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434 EDITORIAL : Vol. 5 No. 1, 2018 by editor in chief 434社论:主编2018年第5卷第1期
Pub Date : 2018-06-20 DOI: 10.22341/jacs.on.00501p434
Yohanes Buang
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引用次数: 0
Preparation of Nanopore Hydroxysodalite Zeolite Membranes by Dry Gel Method 干凝胶法制备纳米孔羟基钠石沸石膜
Pub Date : 2018-06-20 DOI: 10.22341/jacs.on.00501p424
M. Kazemimoghadam
Hydroxysodalite (HS) Zeolite membrane was prepared onto seeded mullite supports using a new crystallization method called Dry Gel Conversion Technique. Molar composition of the starting gel of HS zeolite membrane was SiO2/Al2O3=1.0, Na2O/Al2O3=65, and H2O/Al2O3=1000. X-ray diffraction (XRD) patterns of the membranes exhibited peaks corresponding to the support and the zeolite. The crystal species were characterized by XRD and morphology of the supports subjected to crystallization was characterized by Scanning electron microscopy (SEM). Separation performance of HS zeolite membranes was studied for water-Ethanol mixtures using pervaporation (PV). The membranes showed good selectivity towards water in the water-ethanol mixtures. Water permeates faster because of its preferential adsorption into the nano-pores of the hydrophilic zeolite membrane. In PV of water-ethanol mixtures, the membrane exhibits a hydrophilic behavior, with a high selectivity towards water and a good flux. The best flux and separation factor of the membranes were 2.05 kg/m.h and 10000, respectively. In addition, these membranes used for hydrogen separation from CH4 and it showed high selectivity and permeability ratio to zeolite membrane preparated by conventional method.
采用干凝胶转化技术在莫来石载体上制备了羟基钠石沸石膜。HS沸石膜起始凝胶的摩尔组成为SiO2/Al2O3=1.0, Na2O/Al2O3=65, H2O/Al2O3=1000。膜的x射线衍射(XRD)谱图显示出与载体和沸石对应的峰。用XRD对晶体种类进行了表征,并用扫描电镜(SEM)对结晶后载体的形貌进行了表征。采用渗透蒸发法研究了HS沸石膜对水-乙醇混合物的分离性能。在水-乙醇混合物中,膜对水具有良好的选择性。水的渗透速度更快,因为它优先吸附到亲水沸石膜的纳米孔。在水-乙醇混合物的PV中,膜表现出亲水性,对水具有高选择性和良好的通量。膜的最佳通量和分离系数分别为2.05 kg/m.h和10000。此外,这些膜用于氢与CH4的分离,与传统方法制备的沸石膜相比,具有较高的选择性和渗透性。
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引用次数: 1
Performances of Zeolite, Coconut Shell, and Zeolite+Coconut Shell-Based Water Cartridges to Minimize Contaminants of Drinking Water 沸石,椰子壳和沸石+椰子壳基水筒的性能,以尽量减少饮用水的污染物
Pub Date : 2018-06-20 DOI: 10.22341/jacs.on.00501p377
Yohanes Buang, Suwari Suwari, David Tambaru, A. Ola
Performances of zeolite, coconut shell, and zeolite+coconut shell-based water cartridges to minimize contaminants of drinking waters were conducted in the present study. The zeolite stones and coconut shell charcoal were powdered to be ≥ 60 meshes. The powders were packed into a cartridge to provide zeolite, coconut shell, and zeolite+coconut shell (1:2) cartridges, respectively. Well waters allowed to flow through each cartridge for a month. Thereafter, each water filtrate was harvested and analyzed numbers of parameters from four variables included in the quality table of drinking water. The total coliform found in each 100 mL of the well water equaled to 460 MPN (most possible number) while the fecal coli equaled to 150. When the well water flowed through the developing cartridges, the MPN content varied which depended on the cartridge materials qualitative compositions. Total coliform remained in water filtrates of the well waters flowed through the cartridges made of zeolite, coconut charcoal, and their mixture (1:2 by volume) were 38, 240, and 96 MPN, respectively. These developed cartridges, therefore, could remove these total coliform from the well waters by 92, 48, and 79 %, respectively. Overall, the performance of the developed cartridge made of zeolite was highest among those cartridges.
本文研究了沸石、椰子壳和沸石+椰子壳基水筒对饮用水污染物的影响。沸石、椰壳炭粉≥60目。将粉末装入一个药筒中,分别提供沸石、椰子壳和沸石+椰子壳(1:2)药筒。井水被允许流过每个药筒一个月。然后收集每个水滤液,并分析饮用水质量表中包含的四个变量的参数个数。在每100毫升井水中发现的总大肠菌群相当于460 MPN(最可能的数字),而粪便大肠杆菌相当于150。当井水流过显影筒时,MPN含量随筒体材料的定性组成而变化。沸石、椰子炭制成的筒体流过的井水滤液中残留的大肠菌群总量分别为38、240和96 MPN(体积比1:2)。因此,这些发育好的菌筒可以分别将这些总大肠菌群从井水中去除92%、48%和79%。总体而言,沸石制成的开发药筒的性能是这些药筒中最高的。
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引用次数: 0
Analysis of Mercury (Hg) in Whitening Cream Distributed in Palu City by Atomic Absorption Spectroscopy 原子吸收光谱法分析帕卢市分布的美白乳膏中汞的含量
Pub Date : 2018-06-20 DOI: 10.22341/JACS.ON.00501P430
E. Dwijayanti, Susanti
This study aimed to obtain chemical data of mercury from some whitening cream distributed in Palu City. The whitening cream samples consisted of 3 groups (A, B and C), each sample of the group was extracted through wet destructions. The qualitative analysis was with HCl 2.0 M, KI 0.50 N, NaOH 2.0 N reagents, while the quantitative analysis was performed with Atomic Absorption Spectroscopy (AAS). The results of the qualitative analysis indicated that the A sample reacted with NaOH 2.0 N reagent delivered yellow precipitates and C sample with KI 0.50 N reagent delivered red precipitates. Both data indicated that both samples showed positive reaction of Hg (II). However, the B samples did not occur the positive reaction indicating Hg. Based on Indonesian National Agency of Drug and Food Control (BPOM) regulation, (No.HK.03.1.23.07.11.6662 of 2011) related to the requirements of microbe and heavy metals contamination in cosmetics, the Hg (II) concentration in cream should be no more than 1,000.0 μg g. AAS results found in present study demonstrated that A sample holded mercury content over the level required by the BPOM, which it was 4,554.00 μg g. The B and C samples were 47.18 and 780.32 μg g respectively, both samples did not exceed the limits set by the regulation but continuous application might be toxic for body.
本研究旨在获得分布在帕卢市的一些美白霜中汞的化学数据。美白乳霜样品分为A、B、C 3组,每组样品均采用湿法破坏提取。定性分析采用HCl 2.0 M、KI 0.50 N、NaOH 2.0 N试剂,定量分析采用原子吸收光谱法(AAS)。定性分析结果表明,A样品与NaOH 2.0 N试剂反应产生黄色沉淀,C样品与KI 0.50 N试剂反应产生红色沉淀。根据印尼国家药品和食品管理局(BPOM)法规(2011年hk .03.1.23.07.11.6662号)有关化妆品中微生物和重金属污染的要求,本研究的原子吸收光谱结果表明,A样品的汞含量超过了BPOM要求的标准(4554.00 μg), B和C样品的汞含量分别为47.18和780.32 μg,两种样品的汞含量均未超过规定的限值,但连续使用可能对人体有害。
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引用次数: 4
Making and Comparing the Performance of Zeolite Membranes 沸石膜的制备及性能比较
Pub Date : 2018-06-20 DOI: 10.22341/JACS.ON.00501P394
M. Kazemimoghadam
Zeolite membranes NaA, ZSM-5, Mordenite, NaX and NaY grown onto seeded mullite supports. Separation performance of zeolite membranes were studied for water-dimethylhydrazine mixtures using pervaporation (PV). The best Flux and separation factor of the membranes were 0.62 kg/m.h and 52000, respectively, for NaA zeolite membrane. Strong electrostatic interaction between ionic sites and water molecules (due to its polar nature) makes the zeolite NaA membrane very hydrophilic. Zeolite NaA membranes are thus well suited for separating liquid-phase mixtures by pervaporation. In this study, experiments were conducted with various unsymmetrical dimethylhydrazine (UDMH) –water mixtures (1–20 wt. %) at 25 C  . Total flux for UDMH–water mixtures was found to vary from 0.331 to 0.241 kg/m.h with increasing UDMH concentration from 1 to 20 wt.%. Ionic sites of the NaA zeolite matrix play a very important role in water transport through the membrane. Surface diffusion of water occurs in an activated fashion through these sites. A comparison between experimental flux and calculated flux using Stephan Maxwell (S.M.) correlation was made and a linear trend was found to exist for water flux through the membrane with UDMH concentration.
沸石膜NaA, ZSM-5,丝光沸石,NaX和NaY生长在种子莫来石载体上。采用渗透蒸发法研究了沸石膜对水-二甲基肼混合物的分离性能。NaA沸石膜的最佳通量为0.62 kg/m.h,最佳分离系数为52000 kg/m.h。离子位点与水分子之间的强静电相互作用(由于其极性性质)使沸石NaA膜具有很强的亲水性。沸石NaA膜因此非常适合通过渗透汽化分离液相混合物。在这项研究中,实验是用各种不对称二甲肼(UDMH) -水混合物(1-20 wt. %)在25℃下进行的。随着UDMH浓度从1%增加到20%,UDMH -水混合物的总通量从0.331到0.241 kg/m.h不等。NaA沸石基质的离子位点在水通过膜的运输中起着非常重要的作用。水的表面扩散以活化的方式通过这些位点发生。用Stephan Maxwell (S.M.)关系式对实验通量和计算通量进行了比较,发现水通过膜的通量与UDMH浓度呈线性关系。
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引用次数: 0
Synthetic C-Methoxyphenyl Calix [4] Resorcinarene and Its Antioxidant Activity c -甲氧基苯基杯[4]间苯二烯的合成及其抗氧化活性
Pub Date : 2018-06-20 DOI: 10.22341/jacs.on.00501p403
Budiana I Gusti M. Budiana I Gusti M. Ngurah
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引用次数: 2
Effect of Concentration of Soursop (Annona muricata) Leaf and Soaking Time on Protein and Fat Contents and Sensory Quality of Raw Chicken Meat 番荔枝叶浓度和浸泡时间对生鸡肉蛋白质、脂肪含量及感官品质的影响
Pub Date : 2018-06-20 DOI: 10.22341/JACS.ON.00501P388
Diana A. Wuri, J. F. Bale-Therik, Gomera Bouk
The purpose of this study was to find out the effect of concentration of soursop (Annona muricata) leaf and soaking time on protein and fat contents and sensory quality of raw chicken meat during storage. This research was conducted in Laboratory of Animal Products Technology, Faculty of Animal Husbandry Nusa Cendana University and Laboratory of Veterinary Public Health, East Nusa Tenggara Province Livestock Services Kupang, Indonesia. The experiment was arranged in completely randomized design in a 4x3 factorial lay out with three replications. The first factor was concentration of soursop leaf in water (C) with four levels: 0, 10, 20, and 30 g/L water. The second factor was soaking time of chicken meat (T) with three levels: 0, 10, and 20 minutes. The quality of chicken meat changes were monitored chemically and organoleptically at hours 12 of storage time. Data collected of protein and fat contents of chicken meat were analyzed using Analysis of Variance and continued with Duncan’s Multiple Range Test, while data of organoleptic properties (color and aroma) characteristics were compared using the Kruskal Wallis Test. It was found that both treatment factors concentration of soursop leaf and soaking time with the interactions had significant effect (P<0.01) on protein and fat content of chicken meat. These results also indicated that color characteristics of chicken meat detected by the descriptive panelist were significantly affected by the both factors concentration of soursop leaf and soaking time (P<0.05), while aroma characteristics were insignificantly affected by the treatments.
本研究旨在探讨番荔枝叶浓度和浸泡时间对鸡肉原料贮藏过程中蛋白质、脂肪含量和感官品质的影响。这项研究是在印度尼西亚努沙钦达纳大学畜牧学院动物产品技术实验室和东努沙登加拉省畜牧服务处兽医公共卫生实验室进行的。试验采用4 × 3阶乘完全随机设计,设3个重复。第一个影响因素是在0、10、20和30 g/L水浓度(C) 4个浓度水平下的sour sour leaf in water (C)。第二个因素是鸡肉的浸泡时间(T),分为0分钟、10分钟和20分钟三个级别。在贮藏12 h时,对鸡肉的化学和感官质量变化进行了监测。鸡肉蛋白质和脂肪含量数据采用方差分析和邓肯多元极差检验进行分析,感官(颜色和香气)特征数据采用Kruskal Wallis检验进行比较。结果表明,酸菜叶浓度和浸泡时间及其交互作用对鸡肉蛋白质和脂肪含量均有显著影响(P<0.01)。上述结果还表明,描述性面板检测的鸡肉颜色特征受酸菜叶浓度和浸泡时间的影响显著(P<0.05),而香气特征受处理的影响不显著。
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引用次数: 1
Validation of Analytical Method Determination of Sodium Dodecyl Benzene Sulfonate (DBS) in Catfish (Clarias batrachus L.) by Spectrophotometric Using Methylene Blue 亚甲基蓝分光光度法测定鲶鱼中十二烷基苯磺酸钠(DBS)分析方法的验证
Pub Date : 2018-06-20 DOI: 10.22341/JACS.ON.00501P414
C. Bulin, A. Suratman, Roto
A spectrophotometric method for analysis of DBS anionic surfactant in Clarias batracus has been validated. The method of analysis was divided into two phases. Extraction with solid-liquid extraction using Soxhlet and analysis of DBS. The extraction was performed using solvent of n-hexane and methanol for 9 and 6 hours, respectively. The analysis was performed using Spectrophotometer UV-Vis based on the complex formation of DBS-methylene blue (DBS-MB). This methods is applied to the determination of DBS in local catfish after DBS exposure and that of obtained in markets. The results showed that the parameters of validation methods have high acceptability as linierity (R2 = 0.99), limit of detection (LOD) and limit of quantification (LOQ ) (2.93 mg/g and 9.75 mg/g), sensitivity (ε = 2.44 x 10 L mol-1 cm-1), precision (RSD = 0.14-1.38%) and accuracy (% recovery in a range 82-110 %). The results of analysis of DBS in catfish with 2.5; 5; 10; 15 mg/L of DBS concentration exposure are 0.87; 1.67; 8.50 dan 18.10 mg/kg, respectively and catfish from markets in a range 8.5-61 mg/kg. The result showed that the method of analysis of DBS anionic surfactant using MB could be applied for catfish samples..
采用分光光度法测定了战马claras batracus中DBS阴离子表面活性剂的含量。分析方法分为两个阶段。索氏固液萃取法提取及DBS分析。以正己烷和甲醇为萃取溶剂,萃取时间分别为9小时和6小时。利用分光光度计对dbs -亚甲基蓝(DBS-MB)络合物的形成进行分析。本方法适用于本地鲶鱼接触DBS后的DBS含量测定和市场上获得的DBS含量测定。结果表明,验证方法的线性(R2 = 0.99)、检出限(LOD)和定量限(LOQ)分别为2.93 mg/g和9.75 mg/g)、灵敏度(ε = 2.44 × 10 L mol-1 cm-1)、精密度(RSD = 0.14 ~ 1.38%)和准确度(回收率在82 ~ 110%范围内)具有较高的可接受性。2.5的鲶鱼DBS分析结果;5;10;15 mg/L DBS浓度暴露量为0.87;1.67;分别为8.50至18.10毫克/公斤,市场鲶鱼为8.5至61毫克/公斤。结果表明,用MB分析DBS阴离子表面活性剂的方法可用于鲶鱼样品。
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引用次数: 0
The Effectiveness of Bio-Slurry and Inorganic Fertilizer Combination on the Performance of Rice (Oryza sativa L) 生物浆与无机肥组合对水稻生产性能的影响
Pub Date : 2018-06-20 DOI: 10.22341/JACS.ON.00501P418
Ahmad Khanafi, Yafizham, D. W. Widjajanto
The experiment was aimed to investigate the effectiveness of bio-slurry and inorganic fertilizer combination on the performance of two rice varieties. A completely randomized design of factorial pattern was used throughout the experiment. The first factor was the combination of bioslurry and NPK fertilizer that consisted of P0: no added fertilizer, P1: NPK fertilizer only, 550 kg/ha; P2: bio-slurry 2.3 tons/ha + NPK fertilizer 400 kg/ha; P3: bio-slurry 4.6 tons/ha + NPK fertilizer 250 kg/ha; P4: bio-slurry 6.9 tons/ha + NPK fertilizer 100 kg/ha; and P5: bio-slurry only, 8.5 tons/ha. Treatments were applied based on nitrogen recommended doses of rice, 165 kg N/ha. The second factor was rice varieties that consisted of V1: IR-64 and V2: Ciherang. Each treatment was repeated three times. Parameters observed were plant height, number of tillers, weight of 1,000 grains, and rice production. Data were statistically analyzed using ANOVA and followed by Duncan’s Multiple Range Test. On the basis of the experimental results it was concluded that bio-slurry may replace the role of inorganic fertilizer in rice production, especially IR64 and Ciherang varieties.
本试验旨在研究生物浆与无机肥配施对两个水稻品种生产性能的影响。整个实验采用完全随机的析因模式设计。第一个因素是生物浆与氮磷钾肥的组合,即P0:不施肥,P1:只施肥,550 kg/ha;P2:生物浆2.3吨/公顷+氮磷钾肥料400公斤/公顷;P3:生物浆4.6吨/公顷+氮磷钾肥料250公斤/公顷;P4:生物浆6.9吨/公顷+氮磷钾肥料100公斤/公顷;P5:生物浆,8.5吨/公顷。按水稻推荐施氮量165 kg N/ hm2施用。第二个因素是由V1: IR-64和V2:慈和朗组成的水稻品种。每次治疗重复3次。观察的参数为株高、分蘖数、千粒重和水稻产量。数据采用方差分析和邓肯多元极差检验进行统计学分析。在试验结果的基础上,认为生物浆在水稻生产中,特别是IR64和慈和让品种,可以替代无机肥的作用。
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引用次数: 4
Molecular Docking and Toxicity Test of Apigenin Derivative Compounds as an Anti-Aging Agent 芹菜素衍生物抗衰老分子对接及毒性试验
Pub Date : 2018-06-20 DOI: 10.22341/JACS.ON.00501P409
E. Mumpuni, E. Mulatsari
The intrinsic factors that caused aging are enzymes such as hyaluronidase and elastase by oxidative stress mechanism. Antioxidants are the bioactive compounds which are highly important to fight against oxidative stress that can cause aging. Modified compounds o121–15f apigenin have reported can act as an antioxidant. The aim of this study was to determine candidate of apigenin derivative compounds that were potential to inhibit hyaluronidase and elastase enzyme by using molecular docking method with human target protein with pdb.id : 2JIE and 5JMY. Molecular docking was done using windows operating system with several softwares, i.e: PLANTS, YASARA and MarVinSketch. Visualization of bonding modes between the ligand and amino acid residues was done with PyMol. Of the 50 apigenin derivative compounds tested, obtained 9 compounds with lower docking scores than apigenin in inhibiting hyaluronidase and 5 compounds in inhibiting elastase enzyme. 3’6-diamineapigenin had the lowest docking score (-62.39) in inhibiting hyaluronidase enzyme (2JIE) and 3’amineapigenin had the lowest docking score (-91.31) in inhibiting elastase enzyme (5JMY). The binding interactions of the actively docked conformations of the ligand and the target protein have been identified and showed the most amino acid residues that considered affect hyaluronidase and elastase inhibition process such as VAL_710, GLU_762 and VAL_763. Based on these results, there are some antioxidants of the apigenin derivative compounds that recommended as an anti-aging agent. Keywords: apigenin, antioxidant, anti-aging, molecular docking
氧化应激机制下引起衰老的内在因素是透明质酸酶和弹性酶等酶。抗氧化剂是一种生物活性化合物,对对抗氧化应激非常重要,氧化应激会导致衰老。据报道,修饰的化合物o121-15f芹菜素可以作为抗氧化剂。本研究的目的是利用pdb与人靶蛋白的分子对接方法,确定可能抑制透明质酸酶和弹性酶的芹菜素衍生物候选化合物。id: 2JIE和5JMY。分子对接是在windows操作系统下使用PLANTS、YASARA和MarVinSketch等软件完成的。用PyMol可视化了配体和氨基酸残基之间的键合模式。在50个芹菜素衍生物中,有9个化合物抑制透明质酸酶的对接得分低于芹菜素,5个化合物抑制弹性酶的对接得分低于芹菜素。3′6-二胺芹菜素抑制透明质酸酶(2JIE)的对接评分最低(-62.39),3′胺芹菜素抑制弹性酶(5JMY)的对接评分最低(-91.31)。该配体的活性对接构象与靶蛋白的结合相互作用已被确定,并显示了大多数被认为影响透明质酸酶和弹性酶抑制过程的氨基酸残基,如VAL_710, GLU_762和VAL_763。基于这些结果,有一些抗氧化剂的芹菜素衍生物化合物被推荐作为抗衰老剂。关键词:芹菜素,抗氧化,抗衰老,分子对接
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引用次数: 2
期刊
Journal of Applied Chemical Science
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