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Modeling Thermal Part of Sulfur Recovery Unit and Simulation Based Analysis of Effects of Air Temperature on Entire Plant 硫回收装置热力部分建模及全厂温度影响仿真分析
Pub Date : 2018-12-06 DOI: 10.18689/IJPR-1000139
Oguzhan Dogru, Begum Guzel, Is Gamze, Gizem Kuşoğlu, Mehmet C. Yagci, Murat Kolbasi, Görkem Oğur, E. Alper
Sulfur in feedstocks are increasing steadily. Consequently, changes in regulations force industrial companies to operate Sulfur Recovery Units more efficiently. An industrial Sulfur Recovery Unit of TUPRAS, Turkey was modelled by Matlab by using simplified kinetics. Proposed model was validated with the industrial data of TUPRAS. The model represents the important species with minute deviation. According to the model proposed, conversion and recovery were found to be 65.24% and 86.88%, respectively; where they were calculated to be 64.91% and 82.72% in design case. Moreover, effects of air temperature were studied in this work. According to the simulation results, up to $13,200/year can be saved by removing preheating. Because carbon content is essential in gas mixture, effects of COS and CS 2 on catalytic part after this modification are found to be negligible in short term. This design change also increases the sulfur production by about 600 kg/day. On the other hand, amount of COS, CS 2 , H 2 S released from Selective Oxidation Reactor would be enhanced from 25 to 31 ppmmol, which increase overall SO 2 emission from incinerator.
原料中的硫在稳步增加。因此,法规的变化迫使工业公司更有效地操作硫回收装置。利用Matlab对土耳其TUPRAS工业硫回收装置进行了简化动力学建模。用TUPRAS的工业数据对模型进行了验证。该模型代表了具有微小偏差的重要物种。根据提出的模型,转化率和回收率分别为65.24%和86.88%;其中设计案例分别为64.91%和82.72%。此外,本文还研究了气温的影响。根据模拟结果,取消预热可节省高达13200美元/年。由于混合气体中碳的含量是至关重要的,因此在此改性后,COS和cs2对催化部分的影响在短期内可以忽略不计。这一设计变化还使硫磺产量增加了约600公斤/天。另一方面,选择性氧化反应器释放的COS、cs2、h2s从25 ppmmol增加到31 ppmmol,使焚烧炉总so2排放量增加。
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引用次数: 1
Feasibility study of Improvement Experimental Measurement and Thermodynamic Modelling of Contaminants Effect on the Thermo-Mechanical Properties of Industrial Petroleum recycled plastics wastes 污染物对工业石油再生塑料废渣热机械性能影响的改进实验测量和热力学模型的可行性研究
Pub Date : 2018-12-05 DOI: 10.18689/IJPR-1000138
Khalid Farhod Chasib
The recycled plastics (RHDPE and RLDPE) were exposed to environment conditions for many years. Also the chemical contaminants had effects on the thermo-mechanical and other properties of these wastes. Then a weathering effect data is examined for both Iraqi and Foreign wastes on the thermo-mechanical and chemical properties (Tensile strength, modulus, elongation, impact and permeability).The different mathematical software model were applied to analysis these weathering – properties data in order to estimate which one or several among these properties had more effective by these weathering conditions such as (concentration of contaminant, time, temperature, thickness of specimen, length of spectra, basic property). The results shows that a multi-polynomial model has a best fit for most or several of properties to active weathering variables, also gave a vary residual and deviation than experimental analyzed data for both sources of wastes Iraqi and Foreign RHDPE and RLDPE. Also the results for thermo-mechanical and chemical properties prove that both tensile strength and modulus of elasticity thermo-mechanical properties and permeability / length of spectra chemical property were given a high quality of correction and fitting factor from 93-99 %, with less deviation and residual function was produced. And the results of RHDPE gave a best fit than RLDPE for most of checked analysis properties (thermo-mechanical and chemical properties).
再生塑料(RHDPE和RLDPE)暴露在环境条件下多年。此外,化学污染物对这些废物的热机械性能和其他性能也有影响。然后,对伊拉克和外国废物的热机械和化学特性(抗拉强度、模量、伸长率、冲击和渗透性)的风化效应数据进行了检查。应用不同的数学软件模型对这些风化性能数据进行分析,以估计在不同的风化条件下(污染物浓度、时间、温度、试样厚度、光谱长度、基本性能),哪一种或几种性能更有效。结果表明,多多项式模型能较好地拟合活性风化变量对RHDPE和RLDPE的大部分或部分性能的影响,并给出了与试验分析数据不同的残差和偏差。热力学性能和化学性能的结果表明,拉伸强度和弹性模量、热力学性能和透气性/光谱长度化学性能的校正和拟合系数在93% ~ 99%之间,偏差较小,产生的残余函数也较小。RHDPE的结果比RLDPE更适合于大多数检查的分析性能(热力学和化学性能)。
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引用次数: 0
A Rock Physics based Petroleum Reservoir Characterization. The Case of a West African Reservoir 基于岩石物理的油藏表征西非水库的案例
Pub Date : 2018-12-04 DOI: 10.18689/IJPR-1000137
A. Habib, A. Bello, M. Habib
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引用次数: 0
Scope for optimal Scheduling of Multiproduct Pipelines with Multi-batch Sequential transportation 多产品管道多批次顺序运输的最优调度范围
Pub Date : 2018-11-28 DOI: 10.18689/ijpr-1000136
Qi Liao, Yongtu Liang, Huixia Feng, Zhengbing Li, H. Zhang
The optimal scheduling of multiproduct pipelines is benefit to improve the transport economy and safety, thus making great sense to the operation and management of multiproduct pipelines. During the last decade, a large number of domestic and foreign studies have been widely done on this topic. Based on the related literature, the paper summarizes the research emphasis, analyzes different modeling methods and solving algorithms 4Kand finally provides the outlook for the further researches on the scheduling optimization.
多产品管道的优化调度有利于提高运输的经济性和安全性,对多产品管道的运行管理具有重要意义。近十年来,国内外对这一课题进行了大量的研究。在查阅相关文献的基础上,总结了研究重点,分析了不同的建模方法和求解算法,最后对调度优化的进一步研究进行了展望。
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引用次数: 0
A simple way to nickel based mesoporous carbons: Inexpensive nanocatalysts for the hydrogenolysis of sorbitol 制备镍基介孔碳的一种简单方法:廉价的山梨醇氢解纳米催化剂
Pub Date : 2018-11-15 DOI: 10.18689/IJPR-1000135
Ying Yang
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引用次数: 2
Optimization of preparation conditions for rice husk based activated carbons for the removal of methylene blue dye 稻壳基活性炭去除亚甲基蓝染料制备条件的优化
Pub Date : 2018-08-31 DOI: 10.18689/ijpr-1000133
M. N. Murat, M. A. Ahmad, M. Idris
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引用次数: 1
Chemistry via Art 艺术中的化学
Pub Date : 2018-08-30 DOI: 10.18689/IJPR-1000132
A. Tamir
Chemistry is the science concerned with the composition, structure, and properties of matter, as well as the changes it undergoes during chemical reactions. Chemical reactions are processes by which the original substances are changed into new ones by making or breaking of chemical bonds. Each chemical is characterized by a symbol or a formula derived from the scientific name of the element where a specific reaction is described as combination of the formula of the reactants and products. The major aim of the paper is to demonstrate different aspects if chemistry by artworks which makes the concept of chemistry more clear and easy to understand
化学是一门研究物质的组成、结构和性质以及物质在化学反应中发生变化的科学。化学反应是指通过化学键的形成或断裂使原物质变成新物质的过程。每种化学物质都有一个符号或从元素的学名中得出的公式,其中特定的反应被描述为反应物和产物的公式的组合。本文的主要目的是通过艺术作品展示化学的不同方面,使化学的概念更加清晰易懂
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引用次数: 0
Microwave assisted rice husk based activated carbon for adsorption of methylene blue dye 微波辅助稻壳活性炭对亚甲基蓝染料的吸附
Pub Date : 2018-08-05 DOI: 10.18689/ijpr-1000128
M. A. Ahmad, N. Basir, N. Yahaya
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引用次数: 2
Effects of Secondary reaction of Primary Volatiles on Oil/gas Yield and Quality from Oil Shale Pyrolysis 一次挥发物二次反应对油页岩热解油气收率和质量的影响
Pub Date : 2018-07-12 DOI: 10.18689/IJPR-1000127
Yuming Zhang, Rongxuan Linghu, Lei Huang, Liang Zhang, Guogang Sun, Shu Zhang
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引用次数: 2
Simulation of ice formation on the gas transfer tube surrounded by a water medium 被水介质包围的输气管内结冰的模拟
Pub Date : 2018-06-18 DOI: 10.18689/IJPR-1000125
Marinyuk Boris, Leontev Andrey, Zabugina Anna
The growth rate of ice layer on a surface of the long tube immersed within water medium and containing cold gas flow is considered. It was determined the layer thickness of ice forming along the tube surface as function of gas follow rate and its initial temperature. The temperature of water medium is above zero.
考虑了浸没在水介质中含冷气流的长管表面冰层的生长速率。确定了沿管道表面形成冰的层厚随气体跟随速率和初始温度的变化规律。水介质温度在零度以上。
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引用次数: 0
期刊
International Journal of Petrochemistry and Research
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