This study aims to evaluate the solar and wind energy potential across Razavi Khorasan Province, Iran, with a specific focus on the Khaf region. A preliminary assessment of mean solar radiation, mean wind speeds, and Weibull distribution parameters was conducted for different towns and zones within the province. The findings showed that Khaf has favorable characteristics for further analysis. The solar and wind energy metrics examined include global horizontal irradiance, clearness index, wind rose patterns, and turbulence intensity. At a height of 40 m, Khaf’s wind power density reached 1650 W/m2, indicating exceptional wind energy generation potential. Additionally, Khaf received an average annual solar radiation of 2046 kW·h/m2, representing significant solar energy potential. Harnessing these substantial renewable resources in Khaf could allow Razavi Khorasan Province to reduce reliance on fossil fuels, improve energy sustainability, and mitigate climate change impacts. This research contributes an in-depth assessment of Razavi Khorasan’s solar and wind energy potential, particularly for the promising Khaf region. Further work may examine optimal sites for renewable energy projects and grid integration strategies to leverage these resources.
{"title":"Solar and wind energy potential assessment for Razavi Khorasan Province in Iran","authors":"Amirpouya Hosseini, Faeze Ramezani, Mojtaba Mirhosseini","doi":"10.1007/s11771-023-5535-x","DOIUrl":"https://doi.org/10.1007/s11771-023-5535-x","url":null,"abstract":"<p>This study aims to evaluate the solar and wind energy potential across Razavi Khorasan Province, Iran, with a specific focus on the Khaf region. A preliminary assessment of mean solar radiation, mean wind speeds, and Weibull distribution parameters was conducted for different towns and zones within the province. The findings showed that Khaf has favorable characteristics for further analysis. The solar and wind energy metrics examined include global horizontal irradiance, clearness index, wind rose patterns, and turbulence intensity. At a height of 40 m, Khaf’s wind power density reached 1650 W/m<sup>2</sup>, indicating exceptional wind energy generation potential. Additionally, Khaf received an average annual solar radiation of 2046 kW·h/m<sup>2</sup>, representing significant solar energy potential. Harnessing these substantial renewable resources in Khaf could allow Razavi Khorasan Province to reduce reliance on fossil fuels, improve energy sustainability, and mitigate climate change impacts. This research contributes an in-depth assessment of Razavi Khorasan’s solar and wind energy potential, particularly for the promising Khaf region. Further work may examine optimal sites for renewable energy projects and grid integration strategies to leverage these resources.</p>","PeriodicalId":15231,"journal":{"name":"Journal of Central South University","volume":"42 1","pages":""},"PeriodicalIF":4.4,"publicationDate":"2024-07-23","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"141782955","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2024-07-23DOI: 10.1007/s11771-024-5663-y
Xiao-hui Liu, Qi-jun Hao, Yu Zheng, Zhao-peng Zhang, Yang Xue
Dilatancy is a fundamental volumetric growth behavior observed during loading and serves as a key index to comprehending the intricate nonlinear behavior and constitutive equation structure of rock. This study focuses on Jinping marble obtained from the Jinping Underground Laboratory in China at a depth of 2400 m. Various uniaxial and triaxial tests at different strain rates, along with constant confining pressure tests and reduced confining pressure tests under different confining pressures were conducted to analyze the mechanical response and dilatancy characteristics of the marble under four stress paths. Subsequently, a new empirical dilatancy coefficient is proposed based on the energy dissipation method. The results show that brittle failure characteristics of marble under uniaxial compression are more obvious with the strain rate increasing, and plastic failure characteristics of marble under triaxial compression are gradually strengthened. Furthermore, compared to the constant confining pressure, the volume expansion is relatively lower under unloading condition. The energy dissipation is closely linked to the process of dilatancy, with a rapid increase of dissipated energy coinciding with the beginning of dilatancy. A new empirical dilatancy coefficient is defined according to the change trend of energy dissipation rate curve, of which change trend is consistent with the actual dilatancy response in marble under different stress paths. The existing empirical and theoretical dilatancy models are analyzed, which shows that the empirical dilatancy coefficient based on the energy background is more universal.
{"title":"Mechanical response and dilatancy characteristics of deep marble under different stress paths: A sight from energy dissipation","authors":"Xiao-hui Liu, Qi-jun Hao, Yu Zheng, Zhao-peng Zhang, Yang Xue","doi":"10.1007/s11771-024-5663-y","DOIUrl":"https://doi.org/10.1007/s11771-024-5663-y","url":null,"abstract":"<p>Dilatancy is a fundamental volumetric growth behavior observed during loading and serves as a key index to comprehending the intricate nonlinear behavior and constitutive equation structure of rock. This study focuses on Jinping marble obtained from the Jinping Underground Laboratory in China at a depth of 2400 m. Various uniaxial and triaxial tests at different strain rates, along with constant confining pressure tests and reduced confining pressure tests under different confining pressures were conducted to analyze the mechanical response and dilatancy characteristics of the marble under four stress paths. Subsequently, a new empirical dilatancy coefficient is proposed based on the energy dissipation method. The results show that brittle failure characteristics of marble under uniaxial compression are more obvious with the strain rate increasing, and plastic failure characteristics of marble under triaxial compression are gradually strengthened. Furthermore, compared to the constant confining pressure, the volume expansion is relatively lower under unloading condition. The energy dissipation is closely linked to the process of dilatancy, with a rapid increase of dissipated energy coinciding with the beginning of dilatancy. A new empirical dilatancy coefficient is defined according to the change trend of energy dissipation rate curve, of which change trend is consistent with the actual dilatancy response in marble under different stress paths. The existing empirical and theoretical dilatancy models are analyzed, which shows that the empirical dilatancy coefficient based on the energy background is more universal.</p>","PeriodicalId":15231,"journal":{"name":"Journal of Central South University","volume":"38 1","pages":""},"PeriodicalIF":4.4,"publicationDate":"2024-07-23","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"141782956","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
The long-term storage of phosphate tailings will occupy a large amount of land, pollute soil and groundwater, thus, it is crucial to achieve the harmless disposal of phosphate tailings. In this study, high-performance geopolymers with compressive strength of 38.8 MPa were prepared by using phosphate tailings as the main raw material, fly ash as the active silicon-aluminum material, and water glass as the alkaline activator. The solid content of phosphate tailings and fly ash was 60% and 40%, respectively, and the water-cement ratio was 0.22. The results of XRD, FTIR, SEM-EDS and XPS show that the reactivity of phosphate tailings with alkaline activator is weak, and the silicon-aluminum material can react with alkaline activator to form zeolite and gel, and encapsulate/cover the phosphate tailings to form a dense phosphate tailings-based geopolymer. During the formation of geopolymers, part of the aluminum-oxygen tetrahedron replaced the silicon-oxygen tetrahedron, causing the polycondensation reaction between geopolymers and increasing the strength of geopolymers. The leaching toxicity test results show that the geopolymer has a good solid sealing effect on heavy metal ions. The preparation of geopolymer from phosphate tailings is an important way to alleviate the storage pressure and realize the resource utilization of phosphate tailings.
{"title":"Preparation and interface state of phosphate tailing-based geopolymers","authors":"Shou-xun Zhang, Xian Xie, Rui-qi Xie, Xiong Tong, Yu-yao Wu, Jia-wen Li, Yue Li","doi":"10.1007/s11771-024-5669-5","DOIUrl":"https://doi.org/10.1007/s11771-024-5669-5","url":null,"abstract":"<p>The long-term storage of phosphate tailings will occupy a large amount of land, pollute soil and groundwater, thus, it is crucial to achieve the harmless disposal of phosphate tailings. In this study, high-performance geopolymers with compressive strength of 38.8 MPa were prepared by using phosphate tailings as the main raw material, fly ash as the active silicon-aluminum material, and water glass as the alkaline activator. The solid content of phosphate tailings and fly ash was 60% and 40%, respectively, and the water-cement ratio was 0.22. The results of XRD, FTIR, SEM-EDS and XPS show that the reactivity of phosphate tailings with alkaline activator is weak, and the silicon-aluminum material can react with alkaline activator to form zeolite and gel, and encapsulate/cover the phosphate tailings to form a dense phosphate tailings-based geopolymer. During the formation of geopolymers, part of the aluminum-oxygen tetrahedron replaced the silicon-oxygen tetrahedron, causing the polycondensation reaction between geopolymers and increasing the strength of geopolymers. The leaching toxicity test results show that the geopolymer has a good solid sealing effect on heavy metal ions. The preparation of geopolymer from phosphate tailings is an important way to alleviate the storage pressure and realize the resource utilization of phosphate tailings.</p>","PeriodicalId":15231,"journal":{"name":"Journal of Central South University","volume":"32 1","pages":""},"PeriodicalIF":4.4,"publicationDate":"2024-07-23","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"141782948","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2024-07-23DOI: 10.1007/s11771-024-5665-9
Heng-hong Yang, Ming-nian Wang, Li Yu, Xiao Zhang
The tunnel subjected to strike-slip fault dislocation exhibits severe and catastrophic damage. The existing analysis models frequently assume uniform fault displacement and fixed fault plane position. In contrast, post-earthquake observations indicate that the displacement near the fault zone is typically nonuniform, and the fault plane position is uncertain. In this study, we first established a series of improved governing equations to analyze the mechanical response of tunnels under strike-slip fault dislocation. The proposed methodology incorporated key factors such as nonuniform fault displacement and uncertain fault plane position into the governing equations, thereby significantly enhancing the applicability range and accuracy of the model. In contrast to previous analytical models, the maximum computational error has decreased from 57.1% to 1.1%. Subsequently, we conducted a rigorous validation of the proposed methodology by undertaking a comparative analysis with a 3D finite element numerical model, and the results from both approaches exhibited a high degree of qualitative and quantitative agreement with a maximum error of 9.9%. Finally, the proposed methodology was utilized to perform a parametric analysis to explore the effects of various parameters, such as fault displacement, fault zone width, fault zone strength, the ratio of maximum fault displacement of the hanging wall to the footwall, and fault plane position, on the response of tunnels subjected to strike-slip fault dislocation. The findings indicate a progressive increase in the peak internal forces of the tunnel with the rise in fault displacement and fault zone strength. Conversely, an augmentation in fault zone width is found to contribute to a decrease in the peak internal forces. For example, for a fault zone width of 10 m, the peak values of bending moment, shear force, and axial force are approximately 46.9%, 102.4%, and 28.7% higher, respectively, compared to those observed for a fault zone width of 50 m. Furthermore, the position of the peak internal forces is influenced by variations in the ratio of maximum fault displacement of the hanging wall to footwall and the fault plane location, while the peak values of shear force and axial force always align with the fault plane. The maximum peak internal forces are observed when the footwall exclusively bears the entirety of the fault displacement, corresponding to a ratio of 0: 1. The peak values of bending moment, shear force, and axial force for the ratio of 0:1 amount to approximately 123.8%, 148.6%, and 111.1% of those for the ratio of 0.5:0.5, respectively.
{"title":"Semi-analytical solution for mechanical analysis of tunnels crossing strike-slip fault zone considering nonuniform fault displacement and uncertain fault plane position","authors":"Heng-hong Yang, Ming-nian Wang, Li Yu, Xiao Zhang","doi":"10.1007/s11771-024-5665-9","DOIUrl":"https://doi.org/10.1007/s11771-024-5665-9","url":null,"abstract":"<p>The tunnel subjected to strike-slip fault dislocation exhibits severe and catastrophic damage. The existing analysis models frequently assume uniform fault displacement and fixed fault plane position. In contrast, post-earthquake observations indicate that the displacement near the fault zone is typically nonuniform, and the fault plane position is uncertain. In this study, we first established a series of improved governing equations to analyze the mechanical response of tunnels under strike-slip fault dislocation. The proposed methodology incorporated key factors such as nonuniform fault displacement and uncertain fault plane position into the governing equations, thereby significantly enhancing the applicability range and accuracy of the model. In contrast to previous analytical models, the maximum computational error has decreased from 57.1% to 1.1%. Subsequently, we conducted a rigorous validation of the proposed methodology by undertaking a comparative analysis with a 3D finite element numerical model, and the results from both approaches exhibited a high degree of qualitative and quantitative agreement with a maximum error of 9.9%. Finally, the proposed methodology was utilized to perform a parametric analysis to explore the effects of various parameters, such as fault displacement, fault zone width, fault zone strength, the ratio of maximum fault displacement of the hanging wall to the footwall, and fault plane position, on the response of tunnels subjected to strike-slip fault dislocation. The findings indicate a progressive increase in the peak internal forces of the tunnel with the rise in fault displacement and fault zone strength. Conversely, an augmentation in fault zone width is found to contribute to a decrease in the peak internal forces. For example, for a fault zone width of 10 m, the peak values of bending moment, shear force, and axial force are approximately 46.9%, 102.4%, and 28.7% higher, respectively, compared to those observed for a fault zone width of 50 m. Furthermore, the position of the peak internal forces is influenced by variations in the ratio of maximum fault displacement of the hanging wall to footwall and the fault plane location, while the peak values of shear force and axial force always align with the fault plane. The maximum peak internal forces are observed when the footwall exclusively bears the entirety of the fault displacement, corresponding to a ratio of 0: 1. The peak values of bending moment, shear force, and axial force for the ratio of 0:1 amount to approximately 123.8%, 148.6%, and 111.1% of those for the ratio of 0.5:0.5, respectively.</p>","PeriodicalId":15231,"journal":{"name":"Journal of Central South University","volume":"72 1","pages":""},"PeriodicalIF":4.4,"publicationDate":"2024-07-23","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"141782970","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2024-07-23DOI: 10.1007/s11771-023-5494-2
Verma Lalchand, Meher Ramakanta
This study considers an MHD Jeffery-Hamel nanofluid flow with distinct nanoparticles such as copper, Al2O3 and SiO2 between two rigid non-parallel plane walls with the fuzzy extension of the generalized dual parametric homotopy algorithm. The nanofluids have been formulated to enhance the thermophysical characteristics of fluids, including thermal diffusivity, conductivity, convective heat transfer coefficients and viscosity. Due to the presence of distinct nanofluids, a change in the value of volume fraction occurs that influences the velocity profiles of the flow. The short value of nanoparticles volume fraction is considered an uncertain parameter and represented in a triangular fuzzy number range among [0.0, 0.1, 0.2]. A novel generalized dual parametric homotopy algorithm with fuzzy extension is used here to study the fuzzy velocities at various channel positions. Finally, the effectiveness of the proposed approach has been demonstrated through a comparison with the available results in the crisp case.
{"title":"Numerical investigation on MHD Jeffery-Hamel nanofluid flow with different nanoparticles using fuzzy extension of generalized dual parametric homotopy algorithm","authors":"Verma Lalchand, Meher Ramakanta","doi":"10.1007/s11771-023-5494-2","DOIUrl":"https://doi.org/10.1007/s11771-023-5494-2","url":null,"abstract":"<p>This study considers an MHD Jeffery-Hamel nanofluid flow with distinct nanoparticles such as copper, Al<sub>2</sub>O<sub>3</sub> and SiO<sub>2</sub> between two rigid non-parallel plane walls with the fuzzy extension of the generalized dual parametric homotopy algorithm. The nanofluids have been formulated to enhance the thermophysical characteristics of fluids, including thermal diffusivity, conductivity, convective heat transfer coefficients and viscosity. Due to the presence of distinct nanofluids, a change in the value of volume fraction occurs that influences the velocity profiles of the flow. The short value of nanoparticles volume fraction is considered an uncertain parameter and represented in a triangular fuzzy number range among [0.0, 0.1, 0.2]. A novel generalized dual parametric homotopy algorithm with fuzzy extension is used here to study the fuzzy velocities at various channel positions. Finally, the effectiveness of the proposed approach has been demonstrated through a comparison with the available results in the crisp case.</p>","PeriodicalId":15231,"journal":{"name":"Journal of Central South University","volume":"66 1","pages":""},"PeriodicalIF":4.4,"publicationDate":"2024-07-23","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"141782897","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2024-07-23DOI: 10.1007/s11771-024-5675-7
Jin-hai Zhang, Kai-bo Nie, Jin-hua Zhang, Kun-kun Deng, Zhi-long Liu
In this study, the Mg-3Zn-0.5Zr-χNd (χ=0, 0.6) alloys were subjected to final rolling treatment with large deformation of 50%. The impact of annealing temperatures on the microstructure and mechanical properties was investigated. The rolled Mg-3Zn-0.5Zr-0.6Nd alloy exhibited an ultimate tensile strength of 386 MPa, a yield strength of 361 MPa, and an elongation of 7.1%. Annealing at different temperatures resulted in reduced strength and obviously increased elongation for both alloys. Optimal mechanical properties for the Mg-3Zn-0.5Zr-0.6Nd alloy were achieved after annealing at 200 °C, with an ultimate tensile strength of 287 MPa, a yield strength of 235 MPa, and an elongation of 26.1%. The numerous deformed microstructures, twins, and precipitated phases in the rolled alloy could impede the deformation at room temperature and increase the work hardening rate. After annealing, a decrease in the work hardening effect and an increase in the dynamic recovery effect were obtained due to the formation of fine equiaxed grains, and the increased volume fraction of precipitated phases, which significantly improved the elongation of the alloy. Additionally, the addition of Nd element could enhance the annealing recrystallization rate, reduce the Schmid factor difference between basal and prismatic slip systems, facilitate multi-system slip initiation and improve the alloy plasticity.
{"title":"Effect of annealing temperature on microstructure and mechanical properties of Mg-Zn-Zr-Nd alloy with large final rolling deformation","authors":"Jin-hai Zhang, Kai-bo Nie, Jin-hua Zhang, Kun-kun Deng, Zhi-long Liu","doi":"10.1007/s11771-024-5675-7","DOIUrl":"https://doi.org/10.1007/s11771-024-5675-7","url":null,"abstract":"<p>In this study, the Mg-3Zn-0.5Zr-<i>χ</i>Nd (<i>χ</i>=0, 0.6) alloys were subjected to final rolling treatment with large deformation of 50%. The impact of annealing temperatures on the microstructure and mechanical properties was investigated. The rolled Mg-3Zn-0.5Zr-0.6Nd alloy exhibited an ultimate tensile strength of 386 MPa, a yield strength of 361 MPa, and an elongation of 7.1%. Annealing at different temperatures resulted in reduced strength and obviously increased elongation for both alloys. Optimal mechanical properties for the Mg-3Zn-0.5Zr-0.6Nd alloy were achieved after annealing at 200 °C, with an ultimate tensile strength of 287 MPa, a yield strength of 235 MPa, and an elongation of 26.1%. The numerous deformed microstructures, twins, and precipitated phases in the rolled alloy could impede the deformation at room temperature and increase the work hardening rate. After annealing, a decrease in the work hardening effect and an increase in the dynamic recovery effect were obtained due to the formation of fine equiaxed grains, and the increased volume fraction of precipitated phases, which significantly improved the elongation of the alloy. Additionally, the addition of Nd element could enhance the annealing recrystallization rate, reduce the Schmid factor difference between basal and prismatic slip systems, facilitate multi-system slip initiation and improve the alloy plasticity.</p>","PeriodicalId":15231,"journal":{"name":"Journal of Central South University","volume":"52 1","pages":""},"PeriodicalIF":4.4,"publicationDate":"2024-07-23","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"141782899","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2024-07-23DOI: 10.1007/s11771-023-5335-3
Fatih Selimefendigil, Seda Özcan Çoban, Hakan F. Öztop
Heat and mass transfer of a circular-shaped porous moist object inside a two-dimensional triangle cavity is investigated by using finite element method. The porous object is considered to be a moist food sample, located in the middle of the cavity with inlet and outlet ports with different configurations of inlet/outlet ports. Convective drying performance is numerically assessed for different values of Reynolds numbers (between 50 and 250), dry air inlet temperature (between 40 and 80 °C) and different locations of the port. It is observed that changing the port locations has significant impacts on the flow recirculaitons inside the triangular chamber while convective drying performance is highly affected. The moisture content reduces with longer time and for higher Reynolds number (Re) values. Case P4 where inlet and outlet ports are in the middle of the walls provides the most effective configuration in terms of convective drying performance while the worst case is seen for P1 case where inlet and outlet are closer to the corners of the chamber. There is a 192% difference between the moisture reduction of these two cases at Re=250, T=80 °C and t=120 min.
{"title":"Heat and mass transfer of a circular porous moist object located in a triangular shaped vented cavity","authors":"Fatih Selimefendigil, Seda Özcan Çoban, Hakan F. Öztop","doi":"10.1007/s11771-023-5335-3","DOIUrl":"https://doi.org/10.1007/s11771-023-5335-3","url":null,"abstract":"<p>Heat and mass transfer of a circular-shaped porous moist object inside a two-dimensional triangle cavity is investigated by using finite element method. The porous object is considered to be a moist food sample, located in the middle of the cavity with inlet and outlet ports with different configurations of inlet/outlet ports. Convective drying performance is numerically assessed for different values of Reynolds numbers (between 50 and 250), dry air inlet temperature (between 40 and 80 °C) and different locations of the port. It is observed that changing the port locations has significant impacts on the flow recirculaitons inside the triangular chamber while convective drying performance is highly affected. The moisture content reduces with longer time and for higher Reynolds number (<i>Re</i>) values. Case P4 where inlet and outlet ports are in the middle of the walls provides the most effective configuration in terms of convective drying performance while the worst case is seen for P1 case where inlet and outlet are closer to the corners of the chamber. There is a 192% difference between the moisture reduction of these two cases at <i>Re</i>=250, <i>T</i>=80 °C and <i>t</i>=120 min.</p>","PeriodicalId":15231,"journal":{"name":"Journal of Central South University","volume":"105 1","pages":""},"PeriodicalIF":4.4,"publicationDate":"2024-07-23","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"141782950","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2024-07-23DOI: 10.1007/s11771-024-5689-1
Si-lei Gao, Jian-she Tang, Li Xiang, Jin-wei Long
Manganese ferrite (MnFe2O4) has the advantages of simple preparation, high resistivity, and high crystal symmetry. Herein, we have developed an electrochemical sensor utilizing graphene and MnFe2O4 nanocomposites modified glassy carbon electrode (GCE), which is very efficient and sensitive to detect bisphenol A (BPA). MnFe2O4/graphene (GR) was synthesized by immobilizing the MnFe2O4 microspheres on the graphene nanosheets via a simple one-pot solvothermal method. The morphology and structure of the MnFe2O4/GR nanocomposite have been characterized through scanning electron microscopy (SEM), Fourier transform infrared spectroscopy (FT-IR), X-ray diffraction (XRD) and X-ray photoelectron spectroscopy (XPS). In addition, electrochemical properties of the modified materials are comparably explored by means of cyclic voltammetry (CV), electrochemical impedance spectroscopy (EIS) and differential pulse voltammetry (DPV). Under the optimal conditions, the proposed electrochemical sensor for the detection of BPA has a linear range of 0.8–400 µmol/L and a detection limit of 0.0235 µmol/L (S/N=3) with high sensitivity, good selectivity and high stability. In addition, the proposed sensor was used to measure the content of BPA in real water samples with a recovery rate of 97.94%–104.56%. At present, the synthesis of MnFe2O4/GR provides more opportunities for the electrochemical detection of BPA in practical applications.
锰铁氧体(MnFe2O4)具有制备简单、电阻率高、晶体对称性强等优点。在此,我们开发了一种利用石墨烯和 MnFe2O4 纳米复合材料修饰的玻璃碳电极(GCE)的电化学传感器,它能非常高效、灵敏地检测双酚 A(BPA)。MnFe2O4/ 石墨烯(GR)是通过简单的一锅溶热法将 MnFe2O4 微球固定在石墨烯纳米片上合成的。通过扫描电子显微镜(SEM)、傅立叶变换红外光谱(FT-IR)、X 射线衍射(XRD)和 X 射线光电子能谱(XPS)对 MnFe2O4/GR 纳米复合材料的形貌和结构进行了表征。此外,还通过循环伏安法(CV)、电化学阻抗谱法(EIS)和微分脉冲伏安法(DPV)对改性材料的电化学特性进行了比较研究。在最佳条件下,所提出的检测双酚 A 的电化学传感器的线性范围为 0.8-400 µmol/L,检测限为 0.0235 µmol/L(S/N=3),具有灵敏度高、选择性好和稳定性高等特点。此外,该传感器还被用于测量实际水样中双酚 A 的含量,回收率为 97.94%-104.56%。目前,MnFe2O4/GR 的合成为实际应用中双酚 A 的电化学检测提供了更多机会。
{"title":"Fabrication of a novel electrochemical sensor based on MnFe2O4/graphene modified glassy carbon electrode for the sensitive detection of bisphenol A","authors":"Si-lei Gao, Jian-she Tang, Li Xiang, Jin-wei Long","doi":"10.1007/s11771-024-5689-1","DOIUrl":"https://doi.org/10.1007/s11771-024-5689-1","url":null,"abstract":"<p>Manganese ferrite (MnFe<sub>2</sub>O<sub>4</sub>) has the advantages of simple preparation, high resistivity, and high crystal symmetry. Herein, we have developed an electrochemical sensor utilizing graphene and MnFe<sub>2</sub>O<sub>4</sub> nanocomposites modified glassy carbon electrode (GCE), which is very efficient and sensitive to detect bisphenol A (BPA). MnFe<sub>2</sub>O<sub>4</sub>/graphene (GR) was synthesized by immobilizing the MnFe<sub>2</sub>O<sub>4</sub> microspheres on the graphene nanosheets via a simple one-pot solvothermal method. The morphology and structure of the MnFe<sub>2</sub>O<sub>4</sub>/GR nanocomposite have been characterized through scanning electron microscopy (SEM), Fourier transform infrared spectroscopy (FT-IR), X-ray diffraction (XRD) and X-ray photoelectron spectroscopy (XPS). In addition, electrochemical properties of the modified materials are comparably explored by means of cyclic voltammetry (CV), electrochemical impedance spectroscopy (EIS) and differential pulse voltammetry (DPV). Under the optimal conditions, the proposed electrochemical sensor for the detection of BPA has a linear range of 0.8–400 µmol/L and a detection limit of 0.0235 µmol/L (S/N=3) with high sensitivity, good selectivity and high stability. In addition, the proposed sensor was used to measure the content of BPA in real water samples with a recovery rate of 97.94%–104.56%. At present, the synthesis of MnFe<sub>2</sub>O<sub>4</sub>/GR provides more opportunities for the electrochemical detection of BPA in practical applications.</p>","PeriodicalId":15231,"journal":{"name":"Journal of Central South University","volume":"31 1","pages":""},"PeriodicalIF":4.4,"publicationDate":"2024-07-23","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"141782951","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2024-07-23DOI: 10.1007/s11771-024-5688-2
Xuan-xuan Dai, Yu-zhang Li, Sheng-dan Liu, Ling-ying Ye, Chong-jun Bao
The evolution of mechanical properties, localized corrosion resistance of a high purity Al-Zn-Mg-Cu alloy during non-isothermal aging (NIA) was investigated by hardness test, electrical conductivity test, tensile test, intergranular corrosion test, exfoliation corrosion test, slow strain rate tensile test and electrochemical test, and the mechanism has been discussed based on microstructure examination by optical microscopy, electron back scattered diffraction, scanning electron microscopy and scanning transmission electron microscopy. The NIA treatment includes a heating stage from 40 °C to 180 °C with a rate of 20 °C/h and a cooling stage from 180 °C to 40 °C with a rate of 10 °C/h. The results show that the hardness and strength increase rapidly during the heating stage of NIA since the increasing temperature favors the nucleation and the growth of strengthening precipitates and promotes the transformation of Guinier-Preston (GPI) zones to η′ phase. During the cooling stage, the sizes of η′ phase increase with a little change in the number density, leading to a further slight increase of the hardness and strength. As NIA proceeds, the corroded morphology in the alloy changes from a layering feature to a wavy feature, the maximum corrosion depth decreases, and the reason has been analyzed based on the microstructural and microchemical feature of precipitates at grain boundaries and subgrain boundaries.
通过硬度试验、电导率试验、拉伸试验、晶间腐蚀试验、剥落腐蚀试验、慢应变速率拉伸试验和电化学试验,研究了高纯度铝锌镁铜合金在非等温时效(NIA)过程中的力学性能和耐局部腐蚀性能的变化,并根据光学显微镜、电子背散射衍射、扫描电子显微镜和扫描透射电子显微镜的微观结构检查探讨了其机理。NIA 处理包括从 40 °C 到 180 °C 的加热阶段和从 180 °C 到 40 °C 的冷却阶段,加热速度为 20 °C/h ,冷却速度为 10 °C/h 。结果表明,在 NIA 的加热阶段,硬度和强度迅速增加,因为温度的升高有利于强化析出物的成核和生长,并促进 Guinier-Preston (GPI) 区向 η′ 相的转变。在冷却阶段,η′相的尺寸增大,但数量密度变化不大,从而导致硬度和强度进一步略微增加。随着 NIA 的进行,合金中的腐蚀形态从分层特征变为波浪特征,最大腐蚀深度减小,其原因已根据晶界和亚晶界析出物的微观结构和微观化学特征进行了分析。
{"title":"Evolution of mechanical properties, localized corrosion resistance and microstructure of a high purity Al-Zn-Mg-Cu alloy during non-isothermal aging","authors":"Xuan-xuan Dai, Yu-zhang Li, Sheng-dan Liu, Ling-ying Ye, Chong-jun Bao","doi":"10.1007/s11771-024-5688-2","DOIUrl":"https://doi.org/10.1007/s11771-024-5688-2","url":null,"abstract":"<p>The evolution of mechanical properties, localized corrosion resistance of a high purity Al-Zn-Mg-Cu alloy during non-isothermal aging (NIA) was investigated by hardness test, electrical conductivity test, tensile test, intergranular corrosion test, exfoliation corrosion test, slow strain rate tensile test and electrochemical test, and the mechanism has been discussed based on microstructure examination by optical microscopy, electron back scattered diffraction, scanning electron microscopy and scanning transmission electron microscopy. The NIA treatment includes a heating stage from 40 °C to 180 °C with a rate of 20 °C/h and a cooling stage from 180 °C to 40 °C with a rate of 10 °C/h. The results show that the hardness and strength increase rapidly during the heating stage of NIA since the increasing temperature favors the nucleation and the growth of strengthening precipitates and promotes the transformation of Guinier-Preston (GPI) zones to <i>η</i>′ phase. During the cooling stage, the sizes of <i>η</i>′ phase increase with a little change in the number density, leading to a further slight increase of the hardness and strength. As NIA proceeds, the corroded morphology in the alloy changes from a layering feature to a wavy feature, the maximum corrosion depth decreases, and the reason has been analyzed based on the microstructural and microchemical feature of precipitates at grain boundaries and subgrain boundaries.</p>","PeriodicalId":15231,"journal":{"name":"Journal of Central South University","volume":"71 1","pages":""},"PeriodicalIF":4.4,"publicationDate":"2024-07-23","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"141782892","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
The low-cost Fe-Cu, Fe-Ni, and Cu-based high-entropy alloys exhibit a widespread utilization prospect. However, these potential applications have been limited by their low strength. In this study, a novel Fe31Cu31Ni28Al4Ti3Co3 immiscible high-entropy alloy (HEA) was developed. After vacuum arc melting and copper mold suction casting, this HEA exhibits a unique phase separation microstructure, which consists of striped Cu-rich regions and Fe-rich region. Further magnification of the striped Cu-rich region reveals that it is composed of a Cu-rich dot-like phase and a Fe-rich region. The aging alloy is further strengthened by a L12-Ni3(AlTi) nanoprecipitates, achieving excellent yield strength (1185 MPa) and uniform ductility (∼8.8%). The differential distribution of the L12 nanoprecipitate in the striped Cu-rich region and the external Fe-rich region increased the strength difference between these two regions, which increased the strain gradient and thus improved hetero-deformation induced (HDI) hardening. This work provides a new route to improve the HDI hardening of Fe-Cu alloys.
低成本的铁-铜、铁-镍和铜基高熵合金具有广泛的应用前景。然而,这些合金的低强度限制了其潜在应用。本研究开发了一种新型 Fe31Cu31Ni28Al4Ti3Co3 不相溶高熵合金(HEA)。经过真空电弧熔炼和铜模吸铸后,这种 HEA 呈现出独特的相分离微观结构,由富含铜的条纹区域和富含铁的区域组成。进一步放大条纹状富铜区域,可以发现它是由富铜点状相和富铁区域组成。L12-Ni3(AlTi)纳米沉淀物进一步强化了时效合金,使其获得了优异的屈服强度(1185 兆帕)和均匀的延展性(∼8.8%)。L12 纳米沉淀物在条纹状富铜区域和外部富铁区域的不同分布增加了这两个区域的强度差,从而增加了应变梯度,进而改善了异种变形诱导硬化(HDI)。这项研究为改善铁-铜合金的 HDI 硬化提供了一条新途径。
{"title":"A novel immiscible high entropy alloy strengthened via L12-nanoprecipitate","authors":"Zheng-qin Wang, Ming-yu Fan, Yang Zhang, Jun-peng Li, Li-yuan Liu, Ji-hong Han, Xing-hao Li, Zhong-wu Zhang","doi":"10.1007/s11771-024-5683-7","DOIUrl":"https://doi.org/10.1007/s11771-024-5683-7","url":null,"abstract":"<p>The low-cost Fe-Cu, Fe-Ni, and Cu-based high-entropy alloys exhibit a widespread utilization prospect. However, these potential applications have been limited by their low strength. In this study, a novel Fe<sub>31</sub>Cu<sub>31</sub>Ni<sub>28</sub>Al<sub>4</sub>Ti<sub>3</sub>Co<sub>3</sub> immiscible high-entropy alloy (HEA) was developed. After vacuum arc melting and copper mold suction casting, this HEA exhibits a unique phase separation microstructure, which consists of striped Cu-rich regions and Fe-rich region. Further magnification of the striped Cu-rich region reveals that it is composed of a Cu-rich dot-like phase and a Fe-rich region. The aging alloy is further strengthened by a L1<sub>2</sub>-Ni<sub>3</sub>(AlTi) nanoprecipitates, achieving excellent yield strength (1185 MPa) and uniform ductility (∼8.8%). The differential distribution of the L1<sub>2</sub> nanoprecipitate in the striped Cu-rich region and the external Fe-rich region increased the strength difference between these two regions, which increased the strain gradient and thus improved hetero-deformation induced (HDI) hardening. This work provides a new route to improve the HDI hardening of Fe-Cu alloys.</p>","PeriodicalId":15231,"journal":{"name":"Journal of Central South University","volume":"31 1","pages":""},"PeriodicalIF":4.4,"publicationDate":"2024-07-23","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"141782893","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}