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Aroma profile of the essential oil from different parts of Pimpinella tragium and subspecies population 金凤花不同部位挥发油及亚种种群的香气特征
IF 3 3区 农林科学 Q2 Chemistry Pub Date : 2023-07-20 DOI: 10.1080/10412905.2023.2234374
F. Askari, F. Sefidkon, Zohreh EMAMİ BİSTGANİ
ABSTRACT In this research, aroma profile variation among five population from different parts of Pimpinella tragium and its subspecies were evaluated. According to obtained results, the main chemical component of Pimpinella tragium Vill. in (Khoy) was germacrene D in seed with amount of (51.80%). In Pimpinella tragium Vill. (Ghoshchi), the predominant compound included trans-dictamnol (25.30%) in inflorescence, in addition, in the root part geijerene (26.70%) was the major constituent. Pimpinella tragium Vill. (Tabriz-Ahar), in inflorescence sabinine (36.30%), was introduced as the major compound. In the subspecies of Pimpinella tragium Vill. (Mazandaran), in inflorescence, sabinine (37.10%) was identified as the major constituent as well. In Pimpinella tragium (Alvand-Hamedan) germacrene D (43.5%) was identified in inflorescence as the major compound. In general, it seems that the high value of the essential oil composition within and among Pimpinella tragium and subspecies population could provide useful information for conservation and selection of cross-parents in breeding programs.
摘要本研究对5个种群不同部位的tragium Pimpinella及其亚种的香气谱进行了分析。所得结果表明,凤尾草的主要化学成分。在(Khoy)中,种子中含有germacrene D,含量为51.80%。在Pimpinella tragium村。其主要成分为反式双甘露醇(25.30%),根中主要成分为葛氏烯(26.70%)。凤头凤尾草。(Tabriz-Ahar)以sabinine(36.30%)为主要化合物。在凤尾花属亚种中。(Mazandaran),在花序中,sabinine(37.10%)也是主要成分。鸢尾花(Pimpinella tragium, Alvand-Hamedan)花序中主要化合物为germacrene D(43.5%)。综上所述,高价值的香精油组成可以为杂交亲本的保护和选择提供有用的信息。
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引用次数: 0
Quantification of coumarins, furocoumarins and polymethoxyflavones in hydroalcoholic fragrances by supercritical fluid chromatography‐tandem mass spectrometry 超临界流体色谱-串联质谱法定量分析水醇香精中的香豆素、呋喃香豆素和多甲氧基黄酮
IF 3 3区 农林科学 Q2 Chemistry Pub Date : 2023-07-17 DOI: 10.1080/10412905.2023.2236626
Maria Rita Testa Camillo, M. Russo, A. Trozzi, L. Mondello, P. Dugo
ABSTRACT Citrus essential oils, thanks to their pleasant aroma, are certainly the most used ingredients in the formulation of hydroalcoholic fragrances. The non-volatile fraction of Citrus essential oil is composed for 10–20% of coumarins, furocoumarins and polymethoxyflavones. It is well known that furocoumarins induce photosensitization and have potential carcinogenic and mutagenic effects. It follows that furocoumarins levels in cosmetics product are constantly monitored by opinions and regulations issued by the International Fragrance Association. The aim of this research article was to quantify coumarins, furocoumarins and polymethoxyflavones in thirty commercial hydroalcoholic fragrances using supercritical fluid chromatography in combination with triple quadrupole mass spectrometry technique (SFC-QqQ-MS). According to author’s knowledge, this is the first report on the determination of oxygen heterocyclic compounds in hydroalcoholic fragrances by means of SFC-QqQ-MS technique.
柑橘精油,由于其令人愉悦的香气,当然是最常用的成分,在配制水酒精香水。柑橘精油的非挥发性部分由香豆素,呋喃香豆素和多甲氧基黄酮组成的10-20%。众所周知,呋喃香豆素可诱导光敏,并具有潜在的致癌和致突变作用。因此,国际香氛协会发布的意见和法规不断监测化妆品中呋喃香豆素的含量。采用超临界流体色谱-三重四极杆质谱联用技术(SFC-QqQ-MS)对30种市售水醇香精中的香豆素、呋喃香豆素和多甲氧基黄酮进行定量分析。据笔者所知,本文首次报道了用SFC-QqQ-MS技术测定水醇香精中氧杂环类化合物。
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引用次数: 1
Chemical variability of flower essential oils of ten well-known cultivars of Paeonia × suffruticosa Andr 十个著名芍药品种花精油的化学变异
IF 3 3区 农林科学 Q2 Chemistry Pub Date : 2023-07-04 DOI: 10.1080/10412905.2023.2233508
Gaoming Lei, Chaoying Song, Liangxiu Huang, Shiwei Jian
ABSTRACT This study aimed at chemical variability of flower essential oils of 10 well-known cultivars of Paeonia × suffruticosa Andr. The essential oil yields ranged as 0.19–0.67% (w/w). The chemical compositions varied with cultivars. ‘Xueying Taohua’ essential oil had predominance of citronellol (56.4%). ‘Guifei Chacui’ essential oil was rich in citronellol (35.9%) and phloroglucinol trimethyl ether (25.3%). ‘Sheng Gejin’ and ‘Yuhou Fengguang’ essential oils were rich in phloroglucinol trimethyl ether (36.5%, 26.8%). ‘Yinhong Qiaodui’ essential oil contained geraniol + nerol (23.9%). Those from the other five cultivars did not present typical chemotypes. Nevertheless several compounds were noted, mainly germacrene D, heptadeca-6,9-diene, (Z)-hex-3-en-1-ol and linalool oxide (furan). ‘Luhe Hong’ essential oil contained the most unique components, including α-cadinol, τ-muurolol and δ-cadinene. Lack of phenylethyl alcohol was noticeable in some essential oil samples as compared with hydrolate extracts investigated previously. Multivariate analyses revealed four distinct clusters from all the essential oil samples.
摘要:本研究对10个知名芍药品种丹参花精油的化学变异进行了研究。精油得率为0.19 ~ 0.67% (w/w)。化学成分因品种而异。雪樱桃花精油中香茅醇含量最高(56.4%);桂妃茶翠精油中含有丰富的香茅醇(35.9%)和间苯三酚三甲基醚(25.3%)。“生歌金”和“雨后风光”精油中间苯三酚三甲基醚含量较高(分别为36.5%和26.8%)。银红巧兑精油中含有香叶醇+橙醇(23.9%)。其他5个品种均未表现出典型的化学型。尽管如此,还是发现了一些化合物,主要是烯丙烯D、十六烷基-6,9-二烯、(Z)-己-3-烯-1-醇和氧化芳樟醇(呋喃)。“鹿河红”精油中含有α-二羟基苯酚、τ-穆罗尔和δ-二羟基苯胺等最独特的化学成分。与先前研究的水合提取物相比,在一些精油样品中明显缺乏苯乙醇。多变量分析显示所有精油样品中有四个不同的聚类。
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引用次数: 0
Essential oil components with antidiabetic and anti-obesity properties: a review of mechanisms of action and toxicity 具有抗糖尿病和抗肥胖特性的精油成分:作用机制和毒性的综述
IF 3 3区 农林科学 Q2 Chemistry Pub Date : 2023-07-04 DOI: 10.1080/10412905.2023.2236625
Emmanuel U. Ejiofor, S. Oyedemi, C. Egedigwe-Ekeleme, C. Obike, Chinedu Aguwamba, P. Nweje-anyalowu, M. Ejiofor, Oluchi Okwuonu
ABSTRACT Diabetes and obesity are critical health concerns in the world, characterized by weak insulin secretion and activity, leading to increased blood glucose concentrations and an accumulation of excess body fat. There are conventional drugs currently used to treat these conditions, but they provide only short periods of glycemic control, are expensive, and are scarcely available in underdeveloped and developing countries. EOs are complex mixtures of aromatic and volatile compounds obtained from plants. They have numerous pharmacological and industrial applications, including anti-cancer, insecticidal, anti-microbial, anti-obesity, and antidiabetic. This review sought to investigate and organize established in vitro, in vivo, ex vivo, and in silico data, highlighting possible mechanisms of action of essential oils to treat and/or manage diabetes and obesity. The results showed that numerous essential oils from plant parts possess antidiabetic and anti-obesity properties, suggesting that essential oils can be exploited as potential antidiabetic and anti-obesity drugs.
糖尿病和肥胖症是世界范围内严重的健康问题,其特点是胰岛素分泌和活性减弱,导致血糖浓度升高和体脂积累过多。目前有一些常规药物用于治疗这些疾病,但它们只能提供短期的血糖控制,价格昂贵,而且在不发达国家和发展中国家几乎无法获得。精油是从植物中提取的芳香族和挥发性化合物的复杂混合物。它们有许多药理和工业应用,包括抗癌、杀虫、抗微生物、抗肥胖和抗糖尿病。本综述旨在调查和整理体外、体内、离体和计算机数据,强调精油治疗和/或控制糖尿病和肥胖的可能作用机制。结果表明,许多植物部位的精油具有抗糖尿病和抗肥胖的特性,提示精油可以作为潜在的抗糖尿病和抗肥胖药物开发。
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引用次数: 1
Investigation on effects of walnut essential oil against glutamate toxicity on cortex neuron and LN405 cancer cell lines, diabetes, and some microorganisms 核桃精油抗谷氨酸对皮层神经元、LN405癌细胞、糖尿病及部分微生物的毒性研究
IF 3 3区 农林科学 Q2 Chemistry Pub Date : 2023-07-04 DOI: 10.1080/10412905.2023.2234372
Fatma Yesilyurt, H. Yuca, S. Karakaya, Enes Tekman, B. Demirci, A. Taghizadehghalehjoughi, G. Göger, Muhammed Ziya Şahinöz, Mohaddeseh Nobari̇rezaeyeh, A. Hacimuftuoglu, Z. Güvenalp
ABSTRACT In this study, leaf essential oil effects on glutamate toxicity model formed in cortex neurons and LN405 cell cultures were investigated. Antidiabetic activity was evaluated by α-amylase and α-glucosidase inhibitions. MIC was used for antimicrobial activity. Seven groups were examined with MTT. Glutamate 10-5 mM in cortex showed 62% viability whereas oil viability did not increase in a dose-dependent manner and the highest viability rate was observed. There are four types of glandular trichomes in leaf anatomy of walnut. The oil exhibited half as much α-glucosidase inhibitory activity with an IC50 value of 8105 μg/mL, compared to positive control acarbose (IC50 = 4762 μg/mL). MIC of oil was determined to be 625 μg/mL against E. coli, C. albicans, and C. parapsilosis, whereas S. aureus exhibited a MIC of 1250 μg/mL. Major compounds of oil were found as β-pinene (17.6%), α-pinene (11.3%), β-eudesmol (8.6%), and caryophyllene oxide (6.2%).
摘要本研究探讨了叶精油对皮层神经元和LN405细胞谷氨酸毒性模型的影响。通过α-淀粉酶和α-葡萄糖苷酶的抑制作用来评价其抗糖尿病活性。MIC法测定其抑菌活性。7组采用MTT检测。谷氨酸10-5 mM在皮层的存活率为62%,而油的存活率不随剂量增加而增加,其存活率最高。核桃叶片解剖中有四种类型的腺毛。与阳性对照阿卡波糖(IC50 = 4762 μg/mL)相比,其α-葡萄糖苷酶抑制活性为8105 μg/mL。结果表明,精油对大肠杆菌、白色念珠菌和假丝酵母菌的MIC为625 μg/mL,对金黄色葡萄球菌的MIC为1250 μg/mL。主要化合物为β-蒎烯(17.6%)、α-蒎烯(11.3%)、β-桉树酚(8.6%)和石竹烯氧化物(6.2%)。
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引用次数: 0
The employment for high-density polyethylene active packages (HDPAP) bottles containing Coriandrum sativum (Corainder) essential oil in the improvement of the oxidative stability of sunflower oil 采用高密度聚乙烯活性包装(HDPAP)瓶盛装芫荽(Corainder)精油,提高了葵花籽油的氧化稳定性
IF 3 3区 农林科学 Q2 Chemistry Pub Date : 2023-07-04 DOI: 10.1080/10412905.2023.2232788
Dongying Wang, Haohao Wu, Hao Yang, Yongliang Yu, Xuede Wang
ABSTRACT In this research, the effect of high-density polyethylene active packaging (HDPAP) bottles containing Coriandrum sativum essential oil (CSEO) on the oxidation stability and sensory attributes of sunflower oil (SFO) during the accelerated storage was investigated. The migration test showed that the CSEO could migrate from the package to SFO. In the accelerated storage procedure at 65°C, the increase in the levels of acid value (AV), peroxide value (PV), p-anisidine value (AnV), thiobarbituric acid reactive substances (TBARS), conjugated dienes (K232) and conjugated trienes (K268) of SFO samples was significantly inhibited after the sunflower oil packaged by the HAPAP containing CSEO at 6000 ppm (p < .05), which showed that the HDPAP bottle containing CSEO could delay the oxidation of SFO.   Therefore, the results demonstrated that employment of HDPAP bottles containing CSEO at 6000 ppm could be applied as a good replacement for the direct addition of synthetic antioxidants to the SFO.
摘要本研究考察了含有芫荽籽精油(CSEO)的高密度聚乙烯活性包装(HDPAP)瓶在加速贮藏过程中对葵花籽油(SFO)氧化稳定性和感官特性的影响。迁移测试表明,CSEO可以从包迁移到SFO。在65℃加速贮藏过程中,含有CSEO的HAPAP包装的葵花籽油在6000 ppm时,其酸值(AV)、过氧化物值(PV)、对茴香胺值(AnV)、硫代巴比托酸活性物质(TBARS)、共轭二烯(K232)和共轭三烯(K268)水平的升高被显著抑制(p < 0.05),表明含有CSEO的HDPAP瓶可以延缓SFO的氧化。因此,结果表明,使用含有6000ppm CSEO的HDPAP瓶可以很好地替代直接向SFO中添加合成抗氧化剂。
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引用次数: 0
Essential oil variability of Thymus persicus (Ronniger ex Rech.f.) Jalas (Lamiaceae) during in vitro regeneration and ex situ domestication 胸腺精油的变异研究蓝藻科植物的离体再生和离地驯化
IF 3 3区 农林科学 Q2 Chemistry Pub Date : 2023-07-03 DOI: 10.1080/10412905.2023.2232813
Z. Bakhtiar, A. Sonboli, M. Mirjalili
ABSTRACT Thymus persicus (Lamiaceae) is a range-restricted endemic medicinal and aromatic plant from northwest of Iran. Due to the medicinal importance and over-exploitation of the plant from its natural habitats, conservationand ex situ cultivation of the plant is needed. In the present study, essential oil variability of the plant during its in vitro conservation including in vitro regenerated plant (RP) and acclimated plant (AP) was assessed by GC-FID and GC-MS, and compared with those of growing wild plant (WP). In total, 44, 25 and 25 compounds representing 98.5%, 98.7% and 98.1% were identified in the oils of WP, RP and AP, respectively. The major identified components in the oils were 4,8-β-epoxy-caryophyllene (2.3–10.7%), α-terpineol (9.5–39.2%), linalool (5.7–15.7%) and thymol (2.6–32.8%). In vitro RP with the highest content of thymol had the greatest distance with WP. The AP was also significantly dominated with a large difference in α-terpineol.
麝香(胸腺科)是伊朗西北部的一种地方性药用和芳香植物。由于药用价值和对其自然栖息地的过度开发,需要对其进行保护和移地栽培。本研究采用气相色谱- fid和气相色谱-质谱(GC-MS)分析了该植物在离体保存过程中(包括离体再生植物(RP)和驯化植物(AP))挥发油的变异性,并与生长野生植物(WP)进行了比较。共鉴定出44种、25种和25种化合物,分别占98.5%、98.7%和98.1%。主要鉴定成分为4,8-β-环氧石竹烯(2.3 ~ 10.7%)、α-松油醇(9.5 ~ 39.2%)、芳樟醇(5.7 ~ 15.7%)和百里香酚(2.6 ~ 32.8%)。百里酚含量最高的RP与WP的距离最大。AP也以α-松油醇含量差异较大为主。
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引用次数: 0
Elettaria cardamomum leaves, an underutilized resource: chemical profile of its essential oil and insecticidal activity 未充分利用的小豆叶:其精油的化学成分及其杀虫活性
IF 3 3区 农林科学 Q2 Chemistry Pub Date : 2023-05-02 DOI: 10.1080/10412905.2023.2197437
Akhil Kumar, Rajani Kurup Sukumaryamma Remadevi, A. J. Johnson, Vinayak Venukumar, Farzana M Sha, T. S. Varghese, Sabulal Baby
ABSTRACT Elettaria cardamomum is known as the ‘Queen of spices’; its leaf essential oil (EO) is least investigated and barely utilized. Here we report the chemical composition of E. cardamomum leaf EOs collected from five locations in the southern Western Ghats in India. EOs of fresh and dry capsules were also analyzed for comparison of their chemical profiles. The major constituents in cardamom leaf EOs were β-pinene (35.6–51.9%) and coronarin E (17.7–34.2%). In fumigant toxicity assays against two stored product pests, lowest LC50 against Tribolium castaneum was recorded in EO of fresh capsules (124.05 µL/L), followed by dry capsules (LC50 128.21 µL/L) and leaves (LC50 148.00 µL/L); LC50s of fresh, dry capsule and leaf EOs against Sitophilus oryzae were 30.24, 35.33 and 89.42 µL/L, respectively. This study demonstrates cardamom leaves as a source of untapped bioactive principles which can be viably utilized for the production of botanical pesticides.
小豆蔻被誉为“香料女王”;其叶精油(EO)的研究最少,几乎没有利用。在这里,我们报告了从印度西高止山脉南部五个地点收集的E. cardamomum叶的化学成分。还分析了鲜胶囊和干胶囊的EOs,比较了它们的化学特征。豆蔻叶精油的主要成分为β-蒎烯(35.6% ~ 51.9%)和冠素E(17.7% ~ 34.2%)。在熏蒸剂对两种储存品害虫的毒力测定中,鲜胶囊EO的LC50最低(124.05µL/L),其次是干胶囊EO(128.21µL/L)和叶片EO(148.00µL/L);鲜、干胶囊和叶片对米象虫的lc50分别为30.24、35.33和89.42µL/L。本研究表明,豆蔻叶是一种未开发的生物活性物质,可以有效地用于植物性农药的生产。
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引用次数: 0
The potential of culinary herbs and spices from the genera Curcuma and Zingiber in the management of type 2 diabetes mellitus and Alzheimer’s disease 姜黄和姜属烹饪草药和香料在2型糖尿病和阿尔茨海默病治疗中的潜力
IF 3 3区 农林科学 Q2 Chemistry Pub Date : 2023-04-11 DOI: 10.1080/10412905.2023.2196521
Y. Sivasothy, Usha Sundralingam, Asly Poh-Tze Goh, Toh Kar Men, Kelvin Voon Jian Min
ABSTRACT The consumption of culinary herbs and spices in our daily dietary intake has been known to reduce the risk of developing chronic diseases. The efficacy of these seasoning agents towards preventing or alleviating chronic diseases is facilitated through the synergistic effect of their secondary metabolites. A majority of the scientific reviews which have been conducted till present emphasise that the positive effects of culinary herbs and spices on human health is predominantly due to the presence of dietary polyphenols. This review however will focus on the therapeutic benefits of essential oils of culinary herbs and spices from the genera Curcuma and Zingiber in the management of Type 2 Diabetes Mellitus and Alzheimer’s Disease.
在我们的日常饮食中摄入烹饪草药和香料已经知道可以降低患慢性疾病的风险。这些调味剂预防或减轻慢性疾病的功效是通过其次生代谢产物的协同作用来促进的。迄今为止进行的大多数科学审查都强调,烹饪草药和香料对人类健康的积极影响主要是由于膳食中存在多酚。然而,本综述将重点关注姜黄属和姜属烹饪草药和香料精油在2型糖尿病和阿尔茨海默病治疗中的疗效。
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引用次数: 0
Sesquiterpenes from Pistacia lentiscus L. as potential antibacterial, antifungal and allelopathic agents 从黄连木中提取倍半萜作为潜在的抗菌、抗真菌和化感剂
IF 3 3区 农林科学 Q2 Chemistry Pub Date : 2023-04-03 DOI: 10.1080/10412905.2023.2196527
S. Rguez, W. Aidi Wannes, S. Bourgou, R. Essid, Iness Bettaieb, Mejdi Snoussi, M. Hammami, I. H. Sellami
ABSTRACT The present study investigated the antibacterial, antifungal and allelopathic activities of Pistacia lentiscus essential oils (EOs) isolated at the vegetative, flowering and fructification stages. The chemical composition of EOs varied according to both the phenological stages and the used mix plant parts. The main chemical class was sesquiterpene hydrocarbons with the predominance of germacrene D, δ-cadinene and β-caryophyllene. The antibacterial activity was evaluated against five collection strains. At the vegetative stage, P. lentiscus EO was the most effective against Listeria monocytogenes and Echerchia coli as compared to the other stages. P. lentiscus EO also exhibited significant antifungal activity against the phytopathogenic strain Botrytis cinerea. Microscopic observation showed that EO induced swelling and crumbling of B. cinerea conidia. Moreover, P. lentiscus EO at the vegetative stage possessed significant allelopathic activity by inhibiting low concentration the germination and radical elongation of Raphanus sativus and radical elongation of Lepidium sativum.
摘要本研究研究了黄连木(Pistacia lentiscus)在营养、开花和结果期的抑菌、抗真菌和化感作用。不同的物候阶段和混合植物的不同部位,其化学成分也不同。其主要化学类为倍半萜烃,主要为γ -癸烯D、δ-癸烯和β-石竹烯。对5株收集菌株进行抑菌活性评价。在营养阶段,与其他阶段相比,P. lentiscus EO对单核增生李斯特菌和大肠埃希菌的抑制效果最好。P. lentiscus EO对植物病原菌灰霉病菌(Botrytis cinerea)也有显著的抗真菌活性。显微镜下观察发现,EO可引起葡萄球菌分生孢子的肿胀和破碎。营养期扁豆提取物具有明显的化感作用,可以抑制低浓度莴苣的萌发和根伸长,也可以抑制小黄草的根伸长。
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引用次数: 0
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Journal of Essential Oil Research
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