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Chemical Characteristics and Oxidation Potential of PM1.0 at a Suburban Location in Metropolitan Area 大都市郊区PM1.0的化学特征及氧化潜能
IF 1 Q4 METEOROLOGY & ATMOSPHERIC SCIENCES Pub Date : 2022-06-30 DOI: 10.5572/kosae.2022.38.3.437
Myoung-Ki Song, Jinsoo Park, Minsung Kim, Jinsoo Choi, Sea-Ho Oh, Seoyeong Choe, Geun-Hye Yu, T. Lee, M. Bae
Scientific analyses were carried out to investigate the characteristics of both ultra-fine (PM1.0) and fine particulate matters (PM2.5) based on chemical speciation collected at National Institute of Environmental Research in Incheon, Repulic of Korea. In this study, PM1.0 and PM2.5 mass were monitored using two betaray instruments simultaneously. Organic carbon, elemental carbon, water soluble ionic compounds, and polycyclic aromatic hydrocarbons were analyzed using carbon analyzer, ion chromatography, and gas chromatography, respectively. In addition, the oxidation potential using dithiothreitol were investigated to compare the level of toxicities in PM1.0 and PM2.5. As a result, although characteristics of major chemical components in PM1.0 and PM2.5 were similar, oxidation potential in PM1.0 were presented higher than that in PM2.5 due to organic compounds related to toxic compounds. This result will be able to investigate the health studies and policy strategies associated with PM1.0.
根据韩国仁川国家环境研究所收集的化学形态,进行了科学分析,以调查超细颗粒物(PM1.0)和细颗粒物(PM2.5)的特征。在这项研究中,同时使用两台倍他射线仪器监测PM1.0和PM2.5质量。分别使用碳分析仪、离子色谱法和气相色谱法分析有机碳、元素碳、水溶性离子化合物和多环芳烃。此外,还研究了使用二硫苏糖醇的氧化潜力,以比较PM1.0和PM2.5中的毒性水平。因此,尽管PM1.0和PM2.5中主要化学成分的特征相似,但由于与有毒化合物相关的有机化合物,PM1.0中的氧化潜力高于PM2.5。这一结果将能够调查与PM1.0相关的健康研究和政策策略。
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引用次数: 0
Estimation of Emission Flux of Particulate Matter by Agricultural Burning in Rural Areas using Scanning LIDAR 基于扫描激光雷达的农村农业焚烧颗粒物排放通量估算
IF 1 Q4 METEOROLOGY & ATMOSPHERIC SCIENCES Pub Date : 2022-06-30 DOI: 10.5572/kosae.2022.38.3.414
Ga-Lam Kim, Juseon Shin, Du-Sung Kim, Ju-Yeol Sim, So-Young Joo, Jeong Kim, Sung Hwan Cho, Cheon Woong Kang, Y. Noh
The Korean government enforces a fine dust seasonal management system to reduce aerosols emitted from illegal incineration in rural areas during the winter and spring period. The burning of agricultural by-products in rural areas is prohibited by law but is still prevalent. Illegal incinerations mainly occur on a small scale in a wide area, so managing and controlling them is difficult. To estimate the emission flux of PM from agricultural burning, we used scanning Light Detection and Range (Lidar). The scanning Lidar can observe mass concentration in an area with a radius of 5 km at 30-minute intervals with a distance resolution of 30 m. We calculated the upward velocity using the relationship between the plume central velocity and mass entrainment rate in the plume rise model, then estimated the emission flux using mass concentration and plume distribution range. The emission fluxes of PM 2.5 in stagnant and diffused cases were 1.17 kg/h and 2.09 kg/h, respectively. Annualized values of the emission flux were 0.11 tons/year and 0.20 tons/year according to the number of observations. These were slightly lower than the national emission inventory (4.98 tons/year). The difference might be because the emission inventory was overestimated or there were errors in the process of annualization.
韩国政府为了减少冬季和春季在农村地区非法焚烧产生的气溶胶,实行了可吸入颗粒物季节性管理制度。在农村焚烧农副产品是法律禁止的,但仍然很普遍。非法焚烧主要发生在小范围、大范围,管理和控制难度较大。为了估算农业燃烧产生的PM的发射通量,我们使用了扫描光探测和距离(激光雷达)。扫描式激光雷达每隔30分钟可观测半径为5公里范围内的质量浓度,距离分辨率为30米。利用羽流上升模型中羽流中心速度与质量夹带速率的关系计算上升速度,然后利用质量浓度和羽流分布范围估算发射通量。停滞和扩散情况下pm2.5的排放通量分别为1.17 kg/h和2.09 kg/h。根据观测次数,年化排放通量值分别为0.11和0.20吨/年。这些数据略低于全国排放清单(4.98吨/年)。这种差异可能是由于排放清单被高估或在年化过程中存在误差。
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引用次数: 0
Estimation of Fuel Loadings of Domestic Agricultural Crop Residues to Determine the Air Pollutants Emissions 估算国内农作物残茬燃料负荷以确定空气污染物排放
IF 1 Q4 METEOROLOGY & ATMOSPHERIC SCIENCES Pub Date : 2022-06-30 DOI: 10.5572/kosae.2022.38.3.451
K. Yu, Byung-Tae Lee, K. Han, Hyun-Soo Kim, Hyung-Moon Yim, Myoung-Ki Song, M. Bae
Open burning of agricultural residues is one of the significant sources of air pollution. The quantification of air pollutants emissions by open burning requires the fuel loadings calculated from the biomass and the crop’s burning ratio that indicates the mass fraction of crop residues incinerated to the total crop residues. The survey of 1,004 domestic farmers in 2020 found that the burning ratio was 13.6%, and the compost recycling was 73.5%. The burning ratio varied from region and crop. The burning ratio in Gyeonggi-do was the highest at 31.7%, followed by Chungcheongbuk-do at 21.6%, Jeollabuk-do at 19.1%, and Gyeongsangnam-do at 15.5%. The pepper’s burning ratio was 33.6%, followed by pear at 27.5%, peanut at 25.6%, and barley at 21.0%. Compared to 2014, the burning ratio decreased significantly. The average burning ratio of ten crops dropped by 71.6%, and particularly that of fruit trees’ residue such as pear, apple, peach, and grape decreased by 78.5%. The biomass conversion factors to the annual crop yields provided by Statistics Korea reasonably presented the annual mass of agricultural crop residues. Finally, the fuel loadings at the agricultural open burning for twenty residues were estimated by multiplying the burning ratios by the mass of agricultural crop residues. As of 2019, the fuel loading of apples was the highest at 128,217 ton/yr, and those of pepper and barley were 68,523 ton/yr and 51,661 ton/yr, respectively. Open burning of agricultural crop residues is one of the long-standing treatment ways. However, to reduce the emission of air pollutants, it is most effective to promote recycling, such as compost or livestock feed.
露天焚烧农业残留物是空气污染的重要来源之一。露天焚烧的空气污染物排放量的量化需要根据生物质和作物燃烧比计算的燃料负荷,该燃烧比表示焚烧的作物残留物占总作物残留物的质量分数。2020年对1004名国内农民的调查发现,焚烧率为13.6%,堆肥回收率为73.5%。焚烧率因地区和作物而异。京畿道的燃烧率最高,为31.7%,其次是忠清北道21.6%、全罗北道19.1%和庆尚南道15.5%。辣椒的燃烧率为33.6%,其次是梨27.5%、花生25.6%和大麦21.0%。与2014年相比,燃烧率显著下降。10种作物的平均燃烧率下降了71.6%,尤其是梨、苹果、桃和葡萄等果树的残留物下降了78.5%。韩国统计局提供的生物量与年作物产量的换算系数合理地反映了农业作物残留物的年质量。最后,通过将燃烧比乘以农业作物残留物的质量来估计20个残留物的农业露天燃烧的燃料负荷。截至2019年,苹果的燃料负荷最高,为128217吨/年,辣椒和大麦的燃料负荷分别为68523吨/年和51661吨/年。露天焚烧农业作物残留物是一种长期存在的处理方式。然而,为了减少空气污染物的排放,促进堆肥或牲畜饲料等回收利用是最有效的。
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引用次数: 0
Estimation of Source Apportionment for PM2.5 Data of Air Pollution Monitoring Site in Pohang Using the EPA-PMF Model 利用EPA-PMF模型估算浦项大气污染监测点PM2.5数据的源分配
IF 1 Q4 METEOROLOGY & ATMOSPHERIC SCIENCES Pub Date : 2022-06-30 DOI: 10.5572/kosae.2022.38.3.354
I. Hwang
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引用次数: 1
Determination of Emission Factor for Chemical Compounds from Agricultural Crop Residues Burning using Closed Chamber System : Distributions of Organic Compounds 用密闭室系统测定农业作物残留物燃烧产生的化合物排放因子:有机化合物的分布
IF 1 Q4 METEOROLOGY & ATMOSPHERIC SCIENCES Pub Date : 2022-06-30 DOI: 10.5572/kosae.2022.38.3.470
Geun-Hye Yu, Myoung-Ki Song, Minsung Kim, Sea-Ho Oh, K. Yu, Byung T. Lee, K. Han, M. Bae
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引用次数: 0
Evaluation of Measurement Reliability of Light-scattering PM2.5 Monitor Applied with Referenced-channel Calibration Technology 应用参考通道校准技术的光散射PM2.5监测仪测量可靠性评价
IF 1 Q4 METEOROLOGY & ATMOSPHERIC SCIENCES Pub Date : 2022-06-30 DOI: 10.5572/kosae.2022.38.3.341
Junho Ryu, Siwon Jeong, Gwangryeun Kim, Whokyung Park, S. Park
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引用次数: 2
An Analysis of Meteorological Characteristics for Fine Particles on the Korean Peninsula during Wintertime, 2015-2021 2015-2021年冬季朝鲜半岛细颗粒物气象特征分析
IF 1 Q4 METEOROLOGY & ATMOSPHERIC SCIENCES Pub Date : 2022-06-30 DOI: 10.5572/kosae.2022.38.3.394
J. Jee, Chang-Rae Cho, Sanghyun Kim, M. Song
In order to analyze the characteristics of fine particles on the Korean Peninsula, the synoptic wind field, aerosol optical depth distribution, and surface observation data were used around the East Asia and the Korean Peninsula. In addition, the relationship and relative influence between high-concentration fine particles cases and meteorological variables were evaluated using the General Boosted Machine (GBM) model. In 2020, relatively low concentrations of fine particles appeared due to the weakening of the meridional atmospheric pressure deviation and the weakening of the zonal flow in East Asia. AOD around the Korean Peninsula was high mainly in Incheon and Taean Peninsula, and high AOD was found mainly in the West Sea due to long-range transport from China. In the case of haze or high-concentration fine particles in winter, the PM 2.5 /PM 10 ratio was greater than 0.6, and the ratio increased during long-range transport. In the high-concentration fine particles case, the temperature, wind speed, and boundary layer height (PBLH) were lower than the overall data, and the PM 2.5 /PM 10 ratio was high. When high-concentration cases were analyzed using the GBM model, the fine particles concentration had a high correlation with meteorological and temporal variables. As a result, the relative influence on the fine particles concentration was highest in order of year, week, air temperature, the day of the week, relative humidity, PBLH, hour, wind direction, and wind speed.
为了分析朝鲜半岛细颗粒物的特征,利用了东亚和朝鲜半岛周围的天气风场、气溶胶光学深度分布和地面观测数据。此外,使用通用增压机(GBM)模型评估了高浓度细颗粒物情况与气象变量之间的关系和相对影响。2020年,由于东亚经向大气压力偏差的减弱和纬向气流的减弱,出现了相对较低浓度的细颗粒物。朝鲜半岛周围的AOD主要在仁川和大安半岛,由于来自中国的远程运输,高AOD主要出现在西海。在冬季雾霾或高浓度细颗粒物的情况下,PM 2.5/PM10的比率大于0.6,并且在长距离传输期间该比率增加。在高浓度细颗粒物的情况下,温度、风速和边界层高度(PBLH)低于总体数据,PM 2.5/PM10比率较高。当使用GBM模型分析高浓度情况时,细颗粒物浓度与气象和时间变量具有高度相关性。结果,对细颗粒物浓度的相对影响按年份、周、气温、星期几、相对湿度、PBLH、小时、风向和风速的顺序最高。
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引用次数: 0
Inventory of VOCs Including Ozone Precursors Emitted from Residential Workplaces and Evaluation of Contribution to Ozone Formation 住宅工作场所排放的挥发性有机化合物(包括臭氧前体)清单及对臭氧形成贡献的评估
IF 1 Q4 METEOROLOGY & ATMOSPHERIC SCIENCES Pub Date : 2022-04-30 DOI: 10.5572/kosae.2022.38.2.175
Jeong-Seok Chae, J. Chae, Min-Young Kim, Jun-Min Jeon, Tae-Jung Lee, Youngchul Jo
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引用次数: 2
Effect of Reduced Emissions from Thermal Power Plants in China on Local Air Quality Improvement 中国火力发电厂减排对当地空气质量改善的影响
IF 1 Q4 METEOROLOGY & ATMOSPHERIC SCIENCES Pub Date : 2022-04-30 DOI: 10.5572/kosae.2022.38.2.304
Kwonho Lee, Sung-Kyun Shin
In September 2021, China encountered the shortage of coal and emission activity shrunk to the lowest it had been since February 2020, when coronavirus lockdowns paralyzed the economy. Despite social and economic concerns, this event has brought unexpected positive consequences for environmental quality. In this study, we investigated the impact of restricted thermal power plants operations on local air quality is investigated. For this purpose, social statistics, satellite observations, ground-based air quality measurements, and meteorology data were analyzed to estimate the spatio-temporal characteristics of air pollutants. As a result, significant reductions in the concentrations of air pollutants were found. It was about 11.13% lower than the reduced concentration due to the coronavirus lockdowns period in China. Compared to the average value during the normal year for 2015-2019, large decreased values of SO2 (-38.81%), CO (-24.78%), NO2 (-54.26%), PM 10 (-51.60%), and PM2.5 (-56.35%) were measured in Seoul, Korea. Satellite observation data confirm that these large drop in air pollution levels occurred in both countries, serving as a valuable proof of the emission control impact on local air quality. Moreover, the easterly wind along with the increased precipitation rate in China could affect the wet deposition and dilution of air pollutants.
2021年9月,中国遭遇煤炭短缺,排放活动萎缩至自2020年2月以来的最低水平,当时冠状病毒封锁使经济陷入瘫痪。尽管存在社会和经济方面的担忧,但这一事件给环境质量带来了意想不到的积极影响。在本研究中,我们调查了限制火力发电厂运行对当地空气质量的影响。为此,我们分析了社会统计、卫星观测、地面空气质量测量和气象数据,以估计空气污染物的时空特征。结果发现,空气污染物的浓度显著降低。这比中国冠状病毒封锁期间降低的浓度降低了约11.13%。与2015-2019年正常年的平均值相比,韩国首尔的SO2(-38.81%)、CO(-24.78%)、NO2(-54.26%)、pm10(-51.60%)和PM2.5(-56.35%)下降幅度较大。卫星观测数据证实,这两个国家都出现了空气污染水平的大幅下降,这是排放控制对当地空气质量产生影响的宝贵证据。此外,东风和降水速率的增加会影响大气污染物的湿沉降和稀释。
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引用次数: 0
Seasonal Oxidation Potential of Vehicle Emission using Tunnel Flow Coefficient 基于隧道流量系数的汽车尾气季节性氧化电位
IF 1 Q4 METEOROLOGY & ATMOSPHERIC SCIENCES Pub Date : 2022-04-30 DOI: 10.5572/kosae.2022.38.2.294
Seoyeong Choe, Sea-Ho Oh, Myoungki Song, Eunyoung Kim, Yongmin Lee, S. Seo, G. Park, Minsung Kim, Kyungmin Kim, Taehyoung Lee, M. Bae
Seasonal samples located in Seoul were collected from inside and outside tunnel at the same time to determine the oxidation potential (OP) using dithiothreitol (DTT) method corresponding to real-world vehicle emissions. First, the novel quantitative oxidation potential method was developed using 9,10-phenanthraquinone. Second, quinone normalized DTT-OP was utilized to calculate the seasonal oxidation potential of unit vehicle emission with tunnel flow coefficient. As a result, the overall average for seasonal oxidation potential of unit vehicle emission were shown as 169 μM/veh · km. In addition, the highest concentration was presented from midnight through 6 a.m. for all seasons due to complex parameters including vehicle speeds. This result will be able to investigate the health studies associated with unit of vehicle emissions in real atmosphere.
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引用次数: 1
期刊
Journal of Korean Society for Atmospheric Environment
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