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Effect of Primarily Solidified Structure on the Microstructure and the Mechanical Properties of High Cr White Iron 初凝固组织对高铬白口铁组织和力学性能的影响
Pub Date : 2015-12-31 DOI: 10.7777/JKFS.2015.35.6.178
Hyun-Wook Jo, J. Do, W. Jo, H. Chung, Je-hyun Lee, C. Jo
Due to excellent abrasion resistance the high-chrome white irons are widely used in mining and mineral industries. Minor variation of carbon content in 28% chrome white iron resulted in difference in primarily solidified microstructure. Sub-eutectic (hypoeutectic) composition led to formation of primarily solidified dendrites. Formation of primarily solidified dendrites which were supersaturated with carbon and chrome also caused precipitation of fine secondary carbides that are different from relatively large plate type carbides in the eutectic structure. Small portion of primarily solidified dendrite expected to contribute significantly to the improvement of abrasion resistance of the white iron because the dendrites provided mechanical support to carbides. The relative fraction of primary dendrite increased with reduction of carbon content from the eutectic composition. The increased fraction of primary dendrite increased hardness value of the white irons.
高铬白口铁具有优异的耐磨性,在矿山和矿产工业中得到了广泛的应用。28%铬白口铁中碳含量的微小变化导致初生凝固组织的差异。亚共晶(亚共晶)成分导致了初级凝固枝晶的形成。碳和铬过饱和的初生凝固枝晶的形成也导致细小的次生碳化物的析出,这些次生碳化物不同于共晶结构中较大的板型碳化物。一小部分初固化枝晶对提高白口铁的耐磨性有重要作用,因为这些枝晶为碳化物提供了机械支撑。随着共晶组分中碳含量的降低,初生枝晶的相对含量增加。初生枝晶含量的增加使白口铁的硬度值增加。
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引用次数: 0
Effect of Sc, Sr Elements on Eutectic Mg 2 Si Modification and Castability of Al-4wt%Mg-0.9wt%Si-0.3wt%Mn-0.15wt%Fe Casting Alloy Sc、Sr元素对Al-4wt%Mg-0.9wt%Si-0.3wt%Mn-0.15wt%Fe铸造合金共晶mg2si变质及铸造性能的影响
Pub Date : 2015-12-31 DOI: 10.7777/JKFS.2015.35.6.147
Heon-Joo Kim
The effects of Sc and Sr elements on the modification of the eutectic phase and the castability were investigated in the Al-4wt%Mg-0.9wt%Si-0.3wt%Mn-0.15wt%Fe alloy. Measurements of the cooling curve and microstructure observations were performed to analyze the additional effects of Sc and Sr minor elements during the solidification process. A prominent effect found on the modification of the eutectic phase with additions of the Sr and Sc elements. Here, a fine eutectic phase and a decrease in the growth temperature of the eutectic phase were evident with an addition of Sc element up to 0.2 wt%. The growth temperature of the eutectic phase decreased and the effect on the modification of the eutectic phase increased with the addition of Sr element up to 0.02 wt%. The addition of 0.02wt%Sr had the strongest effect on the modification of the eutectic phase, and the resulting microstructure of the eutectic phase was found to have a fibrous morphology with a decreased aspect ratio and an increased modification ratio. Fluidity and shrinkage tests were conducted to evaluate the castability of the alloy. The addition of 0.02wt%Sr effectively increased the fluidity of the alloy, while an addition of Sc did not show any effect compared to when nothing was added. The maximum filling length was recorded for 0.01wt%TiB-0.02wt%Sr owing to the effect of the fine -Al grains. The macro-shrinkage ratio decreased, while the micro-shrinkage ratio increased with the addition of various eutectic modifiers. The highest ratio of micro-shrinkage was recorded for the 0.02wt%Sr condition. However, the total shrinkage ratio was nearly identical regardless of the amounts added in this study.
研究了Sc和Sr元素对Al-4wt%Mg-0.9wt%Si-0.3wt%Mn-0.15wt%Fe合金共晶相变质和浇注性能的影响。通过对冷却曲线的测量和微观组织的观察,分析了Sc和Sr微量元素在凝固过程中的附加作用。Sr和Sc元素的加入对共晶相的改性有显著的影响。当Sc元素添加量达到0.2 wt%时,共晶相细化,共晶相生长温度明显降低。当Sr元素的添加量达到0.02 wt%时,共晶相的生长温度降低,对共晶相的改性作用增强。添加0.02wt%Sr对共晶相的改性效果最强,共晶相的微观结构呈纤维状,长径比减小,改性比增大。通过流动性和收缩率试验来评价合金的浇注性。添加0.02wt%的Sr有效地提高了合金的流动性,而添加Sc与不添加Sc相比没有任何效果。由于细al晶粒的影响,在0.01wt%TiB-0.02wt%Sr中最大填充长度。随着共晶改性剂的加入,宏观收缩率降低,微观收缩率提高。Sr为0.02wt%时,微收缩率最高。然而,无论在本研究中添加多少,总收缩率几乎是相同的。
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引用次数: 0
Effect of Ti, B, Zr Elements on Grain Refinement and Castability of Al-4wt%Mg-0.9wt%Si-0.3wt%Mn-0.15wt%Fe Casting Alloy Ti、B、Zr元素对Al-4wt%Mg-0.9wt%Si-0.3wt%Mn-0.15wt%Fe铸造合金晶粒细化和浇注性能的影响
Pub Date : 2015-10-31 DOI: 10.7777/JKFS.2015.35.5.120
Heon-Joo Kim, Su-Min Park
The effects of Ti, B and Zr on grain refinement and castability were investigated in Al-4wt%Mg-0.9wt%Si-0.3wt%Mn-0.15wt%Fe alloy. Measurement of cooling curve and micro-structure observation were performed to analyze the effects of the addition of minor elements Ti, B and Zr during solidification. The prominence of effect on grain refinement was in increasing order for Ti, Zr and B element. Fine grain size and an increase of the crystallization temperature for -Al solution were evident as the amount of addition elements increased in this study. Addition of 0.15wt% Ti was most effective for grain refinement, and the resulting grain size of -Al solution for shell mold and steel mold were and , respectively. Fluidity and shrinkage tests were perform to evaluate the castability of the alloy. Maximum fluidity length and minimum ratio of micro shrinkage were recorded for 0.15wt% Ti addition due to the effect of the finest grain size.
研究了Ti、B和Zr对Al-4wt%Mg-0.9wt%Si-0.3wt%Mn-0.15wt%Fe合金晶粒细化和浇注性能的影响。通过冷却曲线测量和显微组织观察,分析了微量元素Ti、B和Zr在凝固过程中的作用。对晶粒细化影响最大的是Ti、Zr和B元素。在本研究中,随着元素添加量的增加,-Al溶液的晶粒尺寸变小,结晶温度升高。添加0.15wt% Ti对晶粒细化最有效,壳型和钢型-Al溶液的晶粒尺寸分别为和。通过流动性和收缩率试验来评价合金的浇注性。当Ti添加量为0.15wt%时,由于晶粒尺寸的影响,记录了最大流动长度和最小微收缩率。
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引用次数: 1
The Effect of Refractory Crucible on Microstructure of Duplex Stainless Steel Cast with Gadolinium during Air Induction Melting 耐火坩埚对含钆双相不锈钢空气感应熔炼组织的影响
Pub Date : 2015-10-31 DOI: 10.7777/JKFS.2015.35.5.114
Ji-Ho Ahn, Jae-Han Lim, B. Moon
This paper reports the effect of a refractory crucible type on the microstructure of duplex stainless steel (DSS) cast with the addition of gadolinium using air-induction melting. Grade 4A DSSs with 1 wt% of gadolinium (Gd) were fabricated in various crucibles including alumina (), magnesia (MgO), calcia (CaO) coated with yttria () and graphite. The standard free energies of the formation of calcium and yttrium oxide were lower than those of gadolinium oxide and other crucible elements based oxide. The yield of Gd in DSS using , MgO, CaO-coated and graphite was 5, 19, 83 and 96%, respectively. As Gd yield increased, the amount of Gd-based inclusions increased, the size of the inclusions were reduced, and the inclusions became evenly distributed.
本文报道了一种耐火坩埚类型对加钆双相不锈钢(DSS)空气感应熔炼组织的影响。采用氧化铝()、氧化镁(MgO)、包覆钇()和石墨的钙(CaO)等坩埚制备了钆(Gd)含量为1wt %的4A级DSSs。氧化钙和氧化钇的标准自由能低于氧化钆和其他基于坩埚元素的氧化物的标准自由能。DSS中Gd的产率分别为5%、19%、83%和96%。随着Gd产率的增加,Gd基夹杂物数量增加,夹杂物尺寸减小,夹杂物分布均匀。
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引用次数: 0
Effect of Austenitizing Ratio on the Delta Ferrite Volume Fraction and Corrosion Resistance of Shell Mold Cast SSC13 Elbow Fitting 奥氏体化率对壳型铸造SSC13弯头件δ铁素体体积分数及耐蚀性的影响
Pub Date : 2015-10-31 DOI: 10.7777/JKFS.2015.35.5.109
Kuk-Jin Kim, Su-gun Lim, H. Ju, S. Pak
In this study, the measurement of FN (ferrite volume fraction) and the solution annealing ratio at a temperature of were determined with 15A elbow fittings of shell cast SSC13, and the corrosion resistance with and without austenitizing solution annealing were investigated in comparison with AISI304. The delta ferrite phase was observed in the material due to the slow cooling effect of the shell mold casting. However, the delta ferrite phase decreased gradually with the solution annealing at a temperature of . The hardness generally decreased with a heat treatment; however, its corrosion resistance was improved with the heat treatment. In addition, when a passivation treatment was applied, its corrosion ratio showed the lowest value. The pattern of general corrosion decreased due to the decrease in the delta ferrite phase with the solution annealing treatment. Consequently, it is suggested that the corrosion resistance of SSC13 elbow fittings can be improved by increasing the ratio of any solution annealing treatment used and by decreasing the ferrite phase. The relationship between the ratio of solution annealing and delta ferrite is expressed as follows: SA (solution annealing ratio,%) = 98 - FN (ferrite volume fraction, %).
本研究以15A壳铸型SSC13弯头管件为材料,测定了FN(铁素体体积分数)和温度下的溶液退火比,并与AISI304进行了奥氏体化溶液退火和未奥氏体化溶液退火的耐蚀性比较。由于壳型铸造冷却缓慢,材料中出现了δ铁素体相。而随着温度的升高,δ铁素体相逐渐减少。热处理后硬度一般降低;但经热处理后,其耐腐蚀性能有所提高。钝化处理后,其腐蚀比最小。固溶退火导致δ铁素体相的减少,从而降低了总体腐蚀模式。因此,建议通过增加固溶退火处理的比例和减少铁素体相来提高SSC13弯头接头的耐腐蚀性。溶液退火比与δ铁素体的关系表示为:SA(溶液退火比,%)= 98 - FN(铁素体体积分数,%)。
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引用次数: 1
The Effect of Oxygen Content on the Glass Forming Ability and Mechanical Properties of the Zr-based Amorphous Alloy Return Scrap 氧含量对zr基非晶合金回料玻璃化成形能力和力学性能的影响
Pub Date : 2015-08-31 DOI: 10.7777/JKFS.2015.35.4.075
Sung-Gyoo Kim, Byung-chul Lee, Heung-Il Park
Commercial Zr-based amorphous alloy was recycled and oxygen was introduced during the recycling process. The oxygen content can have a great effect on the glass forming ability and the mechanical properties of the alloy. Therefore, it was closely examined. The initial oxygen content in the raw material was 1,244 ppm. It was increased to 3,789 ppm in the alloy after ten recycling processes. As the recycling processes were repeated, the oxygen content increased. Specifically, after four recycling processes, it increased sharply as compared to that after three recycling processes. After ten recycling processes, the glass transition temperature (Tg) increased from 613 K to 634 K and the crystallization temperature (Tx) increased from 696 K to 706 K. On the other hand, the super-cooled liquid region () decreased slightly from 83 K to 72 K while the reduced glass transition temperature (Trg = Tg/Tm) was 0.63, remaining constant even when the oxygen content was increased. These results indicated that the increased oxygen content deteriorated the glass forming ability. The bending strength as determined in a three-point bending test showed a sharp decrease from 3,055 to 2,062 MPa as the oxygen content was increased from 1,244 ppm to 3,789 ppm; the extension was also decreased from 3.02 to 1.74 mm. These findings meant that the alloy became brittle.
对工业zr基非晶合金进行了回收,在回收过程中引入了氧气。氧含量对合金的玻璃化成形能力和力学性能有很大的影响。因此,它被仔细检查。原料中初始氧含量为1244 ppm。经过10次循环处理后,合金中的含量提高到3789 ppm。随着循环过程的重复,氧含量增加。具体来说,经过四次回收处理后,与经过三次回收处理后相比,它急剧增加。经过10次循环后,玻璃化转变温度(Tg)由613 K提高到634 K,结晶温度(Tx)由696 K提高到706 K。另一方面,过冷液区()从83 K略微下降到72 K,而降低的玻璃化转变温度(Trg = Tg/Tm)为0.63,即使氧含量增加也保持不变。这些结果表明,氧含量的增加使玻璃形成能力恶化。在三点弯曲试验中,当氧含量从1,244 ppm增加到3,789 ppm时,弯曲强度从3,055急剧下降到2,062 MPa;伸长也从3.02 mm减小到1.74 mm。这些发现意味着合金变脆了。
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引用次数: 0
Effect of Quenching and Tempering Temperatures on Mechanical Properties of A487 Cast with Different C Contents 调质温度对不同含碳量A487铸件力学性能的影响
Pub Date : 2015-08-31 DOI: 10.7777/JKFS.2015.35.4.088
W. Jung, Daeho Jeong, Youngchai Lee, Jae‐Hyun Lee, Sangshik Kim
The effects of quenching and tempering temperatures on the tensile, impact and corrosion properties of A487 alloy cast with different C contents of 0.16, 0.19 to 0.23 wt.% were examined. The impact tests were conducted at and and the immersion test was performed using 3.5% NaCl solution for 14 days. The quenching temperature affected the mechanical properties of A487 alloy cast, while the magnitude of change varied depending on the C content. The increase in tempering temperature showed the typical trend of decreasing tensile strength and increasing impact properties. The change in quenching and tempering temperature in this study did not affect the corrosion properties of A487 alloy significantly. The change in mechanical and corrosion properties of A487 with different C contents was discussed based on the microstructural and fractographic observation.
研究了不同C含量(0.16、0.19 ~ 0.23 wt.%)的A487合金铸件淬火和回火温度对拉伸、冲击和腐蚀性能的影响。冲击试验在和处进行,浸泡试验在3.5% NaCl溶液中进行,浸泡时间为14天。淬火温度对A487合金铸件的力学性能有影响,其影响程度随C含量的不同而不同。回火温度的升高表现出典型的抗拉强度降低、冲击性能提高的趋势。本研究中淬火回火温度的变化对A487合金的腐蚀性能没有明显影响。通过显微组织和断口观察,探讨了不同碳含量A487合金的力学性能和腐蚀性能的变化。
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引用次数: 0
Effect of Casting Thickness and Plunger Velocity on Porosity in Al Plate Diecasting 铸件厚度和柱塞速度对铝板压铸孔隙率的影响
Pub Date : 2015-08-31 DOI: 10.7777/JKFS.2015.35.4.080
Hongling Kang, Jin-young Park, Eok-Soo Kim, Kyung-Mox Cho, I. Park
The Al die casting process has been widely used in the manufacturing of automotive parts when the process requires near-net shape casting and a high productive rate. However, porosity arises in the casting process, and this hampers the wider use of this method for the creation of high-durability automotive components. The porosity can be controlled by the shot condition, but, it is critical to set the shot condition in the sleeve, and it remains difficult to optimize the shot condition to avoid air entrapment efficiently. In this study, the 4.5 mm, 2.0 mm plate die castings were fabricated under various shot conditions, such as plunger velocities of 0.7 m/s ~ 3.0 m/s and fast shot set points of the cavity of -25%, 0%, 25%, and 50%. The mold filling behavior of Al melts in the cavity was analyzed by a numerical method. Also, according to the shot conditions, the results of numerical analyses were compared to those of die-casting experiments. The porosity levels of the plate castings were analyzed by X-ray CT images and by density and microstructural analyses. The effects of the porosity on the mechanical properties were analyzed by tensile tests and hardness tests. The simulation results are in good general agreements with the die-casting experimental results. When plunger velocity and fast shot set point are 1.0 m/s and cavity 25% position, castings had optimum condition for good mechanical properties and a low level of porosity.
铝压铸工艺在汽车零件的制造中得到了广泛的应用,该工艺要求近净形铸造和高生产率。然而,在铸造过程中会出现气孔,这阻碍了这种方法在高耐久性汽车部件制造中的广泛应用。孔隙度可以通过抛丸条件来控制,但抛丸条件的设置至关重要,而如何优化抛丸条件以有效地避免夹气仍然是一个难题。在柱塞速度为0.7 m/s ~ 3.0 m/s,型腔快冲设定值为-25%、0%、25%和50%的条件下,制备了4.5 mm、2.0 mm板压铸件。用数值方法分析了铝熔体在型腔内的充型行为。根据铸态条件,将数值分析结果与压铸试验结果进行了比较。通过x射线CT图像、密度和显微组织分析分析了板状铸件的孔隙度。通过拉伸试验和硬度试验,分析了孔隙率对力学性能的影响。模拟结果与压铸试验结果基本吻合。当柱塞速度为1.0 m/s,快射设定点为1.0 m/s,型腔位置为25%时,铸件具有良好的力学性能和较低的孔隙率。
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引用次数: 0
Effect of Cu Addition on Thermal Properties of Mg-6Zn-xCu alloys Cu添加量对Mg-6Zn-xCu合金热性能的影响
Pub Date : 2015-08-31 DOI: 10.7777/JKFS.2015.35.4.067
D. Ye, Hyun Sik Kim, M. Kang, Hae-Yong Jeong
In this study, Mg-Zn alloys are investigated in terms of their thermal properties after an addition of Cu. Al element is added to improve the mechanical properties and castability in general case. However, it was excluded here because it significantly decreases the thermal conductivity. On the other hand, Zn was added as a major element, which had less influence on reducing the conductivity and can complement the mechanical properties as well. Cu was also added, and it improved the heat transfer characteristics as the amount was increased. The composition ranges of Zn and Cu are 6 wt.% and 0~1.5 wt.%, respectively. Mg-6Zn-xCu alloy was prepared by a gravity casting method using a steel mold and then the thermal conductivity and the microstructure of the as-cast material were investigated. By measuring the density_(), specific heat_(Cp) and thermal diffusivity_(), the thermal conductivity_() was calculated by the equation . As the amount of Cu increased in the Mg-6Zn-xCu alloy, the heat transfer characteristics were improved, resulting in a synergistic effect which is slow when the added Cu exceeds 1 wt.%. In order to investigate the relative thermal conductivity/emission of the Mg-6Zn-xCu alloy, AZ91 and AZ31 were experimentally evaluated and compared using a separate test equipment. As a result, the Mg-6Zn-1.5Cu alloy when compared to AZ91 showed improvements in the thermal conductivity ranging from 30 to 60% with a nearly 20% improvement in the thermal emission.
在本研究中,研究了添加Cu后Mg-Zn合金的热性能。一般情况下,加入铝元素可以改善铸件的力学性能和浇注性能。然而,这里排除了它,因为它显著降低了导热系数。另一方面,添加Zn作为主要元素,对降低电导率的影响较小,并且可以补充力学性能。同时加入Cu,随着Cu用量的增加,Cu的传热特性得到改善。锌和铜的组成范围分别为6 wt.%和0~1.5 wt.%。采用重力铸造法制备了Mg-6Zn-xCu合金,并对铸态材料的导热性能和显微组织进行了研究。通过测量密度_()、比热_(Cp)和热扩散_(),由方程计算出导热系数_()。随着Cu添加量的增加,Mg-6Zn-xCu合金的传热特性得到改善,但当Cu添加量超过1 wt.%时,增效作用缓慢。为了研究Mg-6Zn-xCu合金的相对热导率/发射率,使用单独的测试设备对AZ91和AZ31进行了实验评估和比较。结果表明,与AZ91相比,Mg-6Zn-1.5Cu合金的导热系数提高了30% ~ 60%,热发射性能提高了近20%。
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引用次数: 1
Effect of Zn Addition on Corrosion Behavior of Mg-8%Al Casting Alloy 添加Zn对Mg-8%Al铸造合金腐蚀行为的影响
Pub Date : 2015-06-30 DOI: 10.7777/JKFS.2015.35.3.053
In-Je Hwang, Jung-Hyun Moon, J. Jun, Young-Jig Kim
Effects of Zn addition on the microstructure and corrosion behavior of Mg-8%Al-(0-1)%Zn casting alloys were investigated. With increasing Zn content, the amount of β(Mg17Al12) phase increased, while α-(Mg) dendritic cell size became reduced. The corrosion rate decreased continuously with the increase in the Zn content. The evaluation of the microstructural evolution indicates that the improved barrier effect of β particles formed more continuously along the dendritic cell boundaries and the incorporation of more ZnO into the surface corrosion product, by which the absorption of Cl− ions is impeded, are responsible for the better corrosion resistance in relation to the Zn addition.
研究了添加Zn对Mg-8%Al-(0-1)%Zn铸造合金组织和腐蚀行为的影响。随着Zn含量的增加,β(Mg17Al12)相数量增加,α-(Mg)树突状细胞尺寸减小。随着Zn含量的增加,腐蚀速率不断降低。显微组织演化分析表明,β粒子沿树突细胞边界连续形成的屏障效应增强,表面腐蚀产物中加入更多的ZnO,从而阻碍了Cl−离子的吸收,这是锌对腐蚀产物具有较好的耐蚀性的原因。
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引用次数: 1
期刊
Journal of Korea Foundry Society
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