5-amino-2,4,6-trinitrobenzene-1,3-diol (ATNBD) was synthesized using an improved literature method. The reactions of ATNBD with different N-bases (e.g., ammonia, hydrazine, hydroxylamine, and guani...
{"title":"Synthesis and investigation of 5-amino-2,4,6-trinitrobenzene-1,3-diol and its salts","authors":"Xingcheng Zhang, Jinchao Ma, Yeran Zhai, Dongxu Chen, Fangfang Zou, Qiuju Zhou, Luyao Chen","doi":"10.1080/07370652.2023.2300490","DOIUrl":"https://doi.org/10.1080/07370652.2023.2300490","url":null,"abstract":"5-amino-2,4,6-trinitrobenzene-1,3-diol (ATNBD) was synthesized using an improved literature method. The reactions of ATNBD with different N-bases (e.g., ammonia, hydrazine, hydroxylamine, and guani...","PeriodicalId":15754,"journal":{"name":"Journal of Energetic Materials","volume":null,"pages":null},"PeriodicalIF":2.1,"publicationDate":"2024-01-12","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"139481547","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2024-01-02DOI: 10.1080/07370652.2023.2295280
Matthias Muhr, Emre Ünal, Thomas Klapötke, Phillip Raschke
Hexamethylene triperoxide diamine (HMTD) is a commonly used homemade explosive due to its simple synthesis and availability of reactants. However, its impact sensitivity may vary significantly depe...
{"title":"Sensor-monitored impact sensitivity investigations on HMTD of different aging stages with accompanying PTR-TOF measurements of the substances","authors":"Matthias Muhr, Emre Ünal, Thomas Klapötke, Phillip Raschke","doi":"10.1080/07370652.2023.2295280","DOIUrl":"https://doi.org/10.1080/07370652.2023.2295280","url":null,"abstract":"Hexamethylene triperoxide diamine (HMTD) is a commonly used homemade explosive due to its simple synthesis and availability of reactants. However, its impact sensitivity may vary significantly depe...","PeriodicalId":15754,"journal":{"name":"Journal of Energetic Materials","volume":null,"pages":null},"PeriodicalIF":2.1,"publicationDate":"2024-01-02","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"139077649","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2024-01-02DOI: 10.1080/07370652.2022.2032484
A. F. Tarchoun, D. Trache, T. Klapötke, A. Abdelaziz, Slimane Bekhouche, Hani Boukeciat, Nassima Sahnoun
ABSTRACT This study reported the valorization of various alternative lignocellulosic feedstocks including giant reed (GR), palm fronds (PF) and esparto grass (EG) for the development of promising nitrated structurally modified cellulosic biopolymers (NNCs). The extracted nanostructured cellulose precursors and their nitrated derivatives were analyzed for their physicochemical properties, chemical structure, crystallinity and thermal stability. Experimental findings confirmed the successful formation of the desired energetic NNCs polymers with increased densities (1.698–1.711 g/cm3) and high nitrogen contents (13.10–13.26%) followed the order NNC-EG>NNC-PF>NNC-GR, which are greater than those of the commonly used nitrocellulose (1.650–1.670 g/cm3 and 12.50–12.70%). Furthermore, isoconversional integral models (TAS, it-KAS and VYA/CE) were exploited based on non-isothermal DSC data to investigate their thermal decomposition kinetics. The predicted kinetic parameters displayed that the synthesized energy-rich NNCs presented close values of Arrhenius parameters within the range of 156 ≤ Eα (kJ/mol) ≤163 and 14.7 ≤ Log(A(s−1) ≤ 15.6, and decomposed following diverse reaction mechanisms. Consequently, the explored lignocellulosic biomasses could be considered as valuable alternative non-woody resources for the production of advanced high-energy dense cellulosic biopolymers for potential application in the next generation of solid propellant formulations and composite explosives.
{"title":"Making progress towards promising energetic cellulosic microcrystals developed from alternative lignocellulosic biomasses","authors":"A. F. Tarchoun, D. Trache, T. Klapötke, A. Abdelaziz, Slimane Bekhouche, Hani Boukeciat, Nassima Sahnoun","doi":"10.1080/07370652.2022.2032484","DOIUrl":"https://doi.org/10.1080/07370652.2022.2032484","url":null,"abstract":"ABSTRACT This study reported the valorization of various alternative lignocellulosic feedstocks including giant reed (GR), palm fronds (PF) and esparto grass (EG) for the development of promising nitrated structurally modified cellulosic biopolymers (NNCs). The extracted nanostructured cellulose precursors and their nitrated derivatives were analyzed for their physicochemical properties, chemical structure, crystallinity and thermal stability. Experimental findings confirmed the successful formation of the desired energetic NNCs polymers with increased densities (1.698–1.711 g/cm3) and high nitrogen contents (13.10–13.26%) followed the order NNC-EG>NNC-PF>NNC-GR, which are greater than those of the commonly used nitrocellulose (1.650–1.670 g/cm3 and 12.50–12.70%). Furthermore, isoconversional integral models (TAS, it-KAS and VYA/CE) were exploited based on non-isothermal DSC data to investigate their thermal decomposition kinetics. The predicted kinetic parameters displayed that the synthesized energy-rich NNCs presented close values of Arrhenius parameters within the range of 156 ≤ Eα (kJ/mol) ≤163 and 14.7 ≤ Log(A(s−1) ≤ 15.6, and decomposed following diverse reaction mechanisms. Consequently, the explored lignocellulosic biomasses could be considered as valuable alternative non-woody resources for the production of advanced high-energy dense cellulosic biopolymers for potential application in the next generation of solid propellant formulations and composite explosives.","PeriodicalId":15754,"journal":{"name":"Journal of Energetic Materials","volume":null,"pages":null},"PeriodicalIF":2.1,"publicationDate":"2024-01-02","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"139124687","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2024-01-01DOI: 10.1080/07370652.2023.2300467
M. Mosa, Mohamed Gobara, M. Mokhtar Kotb, Hany Fouda, Sherif Elbasuney
Heat-shielding composite materials containing asbestos has been used for thermal insulation of aerospace rocket motors. However, asbestos has carcinogenic effects on both human and environment. Thi...
{"title":"Nano-hydroxyapatite filled EPDM nanocomposite: towards green elastomeric thermal insulating coating with superior mechanical, thermal, and ablation properties","authors":"M. Mosa, Mohamed Gobara, M. Mokhtar Kotb, Hany Fouda, Sherif Elbasuney","doi":"10.1080/07370652.2023.2300467","DOIUrl":"https://doi.org/10.1080/07370652.2023.2300467","url":null,"abstract":"Heat-shielding composite materials containing asbestos has been used for thermal insulation of aerospace rocket motors. However, asbestos has carcinogenic effects on both human and environment. Thi...","PeriodicalId":15754,"journal":{"name":"Journal of Energetic Materials","volume":null,"pages":null},"PeriodicalIF":2.1,"publicationDate":"2024-01-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"139065194","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Adding energetic metallic particles (EMPs) into high explosive (HE) will increase total energy output, while the energy enhancement differs with the structure of composite explosives (CE). To inves...
{"title":"The efficient activation by adding Energetic metallic particles outside high explosives: a New direction for composite explosives","authors":"Chuan Xiao, Zhan-Dong Wang, Fang Chen, Yu-Xin Xu, Xiao-Long Jiao","doi":"10.1080/07370652.2023.2275196","DOIUrl":"https://doi.org/10.1080/07370652.2023.2275196","url":null,"abstract":"Adding energetic metallic particles (EMPs) into high explosive (HE) will increase total energy output, while the energy enhancement differs with the structure of composite explosives (CE). To inves...","PeriodicalId":15754,"journal":{"name":"Journal of Energetic Materials","volume":null,"pages":null},"PeriodicalIF":2.1,"publicationDate":"2023-12-23","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"139031119","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2023-12-20DOI: 10.1080/07370652.2023.2295259
Ruxin Zhang, Yinguang Xu, Fan Wang, Guangyuan Zhang, Haibin Hou, Lizhen Chen, Jianlong Wang
1-Acetyl-3,5-dinitro-1,3,5-triazacyclohexane, codenamed TAX, is a by-product of the RDX/HMX production process. The thermal decomposition process of TAX has not been studied at present. Understandi...
{"title":"Thermal decomposition mechanism study of 1-acetyl-3,5-dinitro-1,3,5-triazacyclohexane (TAX)","authors":"Ruxin Zhang, Yinguang Xu, Fan Wang, Guangyuan Zhang, Haibin Hou, Lizhen Chen, Jianlong Wang","doi":"10.1080/07370652.2023.2295259","DOIUrl":"https://doi.org/10.1080/07370652.2023.2295259","url":null,"abstract":"1-Acetyl-3,5-dinitro-1,3,5-triazacyclohexane, codenamed TAX, is a by-product of the RDX/HMX production process. The thermal decomposition process of TAX has not been studied at present. Understandi...","PeriodicalId":15754,"journal":{"name":"Journal of Energetic Materials","volume":null,"pages":null},"PeriodicalIF":2.1,"publicationDate":"2023-12-20","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"139031054","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
{"title":"Strategy for improving the energy output efficiency of TKX-50: introduction of nitroamine explosives","authors":"Shu-Ji Wang, Di Wang, Xiao-le Sun, Yong Hu, Peng-Fei Zhu, Xueyong Guo","doi":"10.1080/07370652.2023.2295281","DOIUrl":"https://doi.org/10.1080/07370652.2023.2295281","url":null,"abstract":"","PeriodicalId":15754,"journal":{"name":"Journal of Energetic Materials","volume":null,"pages":null},"PeriodicalIF":2.1,"publicationDate":"2023-12-17","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"138966115","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2023-11-29DOI: 10.1080/07370652.2023.2287466
Rajeev Ranjan, H. Murthy
Composite solid propellants (CSPs) are extensively used in solid rocket motors (SRMs) due to their excellent mechanical properties, stability, and high energy density. Lack of structural integrity ...
复合固体推进剂因其优异的力学性能、稳定性和高能量密度而广泛应用于固体火箭发动机。缺乏结构完整性……
{"title":"A review on material characterization of composite solid propellant","authors":"Rajeev Ranjan, H. Murthy","doi":"10.1080/07370652.2023.2287466","DOIUrl":"https://doi.org/10.1080/07370652.2023.2287466","url":null,"abstract":"Composite solid propellants (CSPs) are extensively used in solid rocket motors (SRMs) due to their excellent mechanical properties, stability, and high energy density. Lack of structural integrity ...","PeriodicalId":15754,"journal":{"name":"Journal of Energetic Materials","volume":null,"pages":null},"PeriodicalIF":2.1,"publicationDate":"2023-11-29","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"138539853","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2023-11-28DOI: 10.1080/07370652.2023.2287457
Benjamin D. Hirt, Chase W. Wernex, Alp Sehirlioglu, Metin Örnek, Steven F. Son
LiCoO2 (LCO) powders were protonated and their catalytic activity on the thermal decomposition of ammonium perchlorate (AP) was tested using differential scanning calorimetry and thermogravimetric ...
{"title":"Novel protonated LiCoO2 as a catalyst for the thermal decomposition of ammonium perchlorate","authors":"Benjamin D. Hirt, Chase W. Wernex, Alp Sehirlioglu, Metin Örnek, Steven F. Son","doi":"10.1080/07370652.2023.2287457","DOIUrl":"https://doi.org/10.1080/07370652.2023.2287457","url":null,"abstract":"LiCoO2 (LCO) powders were protonated and their catalytic activity on the thermal decomposition of ammonium perchlorate (AP) was tested using differential scanning calorimetry and thermogravimetric ...","PeriodicalId":15754,"journal":{"name":"Journal of Energetic Materials","volume":null,"pages":null},"PeriodicalIF":2.1,"publicationDate":"2023-11-28","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"138539852","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2023-11-16DOI: 10.1080/07370652.2023.2275198
Liying Dong, Yanqing Wu, Kun Yang, Junwu Zhu, Xiao Hou
Investigations on high-energy and low-vulnerability propellants can provide a better understanding for improving the operational effectiveness and survivability of strategic and tactical missiles. ...
对高能和低易损性推进剂的研究可以为提高战略和战术导弹的作战效能和生存能力提供更好的理解. ...
{"title":"Study on dynamic deformation-damage-ignition mechanism of GAP/RDX/TEGDN propellant","authors":"Liying Dong, Yanqing Wu, Kun Yang, Junwu Zhu, Xiao Hou","doi":"10.1080/07370652.2023.2275198","DOIUrl":"https://doi.org/10.1080/07370652.2023.2275198","url":null,"abstract":"Investigations on high-energy and low-vulnerability propellants can provide a better understanding for improving the operational effectiveness and survivability of strategic and tactical missiles. ...","PeriodicalId":15754,"journal":{"name":"Journal of Energetic Materials","volume":null,"pages":null},"PeriodicalIF":2.1,"publicationDate":"2023-11-16","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"138539851","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
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