Pub Date : 2024-09-12DOI: 10.1007/s11771-024-5762-9
Shu-zong Chen, Yun-xiao Liu, Yun-long Wang, Cheng Qian, Chang-chun Hua, Jie Sun
Mill vibration is a common problem in rolling production, which directly affects the thickness accuracy of the strip and may even lead to strip fracture accidents in serious cases. The existing vibration prediction models do not consider the features contained in the data, resulting in limited improvement of model accuracy. To address these challenges, this paper proposes a multi-dimensional multi-modal cold rolling vibration time series prediction model (MDMMVPM) based on the deep fusion of multi-level networks. In the model, the long-term and short-term modal features of multi-dimensional data are considered, and the appropriate prediction algorithms are selected for different data features. Based on the established prediction model, the effects of tension and rolling force on mill vibration are analyzed. Taking the 5th stand of a cold mill in a steel mill as the research object, the innovative model is applied to predict the mill vibration for the first time. The experimental results show that the correlation coefficient (R2) of the model proposed in this paper is 92.5%, and the root-mean-square error (RMSE) is 0.0011, which significantly improves the modeling accuracy compared with the existing models. The proposed model is also suitable for the hot rolling process, which provides a new method for the prediction of strip rolling vibration.
{"title":"Multi-dimension and multi-modal rolling mill vibration prediction model based on multi-level network fusion","authors":"Shu-zong Chen, Yun-xiao Liu, Yun-long Wang, Cheng Qian, Chang-chun Hua, Jie Sun","doi":"10.1007/s11771-024-5762-9","DOIUrl":"https://doi.org/10.1007/s11771-024-5762-9","url":null,"abstract":"<p>Mill vibration is a common problem in rolling production, which directly affects the thickness accuracy of the strip and may even lead to strip fracture accidents in serious cases. The existing vibration prediction models do not consider the features contained in the data, resulting in limited improvement of model accuracy. To address these challenges, this paper proposes a multi-dimensional multi-modal cold rolling vibration time series prediction model (MDMMVPM) based on the deep fusion of multi-level networks. In the model, the long-term and short-term modal features of multi-dimensional data are considered, and the appropriate prediction algorithms are selected for different data features. Based on the established prediction model, the effects of tension and rolling force on mill vibration are analyzed. Taking the 5th stand of a cold mill in a steel mill as the research object, the innovative model is applied to predict the mill vibration for the first time. The experimental results show that the correlation coefficient (<i>R</i><sup>2</sup>) of the model proposed in this paper is 92.5%, and the root-mean-square error (RMSE) is 0.0011, which significantly improves the modeling accuracy compared with the existing models. The proposed model is also suitable for the hot rolling process, which provides a new method for the prediction of strip rolling vibration.</p>","PeriodicalId":15231,"journal":{"name":"Journal of Central South University","volume":null,"pages":null},"PeriodicalIF":4.4,"publicationDate":"2024-09-12","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142221056","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
The modification behavior of different Er contents on the microstructures and properties of as-cast 8030 aluminum alloy was investigated by optical microscopy (OM), scanning electron microscopy (SEM), X-ray diffraction (XRD), energy dispersive spectroscopy (EDS), transmission electron microscopy (TEM), hardness test, electrical conductivity test and tensile property test. The results show that the addition of Er can refine the grains of as-cast alloy, which mainly promotes the nucleation of α -Al by causing constitutional supercooling and forming the Al3Er nanoparticles as a heterogeneous nucleation core. Er can change the morphology of Al-Al6Fe eutectic structure of the alloy, furthermore, Er can adsorb on the surface of the Al6Fe phase to refine the Al6Fe phase at eutectic structure. Er can improve the tensile properties, especially the elongation of as-cast 8030 aluminum alloy, which is attributed to the modification of Al-Al6Fe eutectic and Al6Fe phase.
{"title":"Influence of rare earth element erbium on microstructures and properties of as-cast 8030 aluminum alloy","authors":"Hao-qing Tang, Hong-ying Li, Dong Jin, Xiang-hua Hu, Jing Xu, Hua-bin Li","doi":"10.1007/s11771-024-5723-3","DOIUrl":"https://doi.org/10.1007/s11771-024-5723-3","url":null,"abstract":"<p>The modification behavior of different Er contents on the microstructures and properties of as-cast 8030 aluminum alloy was investigated by optical microscopy (OM), scanning electron microscopy (SEM), X-ray diffraction (XRD), energy dispersive spectroscopy (EDS), transmission electron microscopy (TEM), hardness test, electrical conductivity test and tensile property test. The results show that the addition of Er can refine the grains of as-cast alloy, which mainly promotes the nucleation of <i>α</i> -Al by causing constitutional supercooling and forming the Al<sub>3</sub>Er nanoparticles as a heterogeneous nucleation core. Er can change the morphology of Al-Al<sub>6</sub>Fe eutectic structure of the alloy, furthermore, Er can adsorb on the surface of the Al<sub>6</sub>Fe phase to refine the Al<sub>6</sub>Fe phase at eutectic structure. Er can improve the tensile properties, especially the elongation of as-cast 8030 aluminum alloy, which is attributed to the modification of Al-Al<sub>6</sub>Fe eutectic and Al<sub>6</sub>Fe phase.</p>","PeriodicalId":15231,"journal":{"name":"Journal of Central South University","volume":null,"pages":null},"PeriodicalIF":4.4,"publicationDate":"2024-09-11","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142221058","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Machine-learning methodologies have increasingly been embraced in landslide susceptibility assessment. However, the considerable time and financial burdens of landslide inventories often result in persistent data scarcity, which frequently impedes the generation of accurate and informative landslide susceptibility maps. Addressing this challenge, this study compiled a nationwide dataset and developed a transfer learning-based model to evaluate landslide susceptibility in the Chongqing region specifically. Notably, the proposed model, calibrated with the warmup-cosine annealing (WCA) learning rate strategy, demonstrated remarkable predictive capabilities, particularly in scenarios marked by data limitations and when training data were normalized using parameters from the source region. This is evidenced by the area under the receiver operating characteristic curve (AUC) values, which exhibited significant improvements of 51.00%, 24.40% and 2.15%, respectively, compared to a deep learning model, in contexts where only 1%, 5% and 10% of data from the target region were used for retraining. Simultaneously, there were reductions in loss of 16.12%, 27.61% and 15.44%, respectively, in these instances.
{"title":"The improvement of large-scale-region landslide susceptibility mapping accuracy by transfer learning","authors":"Wen-gang Zhang, Song-lin Liu, Lu-qi Wang, Wei-xin Sun, Yan-mei Zhang, Wen Nie","doi":"10.1007/s11771-024-5761-x","DOIUrl":"https://doi.org/10.1007/s11771-024-5761-x","url":null,"abstract":"<p>Machine-learning methodologies have increasingly been embraced in landslide susceptibility assessment. However, the considerable time and financial burdens of landslide inventories often result in persistent data scarcity, which frequently impedes the generation of accurate and informative landslide susceptibility maps. Addressing this challenge, this study compiled a nationwide dataset and developed a transfer learning-based model to evaluate landslide susceptibility in the Chongqing region specifically. Notably, the proposed model, calibrated with the warmup-cosine annealing (WCA) learning rate strategy, demonstrated remarkable predictive capabilities, particularly in scenarios marked by data limitations and when training data were normalized using parameters from the source region. This is evidenced by the area under the receiver operating characteristic curve (AUC) values, which exhibited significant improvements of 51.00%, 24.40% and 2.15%, respectively, compared to a deep learning model, in contexts where only 1%, 5% and 10% of data from the target region were used for retraining. Simultaneously, there were reductions in loss of 16.12%, 27.61% and 15.44%, respectively, in these instances.</p>","PeriodicalId":15231,"journal":{"name":"Journal of Central South University","volume":null,"pages":null},"PeriodicalIF":4.4,"publicationDate":"2024-09-07","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142221044","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2024-08-17DOI: 10.1007/s11771-024-5732-2
Wei-chao Yang, Jian Wang, E. Deng, Yi-kang Liu, Lu-sen Luo, Jia Yang
The breakage and bending of ducts result in a difficulty to cope with ventilation issues in bi-directional excavation tunnels with a long inclined shaft using a single ventilation method based on ducts. To discuss the hybrid ventilation system applied in bi-directional excavation tunnels with a long inclined shaft, this study has established a full-scale computational fluid dynamics model based on field tests, the Poly-Hexcore method, and the sliding mesh technique. The distribution of wind speed, temperature field, and CO in the tunnel are taken as indices to compare the ventilation efficiency of three ventilation systems (duct, duct-ventilation shaft, duct–ventilated shaft-axial fan). The results show that the hybrid ventilation scheme based on duct-ventilation shaft–axial fan performs the best among the three ventilation systems. Compared to the duct, the wind speed and cooling rate in the tunnel are enhanced by 7.5%–30.6% and 14.1%–17.7%, respectively, for the duct-vent shaft-axial fan condition, and the volume fractions of CO are reduced by 26.9%–73.9%. This contributes to the effective design of combined ventilation for bidirectional excavation tunnels with an inclined shaft, ultimately improving the air quality within the tunnel.
{"title":"A hybrid ventilation scheme applied to bi-directional excavation tunnel construction with a long inclined shaft","authors":"Wei-chao Yang, Jian Wang, E. Deng, Yi-kang Liu, Lu-sen Luo, Jia Yang","doi":"10.1007/s11771-024-5732-2","DOIUrl":"https://doi.org/10.1007/s11771-024-5732-2","url":null,"abstract":"<p>The breakage and bending of ducts result in a difficulty to cope with ventilation issues in bi-directional excavation tunnels with a long inclined shaft using a single ventilation method based on ducts. To discuss the hybrid ventilation system applied in bi-directional excavation tunnels with a long inclined shaft, this study has established a full-scale computational fluid dynamics model based on field tests, the Poly-Hexcore method, and the sliding mesh technique. The distribution of wind speed, temperature field, and CO in the tunnel are taken as indices to compare the ventilation efficiency of three ventilation systems (duct, duct-ventilation shaft, duct–ventilated shaft-axial fan). The results show that the hybrid ventilation scheme based on duct-ventilation shaft–axial fan performs the best among the three ventilation systems. Compared to the duct, the wind speed and cooling rate in the tunnel are enhanced by 7.5%–30.6% and 14.1%–17.7%, respectively, for the duct-vent shaft-axial fan condition, and the volume fractions of CO are reduced by 26.9%–73.9%. This contributes to the effective design of combined ventilation for bidirectional excavation tunnels with an inclined shaft, ultimately improving the air quality within the tunnel.</p>","PeriodicalId":15231,"journal":{"name":"Journal of Central South University","volume":null,"pages":null},"PeriodicalIF":4.4,"publicationDate":"2024-08-17","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142221046","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2024-08-17DOI: 10.1007/s11771-024-5734-0
Chun-yang Zhang, Tao Tan, Er-cheng Zhao
Rocks will suffer different degree of damage under FT (freeze-thaw) cycles, which seriously threatens the long-term stability of rock engineering in cold regions. In order to study the mechanism of rock FT damage, energy calculation method and energy self-inhibition model are introduced to explore their energy characteristics in this paper. The applicability of the energy self-inhibition model was verified by combining the data of FT cycles and uniaxial compression tests of intact and pre-cracked sandstone samples, as well as published reference data. In addition, the energy evolution characteristics of FT damaged rocks were discussed accordingly. The results indicate that the energy self-inhibition model perfectly characterizes the energy accumulation characteristics of FT damaged rocks under uniaxial compression before the peak strength and the energy dissipation characteristics before microcrack unstable growth stage. Taking the FT damaged cyan sandstone sample as an example, it has gone through two stages dominated by energy dissipation mechanism and energy accumulation mechanism, and the energy rate curve of the pre-cracked sample shows a fall-rise phenomenon when approaching failure. Based on published reference data, it was found that the peak total input energy and energy storage limit conform to an exponential FT decay model, with corresponding decay constants ranging from 0.0021 to 0.1370 and 0.0018 to 0.1945, respectively. Finally, a linear energy storage equation for FT damaged rocks was proposed, and its high reliability and applicability were verified by combining published reference data,the energy storage coefficient of different types of rocks ranged from 0.823 to 0.992, showing a negative exponential relationship with the initial UCS (uniaxial compressive strength). In summary, the mechanism by which FT weakens the mechanical properties of rocks has been revealed from an energy perspective in this paper, which can provide reference for related issues in cold regions.
岩石在冻融循环作用下会发生不同程度的破坏,严重威胁寒冷地区岩石工程的长期稳定性。为了研究岩石冻融破坏的机理,本文引入了能量计算方法和能量自抑制模型来探讨其能量特征。结合完整砂岩样本和预开裂砂岩样本的 FT 循环和单轴压缩试验数据,以及已公布的参考数据,验证了能量自抑制模型的适用性。此外,还对 FT 破坏岩石的能量演化特征进行了相应的讨论。结果表明,能量自抑制模型完美地描述了单轴压缩下 FT 损伤岩石在强度峰值前的能量积累特征和微裂缝不稳定生长阶段前的能量耗散特征。以 FT 破坏的青色砂岩样品为例,它经历了以能量耗散机制和能量积累机制为主的两个阶段,在接近破坏时,预开裂样品的能量率曲线呈现出下降-上升现象。根据已公布的参考数据,发现总输入能量峰值和储能极限符合指数 FT 衰减模型,相应的衰减常数分别为 0.0021 至 0.1370 和 0.0018 至 0.1945。最后,提出了傅立叶变换破坏岩石的线性储能方程,并结合已发表的参考数据验证了该方程的高度可靠性和适用性,不同类型岩石的储能系数在 0.823 至 0.992 之间,与初始 UCS(单轴抗压强度)呈负指数关系。总之,本文从能量角度揭示了 FT 削弱岩石力学性能的机理,可为寒冷地区的相关问题提供参考。
{"title":"Energy evolution model and energy response characteristics of freeze-thaw damaged sandstone under uniaxial compression","authors":"Chun-yang Zhang, Tao Tan, Er-cheng Zhao","doi":"10.1007/s11771-024-5734-0","DOIUrl":"https://doi.org/10.1007/s11771-024-5734-0","url":null,"abstract":"<p>Rocks will suffer different degree of damage under FT (freeze-thaw) cycles, which seriously threatens the long-term stability of rock engineering in cold regions. In order to study the mechanism of rock FT damage, energy calculation method and energy self-inhibition model are introduced to explore their energy characteristics in this paper. The applicability of the energy self-inhibition model was verified by combining the data of FT cycles and uniaxial compression tests of intact and pre-cracked sandstone samples, as well as published reference data. In addition, the energy evolution characteristics of FT damaged rocks were discussed accordingly. The results indicate that the energy self-inhibition model perfectly characterizes the energy accumulation characteristics of FT damaged rocks under uniaxial compression before the peak strength and the energy dissipation characteristics before microcrack unstable growth stage. Taking the FT damaged cyan sandstone sample as an example, it has gone through two stages dominated by energy dissipation mechanism and energy accumulation mechanism, and the energy rate curve of the pre-cracked sample shows a fall-rise phenomenon when approaching failure. Based on published reference data, it was found that the peak total input energy and energy storage limit conform to an exponential FT decay model, with corresponding decay constants ranging from 0.0021 to 0.1370 and 0.0018 to 0.1945, respectively. Finally, a linear energy storage equation for FT damaged rocks was proposed, and its high reliability and applicability were verified by combining published reference data,the energy storage coefficient of different types of rocks ranged from 0.823 to 0.992, showing a negative exponential relationship with the initial UCS (uniaxial compressive strength). In summary, the mechanism by which FT weakens the mechanical properties of rocks has been revealed from an energy perspective in this paper, which can provide reference for related issues in cold regions.</p>","PeriodicalId":15231,"journal":{"name":"Journal of Central South University","volume":null,"pages":null},"PeriodicalIF":4.4,"publicationDate":"2024-08-17","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142221045","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2024-08-13DOI: 10.1007/s11771-024-5701-9
Xu-rui Chen, Jun Wu, Li Gu, Xue-bo Cao
Carbon nanotubes (CNTs) have garnered significant attention in the fields of science, engineering, and medicine due to their numerous advantages. The initial step towards harnessing the potential of CNTs involves their macroscopic assembly. The present study employed a gentle and direct self-assembly technique, wherein controlled growth of CNT sheaths occurred on the metal wire’s surface, followed by etching of the remaining metal to obtain the hollow tubes composed of CNTs. By controlling the growth time and temperature, it is possible to alter the thickness of the CNTs sheath. After immersing in a solution containing 1 g/L of CNTs at 60 °C for 24 h, the resulting CNTs layer achieved a thickness of up to 60 µm. These hollow CNTs tubes with varying inner diameters were prepared through surface reinforcement using polymers and sacrificing metal wires, thereby exhibiting exceptional attributes such as robustness, flexibility, air tightness, and high adsorption capacity that effectively capture CO2 from the gas mixture.
{"title":"Hollow tubes constructed by carbon nanotubes self-assembly for CO2 capture","authors":"Xu-rui Chen, Jun Wu, Li Gu, Xue-bo Cao","doi":"10.1007/s11771-024-5701-9","DOIUrl":"https://doi.org/10.1007/s11771-024-5701-9","url":null,"abstract":"<p>Carbon nanotubes (CNTs) have garnered significant attention in the fields of science, engineering, and medicine due to their numerous advantages. The initial step towards harnessing the potential of CNTs involves their macroscopic assembly. The present study employed a gentle and direct self-assembly technique, wherein controlled growth of CNT sheaths occurred on the metal wire’s surface, followed by etching of the remaining metal to obtain the hollow tubes composed of CNTs. By controlling the growth time and temperature, it is possible to alter the thickness of the CNTs sheath. After immersing in a solution containing 1 g/L of CNTs at 60 °C for 24 h, the resulting CNTs layer achieved a thickness of up to 60 µm. These hollow CNTs tubes with varying inner diameters were prepared through surface reinforcement using polymers and sacrificing metal wires, thereby exhibiting exceptional attributes such as robustness, flexibility, air tightness, and high adsorption capacity that effectively capture CO<sub>2</sub> from the gas mixture.</p>","PeriodicalId":15231,"journal":{"name":"Journal of Central South University","volume":null,"pages":null},"PeriodicalIF":4.4,"publicationDate":"2024-08-13","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142221055","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2024-08-13DOI: 10.1007/s11771-024-5705-5
Ke Huang, You-ping Yi, Shi-quan Huang, Hai-lin He, Jie Liu, Hong-en Hua, Yun-jian Tang
In this study, the cooling rate was manipulated by quenching with water of different temperatures (30, 60 and 100 °C). Surface and internal residual stresses in the quenched 6061 aluminum alloy samples were measured using hole-drilling and crack compliance methods, respectively. Then, the processability of the quenched samples was evaluated at cryogenic temperatures. The mechanical properties of the as-aged samples were assessed, and microstructure evolution was analyzed. The surface residual stresses of samples W30°C, W60°C and W100°C is −178.7, −161.7 and −117.2 MPa, respectively along x-direction, respectively; and −191.2, −172.1 and −126.2 MPa, respectively along y-direction. The sample quenched in boiling water displaying the lowest residual stress (∼34 % and ∼60% reduction in the surface and core). The generation and distribution of quenching residual stress could be attributed to the lattice distortion gradient. Desirable plasticity was also exhibited in the samples with relatively low quenching cooling rates at cryogenic temperatures. The strengthes of the as-aged samples are 291.2 to 270.1 MPa as the quenching water temperature increase from 30 °C to 100 °C. Fine and homogeneous β″ phases were observed in the as-aged sample quenched with boiling water due to the clusters and Guinier-Preston zones (GP zones) premature precipitated during quenching process.
本研究通过不同温度(30、60 和 100 °C)的水淬火来控制冷却速度。采用钻孔法和裂纹顺应法分别测量了淬火 6061 铝合金样品的表面和内部残余应力。然后,在低温条件下评估了淬火样品的可加工性。评估了老化样品的机械性能,并分析了微观结构的演变。样品 W30°C、W60°C 和 W100°C 的表面残余应力沿 x 方向分别为 -178.7、-161.7 和 -117.2 兆帕;沿 y 方向分别为 -191.2、-172.1 和 -126.2 兆帕。在沸水中淬火的样品残余应力最低(表面和核心分别降低了 ∼34 % 和 ∼60%)。淬火残余应力的产生和分布可归因于晶格畸变梯度。低温淬火冷却速率相对较低的样品也表现出理想的塑性。当淬火水温从 30 °C 升至 100 °C 时,老化样品的强度为 291.2 至 270.1 兆帕。在用沸水淬火的未淬火样品中观察到了细小均匀的β″相,这是由于在淬火过程中过早析出了团簇和吉尼尔-普雷斯顿区(GP 区)。
{"title":"Effect of quenching cooling rate on residual stress and microstructure evolution of 6061 aluminum alloy","authors":"Ke Huang, You-ping Yi, Shi-quan Huang, Hai-lin He, Jie Liu, Hong-en Hua, Yun-jian Tang","doi":"10.1007/s11771-024-5705-5","DOIUrl":"https://doi.org/10.1007/s11771-024-5705-5","url":null,"abstract":"<p>In this study, the cooling rate was manipulated by quenching with water of different temperatures (30, 60 and 100 °C). Surface and internal residual stresses in the quenched 6061 aluminum alloy samples were measured using hole-drilling and crack compliance methods, respectively. Then, the processability of the quenched samples was evaluated at cryogenic temperatures. The mechanical properties of the as-aged samples were assessed, and microstructure evolution was analyzed. The surface residual stresses of samples W30°C, W60°C and W100°C is −178.7, −161.7 and −117.2 MPa, respectively along <i>x</i>-direction, respectively; and −191.2, −172.1 and −126.2 MPa, respectively along <i>y</i>-direction. The sample quenched in boiling water displaying the lowest residual stress (∼34 % and ∼60% reduction in the surface and core). The generation and distribution of quenching residual stress could be attributed to the lattice distortion gradient. Desirable plasticity was also exhibited in the samples with relatively low quenching cooling rates at cryogenic temperatures. The strengthes of the as-aged samples are 291.2 to 270.1 MPa as the quenching water temperature increase from 30 °C to 100 °C. Fine and homogeneous <i>β</i>″ phases were observed in the as-aged sample quenched with boiling water due to the clusters and Guinier-Preston zones (GP zones) premature precipitated during quenching process.</p>","PeriodicalId":15231,"journal":{"name":"Journal of Central South University","volume":null,"pages":null},"PeriodicalIF":4.4,"publicationDate":"2024-08-13","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142221048","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2024-08-13DOI: 10.1007/s11771-024-5736-y
Wei-fang Liu, Zi-han Hu, Qi Zhang
Aqueous zinc ion hybrid capacitors (ZIHCs) are considered one of the most promising electrochemical energy storage systems due to their high safety, environmental friendliness, low cost, and high power density. However, the low energy density and the lack of sustainable design strategies for the cathodes hinder the practical application of ZIHCs. Herein, we design the N and O co-doped porous carbon cathode by annealing metal-organic framework (ZIF-8). ZIF-8 retains the original dodecahedral structure with a high specific surface (2814.67 m2/g) and IG/ID ratio of 1.0 during carbonization and achieves self-doping of N and O heteroatoms. Abundant defect sites are introduced into the porous carbon to provide additional active sites for ion adsorption after the activation of carbonized ZIF-8 by KOH treatment. The ZIHCs assembled with modified ZIF-8 as the cathode and commercial zinc foil as the anode show an energy density of 125 W · h/kg and a power density of 79 W/kg. In addition, this ZIHCs device achieves capacity retention of 77.8% after 9000 electrochemical cycles, which is attributed to the diverse pore structure and plentiful defect sites of ZIF-8-800(KOH). The proposed strategy may be useful in developing high-performance metal-ion hybrid capacitors for large-scale energy storage.
{"title":"Metal-organic framework-derived porous carbon for the advanced aqueous zinc-ion hybrid capacitor","authors":"Wei-fang Liu, Zi-han Hu, Qi Zhang","doi":"10.1007/s11771-024-5736-y","DOIUrl":"https://doi.org/10.1007/s11771-024-5736-y","url":null,"abstract":"<p>Aqueous zinc ion hybrid capacitors (ZIHCs) are considered one of the most promising electrochemical energy storage systems due to their high safety, environmental friendliness, low cost, and high power density. However, the low energy density and the lack of sustainable design strategies for the cathodes hinder the practical application of ZIHCs. Herein, we design the N and O co-doped porous carbon cathode by annealing metal-organic framework (ZIF-8). ZIF-8 retains the original dodecahedral structure with a high specific surface (2814.67 m<sup>2</sup>/g) and <i>I</i><sub>G</sub>/<i>I</i><sub>D</sub> ratio of 1.0 during carbonization and achieves self-doping of N and O heteroatoms. Abundant defect sites are introduced into the porous carbon to provide additional active sites for ion adsorption after the activation of carbonized ZIF-8 by KOH treatment. The ZIHCs assembled with modified ZIF-8 as the cathode and commercial zinc foil as the anode show an energy density of 125 W · h/kg and a power density of 79 W/kg. In addition, this ZIHCs device achieves capacity retention of 77.8% after 9000 electrochemical cycles, which is attributed to the diverse pore structure and plentiful defect sites of ZIF-8-800(KOH). The proposed strategy may be useful in developing high-performance metal-ion hybrid capacitors for large-scale energy storage.</p>","PeriodicalId":15231,"journal":{"name":"Journal of Central South University","volume":null,"pages":null},"PeriodicalIF":4.4,"publicationDate":"2024-08-13","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142221057","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2024-08-13DOI: 10.1007/s11771-024-5580-0
Dong-qiao Liu, Yun-peng Guo, Kai Ling, Jie-yu Li
Bedding structural planes significantly influence the mechanical properties and stability of engineering rock masses. This study conducts uniaxial compression tests on layered sandstone with various bedding angles (0°, 15°, 30°, 45°, 60°, 75° and 90°) to explore the impact of bedding angle on the deformational mechanical response, failure mode, and damage evolution processes of rocks. It develops a damage model based on the Logistic equation derived from the modulus’s degradation considering the combined effect of the sandstone bedding dip angle and load. This model is employed to study the damage accumulation state and its evolution within the layered rock mass. This research also introduces a piecewise constitutive model that considers the initial compaction characteristics to simulate the whole deformation process of layered sandstone under uniaxial compression. The results revealed that as the bedding angle increases from 0° to 90°, the uniaxial compressive strength and elastic modulus of layered sandstone significantly decrease, slightly increase, and then decline again. The corresponding failure modes transition from splitting tensile failure to slipping shear failure and back to splitting tensile failure. As indicated by the modulus’s degradation, the damage characteristics can be categorized into four stages: initial no damage, damage initiation, damage acceleration, and damage deceleration termination. The theoretical damage model based on the Logistic equation effectively simulates and predicts the entire damage evolution process. Moreover, the theoretical constitutive model curves closely align with the actual stress – strain curves of layered sandstone under uniaxial compression. The introduced constitutive model is concise, with fewer parameters, a straightforward parameter determination process, and a clear physical interpretation. This study offers valuable insights into the theory of layered rock mechanics and holds implications for ensuring the safety of rock engineering.
{"title":"A whole process damage constitutive model for layered sandstone under uniaxial compression based on Logistic function","authors":"Dong-qiao Liu, Yun-peng Guo, Kai Ling, Jie-yu Li","doi":"10.1007/s11771-024-5580-0","DOIUrl":"https://doi.org/10.1007/s11771-024-5580-0","url":null,"abstract":"<p>Bedding structural planes significantly influence the mechanical properties and stability of engineering rock masses. This study conducts uniaxial compression tests on layered sandstone with various bedding angles (0°, 15°, 30°, 45°, 60°, 75° and 90°) to explore the impact of bedding angle on the deformational mechanical response, failure mode, and damage evolution processes of rocks. It develops a damage model based on the Logistic equation derived from the modulus’s degradation considering the combined effect of the sandstone bedding dip angle and load. This model is employed to study the damage accumulation state and its evolution within the layered rock mass. This research also introduces a piecewise constitutive model that considers the initial compaction characteristics to simulate the whole deformation process of layered sandstone under uniaxial compression. The results revealed that as the bedding angle increases from 0° to 90°, the uniaxial compressive strength and elastic modulus of layered sandstone significantly decrease, slightly increase, and then decline again. The corresponding failure modes transition from splitting tensile failure to slipping shear failure and back to splitting tensile failure. As indicated by the modulus’s degradation, the damage characteristics can be categorized into four stages: initial no damage, damage initiation, damage acceleration, and damage deceleration termination. The theoretical damage model based on the Logistic equation effectively simulates and predicts the entire damage evolution process. Moreover, the theoretical constitutive model curves closely align with the actual stress – strain curves of layered sandstone under uniaxial compression. The introduced constitutive model is concise, with fewer parameters, a straightforward parameter determination process, and a clear physical interpretation. This study offers valuable insights into the theory of layered rock mechanics and holds implications for ensuring the safety of rock engineering.</p>","PeriodicalId":15231,"journal":{"name":"Journal of Central South University","volume":null,"pages":null},"PeriodicalIF":4.4,"publicationDate":"2024-08-13","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142221077","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2024-08-13DOI: 10.1007/s11771-024-5678-4
Bei Jiang, Ming-zi Wang, Qi Wang, Zhong-xin Xin, Xue-yang Xing, Yu-song Deng, Liang-di Yao
Non-pillar mining technology with automatically formed roadway is a new mining method without coal pillar reservation and roadway excavation. The stability control of automatically formed roadway is the key to the successful application of the new method. In order to realize the stability control of the roadway surrounding rock, the mechanical model of the roof and rib support structure is established, and the influence mechanism of the automatically formed roadway parameters on the compound force is revealed. On this basis, the roof and rib support structure technology of confined lightweight concrete is proposed, and its mechanical tests under different eccentricity are carried out. The results show that the bearing capacity of confined lightweight concrete specimens is basically the same as that of ordinary confined concrete specimens. The bearing capacity of confined lightweight concrete specimens under different eccentricities is 1.95 times higher than those of U-shaped steel specimens. By comparing the test results with the theoretical calculated results of the confined concrete, the calculation method of the bearing capacity for the confined lightweight concrete structure is selected. The design method of confined lightweight concrete support structure is established, and is successfully applied in the extra-large mine, Ningtiaota Coal Mine, China.
自动成巷无煤柱开采技术是一种无煤柱预留和巷道掘进的新型开采方法。自动成型巷道的稳定性控制是新方法成功应用的关键。为实现巷道围岩的稳定性控制,建立了顶板与肋板支护结构的力学模型,揭示了自动成巷参数对复合力的影响机理。在此基础上,提出了约束轻质混凝土顶板与肋板支护结构技术,并对其进行了不同偏心率下的力学试验。结果表明,约束轻质混凝土试件的承载力与普通约束混凝土试件基本相同。不同偏心率下约束轻质混凝土试件的承载力是 U 型钢试件的 1.95 倍。通过试验结果与约束混凝土理论计算结果的对比,筛选出约束轻质混凝土结构承载力的计算方法。建立了约束轻质混凝土支护结构的设计方法,并成功应用于中国特大型矿井宁条塔煤矿。
{"title":"Bearing mechanism of roof and rib support structure in automatically formed roadway and its support design method","authors":"Bei Jiang, Ming-zi Wang, Qi Wang, Zhong-xin Xin, Xue-yang Xing, Yu-song Deng, Liang-di Yao","doi":"10.1007/s11771-024-5678-4","DOIUrl":"https://doi.org/10.1007/s11771-024-5678-4","url":null,"abstract":"<p>Non-pillar mining technology with automatically formed roadway is a new mining method without coal pillar reservation and roadway excavation. The stability control of automatically formed roadway is the key to the successful application of the new method. In order to realize the stability control of the roadway surrounding rock, the mechanical model of the roof and rib support structure is established, and the influence mechanism of the automatically formed roadway parameters on the compound force is revealed. On this basis, the roof and rib support structure technology of confined lightweight concrete is proposed, and its mechanical tests under different eccentricity are carried out. The results show that the bearing capacity of confined lightweight concrete specimens is basically the same as that of ordinary confined concrete specimens. The bearing capacity of confined lightweight concrete specimens under different eccentricities is 1.95 times higher than those of U-shaped steel specimens. By comparing the test results with the theoretical calculated results of the confined concrete, the calculation method of the bearing capacity for the confined lightweight concrete structure is selected. The design method of confined lightweight concrete support structure is established, and is successfully applied in the extra-large mine, Ningtiaota Coal Mine, China.</p>","PeriodicalId":15231,"journal":{"name":"Journal of Central South University","volume":null,"pages":null},"PeriodicalIF":4.4,"publicationDate":"2024-08-13","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142221081","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}