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Continual misidentification of 5-oxolinalool as 2-methylnon-2-en-4-one in essential oils 在精油中,5- oxolinalol连续被误认为是2-甲基non-2-en-4-one
IF 3 3区 农林科学 Q3 CHEMISTRY, APPLIED Pub Date : 2023-08-20 DOI: 10.1080/10412905.2023.2247401
Vidak N. Raičević, N. Radulović
ABSTRACT When employing GC and GC-MS, constituents of essential oils are most frequently identified by comparing retention indices and mass spectra with those reported in the literature or analytical libraries. While this allows for a rapid analysis, incorrect data can lead to a constituent being repeatedly misidentified. This was demonstrated in this work for 5-oxolinalool (6-hydroxy-2,6-dimethylocta-2,7-dien-4-one), an oxygenated monoterpene that was often erroneously identified as 2-methylnon-2-en-4-one. After encountering an unknown constituent of the essential oil of Sambucus nigra L. (Viburnaceae) flowers, we sought to acquire relevant analytical data on both compounds. Even though their mass spectra were rather similar (with 2-methylnon-2-en-4-one missing the peak at m/z 71), their retention indices were found to be significantly different. It follows that a revision of all prior identifications of 2-methylnon-2-en-4-one as an essential-oil constituent is needed.
当使用GC和GC- ms时,最常用的方法是通过与文献或分析库中报道的保留指数和质谱进行比较来鉴定精油的成分。虽然这允许快速分析,但不正确的数据可能导致组件反复被错误识别。在这项研究中,5-oxolinalool(6-羟基-2,6-二甲基locta-2,7-二烯-4-one)证明了这一点,这是一种氧合单萜,经常被错误地识别为2-甲基non-2-en-4-one。在遇到黑参花精油的未知成分后,我们寻求获得这两种化合物的相关分析数据。尽管它们的质谱相当相似(2-甲基-2-en-4- 1在m/z 71处没有峰),但它们的保留指数却有显著差异。因此,需要对所有先前鉴定的2-甲基non-2-en-4-one作为精油成分进行修订。
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引用次数: 0
Chemical constituents, antioxidant and antibacterial activities of essential oils of Ochna afzelii (R. Br. ex Oliv.) 红花挥发油的化学成分及抗氧化、抗菌活性研究。摘要交货)。
IF 3 3区 农林科学 Q3 CHEMISTRY, APPLIED Pub Date : 2023-08-10 DOI: 10.1080/10412905.2023.2243952
Edith N. Ibeh, M. Adeyemi, O. Olaoluwa, O. M. Taiwo, G. Flamini
ABSTRACT      Essential oils (EOs) from Ochna afzelii leaves, stems and roots were extracted and characterised by hydrodistillation and Gas Chromatogragphy-Mass Spectrometry (GC/MS) techniques, respectively. Antioxidant activity was evaluated by 2,2-diphenyl-1-picrylhydrazyl (DPPH*) method while antibacterial activity was determined using agar well diffusion and broth microdilution methods. Leaf, stem, and root oils afforded thirteen, ten and seven compounds, respectively, which were characterized by a high percentage of oxygenated sesquiterpenes and sesquiterpene hydrocarbons. The major compound in O. afzelii leaf and root EOs was β-Atlantol, while the O. afzelii stem EO had (E)-β-ionone as its major compound. The leaf oil displayed highest antioxidant activity (IC50 = 238.14 µL/mL). All the EOs showed antibacterial activities against Escherichia coli, Pseudomonas aeruginosa, Salmonella typhi, and Streptococcus pneumoniae, with the zones of inhibition and MIC values ranging from 12.0–18.0 mm and 2.5–10 µL/mL, respectively. O. afzelii has a mild antioxidant effect, but can be a potential source of natural antibacterial agents.
摘要采用水蒸气蒸馏法、气相色谱-质谱联用(GC/MS)技术分别从红花叶、茎和根中提取精油。采用2,2-二苯基-1-苦味酰肼(DPPH*)法测定抗氧化活性,采用琼脂孔扩散法和肉汤微量稀释法测定抗菌活性。叶油、茎油和根油分别含有13种、10种和7种化合物,其特征是含氧倍半萜烯和倍半萜烯碳氢化合物的比例很高。枫香叶和根的主要成分为β-寰环醇,而枫香茎的主要成分为(E)-β-离子酮。叶精油的抗氧化活性最高(IC50 = 238.14µL/mL)。所有EOs对大肠杆菌、铜绿假单胞菌、伤寒沙门氏菌和肺炎链球菌均有抑菌活性,抑菌区和MIC值分别为12.0 ~ 18.0 mm和2.5 ~ 10µL/mL。黄芪具有温和的抗氧化作用,但也可能是天然抗菌剂的潜在来源。
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引用次数: 0
The effect of exposure to Mentha suaveolens Ehrh. essential oil on the electroencephalographic activity according to gender difference 暴露于薄荷的影响。精油对脑电图活动的影响根据性别而不同
IF 3 3区 农林科学 Q3 CHEMISTRY, APPLIED Pub Date : 2023-08-08 DOI: 10.1080/10412905.2023.2240798
E. Napoli, Minju Kim, K. Sowndhararajan, G. Ruberto, Songmun Kim
ABSTRACT Mentha suaveolens Ehrh. is an aromatic herb, traditionally used in the Mediterranean areas. Our objective was to evaluate the effect of inhalation of a commercial essential oil of M. suaveolens on human electroencephalographic (EEG) activity according to gender differences by measuring EEG power spectrum changes in healthy participants. Piperitenone oxide (55.60%) was the most abundant component in the essential oil. Our findings indicated that the inhalation of M. suaveolens essential oil produced different EEG power spectrum changes as well as affected different brain regions between genders.    It could be concluded that the inhalation of M. suaveolens essential oil significantly changed the EEG wave activity according to gender and these changes may cause some alterations in the psychophysiological functions of humans. Hence, M. suaveolens essential oil may be utilized in aromatherapy for improving the psychophysiological functions of humans.
薄荷是一种甜薄荷。是一种芳香的草药,传统上用于地中海地区。我们的目的是通过测量健康参与者的脑电图功率谱变化来评估吸入一种商业精油对人类脑电图(EEG)活动的影响,这种影响是基于性别差异的。精油中含量最高的成分为氧化胡椒烯酮(55.60%)。研究结果表明,不同性别的人吸入苦参精油会产生不同的脑电图功率谱变化,并影响不同的脑区。综上所述,吸入苦参精油显著改变了不同性别的脑电波活动,这些变化可能引起人类心理生理功能的改变。因此,番石榴精油可用于芳香疗法,以改善人的心理生理功能。
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引用次数: 0
Some quality and essential oil classifications of Turkish aniseed (Pimpinella anisum L.) 土耳其大料(Pimpinella anisum L.)品质及精油分类
IF 3 3区 农林科学 Q3 CHEMISTRY, APPLIED Pub Date : 2023-08-02 DOI: 10.1080/10412905.2023.2240802
Ayşe Betül Avcı, M. Göre, B. Öztürk
ABSTRACT For industries that use aniseed as a raw material, essential oil content and aroma composition are critical factors. Anise fruits were collected from 15 locations to determine these criteria. The essential oil procured by hydrodistillation was analysed by gas chromatography (GC) and gas chromatography–mass spectrometry (GC – MS). The locations were divided into five classes according to the cluster analysis of essential oil components. The most important components that made up the classes were estragole (2.33%), trans–anethole (93.90%), cis-anethole (0.21%), carvone (0.097%), p-anisaldehyde (0.651%), longifolene (1.35%), carvacrol (0.06%) and α-himachalane (0.12%). The rate of essential oil varied between 0.33-3.01% in the locations. Trans–anethole is the main component of the essential oil, while their rates changed according to the populations (90.8–96.6%). Location has a significant (p ≤ 0.05) effect on the essential oil, fruit width, fruit length and a thousand fruit weight; furthermore, it is positively related.
对于以大料为原料的行业来说,精油含量和香气成分是关键因素。从15个地点收集大茴香果实来确定这些标准。采用气相色谱(GC)和气相色谱-质谱联用(GC - MS)对加氢蒸馏所得精油进行分析。根据精油成分的聚类分析,将其划分为5类。主要成分为雌二醇(2.33%)、反式茴香醚(93.90%)、顺式茴香醚(0.21%)、香芹酮(0.097%)、对茴香醛(0.651%)、长叶烯(1.35%)、香芹酚(0.06%)和α-马马烷(0.12%)。各产地精油含量在0.33 ~ 3.01%之间。反式茴香醚是香精油的主要成分,其含量随种群而变化(90.8 ~ 96.6%)。地点对挥发油、果宽、果长、千果重的影响显著(p≤0.05);此外,它是正相关的。
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引用次数: 0
Aroma profile of the essential oil from different parts of Pimpinella tragium and subspecies population 金凤花不同部位挥发油及亚种种群的香气特征
IF 3 3区 农林科学 Q3 CHEMISTRY, APPLIED Pub Date : 2023-07-20 DOI: 10.1080/10412905.2023.2234374
F. Askari, F. Sefidkon, Zohreh EMAMİ BİSTGANİ
ABSTRACT In this research, aroma profile variation among five population from different parts of Pimpinella tragium and its subspecies were evaluated. According to obtained results, the main chemical component of Pimpinella tragium Vill. in (Khoy) was germacrene D in seed with amount of (51.80%). In Pimpinella tragium Vill. (Ghoshchi), the predominant compound included trans-dictamnol (25.30%) in inflorescence, in addition, in the root part geijerene (26.70%) was the major constituent. Pimpinella tragium Vill. (Tabriz-Ahar), in inflorescence sabinine (36.30%), was introduced as the major compound. In the subspecies of Pimpinella tragium Vill. (Mazandaran), in inflorescence, sabinine (37.10%) was identified as the major constituent as well. In Pimpinella tragium (Alvand-Hamedan) germacrene D (43.5%) was identified in inflorescence as the major compound. In general, it seems that the high value of the essential oil composition within and among Pimpinella tragium and subspecies population could provide useful information for conservation and selection of cross-parents in breeding programs.
摘要本研究对5个种群不同部位的tragium Pimpinella及其亚种的香气谱进行了分析。所得结果表明,凤尾草的主要化学成分。在(Khoy)中,种子中含有germacrene D,含量为51.80%。在Pimpinella tragium村。其主要成分为反式双甘露醇(25.30%),根中主要成分为葛氏烯(26.70%)。凤头凤尾草。(Tabriz-Ahar)以sabinine(36.30%)为主要化合物。在凤尾花属亚种中。(Mazandaran),在花序中,sabinine(37.10%)也是主要成分。鸢尾花(Pimpinella tragium, Alvand-Hamedan)花序中主要化合物为germacrene D(43.5%)。综上所述,高价值的香精油组成可以为杂交亲本的保护和选择提供有用的信息。
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引用次数: 0
Quantification of coumarins, furocoumarins and polymethoxyflavones in hydroalcoholic fragrances by supercritical fluid chromatography‐tandem mass spectrometry 超临界流体色谱-串联质谱法定量分析水醇香精中的香豆素、呋喃香豆素和多甲氧基黄酮
IF 3 3区 农林科学 Q3 CHEMISTRY, APPLIED Pub Date : 2023-07-17 DOI: 10.1080/10412905.2023.2236626
Maria Rita Testa Camillo, M. Russo, A. Trozzi, L. Mondello, P. Dugo
ABSTRACT Citrus essential oils, thanks to their pleasant aroma, are certainly the most used ingredients in the formulation of hydroalcoholic fragrances. The non-volatile fraction of Citrus essential oil is composed for 10–20% of coumarins, furocoumarins and polymethoxyflavones. It is well known that furocoumarins induce photosensitization and have potential carcinogenic and mutagenic effects. It follows that furocoumarins levels in cosmetics product are constantly monitored by opinions and regulations issued by the International Fragrance Association. The aim of this research article was to quantify coumarins, furocoumarins and polymethoxyflavones in thirty commercial hydroalcoholic fragrances using supercritical fluid chromatography in combination with triple quadrupole mass spectrometry technique (SFC-QqQ-MS). According to author’s knowledge, this is the first report on the determination of oxygen heterocyclic compounds in hydroalcoholic fragrances by means of SFC-QqQ-MS technique.
柑橘精油,由于其令人愉悦的香气,当然是最常用的成分,在配制水酒精香水。柑橘精油的非挥发性部分由香豆素,呋喃香豆素和多甲氧基黄酮组成的10-20%。众所周知,呋喃香豆素可诱导光敏,并具有潜在的致癌和致突变作用。因此,国际香氛协会发布的意见和法规不断监测化妆品中呋喃香豆素的含量。采用超临界流体色谱-三重四极杆质谱联用技术(SFC-QqQ-MS)对30种市售水醇香精中的香豆素、呋喃香豆素和多甲氧基黄酮进行定量分析。据笔者所知,本文首次报道了用SFC-QqQ-MS技术测定水醇香精中氧杂环类化合物。
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引用次数: 1
Chemical variability of flower essential oils of ten well-known cultivars of Paeonia × suffruticosa Andr 十个著名芍药品种花精油的化学变异
IF 3 3区 农林科学 Q3 CHEMISTRY, APPLIED Pub Date : 2023-07-04 DOI: 10.1080/10412905.2023.2233508
Gaoming Lei, Chaoying Song, Liangxiu Huang, Shiwei Jian
ABSTRACT This study aimed at chemical variability of flower essential oils of 10 well-known cultivars of Paeonia × suffruticosa Andr. The essential oil yields ranged as 0.19–0.67% (w/w). The chemical compositions varied with cultivars. ‘Xueying Taohua’ essential oil had predominance of citronellol (56.4%). ‘Guifei Chacui’ essential oil was rich in citronellol (35.9%) and phloroglucinol trimethyl ether (25.3%). ‘Sheng Gejin’ and ‘Yuhou Fengguang’ essential oils were rich in phloroglucinol trimethyl ether (36.5%, 26.8%). ‘Yinhong Qiaodui’ essential oil contained geraniol + nerol (23.9%). Those from the other five cultivars did not present typical chemotypes. Nevertheless several compounds were noted, mainly germacrene D, heptadeca-6,9-diene, (Z)-hex-3-en-1-ol and linalool oxide (furan). ‘Luhe Hong’ essential oil contained the most unique components, including α-cadinol, τ-muurolol and δ-cadinene. Lack of phenylethyl alcohol was noticeable in some essential oil samples as compared with hydrolate extracts investigated previously. Multivariate analyses revealed four distinct clusters from all the essential oil samples.
摘要:本研究对10个知名芍药品种丹参花精油的化学变异进行了研究。精油得率为0.19 ~ 0.67% (w/w)。化学成分因品种而异。雪樱桃花精油中香茅醇含量最高(56.4%);桂妃茶翠精油中含有丰富的香茅醇(35.9%)和间苯三酚三甲基醚(25.3%)。“生歌金”和“雨后风光”精油中间苯三酚三甲基醚含量较高(分别为36.5%和26.8%)。银红巧兑精油中含有香叶醇+橙醇(23.9%)。其他5个品种均未表现出典型的化学型。尽管如此,还是发现了一些化合物,主要是烯丙烯D、十六烷基-6,9-二烯、(Z)-己-3-烯-1-醇和氧化芳樟醇(呋喃)。“鹿河红”精油中含有α-二羟基苯酚、τ-穆罗尔和δ-二羟基苯胺等最独特的化学成分。与先前研究的水合提取物相比,在一些精油样品中明显缺乏苯乙醇。多变量分析显示所有精油样品中有四个不同的聚类。
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引用次数: 0
Investigation on effects of walnut essential oil against glutamate toxicity on cortex neuron and LN405 cancer cell lines, diabetes, and some microorganisms 核桃精油抗谷氨酸对皮层神经元、LN405癌细胞、糖尿病及部分微生物的毒性研究
IF 3 3区 农林科学 Q3 CHEMISTRY, APPLIED Pub Date : 2023-07-04 DOI: 10.1080/10412905.2023.2234372
Fatma Yesilyurt, H. Yuca, S. Karakaya, Enes Tekman, B. Demirci, A. Taghizadehghalehjoughi, G. Göger, Muhammed Ziya Şahinöz, Mohaddeseh Nobari̇rezaeyeh, A. Hacimuftuoglu, Z. Güvenalp
ABSTRACT In this study, leaf essential oil effects on glutamate toxicity model formed in cortex neurons and LN405 cell cultures were investigated. Antidiabetic activity was evaluated by α-amylase and α-glucosidase inhibitions. MIC was used for antimicrobial activity. Seven groups were examined with MTT. Glutamate 10-5 mM in cortex showed 62% viability whereas oil viability did not increase in a dose-dependent manner and the highest viability rate was observed. There are four types of glandular trichomes in leaf anatomy of walnut. The oil exhibited half as much α-glucosidase inhibitory activity with an IC50 value of 8105 μg/mL, compared to positive control acarbose (IC50 = 4762 μg/mL). MIC of oil was determined to be 625 μg/mL against E. coli, C. albicans, and C. parapsilosis, whereas S. aureus exhibited a MIC of 1250 μg/mL. Major compounds of oil were found as β-pinene (17.6%), α-pinene (11.3%), β-eudesmol (8.6%), and caryophyllene oxide (6.2%).
摘要本研究探讨了叶精油对皮层神经元和LN405细胞谷氨酸毒性模型的影响。通过α-淀粉酶和α-葡萄糖苷酶的抑制作用来评价其抗糖尿病活性。MIC法测定其抑菌活性。7组采用MTT检测。谷氨酸10-5 mM在皮层的存活率为62%,而油的存活率不随剂量增加而增加,其存活率最高。核桃叶片解剖中有四种类型的腺毛。与阳性对照阿卡波糖(IC50 = 4762 μg/mL)相比,其α-葡萄糖苷酶抑制活性为8105 μg/mL。结果表明,精油对大肠杆菌、白色念珠菌和假丝酵母菌的MIC为625 μg/mL,对金黄色葡萄球菌的MIC为1250 μg/mL。主要化合物为β-蒎烯(17.6%)、α-蒎烯(11.3%)、β-桉树酚(8.6%)和石竹烯氧化物(6.2%)。
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引用次数: 0
Essential oil components with antidiabetic and anti-obesity properties: a review of mechanisms of action and toxicity 具有抗糖尿病和抗肥胖特性的精油成分:作用机制和毒性的综述
IF 3 3区 农林科学 Q3 CHEMISTRY, APPLIED Pub Date : 2023-07-04 DOI: 10.1080/10412905.2023.2236625
Emmanuel U. Ejiofor, S. Oyedemi, C. Egedigwe-Ekeleme, C. Obike, Chinedu Aguwamba, P. Nweje-anyalowu, M. Ejiofor, Oluchi Okwuonu
ABSTRACT Diabetes and obesity are critical health concerns in the world, characterized by weak insulin secretion and activity, leading to increased blood glucose concentrations and an accumulation of excess body fat. There are conventional drugs currently used to treat these conditions, but they provide only short periods of glycemic control, are expensive, and are scarcely available in underdeveloped and developing countries. EOs are complex mixtures of aromatic and volatile compounds obtained from plants. They have numerous pharmacological and industrial applications, including anti-cancer, insecticidal, anti-microbial, anti-obesity, and antidiabetic. This review sought to investigate and organize established in vitro, in vivo, ex vivo, and in silico data, highlighting possible mechanisms of action of essential oils to treat and/or manage diabetes and obesity. The results showed that numerous essential oils from plant parts possess antidiabetic and anti-obesity properties, suggesting that essential oils can be exploited as potential antidiabetic and anti-obesity drugs.
糖尿病和肥胖症是世界范围内严重的健康问题,其特点是胰岛素分泌和活性减弱,导致血糖浓度升高和体脂积累过多。目前有一些常规药物用于治疗这些疾病,但它们只能提供短期的血糖控制,价格昂贵,而且在不发达国家和发展中国家几乎无法获得。精油是从植物中提取的芳香族和挥发性化合物的复杂混合物。它们有许多药理和工业应用,包括抗癌、杀虫、抗微生物、抗肥胖和抗糖尿病。本综述旨在调查和整理体外、体内、离体和计算机数据,强调精油治疗和/或控制糖尿病和肥胖的可能作用机制。结果表明,许多植物部位的精油具有抗糖尿病和抗肥胖的特性,提示精油可以作为潜在的抗糖尿病和抗肥胖药物开发。
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引用次数: 1
The employment for high-density polyethylene active packages (HDPAP) bottles containing Coriandrum sativum (Corainder) essential oil in the improvement of the oxidative stability of sunflower oil 采用高密度聚乙烯活性包装(HDPAP)瓶盛装芫荽(Corainder)精油,提高了葵花籽油的氧化稳定性
IF 3 3区 农林科学 Q3 CHEMISTRY, APPLIED Pub Date : 2023-07-04 DOI: 10.1080/10412905.2023.2232788
Dongying Wang, Haohao Wu, Hao Yang, Yongliang Yu, Xuede Wang
ABSTRACT In this research, the effect of high-density polyethylene active packaging (HDPAP) bottles containing Coriandrum sativum essential oil (CSEO) on the oxidation stability and sensory attributes of sunflower oil (SFO) during the accelerated storage was investigated. The migration test showed that the CSEO could migrate from the package to SFO. In the accelerated storage procedure at 65°C, the increase in the levels of acid value (AV), peroxide value (PV), p-anisidine value (AnV), thiobarbituric acid reactive substances (TBARS), conjugated dienes (K232) and conjugated trienes (K268) of SFO samples was significantly inhibited after the sunflower oil packaged by the HAPAP containing CSEO at 6000 ppm (p < .05), which showed that the HDPAP bottle containing CSEO could delay the oxidation of SFO.   Therefore, the results demonstrated that employment of HDPAP bottles containing CSEO at 6000 ppm could be applied as a good replacement for the direct addition of synthetic antioxidants to the SFO.
摘要本研究考察了含有芫荽籽精油(CSEO)的高密度聚乙烯活性包装(HDPAP)瓶在加速贮藏过程中对葵花籽油(SFO)氧化稳定性和感官特性的影响。迁移测试表明,CSEO可以从包迁移到SFO。在65℃加速贮藏过程中,含有CSEO的HAPAP包装的葵花籽油在6000 ppm时,其酸值(AV)、过氧化物值(PV)、对茴香胺值(AnV)、硫代巴比托酸活性物质(TBARS)、共轭二烯(K232)和共轭三烯(K268)水平的升高被显著抑制(p < 0.05),表明含有CSEO的HDPAP瓶可以延缓SFO的氧化。因此,结果表明,使用含有6000ppm CSEO的HDPAP瓶可以很好地替代直接向SFO中添加合成抗氧化剂。
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引用次数: 0
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Journal of Essential Oil Research
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