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Overview of the MMT 60-Day GEER Experiment on Geologic Samples at Venus Surface Conditions MMT金星地表地质样品60天GEER实验综述
IF 4 1区 地球科学 Q1 GEOCHEMISTRY & GEOPHYSICS Pub Date : 2025-11-25 DOI: 10.1029/2025JE009237
Martha S. Gilmore, Alison R. Santos, Jeffrey Balcerski, Laura B. Breitenfeld, M. Darby Dyar, Daniel Gerges, Joern Helbert, Ian Henry, Noam Izenberg, Jennifer M. Jackson, Tibor Kremic, Dorothy Lukco, Molly McCanta, Craig Motil, Kyle Phillips, Sara T. Port, Joseph Rymut, Maximilian C. Scardelletti, Mark Sprouse, Mikhail Yu. Zolotov

Laboratory experiments on the behavior of rock and mineral samples under Venus conditions can yield a better understanding of gas-solid chemical weathering on the Venus surface. The Glenn Extreme Environments Rig (GEER) vessel can maintain Venus surface temperature, pressure and a nine-gas atmosphere for months. We provide an overview of the GEER Test Project Marty's Minerals Test (MMT), which ran for 60 days at 460°C, 93 bars under a 9- component Venus-relevant gas mixture. This experiment included over 90 compositionally unique chips and powders of natural samples selected to explore the pathways and relative rates of alteration of a broad range of mineral and rock types. Temperature, pressure, and gas (CO2, N2, SO2, OCS) composition were monitored over the run. Rapid SO2 depletion from the vessel gas phase occurred throughout the test, indicating sequestration of SO2 via gas-solid reactions. A significant sink for SO2 is the formation of iron oxide and nickel sulfide coatings on some chamber parts, which was compensated by multiple SO2 gas injections during the run. Initial results for selected samples include the formation of secondary minerals at sample surfaces (e.g., on Na2CO3, natrite) and complete alteration of other samples (e.g., FeS, troilite) to oxides and sulfides. Some powdered samples consolidated to form hardened layers or chips. These observations show that some mineral phases are chemically and/or physically unstable over the timescale of the run. This test confirms that the GEER is a critical asset and reference point to support the study of gas-solid interactions at Venus conditions.

在金星条件下对岩石和矿物样品的行为进行实验室实验,可以更好地了解金星表面的气固化学风化。格伦极端环境钻机(GEER)可以维持金星表面的温度、压力和九种气体的大气数月。我们提供了GEER测试项目Marty矿物测试(MMT)的概述,该测试在460°C、93 bar的9组分金星相关气体混合物下进行了60天。该实验包括90多个组成独特的天然样品的碎片和粉末,以探索广泛的矿物和岩石类型的变化途径和相对速率。在整个下入过程中监测温度、压力和气体(CO2、N2、SO2、OCS)组成。在整个测试过程中,容器气相中的SO2快速耗尽,表明通过气固反应封存了SO2。SO2的一个重要沉淀是在某些腔室部件上形成氧化铁和硫化镍涂层,在运行过程中通过多次注入SO2气体来补偿。选定样品的初步结果包括在样品表面(例如,Na2CO3,亚硝酸盐)形成次生矿物,其他样品(例如,FeS, troilite)完全转化为氧化物和硫化物。一些粉末样品固结形成硬化层或碎屑。这些观察结果表明,在运行的时间尺度上,一些矿物相在化学和/或物理上是不稳定的。这次测试证实,GEER是支持金星条件下气固相互作用研究的关键资产和参考点。
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引用次数: 0
Elemental Composition and Isochemical Characteristics of the Clay-Sulfate Transition in Gale Crater, Mars: APXS Results From Mont Mercou to the Marker Band Valley 火星Gale陨石坑中粘土-硫酸盐转变的元素组成和等化学特征:从Mercou山到标记带谷的APXS结果
IF 4 1区 地球科学 Q1 GEOCHEMISTRY & GEOPHYSICS Pub Date : 2025-11-25 DOI: 10.1029/2025JE009350
J. A. Berger, R. Gellert, C. D. O’Connell-Cooper, L. M. Thompson, S. J. VanBommel, M. A. McCraig, A. S. Yen, E. B. Rampe, J. V. Clark, A. A. Fraeman, N. I. Boyd, J. G. Spray

A major mission goal for the Mars Science Laboratory’s rover, Curiosity, is to investigate the transition from clay-bearing to hydrated-Mg-sulfate-bearing sedimentary strata hypothesized to record a transition from a wet to a dry paleoclimate. Alpha Particle X-ray Spectrometer (APXS) results from this region, named the Clay-Sulfate Transition (CST), indicate an overall ∼5% increase in Ca-sulfate, but Mg-sulfate enrichment is limited to diagenetic nodules. Sulfates in the CST change sharply at the contact with the overlying Mg-sulfate unit, which has ∼5% Ca-sulfate and ∼10% Mg-sulfate in the bedrock matrix. Despite this change in sulfate assemblage, and the transition from fluvial-lacustrine to drier aeolian sedimentary deposits, the bulk chemical composition of the aeolian sandstone (sulfate-free basis) effectively has the same altered basalt chemical fingerprint as the underlying fluvial-lacustrine mudstone. That is, the composition of rocks that record the transition from a wet to a dry paleoclimate is isochemical. It is remarkable that the aeolian sandstone has the same altered bulk chemical characteristics as the fluvial-lacustrine mudstone, notwithstanding very different inferred geochemical regimes. We propose a simplified model wherein older basaltic sediment was aqueously altered in a fluvial-lacustrine regime and reworked, likely during cycles of alteration, salt formation, and reworking. This process led to an averaging of the bulk chemical composition of the Mt. Sharp group sediment, resulting in the isochemical characteristics of the paleoenvironment change.

火星科学实验室的“好奇号”火星车的一个主要任务目标是研究从含粘土到含水合硫酸镁的沉积地层的转变,假设这些沉积地层记录了从潮湿到干燥的古气候转变。该区域的α粒子x射线光谱仪(APXS)结果,被命名为粘土-硫酸盐转变(CST),表明总体上Ca-sulfate增加了约5%,但Mg-sulfate富集仅限于成岩结核。CST中的硫酸盐在与上覆的mg -硫酸盐单元接触处急剧变化,基岩基质中含有~ 5%的Ca-sulfate和~ 10%的Mg-sulfate。尽管硫酸盐组合发生了变化,并且从河流-湖泊沉积向干燥风成沉积过渡,但风成砂岩(无硫酸盐基)的总体化学成分与下伏的河流-湖泊泥岩具有相同的蚀变玄武岩化学指纹。也就是说,记录从潮湿到干燥古气候转变的岩石组成是等化学的。值得注意的是,风成砂岩与河湖泥岩具有相同的蚀变体化学特征,尽管推断的地球化学制度非常不同。我们提出了一个简化模型,其中较老的玄武质沉积物在河流-湖泊环境中被水蚀变,并在蚀变、盐形成和再加工的循环过程中被再加工。这一过程对夏普山群沉积物的整体化学成分进行了平均,得到了古环境变化的等化学特征。
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引用次数: 0
Spectral Analysis of the Morphology of Fresh Lunar Craters II: Two-Dimensional Surface Elevations of the Continuous Ejecta, Wall, and Floor 月球新陨石坑形态的光谱分析II:连续喷出物、壁和底的二维表面高程
IF 4 1区 地球科学 Q1 GEOCHEMISTRY & GEOPHYSICS Pub Date : 2025-11-24 DOI: 10.1029/2024JE008890
Jun Du, David A. Minton, Austin M. Blevins, Caleb I. Fassett, Ya-Huei Huang

The morphology of fresh lunar craters provides important clues about how craters of different sizes form, and is used as a baseline for understanding how craters evolve over time. Topographic spectral analysis is a powerful tool for studying the morphology of lunar craters, as it can quantify the scale-dependent topographic variation of individual crater morphologic features. Furthermore, the 2D topographic power spectrum can reveal the spatial directionality of surface features, as an object with a preferred orientation in the space domain will exhibit a pattern rotated by 90° ${}^{circ}$ in the wavenumber domain. In this study, we calculate the 2D power spectral densities of surface elevations of three morphologic features of fresh lunar craters, including the continuous ejecta, wall, and floor, from a subset of 104 Copernican- and Eratosthenian-aged craters larger than 1 km in diameter. The calculated power spectral density in general decreases with increasing wavenumber, indicating that the crater surface is smoother at smaller scales. We fit the obtained 2D power spectral density using a function with four parameters that characterize important topographic properties of fresh lunar craters, including how topographic variation is distributed across length scales and how the relative strength of radial or circumferential topography changes in different morphologic features. We derive the dependence on crater diameter for each of the four fit parameters for each morphologic feature, and then use the empirical fits to generate a 3D shape model for synthetic fresh lunar craters, which can be used as input when modeling lunar landscape evolution.

月球新陨石坑的形态为了解不同大小的陨石坑如何形成提供了重要线索,并被用作了解陨石坑如何随时间演变的基线。地形光谱分析是研究月球陨石坑形态的有力工具,因为它可以量化单个陨石坑形态特征的尺度相关地形变化。此外,二维地形功率谱可以揭示地物的空间方向性,因为在空间域中具有首选方向的物体在波数域中会呈现旋转90°${}^{circ}$的图案。在这项研究中,我们计算了104个直径大于1 km的哥白尼和埃拉托色尼时期的陨石坑的三种形态特征(包括连续喷出物、壁和底)的表面高度的二维功率谱密度。计算得到的功率谱密度总体上随波数的增加而减小,说明在较小的尺度下陨石坑表面更加光滑。我们使用包含四个参数的函数来拟合获得的二维功率谱密度,这些参数表征了月球新陨石坑的重要地形特性,包括地形变化如何在长度尺度上分布,以及不同形态特征下径向或周向地形的相对强度如何变化。我们推导了每个形态特征的4个拟合参数对陨石坑直径的依赖关系,然后利用经验拟合生成合成月球新陨石坑的三维形状模型,该模型可作为建模月球景观演化的输入。
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引用次数: 0
Widespread Depositional Fluvial Systems in Noachis Terra, Mars 火星Noachis Terra的广泛沉积河流系统
IF 4 1区 地球科学 Q1 GEOCHEMISTRY & GEOPHYSICS Pub Date : 2025-11-21 DOI: 10.1029/2025JE009378
Adam Losekoot, Matthew R. Balme, Angela L. Coe, Peter Fawdon, Joel M. Davis

Noachis Terra, in Mars' southern highlands, is a region where “warm/wet” climate models of the early Martian Climate predict high rates of precipitation but which is poorly dissected by Valley Networks (VNs). We searched for Fluvial Sinuous Ridges (FSRs, or “inverted channels”) here because they (a) provide alternate evidence to VNs for flowing surface water in the form of river systems with high rates of deposition, and (b) have also been found in Arabia Terra, a similarly aged but geologically distinct region of the highlands that is also poorly dissected by VNs. Using a 6 m/pixel regional image mosaic, supported by other orbital data sets, we recorded the locations, lengths and morphological characteristics of FSRs. We find that FSRs are common across Noachis Terra, with a cumulative length greater than 15,000 km, increasing the drainage density of mapped fluvial systems in the region by 18%. FSRs can occur as isolated segments, but some systems are hundreds of kilometers in length and form branching networks. The regional abundance of FSRs suggests a distributed source of water (e.g., precipitation) and their 10–30 m relief and interconnectedness at local scales suggest they were relatively long-lived river systems. Our results, especially when taken alongside those in Arabia Terra, point toward widespread, sustained fluvial conditions in Mars’ highlands at ∼3.7 Ga, and provide important input into global climate models of this period. As Noachis Terra is a typical highland region on Mars, we suggest that FSRs are likely to be present throughout highland terrains of similar ages.

位于火星南部高地的诺亚奇特拉是一个早期火星气候的“暖/湿”气候模型预测降水率高的地区,但山谷网络(VNs)对其进行了很差的剖析。我们在这里寻找河流弯曲脊(FSRs,或“倒转河道”),因为它们(a)为河流系统的高沉积速率流动地表水的形式提供了与VNs不同的证据,(b)在阿拉伯地也被发现,这是一个同样古老但地质上独特的高地地区,也没有被VNs解剖。利用6 m/pixel的区域图像拼接,在其他轨道数据集的支持下,记录了fsr的位置、长度和形态特征。我们发现fsr在Noachis Terra上很常见,累计长度超过15,000 km,使该地区已测绘的河流系统的排水密度增加了18%。fsr可以作为孤立的片段出现,但有些系统长达数百公里,并形成分支网络。FSRs的区域丰度表明其水源分布(例如降水),其10-30米的起伏和在局部尺度上的相互联系表明它们是相对长寿的河流系统。我们的研究结果,特别是当与阿拉伯地的研究结果结合起来时,指向了火星高地在~ 3.7 Ga时广泛、持续的河流条件,并为这一时期的全球气候模型提供了重要的输入。由于诺亚奇地是火星上典型的高地地区,我们认为fsr很可能存在于相似年龄的高地地区。
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引用次数: 0
Architectures and Instruments for Enceladus Exploration 土卫二探测的结构和仪器
IF 4 1区 地球科学 Q1 GEOCHEMISTRY & GEOPHYSICS Pub Date : 2025-11-21 DOI: 10.1029/2024JE008908
Jessica M. Weber, L. E. Rodriguez, M. L. Cable, M. Ingham, L. M. Barge, M. Chodas, C. J. Cochrane, C. M. Elder, E. Fayolle, B. L. Henderson, S. Hosseini, A. G. Marusiak, M. Melwani-Daswani, T. A. Nordheim, S. M. Perl, M. Ono

Enceladus, a moon of Saturn with a subsurface ocean containing potential hydrothermal activity, is a crucial target for habitability and life detection missions. While the Cassini mission provided important information about Enceladus, many unanswered and consequential questions remain, including its habitability, geochemical history, and whether Enceladus currently hosts life. We have developed a general science traceability matrix (STM) detailing a set of science objectives relating to its geology and habitability that can be applied to different mission architectures and concepts. This STM was designed to be broad and cover a broad science trade space for mission development; a companion paper discusses the scientific details of the STM (Rodriguez et al., 2025). In this paper, we discuss which mission architectural features would be needed to meet the STM's different science goals and observables. We identify direct access to ocean samples as an important architectural feature to fulfill measurements of habitability and life detection. We additionally propose using integrated instrument suites for life detection science objectives. We highlight opportunities for advancement in research and technology development that could enable different science objectives, including autonomy and instrument design. The results of this workshop detailed in this publication can be used as a framework for mission concept design and development. This document is designed to be used as a roadmap for the development of new technology maturation for future investigations to maximize science return.

土卫二是土星的一颗卫星,它的地下海洋含有潜在的热液活动,是宜居性和生命探测任务的关键目标。虽然卡西尼号的任务提供了关于土卫二的重要信息,但仍有许多悬而未决的问题,包括它的可居住性、地球化学历史,以及土卫二目前是否有生命。我们已经开发了一个通用的科学可追溯性矩阵(STM),详细介绍了一组与地质和可居住性相关的科学目标,这些目标可以应用于不同的任务架构和概念。这个STM被设计得很广泛,涵盖了任务开发的广泛科学贸易空间;另一篇论文讨论了STM的科学细节(Rodriguez et al., 2025)。在本文中,我们讨论了需要哪些任务架构特征来满足STM的不同科学目标和观测值。我们将直接获取海洋样本作为一个重要的建筑特征,以实现可居住性和生命探测的测量。我们还建议使用集成仪器套件来实现生命探测科学目标。我们强调了研究和技术发展的进步机会,这些机会可以实现不同的科学目标,包括自主和仪器设计。本出版物中详细介绍的这次讲习班的结果可以用作任务概念设计和发展的框架。该文件旨在作为未来研究新技术成熟发展的路线图,以最大限度地提高科学回报。
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引用次数: 0
Modeling the Crustal Magnetic Field of Mars With Physics-Informed Neural Networks 用物理信息神经网络模拟火星地壳磁场
IF 4 1区 地球科学 Q1 GEOCHEMISTRY & GEOPHYSICS Pub Date : 2025-11-19 DOI: 10.1029/2025JE009297
T. Delcourt, A. Mittelholz

Satellites orbiting Mars have measured crustal magnetic fields up to two orders of magnitude stronger than those on Earth. Although Mars currently lacks an active global magnetic field, this magnetization preserves a valuable record of the planet's early dynamo activity and crustal evolution. We present a high-resolution model of the crustal magnetic field of Mars, using all currently available magnetic field data collected by the MGS and MAVEN spacecraft (up to 02/2025), combined with a novel modeling approach. Notably, we incorporate recent low-altitude MAVEN data which contain short wavelength signals that were not available for previous models. We show that neural networks trained from spacecraft data can accurately predict the magnetic field at any location around Mars at orbital altitudes. These physics-informed networks use the equations of magnetostatics to enforce the conservative and solenoidal nature of the field, and are enhanced with bagging to mitigate the effect of noise in the data. Using this ensemble approach, we provide an estimate of uncertainties associated with our predictions. To demonstrate the performance of this method, we benchmark it against previous models using the same input and validation data subsets. Our model achieves an unprecedented resolution of spherical harmonics degree 139, corresponding to a spatial resolution of 153 km at the surface. Using our model to investigate small scale magnetic field signatures, we find that magnetic fields over ancient paleolakes are significantly stronger than other surface features or geological units, suggesting that serpentinization may have played a key role in magnetizing the crust.

绕火星运行的卫星已经测量到火星的地壳磁场比地球磁场强两个数量级。虽然火星目前缺乏活跃的全球磁场,但这种磁化保留了火星早期发电机活动和地壳演化的宝贵记录。我们提出了一个高分辨率的火星地壳磁场模型,该模型使用了MGS和MAVEN航天器收集的所有现有磁场数据(截至2025年2月),并结合了一种新的建模方法。值得注意的是,我们纳入了最近的低空MAVEN数据,其中包含以前模型无法获得的短波长的信号。我们表明,从航天器数据训练的神经网络可以准确地预测火星周围轨道高度任何位置的磁场。这些物理信息网络使用静磁方程来加强磁场的保守性和螺线形性质,并通过套袋来增强,以减轻数据中的噪声影响。使用这种集合方法,我们提供了与我们的预测相关的不确定性的估计。为了演示该方法的性能,我们使用相同的输入和验证数据子集对以前的模型进行基准测试。我们的模型实现了前所未有的球面谐波度139的分辨率,对应于地表153 km的空间分辨率。利用我们的模型研究小尺度磁场特征,我们发现古湖泊上的磁场明显强于其他地表特征或地质单元,这表明蛇纹岩化可能在地壳磁化中发挥了关键作用。
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引用次数: 0
Transient Hydrology in Amazonis Planitia (Mars) in the Aftermath of the Tooting Impact 图廷撞击后亚马逊平原(火星)的瞬时水文
IF 4 1区 地球科学 Q1 GEOCHEMISTRY & GEOPHYSICS Pub Date : 2025-11-19 DOI: 10.1029/2024JE008915
Fabio Vittorio De Blasio, Andrea Caccia, Giovanni Battista Crosta

Hydrological flows generated by meteoroid impact are still largely unexplored on Mars and may also have implications for Earth. We reconstructed the hydrological sequence initiated on Mars by a less than 3 Ma old meteoroid impact that formed the 28 km-wide Tooting crater on Amazonis Planitia, an ice-bearing region. Significant thermal and mechanical erosion were produced by the temporary rivers created by the impact on the icy terrain. Through analysis of CTX and HiRISE imagery supplemented with hydrological calculations, we inferred that the meltwater flowed approximately 80 km, eroding deeply the soil. Upon encountering an extensive (more than 100 km) impact-induced fracture line network, the water plummeted in vertical waterfalls, creating thermokarst caverns and ephemeral lakes. Secondary water springs are hypothesized to stem from the impact of ballistic ejecta blocks. Our analysis reveals that the initial hydrologic activity took a short time (hours to one day), while thermal effects were more durable but still geologically rapid. HiRISE imagery reveals slope streaks inside the emptied lacustrine basins. Lines, which emerge from a deep regolith layer, are potentially indicative of aquifer-fed water springs. The consistent origination of multiple lineae at the same stratigraphic level hints at significant subsurface re-mobilized water or ice, when heat was released from temporary warm lakes.

流星体撞击在火星上产生的水文流动在很大程度上仍未被探索,也可能对地球产生影响。我们重建了火星上的水文序列,这是由不到3万年的流星体撞击形成的,该撞击形成了亚马逊平原上28公里宽的图廷陨石坑,这是一个有冰的地区。由于对结冰地形的冲击而形成的临时河流产生了显著的热侵蚀和机械侵蚀。通过对CTX和HiRISE图像的分析,再加上水文计算,我们推断融水流动了大约80公里,深深地侵蚀了土壤。在遇到一个广泛的(超过100公里)撞击引起的裂缝线网络时,水以垂直瀑布的形式下落,形成热溶洞和短暂的湖泊。次级水泉被认为是由弹射块的冲击产生的。我们的分析表明,最初的水文活动花了很短的时间(几个小时到一天),而热效应更持久,但地质上仍然很快。HiRISE图像显示了空湖盆地内部的斜坡条纹。从深层风化层中显露出来的线条,可能预示着地下蓄水层提供的泉水。同一地层水平上多条线的一致起源表明,当热量从暂时温暖的湖泊释放出来时,大量的地下水或冰被重新动员起来。
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引用次数: 0
Direct S-Wave Splitting From Deep Moonquakes: Real or Apparent? 深层月震的直接s波分裂:真实的还是明显的?
IF 4 1区 地球科学 Q1 GEOCHEMISTRY & GEOPHYSICS Pub Date : 2025-11-16 DOI: 10.1029/2025JE009223
Jing Shi, Jiaqi Li, Tao Wang

Mantle flow throughout the lunar evolutionary history could be constrained by shear wave splitting if it is reliably observed in the moonquake waveforms. However, despite the long-standing availability of Apollo seismic data, it remains unclear whether the S-waves from moonquakes exhibit real splitting due to seismic anisotropy or whether apparent splitting arises instead from seismic wave propagation through isotropic heterogeneous media. To date, no systematic investigation has addressed this question. To fill this knowledge gap, we analyze direct S-wave splitting from deep moonquakes with high signal-to-noise ratios. Stacked waveforms from deep moonquakes show that the measurement results are inconsistent across different clusters at the same station and across different stations for the same cluster as well as across different frequency bands. Further analysis of unstacked individual events within the same cluster, differing in location by only a few kilometers, also exhibits large variability in the splitting parameters. Numerical simulations of seismic wave propagation through heterogeneous media demonstrate that the observed S-wave splitting of deep moonquakes can be explained by apparent splitting caused by scattering in addition to the potential intrinsic anisotropy. Therefore, even stacking waveforms of deep moonquakes do not improve the reliability of the splitting measurements. Our results suggest that there are no remnants of large-scale lateral mantle flow in the lunar mantle sampled by these deep moonquakes, or any existing anisotropy is obscured by the stronger effects of structural heterogeneity.

如果在月震波形中可靠地观测到地幔流,那么整个月球演化历史中的地幔流可能受到剪切波分裂的约束。然而,尽管阿波罗地震数据长期可用,但尚不清楚来自月震的s波是否由于地震各向异性而表现出真实的分裂,或者是否由于地震波通过各向同性非均质介质传播而产生明显的分裂。到目前为止,还没有系统的研究解决这个问题。为了填补这一知识空白,我们分析了具有高信噪比的深月震的直接s波分裂。深月震叠波结果表明,同一台站不同簇间、同一簇不同台站间、不同频带间测量结果不一致。对同一簇内未叠加的单个事件的进一步分析,在位置上仅相差几公里的情况下,也显示出分裂参数的巨大变化。非均质介质中地震波传播的数值模拟表明,观测到的深月震s波分裂除了可能的本征各向异性外,还可以用散射引起的视分裂来解释。因此,深月震的均匀叠加波形并不能提高劈裂测量的可靠性。我们的研究结果表明,在这些深月震取样的月幔中没有大规模横向地幔流动的残余,或者任何现有的各向异性都被结构非均质性的更强影响所掩盖。
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引用次数: 0
On the Origins of Mercury's Sodium Exospheric Cold Poles Enhancement: A Multiscale Exosphere Global Model 关于水星钠外逸层冷极增强的起源:一个多尺度外逸层全球模式
IF 4 1区 地球科学 Q1 GEOCHEMISTRY & GEOPHYSICS Pub Date : 2025-11-15 DOI: 10.1029/2025JE009309
S. Verkercke, L. Morrissey, J. Y. Chaufray, A. Georgiou, A. Ricketts, F. Leblanc

Mercury's exosphere is sustained by the continuous ejection of atoms from its surface, driven by solar wind, micro-meteoroid impacts, and surface heating. Due to its 3:2 spin-orbit resonance, some longitudes experience greater solar exposure, creating temperature variations from ∼90 to 700 K. This resonance also creates least exposed longitudes, called cold longitudes. These variations, combined with surface-solar interactions, lead to complex exospheric dynamics. Observations from the MErcury Surface, Space ENvironment, GEochemistry, and Ranging (MESSENGER) spacecraft revealed localized enhancements in sodium column density at cold longitudes near the aphelion, where these regions rotate into the day-side. Existing models do not explain this cold-pole enhancement but assume a smooth, impermeable surface, neglecting the highly porous nature of Mercury's regolith. This porosity allows for subsurface diffusion of volatiles through adsorption and desorption across regolith grains, influenced by temperature and species-specific surface binding energies. We couple a subsurface transport model with a 3D Monte Carlo-based Exosphere Global Model to investigate whether sodium accumulated in Mercury's regolith could explain the cold pole enhancement. Results suggest that at cold longitudes, low temperatures favor sodium retention near the surface. The gradual heating induces a release of sodium from the subsurface, producing the observed localized enhancements. This mechanism reconciles MESSENGER's findings with physical processes and highlights the significance of subsurface reservoirs in volatile dynamics. We highlight the need to consider regolith structure and subsurface processes in exosphere modeling. These results improve our understanding of Mercury's volatile cycle but also offer broader insights into the behavior of surface-bound species on airless planetary bodies.

水星的外逸层是由太阳风、微流星体撞击和表面加热驱动的原子从其表面不断喷射而维持的。由于其3:2的自旋轨道共振,一些经度经历了更大的太阳照射,产生了从~ 90到700 K的温度变化。这种共振也产生了最少暴露的经度,称为冷经度。这些变化,加上地表与太阳的相互作用,导致了复杂的外逸层动力学。来自水星表面、空间环境、地球化学和测距(信使号)航天器的观测显示,在远日点附近的寒冷经度,钠柱密度局部增强,这些区域旋转到白天一侧。现有的模型并不能解释这种冷极的增强,而是假设水星表面光滑、不透水,忽略了水星风化层的高度多孔性。受温度和物种特异性表面结合能的影响,这种孔隙度允许挥发物通过吸附和解吸在风化层颗粒中进行地下扩散。我们将地下运输模型与基于蒙特卡罗的3D外逸层全球模型结合起来,研究水星风化层中钠的积累是否可以解释冷极增强。结果表明,在寒冷的经度,低温有利于钠在表面附近的滞留。逐渐加热诱导钠从地下释放出来,产生观察到的局部增强。这一机制与MESSENGER的发现与物理过程相一致,并突出了地下储层在挥发动力学中的重要性。我们强调需要考虑风化层结构和地下过程的外逸层模拟。这些结果提高了我们对水星挥发循环的理解,同时也为在无空气的行星体上的表面物种的行为提供了更广泛的见解。
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引用次数: 0
SuperCam Raman Activities at Jezero Crater, Mars: Observational Strategies, Data Processing, and Mineral Detections During the First 1000 Sols 火星耶泽洛陨石坑的超级摄像机拉曼活动:观测策略、数据处理和前1000个太阳期间的矿物探测
IF 4 1区 地球科学 Q1 GEOCHEMISTRY & GEOPHYSICS Pub Date : 2025-11-15 DOI: 10.1029/2025JE008943
G. Lopez-Reyes, J. A. Manrique, E. Clavé, A. Ollila, O. Beyssac, P. Pilleri, S. Bernard, E. Dehouck, M. Veneranda, S. K. Sharma, M. Nachon, J. Aramendia, O. Forni, F. Rull, T. Acosta-Maeda, A. Brown, S. M. Angel, K. Castro, E. Cloutis, L. Coloma, J. Comellas, D. Delapp, R. Jakubek, S. Julve-Gonzalez, E. Kelly, J. M. Madariaga, G. Montagnac, I. Poblacion, S. Schröder, S. A. Connell, I. Reyes-Rodriguez, Z. U. Wolf, S. Maurice, O. Gasnault, S. Clegg, A. Cousin, R. C. Wiens, the SuperCam Raman Working Group and the SuperCam Team

The Mars 2020 Perseverance rover introduced Raman spectroscopy to in situ planetary exploration for the first time when it landed in Jezero crater on Mars in February 2021. The SuperCam instrument onboard Perseverance is a multi-analytical tool capable of acquiring time-resolved Raman data from Martian targets at standoff distances of a few meters. This is a particularly challenging task due to the operational constraints, the harsh conditions on the Martian surface, and especially the very fine-grained nature of the Martian soil. To address these challenges, the SuperCam Raman team has invested significant effort into optimizing both the acquisition and post-processing of Raman data collected on Mars, as detailed in this work. Additionally, this paper reviews and discusses the detections made by SuperCam Raman during the first 1,000 sols (almost 3 Earth years) of the Mars 2020 mission. During this period, SuperCam Raman data provided key insights into the mineralogy of Jezero throughout the Crater, Delta, and Margin Campaigns. Key detections include olivine, carbonates, perchlorates, and sulfates (such as anhydrite), identified in both abraded patches and natural surfaces. The high specificity of Raman spectroscopy enables the unequivocal identification of these minerals, allowing for rapid and direct interpretation of Jezero's mineralogy, especially when combined with other techniques from SuperCam or others on the rover. Furthermore, this paper compiles the spectra acquired from the SuperCam Calibration Target samples on Mars, including studies on the degradation of the Ertalyte (PET), an organic polymer sample and analyses of diamond, apatite, and other reference materials.

2021年2月,火星2020毅力号探测器在火星耶泽洛陨石坑着陆,首次将拉曼光谱引入原位行星探测。毅力号上搭载的SuperCam仪器是一种多分析工具,能够从距离几米远的火星目标获取时间分辨拉曼数据。由于操作上的限制,火星表面的恶劣条件,尤其是火星土壤非常细粒度的性质,这是一项特别具有挑战性的任务。为了应对这些挑战,SuperCam拉曼团队投入了大量精力来优化在火星上收集的拉曼数据的采集和后处理,如本工作所述。此外,本文回顾和讨论了SuperCam Raman在火星2020任务的前1000个太阳(几乎3个地球年)中所做的探测。在此期间,SuperCam的拉曼数据为整个陨石坑、三角洲和边缘运动的耶泽洛矿物学提供了关键的见解。关键的检测包括橄榄石、碳酸盐、高氯酸盐和硫酸盐(如硬石膏),在磨损斑块和自然表面均可识别。拉曼光谱的高专一性使这些矿物能够明确地识别出来,从而可以快速直接地解释耶泽罗的矿物学,特别是当与SuperCam或漫游者上的其他技术相结合时。此外,本文汇编了从火星上的SuperCam校准目标样品获得的光谱,包括对有机聚合物样品Ertalyte (PET)的降解研究以及对金刚石,磷灰石和其他参考物质的分析。
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引用次数: 0
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Journal of Geophysical Research: Planets
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