Martha S. Gilmore, Alison R. Santos, Jeffrey Balcerski, Laura B. Breitenfeld, M. Darby Dyar, Daniel Gerges, Joern Helbert, Ian Henry, Noam Izenberg, Jennifer M. Jackson, Tibor Kremic, Dorothy Lukco, Molly McCanta, Craig Motil, Kyle Phillips, Sara T. Port, Joseph Rymut, Maximilian C. Scardelletti, Mark Sprouse, Mikhail Yu. Zolotov
Laboratory experiments on the behavior of rock and mineral samples under Venus conditions can yield a better understanding of gas-solid chemical weathering on the Venus surface. The Glenn Extreme Environments Rig (GEER) vessel can maintain Venus surface temperature, pressure and a nine-gas atmosphere for months. We provide an overview of the GEER Test Project Marty's Minerals Test (MMT), which ran for 60 days at 460°C, 93 bars under a 9- component Venus-relevant gas mixture. This experiment included over 90 compositionally unique chips and powders of natural samples selected to explore the pathways and relative rates of alteration of a broad range of mineral and rock types. Temperature, pressure, and gas (CO2, N2, SO2, OCS) composition were monitored over the run. Rapid SO2 depletion from the vessel gas phase occurred throughout the test, indicating sequestration of SO2 via gas-solid reactions. A significant sink for SO2 is the formation of iron oxide and nickel sulfide coatings on some chamber parts, which was compensated by multiple SO2 gas injections during the run. Initial results for selected samples include the formation of secondary minerals at sample surfaces (e.g., on Na2CO3, natrite) and complete alteration of other samples (e.g., FeS, troilite) to oxides and sulfides. Some powdered samples consolidated to form hardened layers or chips. These observations show that some mineral phases are chemically and/or physically unstable over the timescale of the run. This test confirms that the GEER is a critical asset and reference point to support the study of gas-solid interactions at Venus conditions.
{"title":"Overview of the MMT 60-Day GEER Experiment on Geologic Samples at Venus Surface Conditions","authors":"Martha S. Gilmore, Alison R. Santos, Jeffrey Balcerski, Laura B. Breitenfeld, M. Darby Dyar, Daniel Gerges, Joern Helbert, Ian Henry, Noam Izenberg, Jennifer M. Jackson, Tibor Kremic, Dorothy Lukco, Molly McCanta, Craig Motil, Kyle Phillips, Sara T. Port, Joseph Rymut, Maximilian C. Scardelletti, Mark Sprouse, Mikhail Yu. Zolotov","doi":"10.1029/2025JE009237","DOIUrl":"https://doi.org/10.1029/2025JE009237","url":null,"abstract":"<p>Laboratory experiments on the behavior of rock and mineral samples under Venus conditions can yield a better understanding of gas-solid chemical weathering on the Venus surface. The Glenn Extreme Environments Rig (GEER) vessel can maintain Venus surface temperature, pressure and a nine-gas atmosphere for months. We provide an overview of the GEER Test Project Marty's Minerals Test (MMT), which ran for 60 days at 460°C, 93 bars under a 9- component Venus-relevant gas mixture. This experiment included over 90 compositionally unique chips and powders of natural samples selected to explore the pathways and relative rates of alteration of a broad range of mineral and rock types. Temperature, pressure, and gas (CO<sub>2</sub>, N<sub>2</sub>, SO<sub>2</sub>, OCS) composition were monitored over the run. Rapid SO<sub>2</sub> depletion from the vessel gas phase occurred throughout the test, indicating sequestration of SO<sub>2</sub> via gas-solid reactions. A significant sink for SO<sub>2</sub> is the formation of iron oxide and nickel sulfide coatings on some chamber parts, which was compensated by multiple SO<sub>2</sub> gas injections during the run. Initial results for selected samples include the formation of secondary minerals at sample surfaces (e.g., on Na<sub>2</sub>CO<sub>3</sub>, natrite) and complete alteration of other samples (e.g., FeS, troilite) to oxides and sulfides. Some powdered samples consolidated to form hardened layers or chips. These observations show that some mineral phases are chemically and/or physically unstable over the timescale of the run. This test confirms that the GEER is a critical asset and reference point to support the study of gas-solid interactions at Venus conditions.</p>","PeriodicalId":16101,"journal":{"name":"Journal of Geophysical Research: Planets","volume":"130 12","pages":""},"PeriodicalIF":4.0,"publicationDate":"2025-11-25","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://agupubs.onlinelibrary.wiley.com/doi/epdf/10.1029/2025JE009237","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"145585087","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"地球科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
J. A. Berger, R. Gellert, C. D. O’Connell-Cooper, L. M. Thompson, S. J. VanBommel, M. A. McCraig, A. S. Yen, E. B. Rampe, J. V. Clark, A. A. Fraeman, N. I. Boyd, J. G. Spray
A major mission goal for the Mars Science Laboratory’s rover, Curiosity, is to investigate the transition from clay-bearing to hydrated-Mg-sulfate-bearing sedimentary strata hypothesized to record a transition from a wet to a dry paleoclimate. Alpha Particle X-ray Spectrometer (APXS) results from this region, named the Clay-Sulfate Transition (CST), indicate an overall ∼5% increase in Ca-sulfate, but Mg-sulfate enrichment is limited to diagenetic nodules. Sulfates in the CST change sharply at the contact with the overlying Mg-sulfate unit, which has ∼5% Ca-sulfate and ∼10% Mg-sulfate in the bedrock matrix. Despite this change in sulfate assemblage, and the transition from fluvial-lacustrine to drier aeolian sedimentary deposits, the bulk chemical composition of the aeolian sandstone (sulfate-free basis) effectively has the same altered basalt chemical fingerprint as the underlying fluvial-lacustrine mudstone. That is, the composition of rocks that record the transition from a wet to a dry paleoclimate is isochemical. It is remarkable that the aeolian sandstone has the same altered bulk chemical characteristics as the fluvial-lacustrine mudstone, notwithstanding very different inferred geochemical regimes. We propose a simplified model wherein older basaltic sediment was aqueously altered in a fluvial-lacustrine regime and reworked, likely during cycles of alteration, salt formation, and reworking. This process led to an averaging of the bulk chemical composition of the Mt. Sharp group sediment, resulting in the isochemical characteristics of the paleoenvironment change.
{"title":"Elemental Composition and Isochemical Characteristics of the Clay-Sulfate Transition in Gale Crater, Mars: APXS Results From Mont Mercou to the Marker Band Valley","authors":"J. A. Berger, R. Gellert, C. D. O’Connell-Cooper, L. M. Thompson, S. J. VanBommel, M. A. McCraig, A. S. Yen, E. B. Rampe, J. V. Clark, A. A. Fraeman, N. I. Boyd, J. G. Spray","doi":"10.1029/2025JE009350","DOIUrl":"https://doi.org/10.1029/2025JE009350","url":null,"abstract":"<p>A major mission goal for the Mars Science Laboratory’s rover, <i>Curiosity</i>, is to investigate the transition from clay-bearing to hydrated-Mg-sulfate-bearing sedimentary strata hypothesized to record a transition from a wet to a dry paleoclimate. Alpha Particle X-ray Spectrometer (APXS) results from this region, named the Clay-Sulfate Transition (CST), indicate an overall ∼5% increase in Ca-sulfate, but Mg-sulfate enrichment is limited to diagenetic nodules. Sulfates in the CST change sharply at the contact with the overlying Mg-sulfate unit, which has ∼5% Ca-sulfate and ∼10% Mg-sulfate in the bedrock matrix. Despite this change in sulfate assemblage, and the transition from fluvial-lacustrine to drier aeolian sedimentary deposits, the bulk chemical composition of the aeolian sandstone (sulfate-free basis) effectively has the same altered basalt chemical fingerprint as the underlying fluvial-lacustrine mudstone. That is, the composition of rocks that record the transition from a wet to a dry paleoclimate is isochemical. It is remarkable that the aeolian sandstone has the same altered bulk chemical characteristics as the fluvial-lacustrine mudstone, notwithstanding very different inferred geochemical regimes. We propose a simplified model wherein older basaltic sediment was aqueously altered in a fluvial-lacustrine regime and reworked, likely during cycles of alteration, salt formation, and reworking. This process led to an averaging of the bulk chemical composition of the Mt. Sharp group sediment, resulting in the isochemical characteristics of the paleoenvironment change.</p>","PeriodicalId":16101,"journal":{"name":"Journal of Geophysical Research: Planets","volume":"130 12","pages":""},"PeriodicalIF":4.0,"publicationDate":"2025-11-25","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"145585346","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"地球科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Jun Du, David A. Minton, Austin M. Blevins, Caleb I. Fassett, Ya-Huei Huang
The morphology of fresh lunar craters provides important clues about how craters of different sizes form, and is used as a baseline for understanding how craters evolve over time. Topographic spectral analysis is a powerful tool for studying the morphology of lunar craters, as it can quantify the scale-dependent topographic variation of individual crater morphologic features. Furthermore, the 2D topographic power spectrum can reveal the spatial directionality of surface features, as an object with a preferred orientation in the space domain will exhibit a pattern rotated by 90