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Electron beam additive manufacturing of composite alloy from stainless steel and aluminum bronze: Microstructure and mechanical properties 电子束增材制造不锈钢与铝青铜复合合金:显微组织与力学性能
Pub Date : 2023-06-06 DOI: 10.17073/0368-0797-2023-2-197-205
A. Zykova, A. Panfilov, A. Chumaevskii, A. Vorontsov, S. Tarasov
The authors investigated the microstructure, phase composition and mechanical properties of the steel-bronze composite obtained by electron beam additive manufacturing with simultaneous supply of aluminum bronze wires BrAMc9-2 and stainless steel 06Kh18N9T. X-ray diffraction analysis revealed that the composite contains 25 % (vol.) of aluminum bronze, which leads to the formation of a three-phase structure consisting of γ-Fe, α-Fe and α-Cu grains. According to scanning electron microscopy, the volume fraction of austenite, ferrite and bronze in the steel – 25 % bronze composite is 40.7, 35.7 and 23.6 %, respectively. Unstable conditions of the electron beam additive manufacturing process lead to the release of dispersed particles in austenite and ferrite grains. Dispersion-hardened copper particles with an average particle size of 40 nm, the volume fraction of which is 47 %, are isolated in austenite grains. Dispersion-hardened NiAl particles with a volume fraction of 20 % are isolated in ferrite grains, the average size of which is 44 nm. Transmission electron microscopy data indicate the coherent conjugation of arrays of dispersion-hardened particles with the matrix. Such a composite structure provides an increase in yield strength and tensile strength by an average of 400 and 600 MPa compared with yield strength and tensile strength of 06Kh18N9T steel obtained by electron beam additive manufacturing without bronze addition. Microhardness of the composite is on average 2.2 GPa, which is 0.4 GPa higher than that of 06Kh18N9T steel obtained by electron beam additive manufacturing without bronze addition.
研究了同时供应铝青铜丝BrAMc9-2和不锈钢06Kh18N9T的电子束增材制造制备的钢-青铜复合材料的显微组织、相组成和力学性能。x射线衍射分析表明,复合材料中含有25 % (vol.)的铝青铜,形成了由γ-Fe、α-Fe和α-Cu晶粒组成的三相结构。通过扫描电镜观察,在钢- 25 %青铜复合材料中,奥氏体、铁素体和青铜的体积分数分别为40.7%、35.7%和23.6% %。电子束增材制造工艺的不稳定条件导致奥氏体和铁素体晶粒中分散颗粒的释放。在奥氏体晶粒中分离出平均粒径为40 nm、体积分数为47 %的分散硬化铜颗粒。分散硬化的NiAl颗粒分布在铁素体晶粒中,体积分数为20 %,平均尺寸为44 nm。透射电镜数据表明弥散硬化颗粒阵列与基体存在相干共轭。与不添加青铜的电子束增材制造的06Kh18N9T钢的屈服强度和抗拉强度相比,这种复合结构的屈服强度和抗拉强度平均提高了400和600 MPa。复合材料的显微硬度平均为2.2 GPa,比未添加青铜的电子束增材制造得到的06Kh18N9T钢的显微硬度提高了0.4 GPa。
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引用次数: 0
Prospects and directions of digital transformation in foundry 铸造行业数字化转型的展望与方向
Pub Date : 2023-06-06 DOI: 10.17073/0368-0797-2023-2-140-147
S. Knyazev, A. Kutsenko, A. A. Usol’tsev, N. Kozyrev, A. A. Kutsenko
The time of information technology determines its priorities, which are a prerequisite for building a competitive production and economy. The ubiquitous spread of digitalization is one of the basic principles of new economy, a new type of socio–economic structure that is gradually being formed in the modern world through the introduction of scientific and technological progress and innovative methods of management, intellectualization and capitalization of human knowledge, the use of advanced new information and material technologies, accelerated development of knowledge-intensive sectors of the economy, the formation of creative, efficient, rational information and material production. Currently, at large foundries with mass and large-scale production of castings, the task of automating the control of technological processes using digital control systems was solved in general. They implement algorithms for controlling technological processes of casting in closed circuits (locally). The systems under consideration allow to implement optimal control strategies and automatically perform sequences of operations (start and stop of equipment; calculation and input of metal charge; calculation of formulations, dosing and mixing of molding and core mixtures) of multi-stage periodic casting processes. Digital transformation can significantly change the established practice of foundry production (from direct control and management of technological processes to business planning and document management). The transformation will have an impact on all parameters of the enterprise: economic efficiency of production (productivity, operating costs); reliability (operational readiness); safety (number of incidents); compliance with legislative norms on ecology. The technological criterion for success of the digital transformation of foundry production will be the release of a nomenclature of castings with a minimum level of defect, commercial – the release of a nomenclature of castings in demand on the market (machine parts and mechanisms), with a minimum self-cost, which is determined by the technological level of preparation of the production and its implementation and, as a consequence, low costs and optimal quality of molds, metal and castings.
信息技术的时代决定了其优先事项,这是建立有竞争力的生产和经济的先决条件。数字化无处不在是新经济的基本原则之一。新经济是一种新型的社会经济结构,通过引入科技进步和创新的管理方法,人类知识的智能化和资本化,先进的新信息和物质技术的使用,知识密集型经济部门的加速发展,形成创造性、高效率、理性的信息和物质生产。目前,在大量、大规模生产铸件的大型铸造厂,采用数字控制系统实现工艺过程自动化控制的任务已普遍得到解决。他们实现了在闭环(局部)中控制铸造工艺过程的算法。所考虑的系统允许实施最优控制策略并自动执行操作序列(设备的启动和停止;金属电荷的计算与输入;多阶段周期铸造工艺的配方、加药和模芯混合物的混合计算。数字化转型可以显著改变铸造生产的既定实践(从直接控制和管理技术流程到业务计划和文档管理)。转型将对企业的所有参数产生影响:生产的经济效率(生产率、运营成本);可靠性(操作就绪);安全(事故次数);遵守生态立法规范。铸造生产数字化转型成功的技术标准将是发布具有最低缺陷水平的铸件命名法,商业-发布市场需求的铸件命名法(机器零件和机构),具有最低的自我成本,这取决于生产准备及其实施的技术水平,因此,模具,金属和铸件的低成本和最佳质量。
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引用次数: 0
Development of shear deformation in lath martensite of medium alloy steels under tension 中合金钢板条马氏体受拉剪切变形的发展
Pub Date : 2023-06-06 DOI: 10.17073/0368-0797-2023-2-154-161
L. Teplyakova, A. Kashin, T. Kunitsyna
Evolution of shear deformation in steel with the structure of tempered martensite was studied under active tension. Purpose of the work was to identify the patterns of deformation development at the scale-structural levels: package, plate, fragment of a package and a lath. The authors investigated the deformation relief formed at different stages of plastic deformation by optical, transmission and scanning electron microscopy. Quantitative characteristics of the deformation relief were measured: shear strength (P), distance (X) between the shear traces and their length. Statistical processing was carried out, the average values and relationship with the degree of plastic deformation were determined. It was established that development of shear deformation in the lath component of martensite occurs with the formation of two subsystems of shear traces: thin and coarse. Subsystems of thin traces are formed from the very beginning of plastic deformation. Appearance and evolution of the subsystem of coarse traces correlates with formation of the first (long) neck in the sample, and it is the main mechanism leading to the localization of plastic deformation on the sample scale. The places of localization of rough shift are the border areas of the laths and fragments of the package. Connection between localization of subsystems of coarse shear traces and formation of a fragmented dislocation structure were revealed. The values of the average shear power in thin and coarse traces do not depend on the degree of local plastic deformation of the sample in the entire range of deformation degrees and remain constant until destruction ( = 0.1 μm and = 0.3 μm).
研究了回火马氏体组织钢在主动拉伸作用下的剪切变形演化规律。这项工作的目的是确定变形发展的模式在规模-结构水平:包,板,包的碎片和板条。采用光学显微镜、透射电镜和扫描电镜对不同塑性变形阶段形成的变形起伏进行了研究。测量了变形浮雕的定量特征:剪切强度(P),剪切痕迹之间的距离(X)及其长度。进行统计处理,确定其平均值及其与塑性变形程度的关系。结果表明,马氏体板条成分剪切变形的发展伴随着薄剪切和粗剪切两个子剪切痕迹的形成。细迹子系统从塑性变形开始就形成了。粗迹子系统的出现和演化与试样中第一颈(长颈)的形成有关,是导致试样尺度上塑性变形局部化的主要机制。粗移定位的位置是板条和零件的边缘区域。揭示了粗剪切痕迹的局部化与破碎位错结构的形成之间的联系。在整个变形程度范围内,细迹和粗迹的平均剪切功率值不依赖于试样的局部塑性变形程度,在破坏前(= 0.1 μm和= 0.3 μm)保持不变。
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引用次数: 0
Features of formation of austenite grains in 12 % Cr heat-resistant ferritic-martensitic steels 12% Cr耐热铁素体-马氏体钢中奥氏体晶粒的形成特征
Pub Date : 2023-06-06 DOI: 10.17073/0368-0797-2023-2-168-176
M. Belomyttsev
Ferritic-martensitic heat-resistant high-chromium steels (FMHS) with chromium content of 11 – 12 % are quenched to martensite from temperatures of 1050 – 1100 °С. Possible undesirable consequences of heating to such high temperatures are an increase in the size of austenite grains, increase in the amount of delta ferrite in the final structure, and a decrease in mechanical characteristics. In this work, the change of all these factors during heating of FHMS to quenching temperatures in the range of 950 – 1250 °С was studied. Ratios of the contents of martensite (its amount was identified with the proportion of austenite before quenching) and high-temperature delta ferrite on metallographic sections were analyzed. It was found that behavior of structure of the studied FHMS upon heating to temperatures of 1150 °С and above depends on the steels structural class. In steels whose structure at room temperature consists of martensite and delta ferrite, or in which delta ferrite begins to form at heating temperatures of 1200 °С and higher, size of austenite grain decreases with increasing temperature in the range of 1200 – 1250 °С, and the amount of delta ferrite – increases. Such structural transformations can be associated with features of the phase equilibrium diagrams of steels of this class. Such structural transformations can be associated with a change in the position and (or) inclination of boundaries of the high-temperature region of coexistence of austenite and delta-ferrite in the phase equilibrium diagrams of FHMS at a change in heating temperature in this range. Compression tests at 20 °С of 15Cr12Mn3SiMoW2VB steel samples after heat treatment with heating to temperatures for hardening 1000 – 1250 °С showed that formation of an additional amount of delta ferrite at temperatures above 1200 °С is a stronger factor than the refinement of austenite grains. This causes a decrease in yield strength of the samples quenched from these temperatures followed by high tempering.
铬含量为11 - 12 %的铁素体-马氏体耐热高铬钢(FMHS)在1050 - 1100 °С处淬火为马氏体。加热到如此高的温度可能产生的不良后果是奥氏体晶粒尺寸增大,最终组织中δ铁素体数量增加,机械特性降低。本文研究了FHMS加热至950 ~ 1250 °С范围内淬火温度的变化情况。分析了金相切片上马氏体(其含量以淬火前奥氏体的比例确定)与高温δ铁素体含量的比值。研究发现,在加热到1150 °С及以上温度时,所研究的FHMS的结构行为取决于钢的结构等级。在室温下由马氏体和δ铁素体组成的钢,或在1200 °С及更高温度下开始形成δ铁素体的钢,在1200 - 1250 °С范围内,随着温度的升高,奥氏体晶粒尺寸减小,δ铁素体-的数量增加。这种结构转变可以与这类钢的相平衡图的特征相联系。这种结构转变可能与FHMS相平衡图中奥氏体和δ -铁素体共存高温区域边界的位置和(或)倾角在该范围内加热温度变化有关。15Cr12Mn3SiMoW2VB钢试样在加热到1000 - 1250 °С的硬化温度后,在20 °С的压缩试验表明,在1200 °С以上的温度下,形成额外数量的δ铁素体比奥氏体晶粒细化的影响更大。这导致从这些温度淬火后再进行高回火的样品屈服强度下降。
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引用次数: 0
Occurrence of characteristic defects of grinding balls from rejects of continuously cast billets of rail steel 钢轨钢连铸坯废渣磨球特征缺陷的发生
Pub Date : 2023-06-06 DOI: 10.17073/0368-0797-2023-2-222-228
A. Umanskii, I. S. Morozov, E. Protopopov, A. Simachev, L. Dumova
On the basis of metallographic studies, the authors determined the characteristic defects of grinding balls rolled from the rejects of continuously cast billets of K76F rail steel. Relationship of the presence of internal defects of the balls with their impact resistance was established. Defects in the form of internal cracks with accumulations of non-metallic inclusions in the area of their localization and flocks have the greatest impact on the reduction of balls impact resistance. Such defects are the cause of balls destruction during impact resistance tests in 62 and 17 % of cases, respectively. The effect of internal cracks without significant accumulations of non-metallic inclusions and quenching microcracks located along the boundaries of the phase interface was estimated at 12 and 9 %. The regularities and mechanism of influence of the rejects chemical composition of K76F rail steel billets on the probability of destruction of the balls produced from them during impact resistance tests were established. An increase in sulfur content in the billets of the studied rail steel reduces impact resistance of the balls produced from them, as it contributes to formation of non-plastic sulfides that concentrate in the area of internal cracks. An increase in hydrogen content in rail steel naturally contributes to an increase in probability of formation of the flocks, which significantly reduce the balls stability to shock loads. An increase in carbon content in the initial billets affects the increase in probability of destruction of K76F steel balls during copra tests. It is explained by formation of cementite-type carbides when carbon content corresponding to the eutectoid steel is reached. In general, the relative degree of influence of the K76F rail steel chemical composition on impact resistance of grinding balls is 48 %.
在金相研究的基础上,确定了由K76F钢轨钢连铸坯废渣轧制出的磨球缺陷的特征。建立了钢球内部缺陷的存在与钢球抗冲击性能的关系。以内部裂纹形式存在的缺陷在其局部区域和团块中有非金属夹杂物的堆积,对球的抗冲击性降低影响最大。这些缺陷是导致钢球在抗冲击试验中损坏的原因,分别占62%和17%。无显著非金属夹杂物堆积的内部裂纹和沿相界面边界的淬火微裂纹的影响分别为12%和9%。建立了K76F钢坯抗冲击试验中废渣化学成分对钢球破坏概率的影响规律和机理。所研究的钢坯中硫含量的增加降低了钢球的抗冲击性,因为它有助于形成集中在内部裂纹区域的非塑性硫化物。钢轨钢中氢含量的增加自然会增加球团形成的可能性,这大大降低了钢球在冲击载荷下的稳定性。初始钢坯中含碳量的增加会影响在干燥试验中K76F钢球破坏概率的增加。当碳含量达到与共析钢相对应的水平时,形成了渗碳体型碳化物。一般情况下,K76F钢轨钢化学成分对磨球抗冲击性的相对影响程度为48%。
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引用次数: 0
Influence of laser spot size on structure and properties of high-temperature CompoNIAL-M5-3 alloy produced by selective laser melting 激光光斑尺寸对选择性激光熔化高温component - m5 -3合金组织和性能的影响
Pub Date : 2023-06-06 DOI: 10.17073/0368-0797-2023-2-184-190
Y. Kaplanskii, M. I. Ageev, M. Bychkova, A. Fadeev, E. Levashov
The CompoNiAl-M5-3 high-temperature alloy based on nickel monoaluminide was obtained by selective laser melting (SLM) of a spheroidized powder with particle size in the range of 20 – 45 μm. The powder was manufactured using an integral technology including self-propagating high-temperature synthesis (SHS), briquette grinding, sieve and air classification followed with spheroidization of powder particles in a thermal plasma flow and ultrasonic purification of spheroidized particles from nanofraction. Using parametric studies, the SLM modes were tested on SLM 280H and TruPrint 1000 machines. Mechanical tests of the samples were carried out using the uniaxial compression scheme with the strain rate dε/dt = 10–4 s–1 in the temperature range 1023 – 1273 K. Scanning and transmission electron microscopy methods were used to study the influence of laser spot size on the evolution of microstructure and thermomechanical properties of the SLM-consolidated material in comparison with that obtained by hot isostatic pressing (HIP). The authors established the effect of HIP + HT (aging in vacuum) post-treatment on the structure and mechanical properties of the material. The yield strength at 1073 K of the alloy built on the additive machine with a laser spot diameter of 38 μm after SLM + HIP + HT was 500 MPa, which exceeded the yield strength of the HIP-samples by 220 MPa.
采用选择性激光熔化法制备了粒度为20 ~ 45 μm的球化粉末,制备了以单铝化镍为基体的componal - m5 -3高温合金。该粉体采用自传播高温合成(SHS)、型煤研磨、筛分、空气分级、热等离子体流对粉体颗粒进行球化、纳米分馏中球化颗粒的超声纯化等综合技术制备。通过参数研究,在SLM 280H和TruPrint 1000机器上对SLM模式进行了测试。在1023 ~ 1273 K温度范围内,采用应变率ε/dt = 10-4 s-1的单轴压缩方案对试样进行力学试验。采用扫描电镜和透射电镜方法研究了激光光斑尺寸对slm固结材料微观结构和热力学性能演变的影响,并与热等静压(HIP)方法进行了比较。建立了HIP + 真空时效后处理对材料组织和力学性能的影响。在激光光斑直径为38 μm的增材加工机上制备的合金在1073 K处的屈服强度为500 MPa,比激光光斑直径为 + HIP + HT的合金屈服强度高出220 MPa。
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引用次数: 0
Errors of non-contact temperature measurement 非接触式测温误差
Pub Date : 2023-06-06 DOI: 10.17073/0368-0797-2023-2-229-235
A. A. Kim, M. I. Podglazova, K. Shatokhin
In recent years, there is a trend of improving the performance and efficiency of all existing measuring instruments due to a leap in technology. Almost every industry uses a variety of technologies that apply temperature control. Temperature of a heated body can be estimated by measuring the parameters of its thermal radiation, which are electromagnetic waves of different lengths. Temperature measurement is necessary for comfortable automatic control and management of production processes. The use of non-contact means makes it possible to measure the temperature of, firstly, moving objects, secondly, objects in inaccessible places, thirdly, to avoid damage to the measuring instruments when controlling large temperatures. High speed, the possibility of measuring temperature without disconnecting the object from the technological process, ensuring personnel safety, temperature measurement up to 3000 °C – these are the advantages of non-contact temperature measurement method. To obtain reliable values when measuring thermophysical quantities it is necessary to know the processes occurring in interaction of the measuring device or sensor with the object of measurement. These processes affect the magnitude of the measurement error, that is, magnitude of the result deviation from the true value of the measured parameter. This paper describes the errors of non-contact temperature measurement of pyrometers, namely total radiation pyrometer, partial radiation pyrometer, spectral ratio pyrometer, as well as shows the results of comparative calculations between them. Expressions for the evaluation of methodical errors of total radiation, partial radiation and spectral ratio pyrometers are given, as well as the results of comparative calculations of errors are shown.
近年来,由于技术的飞跃,现有的所有测量仪器都有提高性能和效率的趋势。几乎每个行业都使用各种各样的温度控制技术。一个受热物体的温度可以通过测量其热辐射的参数来估计,热辐射是不同长度的电磁波。温度测量是生产过程自动化控制和管理的必要条件。采用非接触式测量手段,首先可以测量移动物体的温度,其次可以测量难以接近的地方的物体的温度,第三可以避免在控制大温度时损坏测量仪器。速度快,可以在不断开对象与工艺过程的情况下测量温度,确保人员安全,温度测量可达3000°C -这些都是非接触式温度测量方法的优点。为了在测量热物理量时获得可靠的值,有必要了解测量装置或传感器与测量对象相互作用的过程。这些过程影响测量误差的大小,即结果偏离被测参数真实值的大小。本文介绍了全辐射高温计、部分辐射高温计、光谱比高温计非接触式测温的误差,并给出了它们之间的比较计算结果。给出了总辐射、部分辐射和光谱比高温计方法误差的计算公式,并给出了误差的比较计算结果。
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引用次数: 0
Institutionalization of ESG-principles at the international level and in the Russian Federation, their impact on ferrous metallurgy enterprises. Part 1 在国际一级和俄罗斯联邦将环境监测组原则制度化及其对黑色冶金企业的影响。第1部分
Pub Date : 2023-06-06 DOI: 10.17073/0368-0797-2023-2-253-264
O. Glushakova, O. Chernikova
The idea of ESG (Environmental – Social – Governance) is based on the concept of sustainable development and represents a fundamentally new approach to making business, characterized by the involvement of companies in solving environmental, social and management problems. Despite the fact that at the international level, the formation of an institutional framework in the field of ESG was initiated 74 years ago, in our country this process was launched only in 1996 with the adoption of the Concept for the Transition of the Russian Federation to Sustainable Development. Ratification by Russia of a number of international documents – the UN Framework Convention on Climate Change (1992), the Kyoto Protocol (1997), the Paris Agreement on Climate (2015) and the active promotion climate policy by most countries of the world aimed at preserving ozone in the atmosphere layer, necessitated the institutionalization of ESG principles at the national level. The activation of this process took place in 2020 and by mid-2021, the national framework in the field of ESG was created. Ferrous metallurgy is one of the basic sectors of the national economy. The discrepancy of ferrous metallurgy enterprises with the ESG criteria, as well as the high carbon and energy intensity of the products of this industry, in the future may cause the loss of sales markets and disruption of sustainable development. The stages of institutionalization of ESG principles at the international level and in the Russian Federation are considered. The necessity of reducing the carbon intensity and energy intensity of ferrous metallurgy products is substantiated in connection with the emerging global trend – the transition of most countries of the world to a low-carbon economy due to the gradual abandonment of coal energy and the gradual cessation of «inefficient» subsidizing of fossil fuels.
ESG(环境-社会-治理)的理念基于可持续发展的概念,代表了一种全新的经营方式,其特点是公司参与解决环境、社会和管理问题。尽管在国际一级,在ESG领域形成体制框架是在74年前开始的,但在我国,这一进程直到1996年才开始,当时通过了《俄罗斯联邦向可持续发展过渡的概念》。俄罗斯批准了一系列国际文件——《联合国气候变化框架公约》(1992年)、《京都议定书》(1997年)、《巴黎气候协定》(2015年),世界上大多数国家积极推动气候政策,旨在保护大气层中的臭氧,这使得ESG原则在国家层面制度化成为必要。这一进程于2020年启动,到2021年中期,创建了ESG领域的国家框架。黑色冶金是国民经济的基础部门之一。黑色冶金企业与ESG标准的不一致,以及该行业产品的高碳和高能耗,在未来可能会造成销售市场的流失和可持续发展的中断。审议了在国际一级和在俄罗斯联邦将ESG原则制度化的各个阶段。降低铁冶金产品的碳强度和能源强度的必要性与正在出现的全球趋势有关-由于逐渐放弃煤炭能源和逐渐停止对化石燃料的“低效”补贴,世界上大多数国家向低碳经济过渡。
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引用次数: 0
Deoxidation capacity of aluminum in ferromanganese carbon-containing melts 含锰铁碳熔体中铝的脱氧能力
Pub Date : 2023-06-06 DOI: 10.17073/0368-0797-2023-2-206-214
L. Makrovets, O. Samoilova, G. G. Mikhailov
Deoxidation (reduction of oxygen concentration dissolved in liquid metal) is an integral part of steel production technology. For obtaining deeply deoxidized metal, mainly aluminum is used at metallurgical enterprises. It should be taken into account that alloying elements of steels and alloys under certain conditions can act as deoxidizing elements, contributing to the complex nature of the deoxidation process. Almost all steels contain manganese in one concentration or another. The study of interaction processes in the Fe – Mn – Al – O – C system at steelmaking temperatures is of applied importance. In this paper, a thermodynamic analysis of the deoxidation ability of aluminum in oxygen-containing iron-manganese melts was carried out. At the same time, influence of carbon on course of the deoxidation process was taken into account. In the study, it is effective to use a technique for constructing the solubility surface of components in metal (SSCM) – a diagram that connects the compositions of liquid metal with the compositions of conjugated non-metallic phases. In the course of this work, oxygen solubility isotherms in the Fe – Mn – O system were calculated for the temperature range of 1550 – 1650 °C. For the Fe – Mn – Al – O – C (1600 °C) system, composite sections of the SSCM were constructed at fixed carbon concentrations in steel [C] = 0; 0.1; 0.4; 0.8 and 1.2 % (hereafter by weight). It is shown that with the simultaneous presence of manganese and aluminum in an oxygen–containing iron-based melt (at industrially significant concentrations [Al] = 0.001 – 0.010 % and [Mn] – less than 1.0 %), aluminum in the liquid metal will act as a deoxidizing agent, and corundum inclusions will be formed as interaction products. Complex deoxidation by aluminum and manganese with the formation of spinel is typical only for manganese-alloyed steels, where the concentration of manganese is more than 1.5 %.
脱氧(降低溶解在液态金属中的氧浓度)是钢铁生产技术的重要组成部分。为了获得深度脱氧金属,冶金企业主要采用铝。应该考虑到,钢和合金的合金元素在一定条件下可以作为脱氧元素,有助于脱氧过程的复杂性。几乎所有的钢都含有不同浓度的锰。研究炼钢温度下Fe - Mn - Al - O - C体系的相互作用过程具有重要的应用价值。本文对含氧铁锰熔体中铝的脱氧能力进行了热力学分析。同时考虑了碳对脱氧过程的影响。在本研究中,采用了一种构造金属中组分溶解度面(SSCM)的技术——将液态金属的组成与共轭非金属相的组成联系起来的图。在此工作过程中,计算了Fe - Mn - O体系在1550 - 1650 °C温度范围内的氧溶解度等温线。对于Fe - Mn - Al - O - C(1600 °C)体系,在固定碳浓度的钢中构建了SSCM的复合截面[C] = 0;0.1;0.4;0.8和1.2 %(以下按重量计)。结果表明,在含氧铁基熔体中同时存在锰和铝(工业显著浓度[Al] = 0.001 - 0.010 %,[Mn] -小于1.0 %)时,液态金属中的铝将作为脱氧剂,并形成刚玉包裹体作为相互作用产物。铝和锰的复合脱氧与尖晶石的形成是典型的锰合金钢,其中锰的浓度超过1.5%。
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引用次数: 0
Information-modeling system for prediction of the composition and properties of final slag in a blast furnace in real time 实时预测高炉终渣组成和性能的信息建模系统
Pub Date : 2023-06-06 DOI: 10.17073/0368-0797-2023-2-244-252
A. Pavlov, N. Spirin, I. Gurin, V. Lavrov, V. A. Beginyuk, A. Istomin
The article considers general characteristics of the algorithm for prediction of the composition of the final slag in a blast furnace in real time. This algorithm is based on fundamental knowledge on the processes occurring in the furnace and general laws of transient processes. It allows predicting at the current moment of time and for every hour ten hours ahead. A linearized model of the blast furnace process and a natural-mathematical approach are used. The model takes into account the dynamic characteristics of blast furnaces in various impact channels, which change and depend on the type of impact, operating parameters of the furnaces and properties of the melted raw material. This makes it possible to adjust the model to operating conditions of the object, to take into account changes in the composition and properties of iron ore and coke, blast and regime parameters of blast furnace smelting when modeling. The software of the information-modeling system for prediction of the composition and properties of the final slag in a blast furnace in real time was developed in the C# programming language based on the ASP.NET MVC framework using the .NET 5 cross-platform. The web application includes the following main functions: visualization of change APCS parameters and design parameters over time; slag mode diagnostics; modeling of transient processes of composition and properties of slag; prediction of slag composition and properties in real time and prediction history. The software architecture is described and its operation is illustrated. An assessment of the accuracy and reliability of the simulation results based on statistical indicators was carried out. The root-mean-square deviation of the predicted basicity of the CaO/SiO2 slag from that measured at taps is 0.023, the prediction reliability is 92 %, which indicates a satisfactory agreement between the predicted and actual values of the content of individual components in the slag. The information modeling system developed on the basis of the presented algorithm is integrated into the information system of the blast furnace shop of PJSC Magnitogorsk Iron and Steel Works.
本文考虑了实时预测高炉终渣成分算法的一般特点。该算法基于炉内过程的基本知识和瞬态过程的一般规律。它可以预测当前时刻和未来十小时的每小时。采用了高炉过程的线性化模型和自然数学方法。该模型考虑了不同冲击通道中高炉的动态特性,这些特性随冲击类型、高炉运行参数和熔体原料性质的变化而变化。这使得模型可以根据对象的操作条件进行调整,在建模时考虑到铁矿石和焦炭的成分和性质、高炉冶炼的高炉和状态参数的变化。基于ASP,采用c#编程语言开发了高炉终渣成分及性能实时预测信息建模系统软件。.NET MVC框架使用。NET 5跨平台。web应用程序包括以下主要功能:APCS参数和设计参数随时间变化的可视化;渣模诊断;炉渣成分与性能的瞬态过程建模实时预测炉渣成分和性能,预测历史。介绍了该系统的软件体系结构,并对其操作进行了说明。基于统计指标对仿真结果的准确性和可靠性进行了评估。预测结果表明,CaO/SiO2矿渣碱度与实测碱度的均方根偏差为0.023,预测可靠性为92%,矿渣中各组分含量的预测值与实测值吻合较好。在此基础上开发的信息建模系统已集成到PJSC马格尼托戈斯克钢铁厂高炉车间信息系统中。
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Izvestiya. Ferrous Metallurgy
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