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Phyllosilicate Infrared Spectral Features as Tracers of Aqueous Alteration in CM Chondrites and Implications for Remote Sensing of Hydrated Asteroids CM球粒陨石含水蚀变的叶状硅酸盐红外光谱特征及其含水小行星遥感意义
IF 4 1区 地球科学 Q1 GEOCHEMISTRY & GEOPHYSICS Pub Date : 2025-12-20 DOI: 10.1029/2025JE009377
W. M. Lawrence, B. L. Ehlmann

CM (Mighei-type) carbonaceous chondrites host abundant OH/H2O-bearing phyllosilicates formed from water-rock reactions in primitive planetesimals. Their infrared (IR) spectral features resemble those of C-type asteroids, making laboratory analyses of CMs essential for interpreting asteroid observations. However, CM chondrites are often breccias composed of lithologies with variable degrees of aqueous alteration, complicating their interpretation. Here we use in situ analytical techniques to characterize spectral-compositional relationships for phyllosilicates in 8 CM lithologies across two meteorite samples. Micro-Fourier Transform Infrared (μ-FTIR) spectra collected from phyllosilicate-rich matrix regions show that band positions of the 3-μm feature and Si-O stretch Reststrahlen band (RB) systematically vary with alteration. Additional data from spatially correlated electron microprobe and μ-FTIR measurements tie spectral variations to specific cation substitutions in serpentines: the 3-μm feature shifts from 2.78 to 2.70 μm with increased Mg/Fe in octahedral sites, and the Si-O stretch RB shifts from 10.8 to 9.8 μm with increased Si/Fe3+ in tetrahedral sites. Co-variation of these features across the studied CM lithologies defines two successive alteration stages: (1) the Si-O stretch RB and 3-μm feature shift to longer and shorter wavelengths, respectively, as Mg- and cronstedtite-rich phyllosilicates form from incipient chondrule alteration; (2) Si-O stretch RB shifts to shorter wavelengths as Mg-serpentines replace cronstedtite and Mg-rich chondrules. These patterns align with inferred changes in composition and redox state for altering fluids on the CM parent body. Similar features in the spectra of C-type asteroids may reveal information about conditions of aqueous alteration and constrain models of their evolution.

CM (mighei型)碳质球粒陨石富含原始星子水岩反应形成的含OH/ h2o层状硅酸盐。它们的红外(IR)光谱特征与c型小行星相似,使得CMs的实验室分析对解释小行星观测至关重要。然而,CM球粒陨石通常是角砾岩,由不同程度的含水蚀变岩性组成,使其解释复杂化。在这里,我们使用原位分析技术来表征两颗陨石样品中8 CM岩性层状硅酸盐的光谱成分关系。从富含层状硅酸盐的基体区域采集的微傅里叶变换红外(μ-FTIR)光谱显示,3 μm特征和Si-O拉伸Reststrahlen带(RB)的波段位置随蚀变有系统的变化。来自空间相关电子探针和μ ftir测量的其他数据将光谱变化与蛇纹石中的特定阳离子取代联系起来:随着八面体中Mg/Fe的增加,3 μm特征从2.78 μm移动到2.70 μm;随着四面体中Si/Fe3+的增加,Si- o拉伸RB从10.8 μm移动到9.8 μm。这些特征在研究的CM岩性上的共同变化定义了两个连续的蚀变阶段:(1)Si-O拉伸RB和3-μm特征分别从早期的球粒蚀变形成的富含Mg和cronstedte的层状硅酸盐,分别向更长和更短的波长移动;(2)当镁蛇纹石取代了菱铁矿和富镁球粒时,Si-O拉伸RB向更短波长偏移。这些模式与推断的组成和氧化还原状态的变化相一致,以改变CM母体的流体。c型小行星光谱中的类似特征可能揭示含水蚀变条件的信息,并约束它们的演化模型。
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引用次数: 0
Short-Period Migrating Thermal Tides in the Martian Atmosphere Observed by EMM/EMIRS EMM/EMIRS观测的火星大气短周期热潮迁移
IF 4 1区 地球科学 Q1 GEOCHEMISTRY & GEOPHYSICS Pub Date : 2025-12-20 DOI: 10.1029/2025JE009311
Yiran Pan, Chengyun Yang, Tao Li, Siteng Fan, Zhaopeng Wu, Dexin Lai, Xin Fang, Cong Sun

Thermal tides are global-scale atmospheric waves with periods that are subharmonic to a solar day. Among them, short-period tides (e.g., 6-hr and 4-hr) correspond to higher-order harmonics. Based on temperature profiles from Emirates Mars InfraRed Spectrometer (EMIRS) observations, which provide comprehensive local time coverage, we investigate the 6-hr and 4-hr migrating tides in the Martian atmosphere. These short-period migrating tides exhibit distinct seasonal variations: the 6-hr tide reaches a maximum amplitude of ∼0.7 K around the winter solstice, while the 4-hr tide peaks around the equinoxes with an amplitude of ∼0.5 K. Hough mode decomposition reveals that both the 6-hr and 4-hr migrating tides are dominated by low-order, vertically evanescent modes, consistent with the observed feature that their phases remain nearly constant with altitude. Analysis suggests that the amplitudes of these short-period tides are likely modulated by atmospheric dust and water ice clouds. Furthermore, our results provide observational evidence that the superposition of 6-hr and 4-hr tidal winds around the autumn equinox contributes to the pronounced tropical surface pressure enhancements near 8 a.m. and 8 p.m.

热潮汐是全球尺度的大气波,其周期是太阳日的次谐波。其中,短周期潮汐(如6小时和4小时)对应于高次谐波。基于阿联酋火星红外光谱仪(EMIRS)提供的全面的当地时间覆盖的观测数据,我们研究了火星大气中6小时和4小时的迁移潮汐。这些短周期迁移潮表现出明显的季节变化:6小时潮汐在冬至前后达到最大振幅约0.7 K,而4小时潮汐在春分前后达到峰值,振幅约0.5 K。Hough模态分解表明,6-hr和4-hr潮均以低阶、垂直消失模态为主,这与观测到的相位随海拔高度几乎保持恒定的特征相一致。分析表明,这些短周期潮汐的振幅可能受到大气尘埃和水冰云的调节。此外,我们的研究结果提供了观测证据,表明秋分前后6小时和4小时潮汐风的叠加有助于在上午8点和晚上8点附近热带地面气压的明显增强。
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引用次数: 0
Oscillatory Loading in Ice Friction Experiments: Implications for Tidally Driven Activity Along the Tiger Stripes of Enceladus 冰摩擦实验中的振荡载荷:土卫二虎纹潮汐驱动活动的含义
IF 4 1区 地球科学 Q1 GEOCHEMISTRY & GEOPHYSICS Pub Date : 2025-12-18 DOI: 10.1029/2025JE009406
Maheenuz Zaman, Christine McCarthy, Rob M. Skarbek, Heather M. Savage, Noah P. Hammond

We explored the effect of oscillatory loading on the frictional response of polycrystalline water ice and ice + ammonia to better understand the behavior of tidally modulated strike-slip faults on the icy satellites of the outer solar system, particularly Saturn's moon Enceladus. Ice-on-ice friction experiments were conducted between temperatures of 98 and 248 K at a normal stress of 100 kPa (equivalent to ∼1 km depth in the ice shell). A sinusoidal sliding rate was applied over a range of amplitudes and frequencies at a median velocity of 10 μm/s. We calculated the rate-and-state friction parameters for the amplitude-frequency combinations and found that oscillatory loading alters frictional stability relative to steady-state loading, leading to potentially more unstable slip behavior. We observe a full spectrum of slip behavior, from creep to slow slip to stick-slip. Our system shows a temperature- and velocity-dependent phase lag between the sinusoidal sliding rate and frictional response, which may help explain the phase lag between plume activity and peak stresses on the tiger stripes of Enceladus. Through forward modeling of a sinusoidally-driven slider block, using a rate-and-state dependent friction formulation and experimentally derived parameters, we extrapolate the higher-frequency oscillations in the laboratory experiments to lower frequencies analogous to diurnal tidal stresses on icy satellites. We explore the effect of oscillatory friction on frictional heating rates and fault failure depth with implications for the conditions under which shallow frictional melt generation may be favorable.

我们探索了振荡载荷对多晶水冰和冰+氨摩擦响应的影响,以更好地理解潮汐调制走滑断层在太阳系外冰卫星上的行为,特别是土星的卫星土卫二。冰与冰之间的摩擦实验在温度为98至248 K之间进行,法向应力为100 kPa(相当于冰壳中1公里的深度)。在一个振幅和频率范围内施加正弦滑动速率,中间速度为10 μm/s。我们计算了幅频组合的速率和状态摩擦参数,发现相对于稳态加载,振荡加载改变了摩擦稳定性,导致潜在的更不稳定的滑移行为。我们观察了滑移行为的全谱,从蠕变到慢滑再到粘滑。我们的系统显示了正弦滑动率和摩擦响应之间的相位滞后与温度和速度有关,这可能有助于解释土卫二虎纹上羽流活动和峰值应力之间的相位滞后。通过正演模拟正弦驱动滑块,使用速率和状态相关的摩擦公式和实验导出的参数,我们将实验室实验中的高频振荡外推到低频,类似于冰冻卫星上的日潮汐应力。我们探讨了振荡摩擦对摩擦升温速率和断层破坏深度的影响,以及浅层摩擦熔体产生有利条件的影响。
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引用次数: 0
Mid-Infrared Spectroscopy of Lunar High-Ti Basaltic Glassy Analogues 月球高钛玄武岩玻璃状类似物的中红外光谱
IF 4 1区 地球科学 Q1 GEOCHEMISTRY & GEOPHYSICS Pub Date : 2025-12-18 DOI: 10.1029/2024JE008895
C. P. Haupt, A. N. Stojic, A. Morlok, I. Weber, S. Klemme, H. Hiesinger, C. J. Renggli

Laboratory-based mid-infrared (MIR) spectroscopy of terrestrial and planetary analogue materials, combined with chemical and spectral insights from mission-derived data, provides critical tools for advancing our knowledge of planetary surfaces. The returned lunar samples provide information on the chemical variability of the lunar surface. Lunar basalts are notably enriched in TiO2 when compared to their terrestrial equivalents, and are ideal candidates to study the influence of composition on MIR spectral features. We characterized 25 synthetic lunar glasses with variable TiO2 (0.6–18.7 wt%) and SiO2 (35.6–52.1 wt%) in the thermal infrared range using micro-Fourier Transform Infrared Spectrometry (μ-FTIR). Our data reveal a strong linear relationship between the intensity of a spectral shoulder at 14.25 μm (702 cm−1) and the TiO2 content of the analyzed glasses. We suggest that the relationship in our samples reflects an increased distortion of the silicate network with increasing TiO2 concentrations. We observe that TiO2 acts as a network former in specific concentration intervals, thereby affecting the intensity of the observed spectral features in the MIR. This linear relationship is virtually nonexistent in samples that are developing stages of short-range order in the glasses and those samples that show only moderate to low amounts of TiO2. Comparison with data sets from Earth and Mercury analogue materials confirms that the Christiansen Feature (CF) consistently correlates with the SiO2 content, underscoring its robustness as a proxy for glass polymerization across planetary compositions. Finally, we emphasize that incipient crystal nucleation in glassy surfaces affects spectral features in the MIR range.

基于实验室的地球和行星模拟材料的中红外(MIR)光谱,结合任务衍生数据的化学和光谱见解,为提高我们对行星表面的认识提供了关键工具。返回的月球样本提供了关于月球表面化学变化的信息。月球玄武岩的TiO2含量明显高于地球玄武岩,是研究其组成对MIR光谱特征影响的理想候选者。利用微傅里叶变换红外光谱(μ-FTIR)对25种合成月球玻璃进行了表征,其中TiO2 (0.6-18.7 wt%)和SiO2 (35.6-52.1 wt%)在热红外范围内变化。我们的数据揭示了14.25 μm (702 cm−1)处光谱肩的强度与所分析玻璃的TiO2含量之间存在很强的线性关系。我们认为,我们样品中的关系反映了随着TiO2浓度的增加,硅酸盐网络的扭曲程度增加。我们观察到TiO2在特定的浓度间隔内作为网络形成物,从而影响MIR中观察到的光谱特征的强度。这种线性关系在玻璃中处于发展阶段的样品中几乎不存在,而那些样品只显示出中等到低含量的TiO2。与地球和水星模拟材料的数据集进行比较,证实了Christiansen特征(CF)与SiO2含量的一致性,强调了其作为跨行星组成的玻璃聚合代理的稳稳性。最后,我们强调,玻璃表面的早期晶体成核影响光谱特征在MIR范围内。
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引用次数: 0
Radiation Transport Through the Martian Atmosphere as a Function of the Zenith Angle 辐射在火星大气中的传输与天顶角的关系
IF 4 1区 地球科学 Q1 GEOCHEMISTRY & GEOPHYSICS Pub Date : 2025-12-18 DOI: 10.1029/2025JE009352
Salman Khaksari, Phillip H. Phipps, Robert F. Wimmer-Schweingruber, Timothy J. Stubbs, Mark D. Looper, Jingnan Guo, Gabin Charpentier, Bent Ehresmann, Jan Leo Löwe, Daniel Matthiä, Donald M. Hassler, Cary Zeitlin, Sven Löffler

The topographic influence of the radiation environment on the Martian surface radiation is crucial for future human exploration. Topographic maps help assess radiation flux variations, aiding in hazard evaluation. Creating a global radiation map requires accounting for seasonally varying atmospheric density, heliospheric modulation, and topography. Here, we use a radiation model to derive the flux of secondary downward particles generated by the interaction of primary protons with the Martian atmosphere. Our model examines two key factors: (a) the dependence of atmospheric column depth on the zenith angle, affecting radiation directionality as horizon-arriving particles traverse more atmosphere than vertical ones and (b) atmospheric conditions at surface heights in Gale Crater, crucial for developing radiation dose maps that incorporate topographic effects. Our model is validated against Radiation Assessment Detector measurements and benchmarked with existing models. We construct response matrices representing the ratio of secondary particles at the Martian surface to primary inputs across zenith angles, assessing atmospheric effects. We combine these matrices with the incident spectrum to compute secondary particle fluxes from all zenith angles for Galactic Cosmic Rays and Solar Energetic Particles. These fluxes will be integrated into a topographic map of Mars in a follow-up study, providing a detailed representation of surface radiation levels across different terrains. This approach aids mission planners in identifying safe landing sites for astronauts.

辐射环境对火星表面辐射的地形影响对未来人类探索至关重要。地形图有助于评估辐射通量的变化,有助于危害评估。创建全球辐射图需要考虑季节性变化的大气密度、日球层调制和地形。在这里,我们使用辐射模型来推导由初级质子与火星大气相互作用产生的次级向下粒子的通量。我们的模型考察了两个关键因素:(a)大气柱深度对天顶角的依赖,由于到达地平线的粒子比垂直粒子穿过更多的大气,因此天顶角会影响辐射的方向性;(b)盖尔陨石坑表面高度的大气条件,这对于开发包含地形影响的辐射剂量图至关重要。我们的模型是根据辐射评估探测器的测量结果进行验证的,并与现有模型进行基准测试。我们构建了响应矩阵,表示火星表面的次级粒子与天顶角上的主要输入的比例,以评估大气的影响。我们将这些矩阵与入射光谱结合起来计算银河系宇宙射线和太阳高能粒子在所有天顶角的二次粒子通量。在后续研究中,这些通量将被整合到火星地形图中,提供不同地形表面辐射水平的详细表示。这种方法有助于任务规划者确定宇航员的安全着陆点。
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引用次数: 0
Fluid Flow at the Top of Jupiter's Dynamo Region 木星发电机区顶部的流体流动
IF 4 1区 地球科学 Q1 GEOCHEMISTRY & GEOPHYSICS Pub Date : 2025-12-18 DOI: 10.1029/2025JE009024
S. Sharan, M. A. Pais, H. Amit, B. Langlais

The magnetic main field (MF) and secular variation (SV) models for Jupiter can be used to gain insights about the internal dynamo and the flow that drives the field. We use two such models computed from Juno observations up to spherical harmonic degrees 16 and 8 for the MF and SV, respectively. We solve the radial magnetic induction equation in the frozen-flux approximation at the dynamo region outer boundary assuming zero radial velocity for four large-scale physical flow assumptions- unconstrained, toroidal, tangentially geostrophic and columnar. We find flows with root mean square velocity varying between 100 and 400 km/yr (0.3–1.3 cm/s) when the dynamo region spherical boundary is taken at 0.83 Jupiter radius. Equatorially symmetric, toroidal and non-zonal velocity components are larger than the anti-symmetric, poloidal and zonal components, respectively, for almost all cases. Toroidal and tangentially geostrophic flows display similar velocity values and patterns, despite relying on different physical assumptions. The four inverted solutions indicate that the Jovian interior has dominant eastward flows near the Great Blue Spot, in agreement with previous studies. In addition, our more complex flow models shed light on some new features such as a large non-zonal component, meridional flows in the southern hemisphere and field-aligned flows in the north. Finally, our unconstrained flow solution suggests upwelling near the south pole, consistent with thermal wind theory.

木星的主磁场(MF)和长期变化(SV)模型可以用来深入了解木星的内部发电机和驱动磁场的气流。我们使用了两个这样的模型,分别从朱诺观测到的球面调和度16和8中计算出MF和SV。在无约束、环面、切向地转和柱状四种大尺度物理流假设下,求解了发电机区外边界假定径向速度为零的冻结通量近似下的径向磁感应方程。我们发现,当发电机区球面边界为0.83木星半径时,流的均方根速度在100至400 km/yr (0.3-1.3 cm/s)之间变化。在几乎所有情况下,赤道对称、环面和非纬向速度分量分别大于反对称、极向和纬向速度分量。环面和切向地转流显示出相似的速度值和模式,尽管依赖于不同的物理假设。这四个倒置的解表明,木星内部主要是在大蓝点附近向东流动,这与之前的研究一致。此外,我们更复杂的流动模型揭示了一些新的特征,如大的非纬向成分,南半球的经向流动和北半球的场向流动。最后,我们的无约束流动解表明南极附近有上升流,这与热风理论一致。
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引用次数: 0
A Roadmap for the Exploration of Enceladus 探索土卫二的路线图
IF 4 1区 地球科学 Q1 GEOCHEMISTRY & GEOPHYSICS Pub Date : 2025-12-15 DOI: 10.1029/2024JE008907
L. E. Rodriguez, J. M. Weber, M. L. Cable, L. M. Barge, J. C. Castillo-Rogez, M. Chodas, S. N. Ferguson, P. M. Schenk, S. D. Vance, K. Carpenter, M. D. Ingham, C. J. Cochrane, C. M. Elder, B. L. Henderson, S. Hosseini, A. G. Marusiak, A. C. Noell, S. M. Perl, M. Ono

This paper provides key hypotheses to guide future missions to Enceladus for the current decadal cycle and beyond. Enceladus is a high priority target for the fields of astrobiology and planetary science because it contains the three basic ingredients for life as we understand it: organic materials, a liquid solvent, and an energy source. This prioritization is reflected in the National Academies of Sciences, Engineering, and Medicine 2023–2032 Planetary Science and Astrobiology Decadal Survey, which highlights Enceladus in the list of destinations for a NASA New Frontiers class mission and recommends an Enceladus Orbilander mission as the second priority Flagship mission. In 2021 the science definition team behind the Enceladus Vent Explorer, a concept funded under NASA's Innovative Advanced Concepts program, held three workshops to discuss high priority science for Enceladus. Resulting from these workshops was a list of investigations addressing two science goals: (a) “How has the thermal evolution of Enceladus impacted the moon's ability to sustain a liquid ocean and recycle nutrients?” and (b) “How has the astrobiological potential of Enceladus changed over time?” Herein we detail the science background, proposed hypotheses, objectives, and physical parameters for each proposed investigation. In addition, we introduce a novel approach to describe the organic state of a planetary body to facilitate the development of hypotheses related to the emergence of life and to contextualize putative biosignatures. Finally, we provide recommendations for further development of technology and research for ocean world exploration.

这篇论文提供了关键的假设,以指导未来对土卫二的十年周期和未来的任务。土卫二是天体生物学和行星科学领域的优先目标,因为它包含了我们所了解的生命的三种基本成分:有机物质、液体溶剂和能量来源。这种优先顺序反映在美国国家科学院、工程学院和医学院的《2023-2032年行星科学和天体生物学十年调查》中,该调查将土卫二列为NASA新前沿级任务的目的地清单,并建议将土卫二Orbilander任务作为第二优先旗舰任务。2021年,由美国宇航局创新先进概念计划资助的土卫二通风口探测器背后的科学定义团队举办了三次研讨会,讨论土卫二的高优先级科学。这些研讨会的结果是针对两个科学目标的调查清单:(a)“土卫二的热演化如何影响该卫星维持液态海洋和循环养分的能力?”(b)“土卫二的天体生物学潜力如何随时间变化?”在这里,我们详细的科学背景,提出的假设,目标,和物理参数为每一个建议的调查。此外,我们引入了一种新的方法来描述行星体的有机状态,以促进与生命出现有关的假设的发展,并将假定的生物特征置于背景下。最后,对海洋世界勘探技术和研究的进一步发展提出了建议。
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引用次数: 0
Martian South Polar Summer Dust Storms in Observations, Reanalyses, and Modeling 火星南极夏季沙尘暴的观测、再分析和模拟
IF 4 1区 地球科学 Q1 GEOCHEMISTRY & GEOPHYSICS Pub Date : 2025-12-15 DOI: 10.1029/2025JE009268
C. L. Campbell, S. D. Guzewich, J. M. Battalio, S. J. Robbins, C. M. L. Batterson

Dust storms near Mars' South Pole during the perihelion and summer solstice seasons (Ls ∼ 250–290°) are phenomenologically distinct from martian dust storms in other locations and seasons. While they have previously been observed to increase atmospheric dust loading and warm the south polar atmosphere, they have no notable impact on the middle latitudes, tropics, or northern hemisphere. Here, we use a combination of multiple remote sensing instruments, atmosphere reanalyses, and general circulation modeling to study the evolution of dust storms near the Martian South Pole during Mars Year 30 (a prototypical year for such storms). Dust lifting preferentially occurs in the eastern hemisphere (180°–320°E) and follows the retreating seasonal CO2 polar cap to higher latitudes as the season progresses—implicating the strong cap edge thermal forcing and katabatic flows as well as surface dust availability in driving dust lifting. Dust remains confined to the high southern latitudes during this season with strong diurnal variability in both latitudinal and vertical extents. Dust is entrained in the southern circumpolar jet stream, creating filamentation and longitudinal mixing and controlling the flow of dust back onto the polar cap. The diurnally varying atmospheric circulation (Ferrel cell) limits the mixing of dust to lower latitudes and prevents a global thermal response.

在近日点和夏至季节(l ~ 250-290°),火星南极附近的沙尘暴在现象上与其他地点和季节的火星沙尘暴不同。虽然它们以前被观察到增加大气粉尘负荷并使南极大气变暖,但它们对中纬度地区、热带地区或北半球没有显著影响。在这里,我们结合多种遥感仪器、大气再分析和大气环流模型来研究火星南极附近沙尘暴在火星30年(此类风暴的典型年份)的演变。扬尘优先发生在东半球(180°-320°E),并且随着季节的进展,季节性CO2极帽向高纬度地区后退,这意味着强烈的极帽边缘热强迫和降冰流以及地表沙尘可用性推动了扬尘。在这个季节,沙尘仍然局限于南纬高纬度地区,在纬度和垂直范围上都有很强的日变化。尘埃被南方的绕极急流裹挟,形成细丝状和纵向混合,并控制尘埃流回到极帽。日变化的大气环流(Ferrel cell)限制了尘埃在低纬度地区的混合,并阻止了全球热响应。
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引用次数: 0
Trace Element Transport and Deposition During Magmatic Degassing: The Effect on Martian Rocks and Fines 岩浆脱气过程中微量元素的迁移和沉积:对火星岩石和细粒的影响
IF 4 1区 地球科学 Q1 GEOCHEMISTRY & GEOPHYSICS Pub Date : 2025-12-13 DOI: 10.1029/2024JE008906
N. Zimmermann, M. Safari, H. Nekvasil

Martian magmas compositionally resemble those from terrestrial continental hotspot magmatic suites, characterized by low OH and high Cl and S contents. The magmatic gases exsolved from such magmas transport a variety of metal complexes and, upon cooling, precipitate vapor-deposits into vugs and fractures within rocks and on the surfaces of pyroclastics, which are then added to surface fines. Experiments investigated trace element behavior during magmatic degassing as a potential signature of this magmatic process. Low-pressure experimental degassing of P-rich basaltic magma containing Cl, Br, S, minor OH, and trace elements (Sr, Ge, Ga, Zn, Pb, Rb, Cs, Se, Cu, La, and Lu) demonstrated that the gas-transported trace metals become incorporated into vapor-deposited Cs-Pb-Zn-Rb-bearing halides, Ge-Ga-bearing iron oxides, Zn-Se-Cu-bearing sulfides, alkali and iron sulfates, Ge-bearing silicates, rare earth phosphates, and elemental metals. Low-OH and high-Cl magmatic systems produce a variety of halides but inhibit Fe-oxide formation. S-rich systems produce vapor-deposited Na-, K-, and Fe-sulfates, Zn-Cu-Se bearing sulfides, and iron oxides. These results provide a signature for determining the possibility of a significant role for magmatic gas in producing secondary minerals and volatile trace element enrichment in the Gusev plains, Columbia Hills, Jezero crater, and Gale crater. A hallmark of vapor-deposited phases is the presence of local heterogeneities in “alteration” phases and in trace element signatures due to the superposition of high and low temperature phases.

火星岩浆的组成与陆地大陆热点岩浆套相似,具有低OH和高Cl、S含量的特征。从这些岩浆中析出的岩浆气体携带了各种金属络合物,冷却后,将气相沉积物沉淀到岩石中的孔洞和裂缝中,并沉积在火山碎屑表面,然后添加到表面细粒中。实验研究了岩浆脱气过程中微量元素的行为,作为该岩浆过程的潜在标志。对含Cl、Br、S、少量OH和微量元素(Sr、Ge、Ga、Zn、Pb、Rb、Cs、Se、Cu、La、Lu)的富p玄武质岩浆进行低压脱气实验,结果表明,气体输送的微量金属与气相沉积的含Cs-Pb-Zn-Rb卤化物、含Ge-Ga的氧化铁、含Zn-Se-Cu的硫化物、碱和铁硫酸盐、含Ge硅酸盐、稀土磷酸盐和元素金属结合在一起。低oh和高cl岩浆体系产生多种卤化物,但抑制铁氧化物的形成。富s系统产生气相沉积的钠、钾和铁硫酸盐,含锌、铜、硒的硫化物和氧化铁。这些结果为确定岩浆气体在古谢夫平原、哥伦比亚山、耶泽罗陨石坑和盖尔陨石坑次生矿物产生和挥发性微量元素富集中可能起重要作用提供了一个标志。气相沉积相的一个特点是由于高温相和低温相的叠加,在“蚀变”相和微量元素特征中存在局部非均质性。
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引用次数: 0
Spectral Study of Five Major Impact Basins and Their Volcanic Infills on Mercury: A Window Into the Mantle's Properties 五个主要撞击盆地及其对汞的火山充填物的光谱研究:揭示地幔性质的窗口
IF 4 1区 地球科学 Q1 GEOCHEMISTRY & GEOPHYSICS Pub Date : 2025-12-13 DOI: 10.1029/2025JE009359
E. Caminiti, S. Besse, A. Doressoundiram, J. Wright

NASA's MErcury Surface, Space ENvironment, GEochemistry, and Ranging mission has revealed that about 27% of the surface of Mercury is covered by smooth plains, which are mostly volcanic in origin. These plains are mainly located in the northern hemisphere, as well as within and around major impact basins. We used Mercury Atmospheric and Surface Composition Spectrometer data to perform an exhaustive spectral analysis of five major impact basins: Caloris, Rembrandt, Beethoven, Tolstoj, and Rachmaninoff. We highlighted the existence of a new high-reflectance spectral unit, that had previously only been identified within the Rembrandt basin, as a major unit being more widespread. We named this new unit Young High-reflectance Red Plains. We found a common sequence of volcanic episodes that infilled the basins and shaped their current surface spectral properties. We have shown that the size of the basin and the age of the volcanic infills are likely important parameters for the layering of different volcanic plains, defining the surface spectral units. Our study gives access to mantle properties, and we suggest that heterogeneity in the mantle is certainly not necessary to explain the spectral properties of effusive volcanism associated with impact basins. Future observations by the ESA-JAXA-BepiColombo mission are eagerly awaited to better constrain the planet's spectral, compositional, morphological, and geophysical surface properties.

美国宇航局的水星表面、空间环境、地球化学和测距任务显示,水星表面约有27%被光滑的平原覆盖,这些平原大多是火山形成的。这些平原主要位于北半球,以及主要撞击盆地内部和周围。我们使用水星大气和地表成分光谱仪的数据对五个主要撞击盆地:卡洛里斯、伦勃朗、贝多芬、托尔斯泰和拉赫玛尼诺夫进行了详尽的光谱分析。我们强调了一种新的高反射率光谱单元的存在,这种单元以前只在伦勃朗盆地中被发现,是一种更广泛的主要单元。我们将这个新单位命名为年轻高反射率红平原。我们发现了一个共同的火山事件序列,这些火山事件填充了盆地,并塑造了它们目前的表面光谱特性。我们已经证明,盆地的大小和火山填充物的年龄可能是不同火山平原分层的重要参数,定义了地表光谱单位。我们的研究提供了地幔性质的途径,我们认为地幔的非均质性当然不是解释与撞击盆地相关的喷涌火山活动光谱性质的必要条件。人们热切期待ESA-JAXA-BepiColombo任务的未来观测,以更好地了解这颗行星的光谱、成分、形态和地球物理表面特性。
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引用次数: 0
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Journal of Geophysical Research: Planets
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