Alkali-activated materials (AAMs) provide a promising green alternative for recycled concrete aggregates (RCA) surface pretreatment, which are essential for sustainable construction. However, the high shrinkage of AAMs poses a critical challenge to the modified interfacial transition zone of RCA. This study investigates the effects of shrinkage-reducing additives (MgO, CaO and PPG) on the properties of recycled concrete powder-based alkali-activated (AASFR) pastes, and their efficacy in enhancing the interfacial performance of RCA. Shrinkage-reducing additives on the mechanical properties, drying shrinkage, and microstructural of AASFR pastes are investigated. The interfacial bonding performance is analyzed using BSE imaging and nanoindentation. Results demonstrate that 4% MgO yields the best mechanical and interfacial behavior, forming the narrowest new interfacial transition zone (NITZ) and the highest elastic modulus. In comparison, 3% CaO provides a cost-effective solution with significant shrinkage reduction but offers limited long-term strength and interfacial improvement. Although the addition of PPG significantly mitigates drying shrinkage by reducing the pore solution surface tension, it leads to increased porosity and a reduction in compressive strength, presenting a moderate compromise in enhancing the mechanical properties of NITZ. The performance-cost-emissions trade-off analysis identifies MgO-modified paste as optimal for high-performance situation, while CaO-modified paste serves as the most cost-effective sustainable solution. This study provides the first comparative study of these three additive types on the modified interfacial micromechanics of RCA in an alkali-activated system, and focuses on the interfacial micromechanics of alkali-activated modified materials and proposing a comprehensive evaluation method that combines nanoindentation characterization with environmental impact and economic cost. This study provides practical insights for optimizing alkali-activated RCA modification technologies, highlighting the critical role of additive selection in modified interfacial microstructure and practical applications.
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