and creep testing are widely used to measure the viscoelastic properties of complex fluids, few studies on the correlation between the viscoelastic properties measured using these methods have been published. This study aims to provide insights into the differences between these methods and determine which method is better suited for a particular application. The room-temperature viscoelastic properties of a suspension composed of polyethylene beads dispersed in a silicone oil matrix were measured by oscillation and creep testing and compared. The results of oscillation testing indicated that the suspension showed weakly elastic deformation, whereas the results of creep testing revealed that the suspension was relatively elastic, with the liquid phase showing lower viscosity. In addition, the viscosity measured by oscillation testing was lower than that measured by creep testing. When the imposed flow causes microstructural changes, such as when the shear flow and particle‒particle contact induce aggregation, the analyzed flow property considerably differs between testing methods.

了解悬浮液的粘弹性能对许多工业流程至关重要。尽管振荡测试和蠕变测试被广泛用于测量复杂流体的粘弹性能,但有关使用这些方法测量的粘弹性能之间的相关性的研究却鲜有发表。本研究旨在深入探讨这两种方法之间的差异,并确定哪种方法更适合特定应用。通过振荡测试和蠕变测试测量了由分散在硅油基质中的聚乙烯珠组成的悬浮液的室温粘弹性能,并进行了比较。振荡测试结果表明,悬浮液表现出弱弹性变形,而蠕变测试结果表明,悬浮液具有相对弹性,液相粘度较低。此外,振荡测试测得的粘度低于蠕变测试测得的粘度。当外加流动导致微观结构发生变化时,例如当剪切流动和颗粒与颗粒之间的接触引起聚集时,不同测试方法所分析的流动特性会有很大不同。
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引用次数: 0
Microstructure and mechanical properties of gas metal arc-welded Fe-Mn-Si seismic damping alloy 气体金属弧焊铁锰硅减震合金的微观结构和力学性能
IF 1.8 4区 材料科学 Q2 METALLURGY & METALLURGICAL ENGINEERING Pub Date : 2024-07-19 DOI: 10.2355/isijinternational.isijint-2024-174
Tomoya Nagira, Terumi Nakamura, Fumiyoshi Yoshinaka, Takahiro Sawaguchi, Yasuhiko Inoue

A brace-type seismic damper made of an Fe-15Mn-11Cr-7.5Ni-4Si alloy solidified in the ferrite-austenite (FA) mode and SN490B steel, which can be constructed via welding, was proposed. To realize the proposed seismic damper, gas metal arc welding was applied to produce similar FMS/FMS fillet welds and dissimilar FMS/SN490B fillet weld joints. Based on the Schaeffler diagram, similar and dissimilar welding consumables were designed such that the fillet weld metal solidified in the FA mode without solidification cracking. Sound similar fillet welded joints were obtained using two types of welding consumables with different Cr/Ni equivalent ratios although both the similar fillet weld metals had a coarse columnar austenite grain structure. These displayed higher tensile strengths (716–736 MPa) and marginally lower elongations (67–70%) than the FMS alloy. Moreover, a similar fillet weld metal with a chemical composition almost identical to that of the FMS alloy exhibited a remarkable low-cycle fatigue life (5740 cycles). This was shorter than that of the FMS alloy (9351 cycles) owing to the easier formation of α'-martensite. A dissimilar fillet welded joint with a chemical composition within the austenite region was produced without solidification cracking. The dissimilar fillet weld metal showed high tensile strength (867 MPa) and total elongation (61%). These were comparable to those of similar fillet weld metals.

提出了一种由铁素体-奥氏体(FA)模式下凝固的 Fe-15Mn-11Cr-7.5Ni-4Si 合金和 SN490B 钢制成的支撑型地震阻尼器,该阻尼器可通过焊接构建。为了实现所提出的地震阻尼器,采用了气体金属弧焊来生产相似的 FMS/FMS 角焊缝和不相似的 FMS/SN490B 角焊缝。根据舍弗勒图表,设计了相似和不相似的焊材,使角焊缝金属在 FA 模式下凝固而不会产生凝固裂纹。尽管两种相似的角焊缝金属都具有粗大的柱状奥氏体晶粒结构,但使用两种具有不同铬/镍当量比的焊材获得了声音相似的角焊缝。与 FMS 合金相比,它们的抗拉强度更高(716-736 兆帕),伸长率(67-70%)略低。此外,化学成分几乎与 FMS 合金相同的类似角焊缝金属的低循环疲劳寿命(5740 次)也非常出色。由于α'-马氏体更容易形成,因此比 FMS 合金的低循环疲劳寿命(9351 次)更短。生产出的化学成分在奥氏体区域内的异种角焊缝接头没有出现凝固裂纹。异种角焊缝金属显示出较高的抗拉强度(867 兆帕)和总伸长率(61%)。这些指标与同类角焊缝金属相当。
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引用次数: 0
Current trends on deep learning techniques applied in iron and steel making field: A review 钢铁制造领域应用深度学习技术的当前趋势:综述
IF 1.8 4区 材料科学 Q2 METALLURGY & METALLURGICAL ENGINEERING Pub Date : 2024-07-19 DOI: 10.2355/isijinternational.isijint-2024-098
Kazumasa Tsutsui, Tokinaga Namba, Kengo Kihara, Junichi Hirata, Shohei Matsuo, Kazuma Ito

Recently, remarkable advances have been made in statistical analyses based on deep-learning techniques. Applied studies of deep learning have been reported in various industrial fields, including the iron and steel-making industries. The production of iron and steel requires a variety of processes, such as the processing of ingredients, iron-making, casting, and rolling. Consequently, the data acquired from them are diverse, and various tasks exist that can be assisted by deep-learning algorithms. Hence, providing a summary of the application is helpful for researchers specializing in information science to grasp the current trend of applied studies on deep learning techniques and for researchers specializing in each field of the iron and steel-making industry to understand what types of deep learning techniques are being utilized in other specialized fields. Therefore, in this study, we summarize the current studies on the application of deep learning in the iron- and steel-making fields by organizing them into several categories of processes and analytical methodologies. Furthermore, based on the results, we discuss future perspectives on the development of deep-learning techniques in this field.

最近,基于深度学习技术的统计分析取得了显著进展。深度学习在各个工业领域的应用研究都有报道,其中包括钢铁行业。钢铁生产需要多种工序,如原料加工、炼铁、铸造和轧制。因此,从中获取的数据多种多样,深度学习算法可以帮助完成各种任务。因此,对应用情况进行总结有助于信息科学专业的研究人员掌握当前深度学习技术应用研究的趋势,也有助于钢铁行业各领域的专业研究人员了解其他专业领域正在使用哪些类型的深度学习技术。因此,在本研究中,我们将深度学习在炼铁和炼钢领域的应用研究归纳为几类流程和分析方法。此外,基于研究结果,我们还讨论了深度学习技术在该领域的未来发展前景。
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引用次数: 0
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