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Evolution of mechanical properties, localized corrosion resistance and microstructure of a high purity Al-Zn-Mg-Cu alloy during non-isothermal aging 高纯度 Al-Zn-Mg-Cu 合金在非等温时效过程中的机械性能、局部耐腐蚀性和微观结构演变
IF 4.4 2区 材料科学 Q1 METALLURGY & METALLURGICAL ENGINEERING Pub Date : 2024-07-23 DOI: 10.1007/s11771-024-5688-2
Xuan-xuan Dai, Yu-zhang Li, Sheng-dan Liu, Ling-ying Ye, Chong-jun Bao

The evolution of mechanical properties, localized corrosion resistance of a high purity Al-Zn-Mg-Cu alloy during non-isothermal aging (NIA) was investigated by hardness test, electrical conductivity test, tensile test, intergranular corrosion test, exfoliation corrosion test, slow strain rate tensile test and electrochemical test, and the mechanism has been discussed based on microstructure examination by optical microscopy, electron back scattered diffraction, scanning electron microscopy and scanning transmission electron microscopy. The NIA treatment includes a heating stage from 40 °C to 180 °C with a rate of 20 °C/h and a cooling stage from 180 °C to 40 °C with a rate of 10 °C/h. The results show that the hardness and strength increase rapidly during the heating stage of NIA since the increasing temperature favors the nucleation and the growth of strengthening precipitates and promotes the transformation of Guinier-Preston (GPI) zones to η′ phase. During the cooling stage, the sizes of η′ phase increase with a little change in the number density, leading to a further slight increase of the hardness and strength. As NIA proceeds, the corroded morphology in the alloy changes from a layering feature to a wavy feature, the maximum corrosion depth decreases, and the reason has been analyzed based on the microstructural and microchemical feature of precipitates at grain boundaries and subgrain boundaries.

通过硬度试验、电导率试验、拉伸试验、晶间腐蚀试验、剥落腐蚀试验、慢应变速率拉伸试验和电化学试验,研究了高纯度铝锌镁铜合金在非等温时效(NIA)过程中的力学性能和耐局部腐蚀性能的变化,并根据光学显微镜、电子背散射衍射、扫描电子显微镜和扫描透射电子显微镜的微观结构检查探讨了其机理。NIA 处理包括从 40 °C 到 180 °C 的加热阶段和从 180 °C 到 40 °C 的冷却阶段,加热速度为 20 °C/h ,冷却速度为 10 °C/h 。结果表明,在 NIA 的加热阶段,硬度和强度迅速增加,因为温度的升高有利于强化析出物的成核和生长,并促进 Guinier-Preston (GPI) 区向 η′ 相的转变。在冷却阶段,η′相的尺寸增大,但数量密度变化不大,从而导致硬度和强度进一步略微增加。随着 NIA 的进行,合金中的腐蚀形态从分层特征变为波浪特征,最大腐蚀深度减小,其原因已根据晶界和亚晶界析出物的微观结构和微观化学特征进行了分析。
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引用次数: 0
A novel immiscible high entropy alloy strengthened via L12-nanoprecipitate 通过 L12 纳米沉淀强化的新型不相溶高熵合金
IF 4.4 2区 材料科学 Q1 METALLURGY & METALLURGICAL ENGINEERING Pub Date : 2024-07-23 DOI: 10.1007/s11771-024-5683-7
Zheng-qin Wang, Ming-yu Fan, Yang Zhang, Jun-peng Li, Li-yuan Liu, Ji-hong Han, Xing-hao Li, Zhong-wu Zhang

The low-cost Fe-Cu, Fe-Ni, and Cu-based high-entropy alloys exhibit a widespread utilization prospect. However, these potential applications have been limited by their low strength. In this study, a novel Fe31Cu31Ni28Al4Ti3Co3 immiscible high-entropy alloy (HEA) was developed. After vacuum arc melting and copper mold suction casting, this HEA exhibits a unique phase separation microstructure, which consists of striped Cu-rich regions and Fe-rich region. Further magnification of the striped Cu-rich region reveals that it is composed of a Cu-rich dot-like phase and a Fe-rich region. The aging alloy is further strengthened by a L12-Ni3(AlTi) nanoprecipitates, achieving excellent yield strength (1185 MPa) and uniform ductility (∼8.8%). The differential distribution of the L12 nanoprecipitate in the striped Cu-rich region and the external Fe-rich region increased the strength difference between these two regions, which increased the strain gradient and thus improved hetero-deformation induced (HDI) hardening. This work provides a new route to improve the HDI hardening of Fe-Cu alloys.

低成本的铁-铜、铁-镍和铜基高熵合金具有广泛的应用前景。然而,这些合金的低强度限制了其潜在应用。本研究开发了一种新型 Fe31Cu31Ni28Al4Ti3Co3 不相溶高熵合金(HEA)。经过真空电弧熔炼和铜模吸铸后,这种 HEA 呈现出独特的相分离微观结构,由富含铜的条纹区域和富含铁的区域组成。进一步放大条纹状富铜区域,可以发现它是由富铜点状相和富铁区域组成。L12-Ni3(AlTi)纳米沉淀物进一步强化了时效合金,使其获得了优异的屈服强度(1185 兆帕)和均匀的延展性(∼8.8%)。L12 纳米沉淀物在条纹状富铜区域和外部富铁区域的不同分布增加了这两个区域的强度差,从而增加了应变梯度,进而改善了异种变形诱导硬化(HDI)。这项研究为改善铁-铜合金的 HDI 硬化提供了一条新途径。
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引用次数: 0
Effect of temperature on suspension magnetization roasting of hematite using biomass waste as reductant: A perspective of gas evolution 温度对以生物质废料为还原剂的赤铁矿悬浮磁化焙烧的影响:气体演化的视角
IF 4.4 2区 材料科学 Q1 METALLURGY & METALLURGICAL ENGINEERING Pub Date : 2024-07-23 DOI: 10.1007/s11771-024-5691-7
Yue Cao, Yong-sheng Sun, Yue-xin Han, Peng Gao, Yan-jun Li

The magnetization reduction of hematite using biomass waste can effectively utilize waste and reduce CO2 emission to achieve the goals of carbon peaking and carbon neutrality. The effects of temperatures on suspension magnetization roasting of hematite using biomass waste for evolved gases have been investigated using TG-FTIR, Py-GC/MS and gas composition analyzer. The mixture reduction process is divided into four stages. In the temperature range of 200–450 °C for mixture, the release of CO2, acids, and ketones is dominated in gases products. The yield and concentration of small molecules reducing gases increase when the temperature increases from 450 to 900 °C. At 700 °C, the volume concentrations of CO, H2 and CH4 peak at 8.91%, 8.90% and 4.91%, respectively. During the suspension magnetization roasting process, an optimal iron concentrate with an iron grade of 70.86%, a recovery of 98.66% and a magnetic conversion of 45.70% is obtained at 700 °. Therefore, the magnetization reduction could react greatly in the temperature range of 600 to 700 °C owing to the suitable reducing gases. This study shows a detail gaseous evolution of roasting temperature and provides a new insight for studying the reduction process of hematite using biomass waste.

利用生物质废弃物对赤铁矿进行磁化还原,可有效利用废弃物,减少二氧化碳排放,实现碳峰值和碳中和的目标。利用 TG-FTIR、Py-GC/MS 和气体成分分析仪研究了温度对利用生物质废料进行赤铁矿悬浮磁化焙烧产生挥发气体的影响。混合物还原过程分为四个阶段。在混合物 200-450 °C 的温度范围内,气体产物主要是二氧化碳、酸和酮的释放。当温度从 450 ℃ 升至 900 ℃ 时,小分子还原气体的产量和浓度增加。700 °C 时,CO、H2 和 CH4 的体积浓度分别达到 8.91%、8.90% 和 4.91% 的峰值。在悬浮磁化焙烧过程中,700 °时可获得铁品位为 70.86%、回收率为 98.66%、磁转化率为 45.70%的最佳铁精矿。因此,由于使用了合适的还原气体,在 600 至 700 °C 的温度范围内,磁化还原反应非常显著。这项研究详细展示了焙烧温度下的气体演变过程,为研究利用生物废料还原赤铁矿的过程提供了新的视角。
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引用次数: 0
Operation optimization of prefabricated light modular radiant heating system: Thermal resistance analysis and numerical study 预制轻型模块辐射供暖系统的运行优化:热阻分析和数值研究
IF 4.4 2区 材料科学 Q1 METALLURGY & METALLURGICAL ENGINEERING Pub Date : 2024-07-23 DOI: 10.1007/s11771-024-5696-2
Yao Li, Ru-kun Hu, Li Xin, Jie Xue, Fei Huang, Jian-wei Xia, Xiao-hu Yang

The utilization of prefabricated light modular radiant heating system has demonstrated significant increases in heat transfer efficiency and energy conservation capabilities. Within prefabricated building construction, this new heating method presents an opportunity for the development of comprehensive facilities. The parameters for evaluating the effectiveness of such a system are the upper surface layer’s heat flux and temperature. In this paper, thermal resistance analysis calculation based on a simplified model for this unique radiant heating system analysis is presented with the heat transfer mechanism’s evaluation. The results obtained from thermal resistance analysis calculation and numerical simulation indicate that the thermal resistance analysis method is highly accurate with temperature discrepancies ranging from 0.44 °C to −0.44 °C and a heat flux discrepancy of less than 7.54%, which can meet the requirements of practical engineering applications, suggesting a foundation for the prefabricated radiant heating system

预制轻型模块辐射供暖系统的使用表明,其传热效率和节能能力显著提高。在预制建筑结构中,这种新型加热方法为综合设施的发展提供了机遇。评估这种系统有效性的参数是上表面层的热通量和温度。本文介绍了基于简化模型的热阻分析计算,对这种独特的辐射供暖系统进行了分析,并对传热机制进行了评估。热阻分析计算和数值模拟的结果表明,热阻分析方法的精确度很高,温度偏差在 0.44 ℃ 至 -0.44 ℃ 之间,热通量偏差小于 7.54%,能够满足实际工程应用的要求,为预制辐射供暖系统奠定了基础。
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引用次数: 0
Role of outdoor trees on pedestrian wind and thermal conditions around a pre-education building for sustainable energy management 室外树木对学前教育大楼周围行人风和热条件的影响,促进可持续能源管理
IF 4.4 2区 材料科学 Q1 METALLURGY & METALLURGICAL ENGINEERING Pub Date : 2024-07-23 DOI: 10.1007/s11771-024-5694-4
Xiao-jie Li, Hui-li Tang

Finding sustainable energy resources is essential to face the increasing energy demand. Trees are an important part of ancient architecture but are becoming rare in urban areas. Trees can control and tune the pedestrian-level wind velocity and thermal condition. In this study, a numerical investigation is employed to assess the role of trees planted in the windward direction of the building complex on the thermal and pedestrian wind velocity conditions around/inside a pre-education building located in the center of the complex. Compared to the previous studies (which considered only outside buildings), this work considers the effects of trees on microclimate change both inside/outside buildings. Effects of different parameters including the leaf area density and number of trees, number of rows, far-field velocity magnitude, and thermal condition around the main building are assessed. The results show that the flow velocity in the spacing between the first-row buildings is reduced by 30%–40% when the one-row trees with 2 m height are planted 15 m farther than the buildings. Furthermore, two rows of trees are more effective in higher velocities and reduce the maximum velocity by about 50%. The investigation shows that trees also could reduce the temperature by about 1°C around the building.

面对日益增长的能源需求,寻找可持续能源资源至关重要。树木是古代建筑的重要组成部分,但在城市地区却越来越少。树木可以控制和调节人行道上的风速和热状况。本研究采用数值调查的方法,评估了在建筑群的迎风方向种植树木对位于建筑群中心的学前教育大楼周围/内部的热和行人风速条件的影响。与之前的研究(只考虑建筑物外部)相比,本研究同时考虑了树木对建筑物内外微气候变化的影响。研究评估了不同参数的影响,包括树木的叶面积密度和数量、行数、远场速度大小以及主楼周围的热条件。结果表明,当高度为 2 米的单行树木种植在距离建筑物 15 米远的地方时,第一排建筑物间距内的流速会降低 30%-40%。此外,在流速较高的情况下,两排树木的效果更好,可将最大流速降低约 50%。调查显示,树木还能将建筑物周围的温度降低约 1°C。
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引用次数: 0
Ultrahigh strength and improved electrical conductivity in an aging strengthened copper alloy processed by combination of equal channel angular pressing and thermomechanical treatment 等沟道角压和热机械处理相结合的时效强化铜合金的超高强度和更佳导电性能
IF 4.4 2区 材料科学 Q1 METALLURGY & METALLURGICAL ENGINEERING Pub Date : 2024-07-23 DOI: 10.1007/s11771-024-5686-4
Xu Wang, Zhou Li, Xiang-peng Meng, Zhu Xiao

In this paper, equal channel angular pressing and thermomechanical treatment was employed to improve the strength and electrical conductivity of an aging strengthened Cu-Ti-Cr-Mg alloy, and the microstructure and properties of the alloy were investigated in detail. The results showed that the samples deformed by the combination of cryogenic equal channel angular pressing (ECAP) and rolling had good comprehensive properties after aging at 400 °C. The tensile strength of the peak-aged and over-aged samples was 1120 MPa and 940 MPa, with their corresponding electrical conductivity of 14.7%IACS and 22.1%IACS, respectively. ECAP and cryogenic rolling introduced high density dislocations, leading to the inhibition of the softening effects and refinement of the grains. After a long time aging at 400 °C, the alloy exhibited ultra-high strength with obvious increasing electrical conductivity. The high strength was attributed to the synergistic effect of work hardening, grain refinement strengthening and precipitation strengthening. The precipitation of a large amount of Ti atoms from the matrix led to the high electrical conductivity of the over-aged sample.

本文采用等通道角压和热机械处理方法提高了时效强化铜-钛-脆-镁合金的强度和导电性,并详细研究了合金的微观结构和性能。结果表明,通过低温等通道角压(ECAP)和轧制组合变形的样品在 400 °C 老化后具有良好的综合性能。峰值时效和超时效样品的抗拉强度分别为 1120 兆帕和 940 兆帕,相应的导电率分别为 14.7%IACS 和 22.1%IACS。ECAP 和低温轧制引入了高密度位错,从而抑制了软化效应并细化了晶粒。在 400 ℃ 长时间时效后,合金表现出超高强度,同时导电率明显提高。高强度归因于加工硬化、晶粒细化强化和沉淀强化的协同效应。基体中大量 Ti 原子的析出导致了超时效样品的高导电性。
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引用次数: 0
Experimental and numerical investigations on acoustic damping of monoclinic crystalline wideband sound absorbing structures 单晶体宽带吸声结构的声学阻尼实验和数值研究
IF 4.4 2区 材料科学 Q1 METALLURGY & METALLURGICAL ENGINEERING Pub Date : 2024-07-23 DOI: 10.1007/s11771-024-5670-z
Su-chao Xie, Lei He, Hong-yu Yan, Feng-yi Zhang, Guan-di He, Jia-cheng Wang

In order to overcome the limitations of traditional microperforated plate with narrow sound absorption bandwidth and a single structure, two multi-cavity composite sound-absorbing materials were designed based on the shape of monoclinic crystals: uniaxial oblique structure (UOS) and biaxial oblique structure (BOS). Through finite element simulation and experimental research, the theoretical models of UOS and BOS were verified, and their sound absorption mechanisms were revealed. At the same time, the influence of multi-cavity composites on sound absorption performance was analyzed based on the theoretical model, and the influence of structural parameters on sound absorption performance was discussed. The research results show that, in the range of 100–2000 Hz, UOS has three sound absorption peaks and BOS has five sound absorption peaks. The frequency range of the half-absorption bandwidth (α>0.5) of UOS and BOS increases by 242% and 229%, respectively. Compared with traditional microperforated sound-absorbing structures, the series and parallel hybrid methods significantly increase the sound-absorbing bandwidth of the sound-absorbing structure. This research has guiding significance for noise control and has broad application prospects in the fields of transportation, construction, and mechanical design.

为了克服传统微穿孔板吸声带宽窄、结构单一的局限性,设计了两种基于单斜晶体形状的多腔复合吸声材料:单轴斜结构(UOS)和双轴斜结构(BOS)。通过有限元模拟和实验研究,验证了 UOS 和 BOS 的理论模型,揭示了它们的吸声机理。同时,基于理论模型分析了多腔复合材料对吸声性能的影响,讨论了结构参数对吸声性能的影响。研究结果表明,在 100-2000 Hz 范围内,UOS 有三个吸声峰值,BOS 有五个吸声峰值。UOS 和 BOS 的半吸声带宽(α>0.5)频率范围分别增加了 242% 和 229%。与传统的微穿孔吸声结构相比,串联和并联混合法显著提高了吸声结构的吸声带宽。该研究对噪声控制具有指导意义,在交通、建筑、机械设计等领域具有广阔的应用前景。
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引用次数: 0
A review on the cooling of energy conversion and storage systems using thermoelectric modules 利用热电模块冷却能量转换和储存系统综述
IF 4.4 2区 材料科学 Q1 METALLURGY & METALLURGICAL ENGINEERING Pub Date : 2024-07-23 DOI: 10.1007/s11771-023-5529-8
Amirreza Ijadi, Mehran Rajabi Zargarabadi, Saman Rashidi, Amir Mohammad Jadidi

Exploitation of sustainable energy sources requires the use of unique conversion and storage systems, such as solar panels, batteries, fuel cells, and electronic equipment. Thermal load management of these energy conversion and storage systems is one of their challenges and concerns. In this article, the thermal management of these systems using thermoelectric modules is reviewed. The results show that by choosing the right option to remove heat from the hot side of the thermoelectric modules, it will be a suitable local cooling, and the thermoelectric modules increase the power and lifespan of the system by reducing the spot temperature. Thermoelectric modules were effective in reducing panel temperature. They increase the time to reach a temperature above 50 °C in batteries by 3 to 4 times. Also, in their integration with fuel cells, they increase the power density of the fuel cell.

开发可持续能源需要使用独特的转换和存储系统,如太阳能电池板、蓄电池、燃料电池和电子设备。这些能源转换和存储系统的热负荷管理是其面临的挑战和关注的问题之一。本文回顾了使用热电模块对这些系统进行热管理的情况。研究结果表明,通过选择正确的方案从热电模块的热侧带走热量,可以实现适当的局部冷却,热电模块通过降低点温度提高了系统的功率和寿命。热电模块能有效降低面板温度。它们将电池温度达到 50 °C 以上的时间延长了 3 到 4 倍。此外,在与燃料电池集成时,它们还能提高燃料电池的功率密度。
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引用次数: 0
Performance improvement in stepped solar still modified by sponge layer 利用海绵层改善阶梯式太阳能蒸发器的性能
IF 4.4 2区 材料科学 Q1 METALLURGY & METALLURGICAL ENGINEERING Pub Date : 2024-07-23 DOI: 10.1007/s11771-024-5693-5
Mahtab Tarahomi, Saman Rashidi, Faramarz Hormozi, Shahabeddin Ashtiani

In this paper, the experimental investigation on the performance improvement of conventional stepped solar still is conducted. The steps are covered by the porous material to improve the performance of the conventional device and increase the evaporation rate. All the parameters, including the temperature on the glass surface, the water temperature inside the evaporation zone, and the amount of water produced in both conventional and modified stepped solar stills are measured and compared. The efficiency of two devices and their exergy efficiency have been calculated. Finally, the economic analysis of both devices has been done to check the economic feasibility of the modified device. The amount of freshwater generated during one day was 2244.4 and 3076.2 mL/m2, respectively for the conventional and modified stepped solar stills. As a result, the amount of water produced in one day by modified stepped solar still is 35.5% more than the conventional one. Also, the costs for the conventional and modified stepped solar stills have been calculated as 0.0359 and 0.029 $/(L·m−2), respectively.

本文对传统阶梯式太阳能蒸发器的性能改进进行了实验研究。多孔材料覆盖的阶梯改善了常规装置的性能,提高了蒸发率。测量并比较了所有参数,包括玻璃表面的温度、蒸发区内的水温以及传统阶梯式太阳能蒸馏器和改进型阶梯式太阳能蒸馏器的产水量。计算了两种装置的效率及其放能效率。最后,还对两种装置进行了经济分析,以检验改进装置的经济可行性。传统型和改进型阶梯式太阳能蒸馏器一天内产生的淡水量分别为 2244.4 mL/m2 和 3076.2 mL/m2。因此,改进型阶梯式太阳能蒸馏器一天的产水量比传统蒸馏器多 35.5%。此外,根据计算,传统和改进型阶梯式太阳能蒸馏器的成本分别为 0.0359 和 0.029 美元/(L-m-2)。
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引用次数: 0
Industrial utilization of arsenic-containing gold dressing tailings as pellet prepared by straight grate process 以直篦法制备的球团形式对含砷选金尾矿进行工业利用
IF 4.4 2区 材料科学 Q1 METALLURGY & METALLURGICAL ENGINEERING Pub Date : 2024-07-23 DOI: 10.1007/s11771-024-5690-8
Wei Liu, Zheng-qi Guo, De-qing Zhu, Jian Pan, Wu-ju Zhang, Jin Wang, Ying-qun Zhang, Fu-xing Yin

The utilization of arsenic-containing gold dressing tailings is an urgent issue faced by gold production companies worldwide. The thermodynamic analysis results indicate that ferrous arsenate (FeAsO4), pyrite (FeS2) and sodium cyanide (NaCN) in the arsenic-containing gold metallurgical tailings can be effectively removed using straight grate process, and the removal of pyrite and sodium cyanide is basically completed during the preheating stage, while the removal of ferrous arsenate requires the roasting stage. The pellets undergo a transformation from magnetite to hematite during the preheating process, and are solidified through micro-crystalline bonding and high-temperature recrystallization of hematite (Fe2O3) during the roasting process. Ultimately, pellets with removal rates of 80.77% for arsenic, 88.78% for sulfur, and 99.88% for cyanide are obtained, as well as the iron content is 61.1% and the compressive strength is 3071 N, meeting the requirements for blast furnace burden. This study provides an industrially feasible method for treating arsenic-containing gold smelting tailings, benefiting gold production enterprises.

含砷金选矿尾矿的利用是全球黄金生产企业面临的一个紧迫问题。热力学分析结果表明,采用直篦式工艺可有效去除含砷金选冶尾矿中的砷酸亚铁(FeAsO4)、黄铁矿(FeS2)和氰化钠(NaCN),黄铁矿和氰化钠的去除在预热阶段基本完成,而砷酸亚铁的去除则需要焙烧阶段。球团在预热过程中经历了从磁铁矿到赤铁矿的转变,并在焙烧过程中通过赤铁矿(Fe2O3)的微晶结合和高温再结晶而固化。最终得到的球团砷去除率为 80.77%,硫去除率为 88.78%,氰化物去除率为 99.88%,铁含量为 61.1%,抗压强度为 3071 N,满足高炉炉料的要求。该研究为处理含砷黄金冶炼尾矿提供了一种工业上可行的方法,有利于黄金生产企业。
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引用次数: 0
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Journal of Central South University
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