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The Effect of Remelting Cycles and Its Carbon Content on the Glass Forming Ability and Mechanical Properties of the Zr-based Amorphous Alloy Return Scrap 重熔循环次数及含碳量对zr基非晶合金回料玻璃化成形能力及力学性能的影响
Pub Date : 2014-06-30 DOI: 10.7777/JKFS.2014.34.3.094
Byung-chul Lee, Sung-Gyoo Kim, B. Park, Heung-Il Park, H. Park
A commercially used Zr-based amorphous alloy was recycled and the effects of introducing carbon during recycling on the glass forming ability and mechanical properties of the alloy were investigated. The initial carbon content used in this study was 229ppm. The carbon content was gradually increased as the number of recycling iterations was increased and after the 4 recycling it rapidly increased. As return scrap was recycled, polygonal particles precipitated, and they were identified as ZrC. The amount of the precipitates also increased with recycling. Tg, Tx and ∆T of the base alloy were 615 K, 696 K and 81 Kr respectively and they changed to 634 K, 706 K and 72 K after the 10 recycling. The decrease of the ∆T value indicates deterioration of the glass forming ability. Hardness was not changed during three iterations of recycling but after the 4 recycling it significantly increased. This is ascribed to an increase of amount of the hard particles, namely ZrC.
对一种工业用zr基非晶合金进行了回收,研究了在回收过程中引入碳对合金玻璃化成形能力和力学性能的影响。本研究中使用的初始碳含量为229ppm。随着循环次数的增加,碳含量逐渐增加,循环4次后碳含量迅速增加。在回收过程中,有多边形颗粒析出,经鉴定为ZrC。随着循环使用,析出物的数量也有所增加。基体合金的Tg、Tx和∆T分别为615 K、696 K和81 Kr, 10次循环后分别为634 K、706 K和72 K。∆T值的减小表明玻璃化形成能力的恶化。硬度在3次循环中没有变化,但在4次循环后硬度明显增加。这是由于硬颗粒,即ZrC的数量增加。
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引用次数: 0
A Study on Mechanical Characteristic of Hydrogen Charged Al-6.3Zn-2.4Mg Alloy 充氢Al-6.3Zn-2.4Mg合金力学特性研究
Pub Date : 2014-04-30 DOI: 10.7777/JKFS.2014.34.2.054
Dae-hwan Kim, Tae-young Choi, Sung-Young Shim, Su-gun Lim
In this study, the extruded Al-6.3Zn-2.4Mg alloys were selected among the 7000 series aluminum alloys sensitive to hydrogen environment in order to examine the effects of both the aging conditions and the length of hydrogen charging period on the mechanical properties of the alloy. The specimens were aged for 24hours at (under aging (UA)), (peak aging (PA)), and (over aging (OA)), respectively. Charging tests were performed at RT for 12, 24, 36 hours under potentiostatic conditions (-2000 mV vs (Ag/AgCl)) for 12, 24 and 36 hours in 1M and 0.1% solution. The fracture surface was examined by scanning electron microscopy (SEM). X-ray diffraction (XRD) pattern in peak aged sample was obtained before and after hydrogen charging from extruded Al-6.3Zn-2.4Mg alloys. The decreasing rate of tensile strength and elongation is represented in order of over aging in hydrogen charged Al-6.3Zn-2.4Mg alloys has been confirmed by X-ray diffraction studies.
本研究选取对氢环境敏感的7000系铝合金中挤压的Al-6.3Zn-2.4Mg合金,考察时效条件和充氢时间对合金力学性能的影响。分别在(UA)、(峰值时效(PA)和(超时效(OA))下时效24h。在恒电位条件下(-2000 mV vs (Ag/AgCl)),在1M和0.1%溶液中进行12、24和36小时的充电试验。采用扫描电镜(SEM)对断口表面进行了观察。对Al-6.3Zn-2.4Mg合金挤压充氢前后峰时效试样的x射线衍射(XRD)图进行了分析。x射线衍射研究证实了充氢Al-6.3Zn-2.4Mg合金的抗拉强度和伸长率的递减规律,并以过时效的先后顺序表示。
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引用次数: 0
The Effect of Blasting Treatment on the Corrosion Characteristics in the Zr-based Amorphous Alloy Die Castings 爆破处理对zr基非晶合金压铸件腐蚀特性的影响
Pub Date : 2014-04-30 DOI: 10.7777/JKFS.2014.34.2.060
Byung-chul Lee, Sung-Gyoo Kim, B. Park, Cha-Hurn Bae, Heung-Il Park
A Zr-based amorphous alloy specimen was produced by vacuum die casting process. The salt spray test was carried out using the specimens in the as-cast, and particle blasted state. Using these specimens, the SEM-EDX and XRD analyses, DSC measurement and bending strength test were conducted. After the salt spray test, the specimens were not experienced phase change and thermal characteristics of the alloys were remained unchanged. In the as-cast specimen, corrosion products were not observed. However, in the particle blasted specimen, pitting corrosion occurred and the detected corrosion products were and . Due to the salt spray test, bending strength of the blasted specimens showed about 100 MPa lower strength than the other specimens. The bending fracture surface was vein pattern which was shown typically in the amorphous alloys.
采用真空压铸法制备了zr基非晶合金试样。对铸态和颗粒爆破状态的试样进行了盐雾试验。利用这些试样进行了SEM-EDX、XRD分析、DSC测试和抗弯强度测试。盐雾试验后,试样未发生相变,合金的热特性基本保持不变。铸态试样中未观察到腐蚀产物。而在颗粒爆破试样中,出现点蚀现象,检测到的腐蚀产物为和。由于盐雾试验,爆破后试件的抗弯强度比其他试件低约100 MPa。弯曲断口呈脉状,这是非晶合金的典型特征。
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引用次数: 0
The Effect of Sn on the Glass Formation Ability of the Zr-based Amorphous Alloy Sn对zr基非晶合金玻璃化能力的影响
Pub Date : 2014-04-30 DOI: 10.7777/JKFS.2014.34.2.049
Byung-chul Lee, Heong Park, B. Park, Sung-Gyoo Kim
In commercial Zr-Nb-Cu-Ni-Al amorphous alloys, expensive element, Zr, was substituted to Sn which was cheaper one, and then, glass forming ability, compressive strength and hardness of them were estimated. Even though the Sn was added up to 1.5%, resulting phase was not changed to the crystalline form. It was confirmed by X-ray diffraction and thermal analyses. In the X-ray profiles, there were no peaks for crystalline phases and typical halo pattern for amorphous phase was appeared at the diffraction angle of 35o~45o. Thermal analyses also showed that the Sn modified alloys were corresponded to the amorphous standards where ∆T(= Tx − Tg) and Trg(= Tg/Tm) affecting to the amorphous forming ability were more than 50K and 0.60 respectively. Compressive strengths were 1.77 GPa, 1.63 GPa, 1.65 GPa and 1.77 GPa for 0%Sn, 0.5%Sn, 1.0%Sn and 1.5%Sn respectively. Hardnesses of the Sn modified alloys were decreased from 752 Hv to 702 Hv in 1.0%Sn and recovered to 746 Hv in 1.5%Sn.
在工业Zr- nb - cu - ni - al非晶合金中,用昂贵元素Zr代替便宜元素Sn,对其玻璃化形成能力、抗压强度和硬度进行了评价。当Sn添加量达到1.5%时,产物相仍未转变为结晶形态。经x射线衍射和热分析证实。在衍射角为35o~45o的x射线衍射谱中,无晶相峰,出现典型的非晶相晕状。热分析表明,Sn改性合金符合非晶态标准,∆T(= Tx−Tg)和Trg(= Tg/Tm)对非晶态形成能力的影响分别大于50K和0.60。0%Sn、0.5%Sn、1.0%Sn和1.5%Sn的抗压强度分别为1.77 GPa、1.63 GPa、1.65 GPa和1.77 GPa。当Sn含量为1.0%时,合金硬度从752 Hv下降到702 Hv,当Sn含量为1.5%时,合金硬度恢复到746 Hv。
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引用次数: 0
Effect of Shrinkage Defect on Fracture Impact Energy of A356 Cast Aluminum Alloy 收缩缺陷对A356铸造铝合金断裂冲击能的影响
Pub Date : 2014-02-28 DOI: 10.7777/JKFS.2014.34.1.022
Hwang-Seong Chul, S. Kwak
Internal defects, such as shrinkage during casting, cause stress concentrations and initiate cracking. Therefore, it is important to understand the effects of internal defects on the mechanical properties including the impact behavior. This study evaluates the effects of internal casting defects on the impact performance of A356 Al-alloy castings. The internal shrinkage defects in the casting impact specimen are scanned using an industrial Computed Tomography (CT) scanner, and drop impact tests are performed with varing impact velocities on the A356 casting aluminium specimen (10 mm × 10 mm section area) in order to locate the fracture energy under an impact load. The specimens with defects with a diameter less than 0.35 mm exhibit equivalent fracture impact energies of approximately 32 J and those with a 1.7 mm diameter defect reduced the fracture impact energy by 35%.
内部缺陷,如铸造时的收缩,会引起应力集中并引发开裂。因此,了解内部缺陷对包括冲击行为在内的力学性能的影响是非常重要的。研究了铸件内部缺陷对A356铝合金铸件冲击性能的影响。利用工业计算机断层扫描(CT)扫描铸件冲击试样的内部收缩缺陷,并对A356铸造铝试样(10 mm × 10 mm断面面积)进行不同冲击速度的跌落冲击试验,以确定冲击载荷作用下的断裂能。当缺陷直径小于0.35 mm时,试件的等效断裂冲击能约为32 J,当缺陷直径为1.7 mm时,试件的等效断裂冲击能降低35%。
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引用次数: 1
Mechanical Properties of Low-Pressure Die Cast A356-T6 alloys for Automotive Wheels 汽车车轮用低压压铸A356-T6合金的力学性能
Pub Date : 2014-02-28 DOI: 10.7777/JKFS.2014.34.1.006
B. Yoo, Jeong-Ho Kim, H. Yoon, S. Ur
Abstract The mechanical properties of low-pressure die cast (LPDC) A356-T6 automotive road wheels are evaluated and correlated withtheir corresponding microstructures. In this study, two types of alloy wheels processed using different LPDC gating system areinvestigated. The yield stress, tensile stress, and elongation values tested at room temperature are correlated with the secondary den-drite arm spacing (SDAS) with respect to the gating system, and are also compared with similar studies. The SDAS and precipitatesare examined using optical microscopy, scanning electron microscopy (SEM) and energy-dispersive spectroscopy. The phase infor-mation is also investigated using X-ray diffraction. Charpy impact tests are also performed from −100 o C to 200 o C, and the fracturesurfaces are examined using SEM. The impact energy is demonstrated to increase with increasing temperatures without exhibitingspecific transition behaviors as in other nonferrous alloys. The fracture toughness is also evaluated using three point bend test withsingle-edged bend specimens. The obtained fracture toughness values are in good agreement with those in similar studies.Key words: Mechanical property, SDAS, Impact test, Fracture toughness, A356-T6 alloy
对低压压铸(LPDC) A356-T6汽车道路车轮的力学性能进行了评价,并与相应的组织进行了对比。本研究对采用不同LPDC浇注系统加工的两种合金轮毂进行了研究。在室温下测试的屈服应力、拉应力和延伸率值与浇注系统的二次枝晶臂间距(SDAS)相关,并与类似研究进行了比较。利用光学显微镜、扫描电子显微镜和能量色散光谱对SDAS和沉淀物进行了检测。用x射线衍射研究了相信息。在- 100℃至200℃范围内进行了夏比冲击试验,并用扫描电镜对断口表面进行了检查。结果表明,冲击能随温度升高而增加,而不像其他有色合金那样表现出特定的转变行为。断裂韧性也用单刃弯曲试样的三点弯曲试验来评估。所得断裂韧性值与同类研究结果吻合较好。关键词:力学性能,SDAS,冲击试验,断裂韧性,A356-T6合金
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引用次数: 0
The Austempering Transformation Behavior of Fe-0.7wt.%C-2.3wt.%Si-0.3wt.%Mn Steel Fe-0.7wt.%C-2.3wt.%Si-0.3wt的等温回火相变行为。% Mn钢
Pub Date : 2014-02-28 DOI: 10.7777/JKFS.2014.34.1.001
Sang-Yun Shin, Do-Hoon Lee, Seo-Eun Kim, B. Ye
The austempering transformation behavior in Fe-0.7wt.%C-2.3wt.%Si-0.3wt.%Mn steel is investigated. Each specimen was aus-tenitized for 60 min at 900 o C, and austempered at 380 o C for different time periods varying from 2 min to 256 min. After the austempering heat treatment, the Stage I and II evolutions are performed using optical metallography, X-ray diffraction and image analyses. Variations in the X-ray diffraction patterns and lattice parameters of the ferrite and austenite demonstrate that the residual austenite decomposes into ferrite and carbide during the Stage II evolution; moreover the amount of ferrite increases during the Stage I evolution. While the amount of austenite increases during Stage I, it dicreases during Stage II. Overall, the variations in the volume fractions of the microstructure and carbide formation in stages I and II meet high temperature austempering reaction of the ausferrite microstructure.
在Fe-0.7wt.%C-2.3wt.%Si-0.3wt中等温回火相变行为。对%Mn钢进行了研究。每个试样在900℃下进行60分钟的高温热处理,然后在380℃下进行2分钟至256分钟不等的等温热处理。等温热处理后,使用光学金相、x射线衍射和图像分析进行I阶段和II阶段的演变。铁素体和奥氏体的x射线衍射图和晶格参数的变化表明,残余奥氏体在第二阶段演化过程中分解为铁素体和碳化物;铁素体的数量在第I阶段逐渐增加。第一阶段奥氏体数量增加,第二阶段奥氏体数量减少。总体而言,第一阶段和第二阶段组织体积分数和碳化物形成的变化符合奥氏体组织的高温等温回火反应。
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引用次数: 1
The Quantitative Evaluation for Impurities of Magnesium Diecasting Alloys 镁压铸合金杂质的定量评价
Pub Date : 2014-02-28 DOI: 10.7777/JKFS.2014.34.1.014
Hyun Sik Kim, D. Ye, M. Kang, K. Sohn, Hae-Yong Jeong
Magnesium and its alloys are being applied to various kinds of industrial fields, especially their use on automotive parts and electronic part. These parts are manufactured mainly through diecasting process and magnesium ingots are used as raw materials. In the case that ingot quality is not secured, massive casting defects can occur and some manufactures can be damaged by the defects. This study is to evaluate ingots` cleanliness of magnesium alloys. It includes composition analysis by spectrometer, measurement of inclusion contents by SEM, brightness test on fractured surface and etc. Especially, the brightness test is a very easy and quick evaluation method. The brightness becomes low when the amount of oxides or inclusions on the surface increases. The brightness test data have been compared with those obtained from other methods for measuring the mount of impurities, which showed good relationship between the brightness and the others. Thus, the brightness test could be a promising method to measure the cleanliness of magnesium alloys.
镁及其合金正被应用于各种工业领域,特别是在汽车零件和电子零件上的应用。这些部件主要采用压铸工艺制造,以镁锭为原料。在铸锭质量得不到保证的情况下,可能会出现大量的铸造缺陷,一些制造商可能会受到这些缺陷的损害。本研究是对镁合金铸锭清洁度的评价。包括成分分析、扫描电镜测定夹杂物含量、断口亮度测试等。其中,亮度测试是一种简便快捷的评价方法。随着表面氧化物或夹杂物含量的增加,光亮度变低。将亮度测试数据与其它方法测得的杂质含量数据进行了比较,结果表明亮度与其它方法之间存在良好的关系。因此,亮度测试是一种很有前途的测量镁合金洁净度的方法。
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引用次数: 0
Effect of Fe, Mn Content on the Castability in Al-9wt%Si-Mg System Alloys for High Elongation Fe、Mn含量对Al-9wt%Si-Mg系高延伸合金浇注性能的影响
Pub Date : 2013-12-31 DOI: 10.7777/JKFS.2013.33.6.233
Heon-Joo Kim, C. Jeong
Effect of Fe and Mn contents on the castability of Al-9wt%Si-xMg-yFe-zMn alloy has been studied. The alloy was composed of α-Al phase, Al+eutectic Si phase, β-Al5FeSi compound and chinese script α-Al15(Mn,Fe)3Si2 compound. β-Al5FeSi and αAl15(Mn,Fe)3Si2 compounds assumed to effect the fluidity and shrinkage behaviors of the alloy during solidification due to the crystallization of α-Al15(Fe,Mn)3Si2 and β-Al5FeSi compounds above eutectic temperature. As Fe and Mn contents of Al-9wt%Si0.3wt%Mg system alloy increased from 0.15wt% to 0.6wt% and from 0.3wt% to 0.7wt%, fluidity of the alloy decreased by 5.7% and 3.3%, respectively. And as Mg content of Al-9wt%Si-0.45wt%Fe-0.5wt%Mn system alloy increased from 0.3wt% to 0.4wt%, fluidity of the alloy decreased by 8.6%. When Fe content of the alloy increased from 0.15wt% to 0.6wt%, macro shrinkage ratio decreased from 6.1% to 4.1%, and micro shrinkage ratio increased from 0.04% to 0.24%. Similarly, Mn content of the alloy increased from 0.3wt% to 0.7wt%, macro shrinkage ratio decreased from 6.0% to 4.5% and micro shrinkage ratio increased from 0.12% to 0.18%. Judging from the castability of the alloy, Al-9wt%Si-0.3wt%Mg alloy with low content of Fe and Mn, 0.1wt% Fe and 0.3wt% Mn, is recommendable.
研究了Fe和Mn含量对Al-9wt%Si-xMg-yFe-zMn合金浇注性能的影响。该合金由α-Al相、Al+共晶Si相、β-Al5FeSi化合物和汉字α-Al15(Mn,Fe)3Si2化合物组成。β-Al5FeSi和αAl15(Mn,Fe)3Si2化合物影响合金凝固过程中的流动性和收缩行为,这是由于α-Al15(Fe,Mn)3Si2化合物和β-Al5FeSi化合物在共晶温度以上结晶所致。Al-9wt%Si0.3wt%Mg系合金的Fe、Mn含量从0.15wt%增加到0.6wt%,从0.3wt%增加到0.7wt%,合金的流动性分别下降5.7%和3.3%。Al-9wt%Si-0.45wt%Fe-0.5wt%Mn系合金的Mg含量从0.3wt%增加到0.4wt%,合金的流动性下降8.6%。当合金中Fe含量从0.15wt%增加到0.6wt%时,宏观收缩率从6.1%降低到4.1%,微观收缩率从0.04%提高到0.24%。合金的Mn含量由0.3wt%提高到0.7wt%,宏观收缩率由6.0%降低到4.5%,微观收缩率由0.12%提高到0.18%。从合金的浇注性来看,推荐使用Fe、Mn含量较低的Al-9wt%Si-0.3wt%Mg合金,Fe含量为0.1wt%, Mn含量为0.3wt%。
{"title":"Effect of Fe, Mn Content on the Castability in Al-9wt%Si-Mg System Alloys for High Elongation","authors":"Heon-Joo Kim, C. Jeong","doi":"10.7777/JKFS.2013.33.6.233","DOIUrl":"https://doi.org/10.7777/JKFS.2013.33.6.233","url":null,"abstract":"Effect of Fe and Mn contents on the castability of Al-9wt%Si-xMg-yFe-zMn alloy has been studied. The alloy was composed of α-Al phase, Al+eutectic Si phase, β-Al5FeSi compound and chinese script α-Al15(Mn,Fe)3Si2 compound. β-Al5FeSi and αAl15(Mn,Fe)3Si2 compounds assumed to effect the fluidity and shrinkage behaviors of the alloy during solidification due to the crystallization of α-Al15(Fe,Mn)3Si2 and β-Al5FeSi compounds above eutectic temperature. As Fe and Mn contents of Al-9wt%Si0.3wt%Mg system alloy increased from 0.15wt% to 0.6wt% and from 0.3wt% to 0.7wt%, fluidity of the alloy decreased by 5.7% and 3.3%, respectively. And as Mg content of Al-9wt%Si-0.45wt%Fe-0.5wt%Mn system alloy increased from 0.3wt% to 0.4wt%, fluidity of the alloy decreased by 8.6%. When Fe content of the alloy increased from 0.15wt% to 0.6wt%, macro shrinkage ratio decreased from 6.1% to 4.1%, and micro shrinkage ratio increased from 0.04% to 0.24%. Similarly, Mn content of the alloy increased from 0.3wt% to 0.7wt%, macro shrinkage ratio decreased from 6.0% to 4.5% and micro shrinkage ratio increased from 0.12% to 0.18%. Judging from the castability of the alloy, Al-9wt%Si-0.3wt%Mg alloy with low content of Fe and Mn, 0.1wt% Fe and 0.3wt% Mn, is recommendable.","PeriodicalId":16318,"journal":{"name":"Journal of Korea Foundry Society","volume":"1 1","pages":"233-241"},"PeriodicalIF":0.0,"publicationDate":"2013-12-31","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"81237419","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Properties and Casting Capabilities of Al-Fe-Zn-Cu Alloys for High Conductivity Parts 高导电性零件用Al-Fe-Zn-Cu合金的性能及铸造性能
Pub Date : 2013-12-31 DOI: 10.7777/JKFS.2013.33.6.242
H. Yun, Jeong-Min Kim, Joonsik Park, K. Kim, Se-Hyun Ko
The most widely utilized commercial, aluminum-casting alloys are based on an aluminum-silicon system due to its excellent casting, and good mechanical, properties. Unfortunately, these Al-Si based alloys are inherently poor energy conductors; compared to pure aluminum, because of their high silicon content. This means that they are not suitable for applications demanding high eletrical or thermal conductivity. Therefore, efforts are currently being made to develop new, highly-conductive aluminum-casting alloys containing no silicon. In this research, a number of properties; including potential for castability, were investigated for a number of Al-Fe-Zn-Cu alloys with varying Cu content. As the copper content was increased, the tensile strength of Al-Fe-Zn-Cu alloy tended to increase gradually, while the electrical conductivity was slightly reduced. Fluidity was found to be lower in high-Cu alloys, and susceptibility to hot-cracking was generally high in all the alloys investigated.
铝-硅合金由于其优异的铸造性能和良好的机械性能,是应用最广泛的商用铝-硅合金。不幸的是,这些铝硅基合金本质上是较差的能量导体;与纯铝相比,由于其硅含量高。这意味着它们不适合要求高导电性或导热性的应用。因此,目前正在努力开发新的、高导电性的不含硅铝铸造合金。在本研究中,一些性质;研究了不同Cu含量的Al-Fe-Zn-Cu合金的铸造性能。随着铜含量的增加,Al-Fe-Zn-Cu合金的抗拉强度有逐渐提高的趋势,而电导率略有下降。高铜合金的流动性较低,所有合金的热裂敏感性普遍较高。
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引用次数: 1
期刊
Journal of Korea Foundry Society
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