Ahmed A. Alshahrani, A. A. El-Habeeb, Arwa A. Almutairi, Dimah A. Almuaither, Sara A. Abudajeen, Hassan M. A. Hassan, I. Alsohaimi
Amidst the ongoing advancements in membrane technology, a leading method has come to the forefront. Recent research has emphasized the substantial influence of surface attributes in augmenting the effectiveness of thin-film membranes in water treatments. These studies reveal how surface properties play a crucial role in optimizing the performance of these membranes, further establishing their prominence in the field of membrane technology. This recognition stems from the precise engineering of surfaces, ensuring they meet the demanding requirements of advanced separation processes. This study utilizes polyamide as a discerning layer, applied atop a polysulfone support sheet through interfacial polymerization (IP) for membrane fabrication. The amounts in the various membranes were created to vary. The membrane’s permeability to water with significant salt rejection was enhanced, which improved its effectiveness. The polyamide (PA) membrane comprising graphene oxide (rGO, 0.015%) had a water permeability of 48.90 L/m2 h at 22 bar, which was much higher than the mean permeability of polyamide membranes (25.0 L/m2 h at 22 bar). On the other hand, the PA–rGO/CHIT membranes exhibited the lowest water permeability due to their decreased surface roughness. However, the membranes’ effectiveness in rejecting salts ranged from 80% to 95% for PA–rGO and PA–rGO/CHIT membranes.
{"title":"Preparation, Characterization and Evaluation of Polyamide-Reduced Graphene Oxide as Selective Membranes for Water Purification","authors":"Ahmed A. Alshahrani, A. A. El-Habeeb, Arwa A. Almutairi, Dimah A. Almuaither, Sara A. Abudajeen, Hassan M. A. Hassan, I. Alsohaimi","doi":"10.3390/jcs8010024","DOIUrl":"https://doi.org/10.3390/jcs8010024","url":null,"abstract":"Amidst the ongoing advancements in membrane technology, a leading method has come to the forefront. Recent research has emphasized the substantial influence of surface attributes in augmenting the effectiveness of thin-film membranes in water treatments. These studies reveal how surface properties play a crucial role in optimizing the performance of these membranes, further establishing their prominence in the field of membrane technology. This recognition stems from the precise engineering of surfaces, ensuring they meet the demanding requirements of advanced separation processes. This study utilizes polyamide as a discerning layer, applied atop a polysulfone support sheet through interfacial polymerization (IP) for membrane fabrication. The amounts in the various membranes were created to vary. The membrane’s permeability to water with significant salt rejection was enhanced, which improved its effectiveness. The polyamide (PA) membrane comprising graphene oxide (rGO, 0.015%) had a water permeability of 48.90 L/m2 h at 22 bar, which was much higher than the mean permeability of polyamide membranes (25.0 L/m2 h at 22 bar). On the other hand, the PA–rGO/CHIT membranes exhibited the lowest water permeability due to their decreased surface roughness. However, the membranes’ effectiveness in rejecting salts ranged from 80% to 95% for PA–rGO and PA–rGO/CHIT membranes.","PeriodicalId":15435,"journal":{"name":"Journal of Composites Science","volume":"5 1","pages":""},"PeriodicalIF":3.3,"publicationDate":"2024-01-10","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"139438900","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Sandwich composites are often used as primary load-bearing structures in various industries like aviation, wind, and marine due to their high strength-to-weight and stiffness-to-weight ratios, but they are vulnerable to damage from Low-velocity-impact (LVI) events like dropped tools, hail, and birdstrikes. This often manifests in the form of Facesheet-Core-Debonding (FCD) and is often termed Barely-Visible-Impact-Damage (BVID), which is difficult to detect and can considerably reduce mechanical properties. In general, a balsa core sandwich is especially vulnerable to FCD under LVI as it has poorer adhesion than synthetic core materials. A cork core sandwich does show promise in absorbing LVI with low permanent indentation depth. This paper also reviews surface treatment/modification as a means of improving the adhesion of composite core and fiber materials: key concepts involved, a comparison of surface free energies of various materials, and research literature on surface modification of cork, glass, and carbon fibers. Since both balsa and cork have a relatively low surface free energy compared to other materials, this paper concludes that it may be possible to use surface modification techniques to boost adhesion and thus FCD on balsa or cork sandwich composites under LVI, which has not been covered by existing research literature.
{"title":"Effects of Low-Velocity-Impact on Facesheet-Core Debonding of Natural-Core Composite Sandwich Structures—A Review of Experimental Research","authors":"Michael Ong, Arlindo Silva","doi":"10.3390/jcs8010023","DOIUrl":"https://doi.org/10.3390/jcs8010023","url":null,"abstract":"Sandwich composites are often used as primary load-bearing structures in various industries like aviation, wind, and marine due to their high strength-to-weight and stiffness-to-weight ratios, but they are vulnerable to damage from Low-velocity-impact (LVI) events like dropped tools, hail, and birdstrikes. This often manifests in the form of Facesheet-Core-Debonding (FCD) and is often termed Barely-Visible-Impact-Damage (BVID), which is difficult to detect and can considerably reduce mechanical properties. In general, a balsa core sandwich is especially vulnerable to FCD under LVI as it has poorer adhesion than synthetic core materials. A cork core sandwich does show promise in absorbing LVI with low permanent indentation depth. This paper also reviews surface treatment/modification as a means of improving the adhesion of composite core and fiber materials: key concepts involved, a comparison of surface free energies of various materials, and research literature on surface modification of cork, glass, and carbon fibers. Since both balsa and cork have a relatively low surface free energy compared to other materials, this paper concludes that it may be possible to use surface modification techniques to boost adhesion and thus FCD on balsa or cork sandwich composites under LVI, which has not been covered by existing research literature.","PeriodicalId":15435,"journal":{"name":"Journal of Composites Science","volume":"27 8","pages":""},"PeriodicalIF":3.3,"publicationDate":"2024-01-09","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"139441687","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Miguel A. R. Pereira, Ivan Galvão, José Domingos Costa, Rui M. Leal, Ana M. Amaro
The joining of aluminium alloy AA6082-T6 to polyamide 6 (PA6) by friction stir spot welding (FSSW) was investigated in the current work. Although previous studies can be found on the joining of polymers and metals by FSSW, welding using aluminium plates as thin as the ones used in this work (1 mm) was not found. The influence of the plunge depth (0.1 to 0.5 mm) and the dwell time (15 and 30 s) parameters on the welding results was studied. In general, the increase of these parameters led to the improvement of the maximum load of the joints under tensile-shear testing. Additionally, the feasibility of multiple spot welding was tested and proven. Finally, although most of the welds were performed with a pinless tool, a tool with a conical pin and a concave shoulder was used for comparison. The use of this more conventional tool resulted in joints easily broken by handling. Still, the potential of the conical pin tool was demonstrated. The different conditions were evaluated based on morphology and tensile-shear testing. The weld with the best mechanical behaviour was produced with multiple spot welding, which failed for a maximum load of about 2350 N.
{"title":"Friction Stir Spot Welding of Thin Aluminium Sheets to Polyamide 6: A Study of the Welding Parameters and Strategies","authors":"Miguel A. R. Pereira, Ivan Galvão, José Domingos Costa, Rui M. Leal, Ana M. Amaro","doi":"10.3390/jcs8010021","DOIUrl":"https://doi.org/10.3390/jcs8010021","url":null,"abstract":"The joining of aluminium alloy AA6082-T6 to polyamide 6 (PA6) by friction stir spot welding (FSSW) was investigated in the current work. Although previous studies can be found on the joining of polymers and metals by FSSW, welding using aluminium plates as thin as the ones used in this work (1 mm) was not found. The influence of the plunge depth (0.1 to 0.5 mm) and the dwell time (15 and 30 s) parameters on the welding results was studied. In general, the increase of these parameters led to the improvement of the maximum load of the joints under tensile-shear testing. Additionally, the feasibility of multiple spot welding was tested and proven. Finally, although most of the welds were performed with a pinless tool, a tool with a conical pin and a concave shoulder was used for comparison. The use of this more conventional tool resulted in joints easily broken by handling. Still, the potential of the conical pin tool was demonstrated. The different conditions were evaluated based on morphology and tensile-shear testing. The weld with the best mechanical behaviour was produced with multiple spot welding, which failed for a maximum load of about 2350 N.","PeriodicalId":15435,"journal":{"name":"Journal of Composites Science","volume":"32 8","pages":""},"PeriodicalIF":3.3,"publicationDate":"2024-01-08","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"139444862","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Conventional scar treatment options of single pressure garment therapy (PGT) or silicone gel sheeting (SGS, Cica-Care®, Smith and Nephew, London, UK) alone lack mechanical property tunability. This article discusses a scar healing composite (PGF-Biopor®AB, Dreve Otoplastik GmbH, Unna, Germany) and how its mechanical properties can be tuned for improved mechanotherapy. A balance between compression and tension was achieved by tuning the tensile and shear properties, facilitating tension shielding and pressure redistribution for scar therapeutics. Biopor®AB-wrapping on biaxial-tensioned pressure garment fabric (PGF) allowed compression therapy and internal pressure redistribution. The Biopor®AB surface, with a coefficient of friction close to 1, strategically localizes stress for effective tension shielding. A substantial five-fold reduction in silicone tension, amounting to 1.060 N, achieves tension shielding and pressure redistribution. Simultaneously, a dynamic internal pressure-sharing mechanism distributes 0.222 kPa from each SPK-filament bundle, effectively managing internal pressure. Alongside the principle compression-silicone dual therapy, this composite design with dynamic internal pressure sharing and mechanical property tunability provides an additional pressure-relieving strategy for multiple scar therapeutics.
{"title":"Tuning the Tensile and Shear Properties of a Scar Healing Composite for Mechanotherapy","authors":"K. Lui, Xungai Wang, Chi-Wai Kan","doi":"10.3390/jcs8010022","DOIUrl":"https://doi.org/10.3390/jcs8010022","url":null,"abstract":"Conventional scar treatment options of single pressure garment therapy (PGT) or silicone gel sheeting (SGS, Cica-Care®, Smith and Nephew, London, UK) alone lack mechanical property tunability. This article discusses a scar healing composite (PGF-Biopor®AB, Dreve Otoplastik GmbH, Unna, Germany) and how its mechanical properties can be tuned for improved mechanotherapy. A balance between compression and tension was achieved by tuning the tensile and shear properties, facilitating tension shielding and pressure redistribution for scar therapeutics. Biopor®AB-wrapping on biaxial-tensioned pressure garment fabric (PGF) allowed compression therapy and internal pressure redistribution. The Biopor®AB surface, with a coefficient of friction close to 1, strategically localizes stress for effective tension shielding. A substantial five-fold reduction in silicone tension, amounting to 1.060 N, achieves tension shielding and pressure redistribution. Simultaneously, a dynamic internal pressure-sharing mechanism distributes 0.222 kPa from each SPK-filament bundle, effectively managing internal pressure. Alongside the principle compression-silicone dual therapy, this composite design with dynamic internal pressure sharing and mechanical property tunability provides an additional pressure-relieving strategy for multiple scar therapeutics.","PeriodicalId":15435,"journal":{"name":"Journal of Composites Science","volume":"1 5","pages":""},"PeriodicalIF":3.3,"publicationDate":"2024-01-08","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"139446094","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Abrasive Water Jet Machining (AWJM) is a popular machining method used to machine polymer matrix composites that are sensitive to temperature. This method is non-thermal, and each input parameter has a significant effect on output parameters, such as material removal rate, kerf width, surface roughness, and the potential for delamination. To ensure high-quality machining, it is crucial to set these input parameters at their optimal level. This paper proposes a simple approach to predict the optimum process parameters of water jet machining operations on jute fiber-reinforced polymer composite (JFRPC). The process parameters considered are standoff distance (SOD), traverse speed (TS), and abrasive material flow rate (MFR). Conversely, surface roughness (Ra) and delamination (Da) are the output parameters. Process parameters are set using Taguchi’s L27 array, with consideration given to three levels of each input parameter. The best value for process parameters is found using grey relational analysis (GRA), and an ANOVA on GRA illustrates the impact of each input variable. After a confirmation test, it was found that the suggested parameters guarantee the best possible results.
{"title":"Study on Machining Quality in Abrasive Water Jet Machining of Jute-Polymer Composite and Optimization of Process Parameters through Grey Relational Analysis","authors":"Murthy Brn, Rajendra Beedu, J. P K, S. Potti","doi":"10.3390/jcs8010020","DOIUrl":"https://doi.org/10.3390/jcs8010020","url":null,"abstract":"Abrasive Water Jet Machining (AWJM) is a popular machining method used to machine polymer matrix composites that are sensitive to temperature. This method is non-thermal, and each input parameter has a significant effect on output parameters, such as material removal rate, kerf width, surface roughness, and the potential for delamination. To ensure high-quality machining, it is crucial to set these input parameters at their optimal level. This paper proposes a simple approach to predict the optimum process parameters of water jet machining operations on jute fiber-reinforced polymer composite (JFRPC). The process parameters considered are standoff distance (SOD), traverse speed (TS), and abrasive material flow rate (MFR). Conversely, surface roughness (Ra) and delamination (Da) are the output parameters. Process parameters are set using Taguchi’s L27 array, with consideration given to three levels of each input parameter. The best value for process parameters is found using grey relational analysis (GRA), and an ANOVA on GRA illustrates the impact of each input variable. After a confirmation test, it was found that the suggested parameters guarantee the best possible results.","PeriodicalId":15435,"journal":{"name":"Journal of Composites Science","volume":"20 4","pages":""},"PeriodicalIF":3.3,"publicationDate":"2024-01-08","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"139445664","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
T. Latsuzbaya, Peter Middendorf, D. Voelkle, Christoph Weber
The application of fiber-reinforced thermoplastic mono-material sandwich panels has many advantages, such as recyclability, reduction in processing cycle times, integration of additional elements by means of welding, and a great potential for in-line production. The most efficient way to produce a curved thermoplastic sandwich panel is thermoforming, which has several challenges. One of them is to achieve a higher thermal gradient in the panel. On the one hand, the temperature at the skin–core interface must exceed the softening point of the polymer to reach a sufficient bonding degree. On the other hand, the core should not be overheated and overloaded to avoid its collapse. Furthermore, several fiber distortions, such as wrinkles or buckles, can be developed during thermoforming. All these flaws have a negative impact on the mechanical performance of the sandwich structure. The objective of this study is the development of a simulation tool for the thermoforming process, which can replace the time-consuming trial-and-error-based method. Therefore, a coupled thermomechanical model was developed for a novel thermoplastic sandwich structure, which is able to predict the temperature distribution and its influence on the mechanical properties of the panel. Experimental trials were conducted to validate the thermomechanical forming model, which demonstrated a good agreement with numerical results.
{"title":"Thermomechanical Analysis of Thermoplastic Mono-Material Sandwich Structures with Honeycomb Core","authors":"T. Latsuzbaya, Peter Middendorf, D. Voelkle, Christoph Weber","doi":"10.3390/jcs8010018","DOIUrl":"https://doi.org/10.3390/jcs8010018","url":null,"abstract":"The application of fiber-reinforced thermoplastic mono-material sandwich panels has many advantages, such as recyclability, reduction in processing cycle times, integration of additional elements by means of welding, and a great potential for in-line production. The most efficient way to produce a curved thermoplastic sandwich panel is thermoforming, which has several challenges. One of them is to achieve a higher thermal gradient in the panel. On the one hand, the temperature at the skin–core interface must exceed the softening point of the polymer to reach a sufficient bonding degree. On the other hand, the core should not be overheated and overloaded to avoid its collapse. Furthermore, several fiber distortions, such as wrinkles or buckles, can be developed during thermoforming. All these flaws have a negative impact on the mechanical performance of the sandwich structure. The objective of this study is the development of a simulation tool for the thermoforming process, which can replace the time-consuming trial-and-error-based method. Therefore, a coupled thermomechanical model was developed for a novel thermoplastic sandwich structure, which is able to predict the temperature distribution and its influence on the mechanical properties of the panel. Experimental trials were conducted to validate the thermomechanical forming model, which demonstrated a good agreement with numerical results.","PeriodicalId":15435,"journal":{"name":"Journal of Composites Science","volume":"66 33","pages":""},"PeriodicalIF":3.3,"publicationDate":"2024-01-07","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"139448894","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Ar, Ar/H2 (95:5), and Ar/O2 (95:5) plasmas are used for treating the NiCo metal–organic framework (MOF), and the plasma-processed NiCo MOF is applied for catalyzing the oxygen evolution reaction (OER) in a 1 M KOH electrolyte. Linear sweep voltammetry measurements show that after plasma treatment with Ar/H2 (95:5) and Ar gases, the overpotential reaches 552 and 540 mV, respectively, at a current density of 100 mA/cm2. The increase in the double-layer capacitance further confirms the enhanced oxygen production activity. We test the Ar plasma-treated NiCo MOF as an electrocatalyst at the OER electrode and Ru as an electrocatalyst at the hydrogen evolution reaction (HER) electrode in the alkaline water electrolysis module. The energy efficiency of the electrolyzer with the Ar plasma-processed NiCo-MOF catalyst increases from 54.7% to 62.5% at a current density of 500 mA/cm2 at 25 °C. The alkaline water electrolysis module with the Ar plasma-processed catalyst also exhibits a specific energy consumption of 5.20 kWh/m3 and 4.69 kWh/m3 at 25 °C and 70 °C, respectively. The alkaline water electrolysis module performance parameters such as the hydrogen production rate, specific energy consumption, and energy efficiency are characterized at temperatures between 25 °C and 70 °C. Our experimental results show that the NiCo MOF is an efficient OER electrocatalyst for the alkaline water electrolysis module.
使用氩气、氩气/H2 (95:5) 和氩气/氧气 (95:5) 等离子体处理镍钴金属有机框架 (MOF)，并将等离子体处理后的镍钴金属有机框架用于催化 1 M KOH 电解质中的氧进化反应 (OER)。线性扫频伏安法测量结果表明，用 Ar/H2 (95:5) 和 Ar 气体进行等离子处理后，在 100 mA/cm2 的电流密度下，过电位分别达到 552 mV 和 540 mV。双层电容的增加进一步证实了制氧活性的增强。在碱性水电解模块中，我们测试了经氩等离子体处理的 NiCo MOF 作为 OER 电极的电催化剂和 Ru 作为氢进化反应（HER）电极的电催化剂。在 25 °C、电流密度为 500 mA/cm2 时，使用氩等离子体处理的 NiCo-MOF 催化剂的电解槽能效从 54.7% 提高到 62.5%。使用氩等离子体催化剂的碱性水电解模块在 25 °C 和 70 °C 条件下的能耗分别为 5.20 kWh/m3 和 4.69 kWh/m3。碱性水电解模块的性能参数，如制氢率、比能耗和能效，是在 25 °C 和 70 °C 温度下表征的。实验结果表明，镍钴 MOF 是碱性水电解模块的高效 OER 电催化剂。
{"title":"Low-Pressure Plasma-Processed NiCo Metal–Organic Framework for Oxygen Evolution Reaction and Its Application in Alkaline Water Electrolysis Module","authors":"Yu-Lun Su, Shuo-En Yu, I‐Chih Ni, Chih-I Wu, Yong-Song Chen, Yi-Cheng Chuang, I-Chun Cheng, Jian-Zhang Chen","doi":"10.3390/jcs8010019","DOIUrl":"https://doi.org/10.3390/jcs8010019","url":null,"abstract":"Ar, Ar/H2 (95:5), and Ar/O2 (95:5) plasmas are used for treating the NiCo metal–organic framework (MOF), and the plasma-processed NiCo MOF is applied for catalyzing the oxygen evolution reaction (OER) in a 1 M KOH electrolyte. Linear sweep voltammetry measurements show that after plasma treatment with Ar/H2 (95:5) and Ar gases, the overpotential reaches 552 and 540 mV, respectively, at a current density of 100 mA/cm2. The increase in the double-layer capacitance further confirms the enhanced oxygen production activity. We test the Ar plasma-treated NiCo MOF as an electrocatalyst at the OER electrode and Ru as an electrocatalyst at the hydrogen evolution reaction (HER) electrode in the alkaline water electrolysis module. The energy efficiency of the electrolyzer with the Ar plasma-processed NiCo-MOF catalyst increases from 54.7% to 62.5% at a current density of 500 mA/cm2 at 25 °C. The alkaline water electrolysis module with the Ar plasma-processed catalyst also exhibits a specific energy consumption of 5.20 kWh/m3 and 4.69 kWh/m3 at 25 °C and 70 °C, respectively. The alkaline water electrolysis module performance parameters such as the hydrogen production rate, specific energy consumption, and energy efficiency are characterized at temperatures between 25 °C and 70 °C. Our experimental results show that the NiCo MOF is an efficient OER electrocatalyst for the alkaline water electrolysis module.","PeriodicalId":15435,"journal":{"name":"Journal of Composites Science","volume":"35 9","pages":""},"PeriodicalIF":3.3,"publicationDate":"2024-01-07","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"139448108","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Yihao Zhang, Ning Kang, Shipu Jiao, Yang Li, Xu Zhang, Xianhua Liu
The pyrolysis of metal-organic frameworks (MOFs) is a popular strategy for the synthesis of nanoporous structures. Polymetallic oxides (POMs) are a class of polyhedral structural compounds with unique physicochemical properties. Little effort has been paid to evaluate MOF-POM hybrid-derived materials for peroxomonosulfate (PMS) activation. In this study, a cobalt-based MOF, ZIF-67, together with three types of POMs (phosphomolybdic acid, silicotungstic acid, and phosphotungstic acid), were used as precursors for the synthesis of PMS activation catalyst via pyrolysis. Three T-POMs@ZIF-67 nanohybrids (T-PMo@ZIF-67, T-SiW@ZIF-67, and T-PW@ZIF-67) were obtained by pyrolyzing the prepared precursors at 500 °C. Furthermore, the prepared T-POMs@ZIF-67 nanomaterials were evaluated for the catalytic activation of PMS in the degradation of levofloxacin (LEV). The results showed that the LEV degradation rate could reach 91.46% within 30 min under the optimized conditions when T-PW@ZIF-67 was used as the PMS activation catalyst. The catalytic efficiency of the catalyst decreased by only 9.63% after five cycles, indicating that the material has good stability. This work demonstrates the great potential of POMs@MOF derivatives for application in the field of wastewater treatment.
{"title":"Removal of Levofloxacin by Activation of Peroxomonosulfate Using T-POMs@ZIF-67","authors":"Yihao Zhang, Ning Kang, Shipu Jiao, Yang Li, Xu Zhang, Xianhua Liu","doi":"10.3390/jcs8010013","DOIUrl":"https://doi.org/10.3390/jcs8010013","url":null,"abstract":"The pyrolysis of metal-organic frameworks (MOFs) is a popular strategy for the synthesis of nanoporous structures. Polymetallic oxides (POMs) are a class of polyhedral structural compounds with unique physicochemical properties. Little effort has been paid to evaluate MOF-POM hybrid-derived materials for peroxomonosulfate (PMS) activation. In this study, a cobalt-based MOF, ZIF-67, together with three types of POMs (phosphomolybdic acid, silicotungstic acid, and phosphotungstic acid), were used as precursors for the synthesis of PMS activation catalyst via pyrolysis. Three T-POMs@ZIF-67 nanohybrids (T-PMo@ZIF-67, T-SiW@ZIF-67, and T-PW@ZIF-67) were obtained by pyrolyzing the prepared precursors at 500 °C. Furthermore, the prepared T-POMs@ZIF-67 nanomaterials were evaluated for the catalytic activation of PMS in the degradation of levofloxacin (LEV). The results showed that the LEV degradation rate could reach 91.46% within 30 min under the optimized conditions when T-PW@ZIF-67 was used as the PMS activation catalyst. The catalytic efficiency of the catalyst decreased by only 9.63% after five cycles, indicating that the material has good stability. This work demonstrates the great potential of POMs@MOF derivatives for application in the field of wastewater treatment.","PeriodicalId":15435,"journal":{"name":"Journal of Composites Science","volume":" 15","pages":""},"PeriodicalIF":3.3,"publicationDate":"2023-12-29","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"139142568","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Andres Arce, Panagiotis Kapsalis, C. Papanicolaou, T. C. Triantafillou
This paper discusses the integration of an alkali-activated mortar (AAM), based on industrial waste, into a novel composite material fit for structural upgrading purposes and rendered with high temperature endurance and a low CO2 footprint. The AAM combined with carbon fiber textiles form a new generation of sustainable inorganic matrix composites—that of textile-reinforced alkali-activated mortars (TRAAM). A test program was designed to assess the effectiveness of carbon TRAAM overlays in increasing the shear capacity of masonry wall specimens comprising solid clay bricks bonded with lime-based mortar and furnished with TRAAM jackets on both sides. The initial and the residual capacity of the reinforced walls were evaluated, the latter by performing diagonal compression tests after exposure to 300 °C and 550 °C. It was shown that TRAAM jacketing can increase the shear capacity of unfired masonry walls by 260% and 335% when a single or a double layer of textile is used, respectively. Rapid heating to temperatures up to 550 °C, one-hour-long steady-state heating, and natural cooling bore no visible thermal cracks on the specimens and had little effect on their residual capacity. Based on these results, the prospect of using TRAAM for retrofitting applications for fire-resilient structures seems very auspicious.
本文讨论了如何将一种基于工业废料的碱活性砂浆（AAM）整合到一种新型复合材料中，这种材料适用于结构升级，具有耐高温和二氧化碳排放量低的特点。碱活性砂浆与碳纤维纺织品相结合，形成了新一代可持续无机基复合材料--纺织品增强碱活性砂浆（TRAAM）。我们设计了一个测试程序，以评估碳纤维 TRAAM 覆盖层在提高砌体墙试样抗剪能力方面的有效性，该试样由实心粘土砖组成，粘结有石灰基砂浆，两面都有 TRAAM 护套。我们评估了加固墙体的初始承载力和剩余承载力，后者是通过在暴露于 300 °C 和 550 °C 温度后进行对角压缩试验来实现的。结果表明，当使用单层或双层织物时，TRAAM 护套可将未烧制砌体墙的抗剪能力分别提高 260% 和 335%。快速加热至 550 °C、一小时稳态加热和自然冷却都不会在试样上产生明显的热裂缝，对其剩余承载力的影响也很小。基于这些结果，将 TRAAM 用于耐火结构改造的前景似乎非常乐观。
{"title":"Diagonal Compression Tests on Unfired and Fired Masonry Wallettes Retrofitted with Textile-Reinforced Alkali-Activated Mortar","authors":"Andres Arce, Panagiotis Kapsalis, C. Papanicolaou, T. C. Triantafillou","doi":"10.3390/jcs8010014","DOIUrl":"https://doi.org/10.3390/jcs8010014","url":null,"abstract":"This paper discusses the integration of an alkali-activated mortar (AAM), based on industrial waste, into a novel composite material fit for structural upgrading purposes and rendered with high temperature endurance and a low CO2 footprint. The AAM combined with carbon fiber textiles form a new generation of sustainable inorganic matrix composites—that of textile-reinforced alkali-activated mortars (TRAAM). A test program was designed to assess the effectiveness of carbon TRAAM overlays in increasing the shear capacity of masonry wall specimens comprising solid clay bricks bonded with lime-based mortar and furnished with TRAAM jackets on both sides. The initial and the residual capacity of the reinforced walls were evaluated, the latter by performing diagonal compression tests after exposure to 300 °C and 550 °C. It was shown that TRAAM jacketing can increase the shear capacity of unfired masonry walls by 260% and 335% when a single or a double layer of textile is used, respectively. Rapid heating to temperatures up to 550 °C, one-hour-long steady-state heating, and natural cooling bore no visible thermal cracks on the specimens and had little effect on their residual capacity. Based on these results, the prospect of using TRAAM for retrofitting applications for fire-resilient structures seems very auspicious.","PeriodicalId":15435,"journal":{"name":"Journal of Composites Science","volume":" 44","pages":""},"PeriodicalIF":3.3,"publicationDate":"2023-12-29","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"139143933","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Moises Jimenez-Martinez, Julio Varela-Soriano, Julio S. De La Trinidad-Rendon, S. G. Torres-Cedillo, Jacinto Cortés-Pérez, Manuel Coca-Gonzalez
The transformation of powertrains, powered by internal combustion engines, into electrical systems generates new challenges in developing lightweight materials because electric vehicles are typically heavy. It is therefore important to develop new vehicles and seek more aesthetic and environmentally friendly designs whilst integrating manufacturing processes that contribute to reducing the carbon footprint. At the same time, this research explores the development of new prototypes and custom components using printed composite materials. In this framework, it is essential to formulate new approaches to estimate fatigue life, specifically for components tailored and fabricated with these kinds of advanced materials. This study introduces a novel fatigue life prediction approach based on an artificial neural network. When presented with given inputs, this neural network is trained to predict the accumulation of fatigue damage and the temperature generated during cyclic loading, along with the mechanical properties of the compound. Its validation involves comparing the network’s response with the load ratio result, which can be calculated using the fatigue damage parameter. Comparing both results, the network can successfully predict the fatigue damage accumulation; this implies an ability to directly employ data on the mechanical behavior of the component, eliminating the necessity for experimental testing. Then, the current study introduces a neural network designed to predict the accumulated fatigue damage in printed composite materials with an Onyx matrix and Kevlar reinforcement.
{"title":"Fatigue Analysis of Printed Composites of Onyx and Kevlar","authors":"Moises Jimenez-Martinez, Julio Varela-Soriano, Julio S. De La Trinidad-Rendon, S. G. Torres-Cedillo, Jacinto Cortés-Pérez, Manuel Coca-Gonzalez","doi":"10.3390/jcs8010012","DOIUrl":"https://doi.org/10.3390/jcs8010012","url":null,"abstract":"The transformation of powertrains, powered by internal combustion engines, into electrical systems generates new challenges in developing lightweight materials because electric vehicles are typically heavy. It is therefore important to develop new vehicles and seek more aesthetic and environmentally friendly designs whilst integrating manufacturing processes that contribute to reducing the carbon footprint. At the same time, this research explores the development of new prototypes and custom components using printed composite materials. In this framework, it is essential to formulate new approaches to estimate fatigue life, specifically for components tailored and fabricated with these kinds of advanced materials. This study introduces a novel fatigue life prediction approach based on an artificial neural network. When presented with given inputs, this neural network is trained to predict the accumulation of fatigue damage and the temperature generated during cyclic loading, along with the mechanical properties of the compound. Its validation involves comparing the network’s response with the load ratio result, which can be calculated using the fatigue damage parameter. Comparing both results, the network can successfully predict the fatigue damage accumulation; this implies an ability to directly employ data on the mechanical behavior of the component, eliminating the necessity for experimental testing. Then, the current study introduces a neural network designed to predict the accumulated fatigue damage in printed composite materials with an Onyx matrix and Kevlar reinforcement.","PeriodicalId":15435,"journal":{"name":"Journal of Composites Science","volume":"22 24","pages":""},"PeriodicalIF":3.3,"publicationDate":"2023-12-29","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"139147732","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
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