High Energy Density Materials (HEDMs) refer to materials with extensive applications in the fields of rocketry, propellants, and explosives chemistry. CL-20 is not only stands as the most powerful ...
{"title":"An overview on CL-20 synthesis and key issues with the TAIW route, along with improvement strategies","authors":"Jianhong Jin, Shuyuan Lou, Qingtao Wang, Xiaoliang Xu, Qunfeng Zhang, Xiaonian Li","doi":"10.1080/07370652.2024.2330968","DOIUrl":"https://doi.org/10.1080/07370652.2024.2330968","url":null,"abstract":"High Energy Density Materials (HEDMs) refer to materials with extensive applications in the fields of rocketry, propellants, and explosives chemistry. CL-20 is not only stands as the most powerful ...","PeriodicalId":15754,"journal":{"name":"Journal of Energetic Materials","volume":"157 1","pages":""},"PeriodicalIF":2.1,"publicationDate":"2024-03-27","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"140322815","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2024-03-20DOI: 10.1080/07370652.2024.2330965
Ali Said, Ahmed Maraden, Tarek M. Elhedery, M. Yehia, Ahmed Saleh, M. Gaber Zaky, Sherif Elbasuney
Whereas aluminum with combustion enthalpy of 32 KJ/g is the universal reactive metal particles, its passive protective oxide layer could encounter its efficient combustion. While titanium can offer...
{"title":"Titanium a novel catalyst and high energy dense material: an opportunity for composite propellants with enhanced performance","authors":"Ali Said, Ahmed Maraden, Tarek M. Elhedery, M. Yehia, Ahmed Saleh, M. Gaber Zaky, Sherif Elbasuney","doi":"10.1080/07370652.2024.2330965","DOIUrl":"https://doi.org/10.1080/07370652.2024.2330965","url":null,"abstract":"Whereas aluminum with combustion enthalpy of 32 KJ/g is the universal reactive metal particles, its passive protective oxide layer could encounter its efficient combustion. While titanium can offer...","PeriodicalId":15754,"journal":{"name":"Journal of Energetic Materials","volume":"280 1","pages":""},"PeriodicalIF":2.1,"publicationDate":"2024-03-20","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"140202012","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2024-03-18DOI: 10.1080/07370652.2024.2330969
Ali Said, Tarek M. Elhedery, Ahmed Maraden, Ali M. abd Elall, Shukri Ismael, Sherif Elbasuney
Passive oxide layer could expose a significant impact on reactive metal combustion. Boron and aluminum experience combustion enthalpy of 59.3 and 31.1 KJ/g and passive oxide layer of 200 and 7 nm, ...
{"title":"The significant role of passive oxide layer on reactive metal combustion: insights into composite solid propellant with superior performance","authors":"Ali Said, Tarek M. Elhedery, Ahmed Maraden, Ali M. abd Elall, Shukri Ismael, Sherif Elbasuney","doi":"10.1080/07370652.2024.2330969","DOIUrl":"https://doi.org/10.1080/07370652.2024.2330969","url":null,"abstract":"Passive oxide layer could expose a significant impact on reactive metal combustion. Boron and aluminum experience combustion enthalpy of 59.3 and 31.1 KJ/g and passive oxide layer of 200 and 7 nm, ...","PeriodicalId":15754,"journal":{"name":"Journal of Energetic Materials","volume":"40 1","pages":""},"PeriodicalIF":2.1,"publicationDate":"2024-03-18","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"140165500","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2024-03-18DOI: 10.1080/07370652.2024.2330966
Memdouh Chebbah, Fouad Benaliouche, Djalal Trache, Amir Abdelaziz, Ahmed Fouzi Tarchoun
In the present work, to enhance the thermal stability of nitrocellulose (NC), the effect of inorganic stabilizers, namely, Y-ammonium or Y-hydrogen zeolites, has been investigated. Comparative test...
{"title":"Effect of faujasite zeolites on the thermal stability and degradation kinetics of nitrocellulose","authors":"Memdouh Chebbah, Fouad Benaliouche, Djalal Trache, Amir Abdelaziz, Ahmed Fouzi Tarchoun","doi":"10.1080/07370652.2024.2330966","DOIUrl":"https://doi.org/10.1080/07370652.2024.2330966","url":null,"abstract":"In the present work, to enhance the thermal stability of nitrocellulose (NC), the effect of inorganic stabilizers, namely, Y-ammonium or Y-hydrogen zeolites, has been investigated. Comparative test...","PeriodicalId":15754,"journal":{"name":"Journal of Energetic Materials","volume":"26 1","pages":""},"PeriodicalIF":2.1,"publicationDate":"2024-03-18","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"140165582","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
The compatibility of binders and plasticizers has a significant influence on the properties of polymer-bonded explosives. Molecular dynamics was employed to explore the compatibility between nitroc...
{"title":"Evaluation of the compatibility of energetic nitrocellulose/plasticizer blends through molecular dynamics simulation","authors":"Weifeng Meng, Weihua Qin, Ting Zhang, Zhuiyue Guo, Yizheng Fu, Yanhua Lan","doi":"10.1080/07370652.2024.2330964","DOIUrl":"https://doi.org/10.1080/07370652.2024.2330964","url":null,"abstract":"The compatibility of binders and plasticizers has a significant influence on the properties of polymer-bonded explosives. Molecular dynamics was employed to explore the compatibility between nitroc...","PeriodicalId":15754,"journal":{"name":"Journal of Energetic Materials","volume":"86 1","pages":""},"PeriodicalIF":2.1,"publicationDate":"2024-03-15","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"140202402","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2024-02-15DOI: 10.1080/07370652.2024.2316145
Shengfan Bi, Yong Huang, Jinyu Zhao, Shuyao Wang, Hao Wang
The powder burn model is a mathematical model used to characterize the combustion behavior of energetic materials. In this paper, a parameter determination method for the powder burn model is propo...
粉末燃烧模型是一种用于描述高能材料燃烧行为的数学模型。本文提出了粉末燃烧模型的参数确定方法。
{"title":"A parameter determination method of powder burn model based on Levenberg-Marquardt optimization","authors":"Shengfan Bi, Yong Huang, Jinyu Zhao, Shuyao Wang, Hao Wang","doi":"10.1080/07370652.2024.2316145","DOIUrl":"https://doi.org/10.1080/07370652.2024.2316145","url":null,"abstract":"The powder burn model is a mathematical model used to characterize the combustion behavior of energetic materials. In this paper, a parameter determination method for the powder burn model is propo...","PeriodicalId":15754,"journal":{"name":"Journal of Energetic Materials","volume":"3 1","pages":""},"PeriodicalIF":2.1,"publicationDate":"2024-02-15","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"139760632","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2024-02-14DOI: 10.1080/07370652.2024.2316148
Wenxiang Bian, Yaning Li, Peng Bao, Boliang Wang
Ammonium dinitramide (ADN) has the advantages of chlorine free, low characteristic signal and high energy compared with ammonium perchlorate (AP), which is the most likely oxidant to replace ammoni...
{"title":"Comparative study on detonation parameters of ammonium dinitramide and ammonium perchlorate in composite explosives","authors":"Wenxiang Bian, Yaning Li, Peng Bao, Boliang Wang","doi":"10.1080/07370652.2024.2316148","DOIUrl":"https://doi.org/10.1080/07370652.2024.2316148","url":null,"abstract":"Ammonium dinitramide (ADN) has the advantages of chlorine free, low characteristic signal and high energy compared with ammonium perchlorate (AP), which is the most likely oxidant to replace ammoni...","PeriodicalId":15754,"journal":{"name":"Journal of Energetic Materials","volume":"16 1","pages":""},"PeriodicalIF":2.1,"publicationDate":"2024-02-14","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"139770995","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
5-amino-2,4,6-trinitrobenzene-1,3-diol (ATNBD) was synthesized using an improved literature method. The reactions of ATNBD with different N-bases (e.g., ammonia, hydrazine, hydroxylamine, and guani...
{"title":"Synthesis and investigation of 5-amino-2,4,6-trinitrobenzene-1,3-diol and its salts","authors":"Xingcheng Zhang, Jinchao Ma, Yeran Zhai, Dongxu Chen, Fangfang Zou, Qiuju Zhou, Luyao Chen","doi":"10.1080/07370652.2023.2300490","DOIUrl":"https://doi.org/10.1080/07370652.2023.2300490","url":null,"abstract":"5-amino-2,4,6-trinitrobenzene-1,3-diol (ATNBD) was synthesized using an improved literature method. The reactions of ATNBD with different N-bases (e.g., ammonia, hydrazine, hydroxylamine, and guani...","PeriodicalId":15754,"journal":{"name":"Journal of Energetic Materials","volume":"218 1","pages":""},"PeriodicalIF":2.1,"publicationDate":"2024-01-12","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"139481547","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2024-01-02DOI: 10.1080/07370652.2023.2295280
Matthias Muhr, Emre Ünal, Thomas Klapötke, Phillip Raschke
Hexamethylene triperoxide diamine (HMTD) is a commonly used homemade explosive due to its simple synthesis and availability of reactants. However, its impact sensitivity may vary significantly depe...
{"title":"Sensor-monitored impact sensitivity investigations on HMTD of different aging stages with accompanying PTR-TOF measurements of the substances","authors":"Matthias Muhr, Emre Ünal, Thomas Klapötke, Phillip Raschke","doi":"10.1080/07370652.2023.2295280","DOIUrl":"https://doi.org/10.1080/07370652.2023.2295280","url":null,"abstract":"Hexamethylene triperoxide diamine (HMTD) is a commonly used homemade explosive due to its simple synthesis and availability of reactants. However, its impact sensitivity may vary significantly depe...","PeriodicalId":15754,"journal":{"name":"Journal of Energetic Materials","volume":"5 1","pages":""},"PeriodicalIF":2.1,"publicationDate":"2024-01-02","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"139077649","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2024-01-02DOI: 10.1080/07370652.2022.2032484
A. F. Tarchoun, D. Trache, T. Klapötke, A. Abdelaziz, Slimane Bekhouche, Hani Boukeciat, Nassima Sahnoun
ABSTRACT This study reported the valorization of various alternative lignocellulosic feedstocks including giant reed (GR), palm fronds (PF) and esparto grass (EG) for the development of promising nitrated structurally modified cellulosic biopolymers (NNCs). The extracted nanostructured cellulose precursors and their nitrated derivatives were analyzed for their physicochemical properties, chemical structure, crystallinity and thermal stability. Experimental findings confirmed the successful formation of the desired energetic NNCs polymers with increased densities (1.698–1.711 g/cm3) and high nitrogen contents (13.10–13.26%) followed the order NNC-EG>NNC-PF>NNC-GR, which are greater than those of the commonly used nitrocellulose (1.650–1.670 g/cm3 and 12.50–12.70%). Furthermore, isoconversional integral models (TAS, it-KAS and VYA/CE) were exploited based on non-isothermal DSC data to investigate their thermal decomposition kinetics. The predicted kinetic parameters displayed that the synthesized energy-rich NNCs presented close values of Arrhenius parameters within the range of 156 ≤ Eα (kJ/mol) ≤163 and 14.7 ≤ Log(A(s−1) ≤ 15.6, and decomposed following diverse reaction mechanisms. Consequently, the explored lignocellulosic biomasses could be considered as valuable alternative non-woody resources for the production of advanced high-energy dense cellulosic biopolymers for potential application in the next generation of solid propellant formulations and composite explosives.
{"title":"Making progress towards promising energetic cellulosic microcrystals developed from alternative lignocellulosic biomasses","authors":"A. F. Tarchoun, D. Trache, T. Klapötke, A. Abdelaziz, Slimane Bekhouche, Hani Boukeciat, Nassima Sahnoun","doi":"10.1080/07370652.2022.2032484","DOIUrl":"https://doi.org/10.1080/07370652.2022.2032484","url":null,"abstract":"ABSTRACT This study reported the valorization of various alternative lignocellulosic feedstocks including giant reed (GR), palm fronds (PF) and esparto grass (EG) for the development of promising nitrated structurally modified cellulosic biopolymers (NNCs). The extracted nanostructured cellulose precursors and their nitrated derivatives were analyzed for their physicochemical properties, chemical structure, crystallinity and thermal stability. Experimental findings confirmed the successful formation of the desired energetic NNCs polymers with increased densities (1.698–1.711 g/cm3) and high nitrogen contents (13.10–13.26%) followed the order NNC-EG>NNC-PF>NNC-GR, which are greater than those of the commonly used nitrocellulose (1.650–1.670 g/cm3 and 12.50–12.70%). Furthermore, isoconversional integral models (TAS, it-KAS and VYA/CE) were exploited based on non-isothermal DSC data to investigate their thermal decomposition kinetics. The predicted kinetic parameters displayed that the synthesized energy-rich NNCs presented close values of Arrhenius parameters within the range of 156 ≤ Eα (kJ/mol) ≤163 and 14.7 ≤ Log(A(s−1) ≤ 15.6, and decomposed following diverse reaction mechanisms. Consequently, the explored lignocellulosic biomasses could be considered as valuable alternative non-woody resources for the production of advanced high-energy dense cellulosic biopolymers for potential application in the next generation of solid propellant formulations and composite explosives.","PeriodicalId":15754,"journal":{"name":"Journal of Energetic Materials","volume":"1 2","pages":"97 - 122"},"PeriodicalIF":2.1,"publicationDate":"2024-01-02","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"139124687","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
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