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Earth as Organic Chemist 地球是有机化学家
Pub Date : 2019-10-01 DOI: 10.1017/9781108677950.014
E. Shock, C. Bockisch, C. Estrada, K. Fecteau, I. Gould, H. Hartnett, Kristin Johnson, K. Robinson, Jessie Shipp, L. Williams
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引用次数: 7
Carbon-Bearing Phases throughout Earth’s Interior 地球内部的含碳阶段
Pub Date : 2019-10-01 DOI: 10.1017/9781108677950.004
V. Stagno, V. Cerantola, S. Aulbach, S. Lobanov, C. McCammon, M. Merlini
Carbon (C) occurs in the mantle in its elemental state in the form of graphite and diamond, but also as oxidized compounds that include carbonate minerals and carbonated magmas, as reduced components such as methane and carbide, and as gaseous phases in the C–O–H chemical system. The occurrence of C-bearing phases characterized by different oxidation states reflects magmatic processes occurring in Earth’s interior that link to its oxygenation through space and time. Improving our understanding of the physical and chemical behavior of carbon at extreme conditions sheds light on the type and depth of possible reactions taking place in the interior of Earth and other planets over time and allows the identification of deep carbon reservoirs and mechanisms that move carbon among different reservoirs from the surface to the atmosphere, thereby affecting the total terrestrial budget of carbon ingassing and outgassing. Carbon occurs in diverse forms depending on surrounding conditions such as pressure, temperature, oxygen fugacity (fO2), and the availability of chemical elements that are particularly reactive with carbon to form minerals and fluids. Despite the low abundance of carbon within Earth, the stability of C-rich phases in equilibrium with surrounding minerals provides an important geochemical tracer of redox evolution in Earth and other planets, as well as an important economic resource in the form of diamonds. Knowledge of carbon cycling through the mantle requires an understanding of the stable forms of carbon-bearing phases and their abundance at pressures, temperatures, and fO2 values that are representative of Earth’s interior. Such information is necessary to identify potential carbon reservoirs and the petrogenetic processes by which carbon may be (re) cycled through the mantle over time, eventually being brought to the surface by magmas and to the atmosphere as dissolved gaseous species. Accurate estimates of carbon abundance in Earth’s interior are challenging for many reasons, such as the unknown primordial budget of carbon, the low solubility of carbon in the dominant silicate minerals of the upper and lower mantle, the low modal abundance of accessory carbon-bearing minerals and graphite/diamond in mantle xenoliths, and because magmas occurring at shallow depths are the product of igneous differentiation, magma chamber processes, and degassing. Experimental studies conducted at high
碳(C)以石墨和金刚石的单质形式存在于地幔中,但也以氧化化合物的形式存在,包括碳酸盐矿物和碳酸化岩浆,以还原组分的形式存在,如甲烷和碳化物,以及以C - o - h化学体系中的气相存在。以不同氧化态为特征的含c相的出现反映了地球内部发生的岩浆过程,这些岩浆过程通过空间和时间与地球的氧化作用联系在一起。提高我们对极端条件下碳的物理和化学行为的理解,揭示了地球和其他行星内部随着时间的推移可能发生的反应的类型和深度,并使我们能够确定深层碳储层和碳在不同储层之间从地表转移到大气的机制,从而影响地球碳吸入和释放的总预算。碳以不同的形式存在,这取决于周围的条件,如压力、温度、氧逸度(fO2),以及与碳反应形成矿物和流体的化学元素的可用性。尽管地球内部的碳丰度很低,但富c相与周围矿物平衡的稳定性为地球和其他行星的氧化还原演化提供了重要的地球化学示踪剂,也是钻石形式的重要经济资源。要了解地幔中的碳循环,就必须了解含碳相的稳定形式,以及它们在压力、温度和fO2值下的丰度,这些都是地球内部的代表。这些信息对于确定潜在的碳储集层和岩石形成过程是必要的,通过这些过程,碳可能随着时间的推移在地幔中(再)循环,最终被岩浆带到地表,并以溶解的气态物种的形式进入大气。由于许多原因,对地球内部碳丰度的准确估计具有挑战性,例如未知的原始碳预算,碳在上下地幔主要硅酸盐矿物中的溶解度低,地幔包体中辅助含碳矿物和石墨/金刚石的低模态丰度,以及发生在浅层深处的岩浆是火成岩分异、岩浆房过程和脱气的产物。实验研究在高
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引用次数: 6
A Framework for Understanding Whole-Earth Carbon Cycling 理解全地球碳循环的框架
Pub Date : 2019-10-01 DOI: 10.1017/9781108677950.011
Cin-Ty A. Lee, Hehe Jiang, R. Dasgupta, M. Torres
increasing the sensitivity of the global weathering feedback (states a to b), which buffers the rise of pCO 2 . After magmatism ends, physical and chemical weathering persist, driving pCO 2 to low levels. Magmatic orogens can potentially drive greenhouses, but are followed by global cooling due to protracted weathering.
增加了全球风化反馈(状态a到b)的敏感性,从而缓冲了pco2的上升。岩浆活动结束后,物理和化学风化作用持续存在,使pco2降至较低水平。岩浆造山带可以潜在地驱动温室,但由于长期的风化作用,随之而来的是全球变冷。
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引用次数: 38
CO2-Rich Melts in Earth 地球上富含二氧化碳的融化物
Pub Date : 2019-10-01 DOI: 10.1017/9781108677950.006
G. Yaxley, S. Ghosh, E. Kiseeva, A. Mallik, C. Spandler, A. Thomson, M. Walter
deep Earth, from lower mantle to crust. We fi rst outline constraints from high-pressure experimental petrology and thermodynamic considerations on their stability, as functions of variables such as pressure (P), temperature (T), and oxygen fugacity ( f O 2 These constraints are then used in the context of different tectonic settings in Earth to infer the presence and nature of carbonate melts in those various locations. vapor at pressures lower than 2 GPa At the redox front, reduced carbon present in the eclogite or peridotite oxidizes to form trace to minor amounts of carbonatitic melt (labeled (1)). carbonatitic melt causes fl uxed partial melting of eclogite and peridotite because the carbonated of peridotite and eclogite are at much lower of of produces of with surrounding subsolidus volatile-free peridotite, and a similar melt-rock reaction as proposed (i) takes place.
地球深处,从下地幔到地壳我们首先概述了高压实验岩石学和热力学对其稳定性的限制,作为压力(P)、温度(T)和氧逸度(fo2)等变量的函数,然后将这些限制用于地球不同构造背景下,以推断这些不同位置的碳酸盐熔体的存在和性质。在氧化还原前沿,榴辉岩或橄榄岩中的还原碳氧化形成微量的碳质熔体(标记为(1))。由于橄榄岩和榴辉岩的碳酸化程度与周围的亚固体无挥发物橄榄岩的生成量要低得多,因此碳酸盐岩熔体导致榴辉岩和橄榄岩的流动部分熔融,发生了与(1)相似的熔融-岩反应。
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引用次数: 18
Carbon in the Deep Biosphere 深层生物圈中的碳
Pub Date : 2019-10-01 DOI: 10.1017/9781108677950.016
S. Lang, M. Osburn, A. D. Steen
The form, fate, and biogeochemical cycling of carbon in subsurface environments impacts and reflects microbial activity and has important implications for global elemental fluxes. Photosynthetically derived organic matter (OM) is transported to a depth where it can continue to fuel life far from solar inputs. Alternative energy-yielding reactions such as the oxidation of minerals and reduced gases can fuel life in the rocky subsurface of both the ocean and continents, altering the distribution and characteristics of carbon compounds. Nonbiological reactions such as the precipitation of calcium carbonate influence the availability of dissolved inorganic carbon for lithoautotrophs and, simultaneously, the carbon cycle over geologic time. The abundances, characteristics, and distributions of carbon in the subsurface can therefore provide an integrated history of biotic and abiotic processes and a template for interpreting similar patterns from other planetary bodies. The goal of this chapter is to compile insights from disparate environments in order to build a mechanistic understanding of the controls on carbon abundance and distribution in the subsurface. The sections below summarize what is known from the oceanic and continental subsurface, realms that are often studied separately. We synthesize commonalities across these environments, highlight what remains unknown, and propose ideas for future directions. One challenge with working across the marine–continental divide is that the terminology used to describe organic carbon varies between the two. We will use the following terms and abbreviations: particulate organic carbon (POC), dissolved organic carbon (DOC), and dissolved inorganic carbon (DIC). Another discrepancy between communities is in the use of units, with ppm or mg/L dominating the continental literature and μM or mM in the marine literature. We will use molar units throughout for comparison’s sake. Finally, while the soil community has moved away from the terms “refractory” and “recalcitrant” OM, they are still common in the marine community. Here, these terms refer to OM that has escaped remineralization due to its inherent molecular structure, physical associations with minerals, energetically unfavorable conditions, or the lack of a specific microbial community adapted to carry out the necessary degradative processes.
地下环境中碳的形态、命运和生物地球化学循环影响并反映微生物活动,对全球元素通量具有重要意义。光合作用产生的有机物(OM)被输送到一个深度,在那里它可以继续为远离太阳能输入的生命提供燃料。矿物氧化和还原气体等产生能量的替代反应可以为海洋和大陆地下岩石中的生命提供燃料,从而改变碳化合物的分布和特征。非生物反应,如碳酸钙的沉淀,影响了岩石自养生物溶解无机碳的可用性,同时影响了地质时期的碳循环。因此,地下碳的丰度、特征和分布可以提供生物和非生物过程的综合历史,并为解释其他行星体的类似模式提供模板。本章的目标是汇编来自不同环境的见解,以便建立对地下碳丰度和分布控制的机制理解。下面几节总结了从海洋和大陆地下所知的情况,这两个领域通常是分开研究的。我们综合了这些环境的共性,强调了仍然未知的东西,并提出了未来发展方向的想法。跨越海洋-大陆分界线的一个挑战是,用于描述有机碳的术语在两者之间有所不同。我们将使用以下术语和缩写:颗粒有机碳(POC),溶解有机碳(DOC)和溶解无机碳(DIC)。群落之间的另一个差异是单位的使用,大陆文献中以ppm或mg/L为主,海洋文献中以μM或mM为主。为了便于比较,我们一直使用摩尔单位。最后,虽然土壤群落已经不再使用“难降解”和“难降解”这两个术语,但它们在海洋群落中仍然很常见。在这里,这些术语指的是由于其固有的分子结构、与矿物质的物理关联、能量不利的条件或缺乏适应进行必要降解过程的特定微生物群落而逃脱再矿化的OM。
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引用次数: 1
Carbon in the Convecting Mantle 对流地幔中的碳
Pub Date : 2019-10-01 DOI: 10.1017/9781108677950.009
E. Hauri, E. Cottrell, Katherine A. Kelley, J. Tucker, K. Shimizu, M. L. Voyer, J. Marske, A. Saal
melt inclusions. This provides independent evidence that the MORB source is not graphite saturated; however, these curves could be relevant when considering more reduced planetary bodies, such as Mars.
熔体包裹体。这提供了独立的证据,证明MORB源不是石墨饱和的;然而,这些曲线在考虑更小的行星体时可能是相关的,比如火星。
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引用次数: 17
Origin and Early Differentiation of Carbon and Associated Life-Essential Volatile Elements on Earth 地球上碳及相关生命必需挥发性元素的起源与早期分化
Pub Date : 2019-10-01 DOI: 10.1017/9781108677950.002
R. Dasgupta, D. Grewal
coef fi cients and solubilities of LEVEs in the silicate melts to examine the effect of core formation, with varying degrees of alloy – silicate equilibration, with or without loss of an early atmosphere formed via MO degassing on the remnant abundances of LEVEs in the bulk silicate reservoir. (a) LEVEs, when delivered as 0.015 M E late-accreting materials (i.e. 0% alloy – silicate equilibration), cause the volatile abundance to be higher than the present-day BSE. Core formation with increasing degrees of alloy – silicate equilibration increasingly the remnant MO in all LEVEs, with C being much more depleted than other LEVEs, leading to subchondritic C/N, C/H, and C/S ratios. (b) Combining early atmospheric loss with core formation cannot offset C loss to the core due to the lower solubility of C relative to the other LEVEs in the silicate MOs. Bulk Earth volatile abundance data are from McDonough, 83 while the alloy – silicate partition coef fi cients in a deep MO (P = 50 GPa, T = 3500 K; e.g. Siebert et al. 104 ) for C, N, S, and H are from the parametrized relationships of Chi et al., 71 Grewal et al., 105 Boujibar et al., 106 and Clesi et al., 107 respectively. Solubility constant data for C, N, S, and H in the silicate melt are from Armstrong et al., et O and
系数和硅酸盐熔体中LEVEs的溶解度,以考察具有不同程度合金-硅酸盐平衡的岩心形成,有无MO脱气形成的早期大气损失,对大块硅酸盐储层中LEVEs残留丰度的影响。(a)当以0.015 M E后期增积物质(即0%合金-硅酸盐平衡)输送时,水平导致挥发丰度高于当今的BSE。随着合金-硅酸盐平衡程度的增加,岩心形成中MO的残余含量逐渐增加,而C的耗尽程度远高于其他水平,导致了亚球粒C/N、C/H和C/S比值的增加。(b)将早期大气损失与岩心形成相结合不能抵消碳对岩心的损失,因为相对于硅酸盐钼中其他水平的碳溶解度较低。块状土挥发丰度数据来自McDonough, 83,而合金-硅酸盐在深层MO中的分配系数(P = 50 GPa, T = 3500 K;例如Siebert et al. 104), C、N、S和H分别来自Chi et al., 71 Grewal et al., 105 Boujibar et al., 106和Clesi et al., 107。C、N、S和H在硅酸盐熔体中的溶解度常数数据来自Armstrong等人,et O和
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引用次数: 23
Biogeography, Ecology, and Evolution of Deep Life 深层生命的生物地理学、生态学和进化
Pub Date : 2019-10-01 DOI: 10.1017/9781108677950.017
C. Magnabosco, J. Biddle, C. Cockell, S. Jungbluth, K. I. Twing
When we ponder the existence of life extending deep into Earth, a phrase from the movie Jurassic Park is often used: that “life finds a way.” Numerous investigations into the continental and marine subsurface have shown that life indeed finds a way to exist deep into the subsurface, provided that physical influences, particularly heat, allow for the existence of biomolecules. In this chapter, we will review what is known about the biogeography, ecology, and evolution of deep life, acknowledging along the way that this field is rapidly developing with every new set of experiments and continued exploration. The subsurface biosphere is loosely defined as the habitable region beneath the soil and sediments where the limits of habitability are typically defined by some physical process (also see Chapter 19, this volume). Current estimates of the habitable volume of the subsurface range from ~2.0 to 2.3 10 km, or roughly twice the volume of our oceans (Table 17.1). This large biosphere is estimated to hold ~70% of all bacterial and archaeal cells (Figures 17.1 and 17.2) and potentially over 80% all bacterial and archaeal species (for a review, see 1). A variety of habitats and sampling techniques to study the subsurface biosphere have been explored by scientists for nearly a century and are further described throughout this chapter (Sections 17.1.1–17.1.5; also see Figure 16.1 in Chapter 16, this volume).
当我们思考地球深处是否存在生命时,经常会用到电影《侏罗纪公园》中的一句话:“生命自有出路。”对大陆和海洋地下的大量调查表明,只要物理影响,特别是热影响,允许生物分子存在,生命确实能在地下深处找到生存的途径。在本章中,我们将回顾已知的生物地理学、生态学和深层生命的进化,并承认随着每一组新的实验和持续的探索,这一领域正在迅速发展。地下生物圈被粗略地定义为土壤和沉积物下面的可居住区域,在那里可居住的界限通常由一些物理过程确定(也见本卷第19章)。目前对地下可居住面积的估计范围为~2.0至2.3 10公里,大约是海洋面积的两倍(表17.1)。据估计,这个大的生物圈容纳了约70%的细菌和古细菌细胞(图17.1和17.2),可能超过80%的细菌和古细菌物种(回顾,见1)。近一个世纪以来,科学家们已经探索了各种栖息地和采样技术来研究地下生物圈,并在本章中进一步描述(第17.1.1-17.1.5节;(参见本卷第16章图16.1)。
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引用次数: 7
Carbon Dioxide Emissions from Subaerial Volcanic Regions 陆地火山地区的二氧化碳排放
Pub Date : 2019-10-01 DOI: 10.1017/9781108677950.008
C. Werner, T. Fischer, A. Aiuppa, M. Edmonds, C. Cardellini, S. Carn, G. Chiodini, E. Cottrell, M. Burton, H. Shinohara, P. Allard
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引用次数: 40
The Link between the Physical and Chemical Properties of Carbon-Bearing Melts and Their Application for Geophysical Imaging of Earth’s Mantle 含碳熔体物理化学性质与地幔物探成像的联系
Pub Date : 2019-10-01 DOI: 10.1017/9781108677950.007
F. Gaillard, N. Sator, E. Gardes, B. Guillot, M. Massuyeau, D. Sifre, T. Hammouda, G. Richard
Significant investment in new capacities for experimental research at high temperatures and pressures have provided new levels of understanding about the physical properties of carbon in fluids and melts, including its viscosity, electrical conductivity, and density. This chapter reviews the physical properties of carbon-bearing melts and fluids at high temperatures and pressures and highlights remaining unknowns left to be explored. The chapter also reviews how the remote sensing of the inaccessible parts of the Earth via various geophysical techniques – seismic shear wave velocity, attenuation, and electromagnetic signals of mantle depths – can be reconciled with the potential presence of carbon-bearing melts or fluids
对高温高压实验研究新能力的大量投资,使人们对流体和熔体中碳的物理性质(包括粘度、导电性和密度)有了新的认识。本章回顾了含碳熔体和流体在高温高压下的物理性质,并强调了尚待探索的未知问题。本章还回顾了如何通过各种地球物理技术——地震横波速度、衰减和地幔深度的电磁信号——对地球上无法到达的部分进行遥感,从而与含碳熔体或流体的潜在存在相协调
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引用次数: 6
期刊
Deep Carbon
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