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A geospatial analysis of coal mine overburden reclamation: Land use, carbon stock, biomass, and soil genesis in chronosequence plantations 煤矿覆土复垦的地理空间分析:时序种植园的土地利用、碳储量、生物量和土壤成因
IF 3.4 2区 地球科学 Q1 GEOCHEMISTRY & GEOPHYSICS Pub Date : 2025-01-11 DOI: 10.1016/j.gexplo.2025.107674
Tarun Kumar Thakur , Digvesh Kumar Patel , Sandhya Saini , Anita Thakur , Singam Laxmana Swamy , Sanjeev Bakshi , Amit Kumar , Fohad Mabood Husain , Rupesh Kumar
Coal remains a pivotal energy source, meeting 27 % of global energy demand and 70 % of India's energy requirements. However, coal mining significantly disrupts land use, necessitating effective reclamation strategies. This study examines the repercussions of coal mining on land use disruption and assesses the benefits of revegetation on structural attributes, biomass, carbon sequestration, and soil restoration in central India. Utilizing Landsat 9 satellite imagery, we characterized land use and vegetation dynamics, employing the Normalized Difference Vegetation Index (NDVI) to classify five distinct age sequence classes with median ages of 5, 10, 20, 30, and 40 years. Results indicated a decrease in tree density from 1408 to 588 trees per hectare as plantations aged from 5 to 40 years, while the basal area increased from 5.88 to 28.25 m2 per hectare. Notably, values in 40-year-old stands approached those of natural forests. Key novelties include the identification of a strong correlation between spectral vegetation indices (SVIs) and soil quality indicators, providing a remote-sensing-based framework for monitoring ecological restoration. Both total standing biomass and carbon stock exhibited significant (p ≤ 0.05) increases with plantation age, ranging from 10.25 to 66.41 Mg ha−1 and 5.16 to 32.74 Mg ha−1, respectively. Soil carbon content decreased with depth, with values ranging from 7.68 to 18.98 Mg ha−1 at 0–20 cm depth, and soil nitrogen values spanning 82.66 to 216.08 kg ha−1. These findings underscore the necessity of site-specific management strategies that integrate technological, ecological, and economic considerations to advance ecological restoration and align with the Sustainable Development Goals by 2030.
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引用次数: 0
Distribution dynamics and health risks of polyaromatic hydrocarbons and heavy metals in the anthropogenically impacted Omi-Asoro Stream, Nigeria
IF 3.4 2区 地球科学 Q1 GEOCHEMISTRY & GEOPHYSICS Pub Date : 2025-01-11 DOI: 10.1016/j.gexplo.2025.107675
Adebanjo Jacob Anifowose , Gideon Temitope Arowosaye , Oluwaseyi Esther Adaramodu , Esther Oluwaponmile Akintola , Jesufunmilayo Abosede Otunniya , Adedoyin Demilade Makinde , Tesleem Olalekan Kolawole , Shola Hezekiah Awojide
The study carried out concerted analytical measurements of twenty polyaromatic hydrocarbons (PAHs) and eighteen heavy metals in the Omi-Asoro Stream, Ilesa, Nigeria to unravel their sources and the impacts of anthropogenic activities around it. Samples from the stream water were collected in March 2023. The resident PAHs were subjected to solid-phase extraction (SPE) and analyzed on a gas chromatograph-mass spectrometer. The acid-extracted heavy metals were also analyzed with an inductively coupled plasma-optical emission spectrometer (ICP-OES). Results showed that naphthalene (6.00 ± 7.79 μg/L) and fluoranthene (2.99 ± 4.24 μg/L) were the two dominant PAHs in the stream water. Similarly, Fe and Zn, with concentrations (μg/L) of 1291 ± 2361 and 53.1 ± 89.3, respectively, were the dominant heavy metals. Fe concentration constituted 84.4% of the total heavy metals in the water. Using principal component analysis (PCA), the PAH sources were traced to internal combustion engines, biomass burning, and pesticides/wood preservatives. The heavy metal sources were resolved to internal combustion of engines, metallic wear/rust, electronic devices, geogenic releases and agrochemicals. The risk assessment showed that among the detected PAHs, benzo(a)pyrene constituted a carcinogenic effect on humans. The heavy metals which posed carcinogenic effects included As, Ni, Cd and Cr. Thus, the industrial and agricultural activities, as well as emissions from the internal combustion of engines in the area released the environmental pollutants which adversely impacted the stream.
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引用次数: 0
Unsupervised detection of multivariate geochemical anomalies using a high-performance deep autoencoder Gaussian mixture model
IF 3.4 2区 地球科学 Q1 GEOCHEMISTRY & GEOPHYSICS Pub Date : 2025-01-11 DOI: 10.1016/j.gexplo.2025.107671
Xuemei Wang, Yongliang Chen
It is of great significance to construct an efficient geochemical anomaly detection model for the successful accomplishment of a mineral exploration process in a complex geological environment. However, the complex geological environment of the prospecting area often results in the high-dimensional unknown complex population distribution of geochemical exploration data. This complex distribution is difficult to fit with a theoretical probability distribution model. As a result, it becomes a challenge to carry out an effective detection of geochemical anomalies. Therefore, to develop an anomaly detection model that can effectively fit the complex population distribution of geochemical exploration data is the key for accurately detecting geochemical anomalies. For this reason, the deep autoencoder Gaussian mixture model (DAGMM) was adopted to model the geochemical exploration data obtained in the 1:200,000 geological survey conducted in the Baishan area (Jilin, China) to check its superiority in identifying multivariate geochemical anomalies. As an innovative deep learning framework for unsupervised anomaly detection, DAGMM ingeniously combines the data dimensionality reduction and compression capabilities of a deep autoencoder (DAE) with the probability density estimation advantage of the Gaussian mixture model (GMM). The DAGMM model can deeply explore the deep-level features of geochemical exploration data and effectively model the complex unknown data distribution through the synergistically work and joint optimization strategy in training the DAE and GMM model, so it can accurately identify geochemical anomalies. To show the superiority of the DAGMM model in detecting polymetallic geochemical anomalies, the DAGMM model was compared with the GMM and DAE models. The receiver operating characteristic (ROC) curves of the three models were plotted, and the areas under the ROC curves (AUCs) and lift indices were calculated. The ROC curve of the DAGMM model dominates that of the DAE model and GMM model. The DAGMM model has an AUC of 0.904 and a lift index of 10.44, respectively, which are much larger than those of the GMM model (AUC = 0.858, lift index = 3.63) and DAE model (AUC = 0.83, lift index = 5.31). Therefore, the DAGMM model significantly outperforms the other two models in detecting multivariate geochemical anomalies and the polymetallic geochemical anomalies detected by the DAGMM model contain all the known polymetallic deposits. Compared with DAE and GMM, DAGMM is more efficient and more powerful in detecting multivariate geochemical anomalies in complex geological environments.
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引用次数: 0
Modeling mineralization potential of catchment basins: Insight from geochemical fingerprint
IF 3.4 2区 地球科学 Q1 GEOCHEMISTRY & GEOPHYSICS Pub Date : 2025-01-11 DOI: 10.1016/j.gexplo.2025.107669
Haicheng Wang , Ruiwen Shen , Liuan Duan , Qiuming Cheng , Zhaoxian Yuan , Shengyuan Zhang
Stream sediments are common sampling media in cost-effective regional exploration programs. Catchment basins are the basic sampling units of steam sediments, which have distinct geochemical characteristics. In this study, the mineralization potential of catchment basin using stream sediments is evaluated from the perspective of geochemical fingerprints. Firstly, the spatial distribution of catchment basins was acquired based on digital elevation model data. The local singularity analysis was employed to reduce the impact of the overburden, revealing the weak geochemical anomalies. The catchment basins with known mineral occurrences as the prior dataset were used to train the random forest model, which improved the model accuracy and interpretability. The geochemical fingerprints of different types of mineralization were constructed based on the importance of geochemical variables in the random forest modeling, which revealed the importance of geochemical elements for different types of mineralization occurrences. All catchment basins lacking mineral occurrences were categorized based on the trained random forest model, achieving the potential types of mineralization for each catchment basin. Most of catchment basins with the same types of mineralization occurrences exhibited the spatial cluster, suggesting the migration characteristics of metal element in stream sediments through river system. Geochemical fingerprinting is a valuable tool for classifying the different types of mineralization occurrences at the scale of catchment basins. The delineated potential mineral occurrence types for catchment basins provided an indicator for future mineral exploration endeavors.
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引用次数: 0
Uptake and toxicity of heavy metals: The protective frontiers of metal binding proteins
IF 3.4 2区 地球科学 Q1 GEOCHEMISTRY & GEOPHYSICS Pub Date : 2025-01-10 DOI: 10.1016/j.gexplo.2025.107673
Ravneet Kaur, Harleen Kaur, Ashish Sharma
In environment, several contaminants and pollutants are released, the content of which is increasing alarmingly. Out of several contaminants released into environment, one such contaminant is heavy metals. Such contaminants being released into the environment then enter into plant system via soil. Plants uptake heavy metals from soil via apoplast symplast continuum. Plant require several nutrients in minute concentrations however presence of such nutrients in excess cause toxic effects on plants. Such heavy metals caused varied toxicities such as chlorosis, impaired photosynthesis, lipid peroxidation etc. in plants resulting in overall decline in plant biomass. Excess concentration of heavy metals such as copper, chromium, nickel are known to induce morphological, physiological deformities in several plant species. In response to ROS generated due to heavy metal toxicity, plants activate several defense mechanisms. In addition to this, several metal binding proteins such as metallothioneins, phytochelatins, glutathione etc. are activated. These metal binding protein act to reduce the toxic effects of heavy metals by binfing to them and sequestering then into vacuoles. The current review will highlight the uptake mechanism of heavy metals by plants, toxicity caused by some commonly occurring heavy metals in plants and role of metal binding proteins in sequestering such heavy metals.
环境中会释放出多种污染物和污物,其含量正在以惊人的速度增加。在释放到环境中的多种污染物中,重金属就是其中一种。释放到环境中的这些污染物会通过土壤进入植物系统。植物通过细胞质和细胞质的连续作用从土壤中吸收重金属。植物需要多种微量营养元素,但过量的营养元素会对植物产生毒害作用。这些重金属会对植物造成各种毒性,如萎黄病、光合作用受损、脂质过氧化等,导致植物生物量整体下降。众所周知,铜、铬、镍等重金属浓度过高会导致多种植物出现形态和生理畸形。为了应对重金属毒性产生的 ROS,植物会启动多种防御机制。除此之外,一些金属结合蛋白也会被激活,如金属硫蛋白、植物螯合蛋白、谷胱甘肽等。这些金属结合蛋白通过与重金属结合并将其封存在液泡中,从而降低重金属的毒性作用。本综述将重点介绍植物吸收重金属的机制、植物中常见的一些重金属造成的毒性以及金属结合蛋白在固存这些重金属中的作用。
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引用次数: 0
Using principal component analysis to distinguish sources of radioactivity and nitrates contamination in Southern Tunisian groundwater samples
IF 3.4 2区 地球科学 Q1 GEOCHEMISTRY & GEOPHYSICS Pub Date : 2025-01-10 DOI: 10.1016/j.gexplo.2025.107670
Tiziano Boschetti , Younes Hamed , Rihab Hadji , Maurizio Barbieri , Matteo Gentilucci , Mattia Rossi , Rayan Khalil , Shuhab D. Khan , Bassem Asghar , Abdulrasoul Al-Omran , Elimame Elaloui
The manuscript discusses using Principal Component Analysis (PCA) to distinguish the sources of radioactive and nitrate contamination in 33 groundwater samples from southern Tunisia. The study focuses on the Gafsa basin, an area known for its phosphate mining activities and significant agricultural use, both of which contribute to the contamination of groundwater resources. The radioactivity in the water is primarily attributed to phosphate mining and deep groundwater sources from the North Western Sahara Aquifer System (NWSAS). Additionally, the nitrate contamination is largely due to agricultural runoff, though secondary sources related to phosphate mining are also considered.
Through the application of PCA, the study was able to classify the groundwater samples into different groups based on their contamination sources: phosphate mining, combined agricultural and mining activities, fossil geothermal waters, and low-agricultural areas. The PCA revealed that samples most affected by anthropogenic activities exhibited high levels of radium and nitrate, with contamination patterns correlating with specific environmental and chemical factors.
This analysis underscores the complexity of groundwater contamination in the region and highlights the need for targeted mitigation strategies to address radioactive and nitrate pollution in southern Tunisia. The study provides critical insights for managing water quality in areas with similar environmental challenges.
该手稿讨论了如何利用主成分分析法(PCA)来区分突尼斯南部 33 个地下水样本中的放射性和硝酸盐污染源。研究的重点是加夫萨盆地,该地区以磷酸盐开采活动和大量农业使用而闻名,这两种活动都造成了地下水资源的污染。水中的放射性主要归因于磷酸盐开采和来自西北撒哈拉含水层系统 (NWSAS) 的深层地下水源。此外,硝酸盐污染主要是由于农业径流造成的,但也考虑到了与磷酸盐开采有关的次要来源。通过应用 PCA,该研究能够根据污染源将地下水样本分为不同的组别:磷酸盐开采、农业和采矿活动相结合、化石地热水和低农业区。该分析凸显了该地区地下水污染的复杂性,并强调有必要制定有针对性的缓解战略,以解决突尼斯南部的放射性和硝酸盐污染问题。这项研究为面临类似环境挑战的地区的水质管理提供了重要启示。
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引用次数: 0
Corrigendum to “Assessment of potentially toxic elements in some wild edible plants of district Doda, Jammu and Kashmir, India” [J. Geochem. Explor. 267, p. 107604. (Dec 2024)]
IF 3.4 2区 地球科学 Q1 GEOCHEMISTRY & GEOPHYSICS Pub Date : 2024-12-24 DOI: 10.1016/j.gexplo.2024.107668
Sania Hamid , Devendra Kumar Pandey , Deepika Singh
{"title":"Corrigendum to “Assessment of potentially toxic elements in some wild edible plants of district Doda, Jammu and Kashmir, India” [J. Geochem. Explor. 267, p. 107604. (Dec 2024)]","authors":"Sania Hamid ,&nbsp;Devendra Kumar Pandey ,&nbsp;Deepika Singh","doi":"10.1016/j.gexplo.2024.107668","DOIUrl":"10.1016/j.gexplo.2024.107668","url":null,"abstract":"","PeriodicalId":16336,"journal":{"name":"Journal of Geochemical Exploration","volume":"270 ","pages":"Article 107668"},"PeriodicalIF":3.4,"publicationDate":"2024-12-24","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143164552","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"地球科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Vectoring towards buried high-purity quartz metapegmatites using low-elevation radiometric and soil geochemical surveying: Method validation in Tysfjord, Norway
IF 3.4 2区 地球科学 Q1 GEOCHEMISTRY & GEOPHYSICS Pub Date : 2024-12-19 DOI: 10.1016/j.gexplo.2024.107667
Mario Hopfner , Marco Brönner , Lawrence Carter , Teimoor Nazari-Dehkordi , Julian Menuge , Axel Müller , Ben Williamson
Group 2/NYF pegmatites may be economically enriched in rare minerals. In this study we report testing of two exploration methods, gamma ray surveying and soil geochemical mapping, undertaken within the GREENPEG project. Palaeoproterozoic metapegmatites in the Tysfjord area, Nordland, Norway, include some which have been mined for pure quartz. Geologically, the ore zones are the quartz cores of metapegmatites whose other zones and metasomatic halos are enriched in U, Th, REE, Nb and other rare elements. The Jennyhaugen metapegmatite was the main test site because its subcrop beneath 0.1–1.0 m soil can be traced from an open pit mine, and aerial surveying is unobstructed by trees. Helicopter-borne radiometry at 60 m altitude and drone-borne radiometry at 25–35 m altitude detect the metapegmatite, while walking (1.0 or 1.6 m height) and 15 m altitude drone-borne radiometry resolve the metapegmatite and metasomatic halo subcrop in detail. Total gamma ray count measurements provide as good an exploration tool as Th or U radiation; K radiation does not show useful anomalies. Both A- and C-horizon soil geochemical mapping also reveal U, Th, Nb and other geochemical anomalies above metapegmatite and halo subcrop. A-horizon soil samples appear to more accurately locate these targets, perhaps because they effectively sample larger surface areas of subcropping rock, whose grain size is very coarse (typically metre scale) within the metapegmatite. C-horizon samples collected from the soil-rock interface are less likely to be representative of the metapegmatite. Gamma ray surveying is recommended rather than soil chemical mapping for exploration, by helicopter at district scale and by drone or walking at prospect scale. It is quicker, requires less field workers, has higher resolution and is less expensive than soil geochemical mapping. Soil chemistry may be preferred for prospect-scale exploration, however, where the commodity sought does not spatially correlate with U and/or Th concentrations.
{"title":"Vectoring towards buried high-purity quartz metapegmatites using low-elevation radiometric and soil geochemical surveying: Method validation in Tysfjord, Norway","authors":"Mario Hopfner ,&nbsp;Marco Brönner ,&nbsp;Lawrence Carter ,&nbsp;Teimoor Nazari-Dehkordi ,&nbsp;Julian Menuge ,&nbsp;Axel Müller ,&nbsp;Ben Williamson","doi":"10.1016/j.gexplo.2024.107667","DOIUrl":"10.1016/j.gexplo.2024.107667","url":null,"abstract":"<div><div>Group 2/NYF pegmatites may be economically enriched in rare minerals. In this study we report testing of two exploration methods, gamma ray surveying and soil geochemical mapping, undertaken within the GREENPEG project. Palaeoproterozoic metapegmatites in the Tysfjord area, Nordland, Norway, include some which have been mined for pure quartz. Geologically, the ore zones are the quartz cores of metapegmatites whose other zones and metasomatic halos are enriched in U, Th, REE, Nb and other rare elements. The Jennyhaugen metapegmatite was the main test site because its subcrop beneath 0.1–1.0 m soil can be traced from an open pit mine, and aerial surveying is unobstructed by trees. Helicopter-borne radiometry at 60 m altitude and drone-borne radiometry at 25–35 m altitude detect the metapegmatite, while walking (1.0 or 1.6 m height) and 15 m altitude drone-borne radiometry resolve the metapegmatite and metasomatic halo subcrop in detail. Total gamma ray count measurements provide as good an exploration tool as Th or U radiation; K radiation does not show useful anomalies. Both A- and C-horizon soil geochemical mapping also reveal U, Th, Nb and other geochemical anomalies above metapegmatite and halo subcrop. A-horizon soil samples appear to more accurately locate these targets, perhaps because they effectively sample larger surface areas of subcropping rock, whose grain size is very coarse (typically metre scale) within the metapegmatite. C-horizon samples collected from the soil-rock interface are less likely to be representative of the metapegmatite. Gamma ray surveying is recommended rather than soil chemical mapping for exploration, by helicopter at district scale and by drone or walking at prospect scale. It is quicker, requires less field workers, has higher resolution and is less expensive than soil geochemical mapping. Soil chemistry may be preferred for prospect-scale exploration, however, where the commodity sought does not spatially correlate with U and/or Th concentrations.</div></div>","PeriodicalId":16336,"journal":{"name":"Journal of Geochemical Exploration","volume":"270 ","pages":"Article 107667"},"PeriodicalIF":3.4,"publicationDate":"2024-12-19","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143164546","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"地球科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Ore-forming processes of giant carbonate-hosted ZnPb deposit and Ge enrichment mechanism in Zhugongtang, Guizhou Province, China: Constraints from trace element and isotopic compositions of sulfides
IF 3.4 2区 地球科学 Q1 GEOCHEMISTRY & GEOPHYSICS Pub Date : 2024-12-18 DOI: 10.1016/j.gexplo.2024.107666
Qing Yang , Shao-Yong Jiang , Suo-Fei Xiong , Jun-Jie Hou
The Zhugongtang ZnPb deposit, with >3.27 million tons of Zn + Pb averaging 6.76 % Zn and 2.27 % Pb, along with 592 tons of Ge, is a newly discovered giant ZnPb deposit in northwest Guizhou Province of the Sichuan-Yunnan-Guizhou metallogenic region, Southwest China. This deposit is hosted in Devonian, Carboniferous, and Permian carbonate rocks. Three stages of hydrothermal mineralization were identified: (1) the pyrite-sphalerite-quartz stage, (2) the sphalerite-galena-pyrite-calcite stage, and (3) the carbonate stage, and three generations of sphalerite (Sp-1, Sp-2, and Sp-3) were identified. In this study, analyses of in situ trace element compositions in sphalerite and SPb isotopic compositions of sulfides were conducted to determine the origin and mineralization processes of the Zhugongtang deposit. Sphalerite is characterized by enrichment of Ge (mean = 109 ppm), Cd (mean = 875 ppm), and Ga (mean = 30 ppm) and depletion of In, Sn, and Co, with increasing Ge and Cu and decreasing Mn, Ag and Pb from the early to late stages. Ge incorporates into sphalerite via a coupled substitution of 3Cu+ + Sb3+ + Ge4+ ↔ 5Zn2+. The temperature and sulfur fugacity (fS2) are estimated from the trace element concentrations in sphalerite, which indicate medium- to low-temperature and intermediate-sulfidation conditions with decreasing temperature and fS2 from Sp-1 to Sp-3. The pyrite, sphalerite, and galena have δ34S values ranging from 11.3 to 17.8 ‰, 10.2 to 17.3 ‰, and 8.4 to 14.7 ‰, respectively, indicating that the reduced sulfur likely originated from the thermochemical reduction of sulfate (TSR) with multiple sources. High-precision in situ Pb isotope ratios of 208Pb/204Pb, 207Pb/204Pb, and 206Pb/204Pb range from 39.609 to 40.230, 15.860 to 16.042, and 18.768 to 18.984, respectively, which implies that the lead was sourced primarily from the host rock and basement strata. On the basis of a comprehensive analysis of ore geology and geochemical data, the Zhugongtang deposit is classified as an MVT deposit. With the gradual decrease in temperature and fS2, sphalerite (Sp-2 and Sp-3) precipitated in large quantities with significant enrichment of Ge (mean 147 ppm).
{"title":"Ore-forming processes of giant carbonate-hosted ZnPb deposit and Ge enrichment mechanism in Zhugongtang, Guizhou Province, China: Constraints from trace element and isotopic compositions of sulfides","authors":"Qing Yang ,&nbsp;Shao-Yong Jiang ,&nbsp;Suo-Fei Xiong ,&nbsp;Jun-Jie Hou","doi":"10.1016/j.gexplo.2024.107666","DOIUrl":"10.1016/j.gexplo.2024.107666","url":null,"abstract":"<div><div>The Zhugongtang Zn<img>Pb deposit, with &gt;3.27 million tons of Zn + Pb averaging 6.76 % Zn and 2.27 % Pb, along with 592 tons of Ge, is a newly discovered giant Zn<img>Pb deposit in northwest Guizhou Province of the Sichuan-Yunnan-Guizhou metallogenic region, Southwest China. This deposit is hosted in Devonian, Carboniferous, and Permian carbonate rocks. Three stages of hydrothermal mineralization were identified: (1) the pyrite-sphalerite-quartz stage, (2) the sphalerite-galena-pyrite-calcite stage, and (3) the carbonate stage, and three generations of sphalerite (Sp-1, Sp-2, and Sp-3) were identified. In this study, analyses of in situ trace element compositions in sphalerite and S<img>Pb isotopic compositions of sulfides were conducted to determine the origin and mineralization processes of the Zhugongtang deposit. Sphalerite is characterized by enrichment of Ge (mean = 109 ppm), Cd (mean = 875 ppm), and Ga (mean = 30 ppm) and depletion of In, Sn, and Co, with increasing Ge and Cu and decreasing Mn, Ag and Pb from the early to late stages. Ge incorporates into sphalerite via a coupled substitution of 3Cu<sup>+</sup> + Sb<sup>3+</sup> + Ge<sup>4+</sup> ↔ 5Zn<sup>2+</sup>. The temperature and sulfur fugacity (<em>f</em>S<sub>2</sub>) are estimated from the trace element concentrations in sphalerite, which indicate medium- to low-temperature and intermediate-sulfidation conditions with decreasing temperature and <em>f</em>S<sub>2</sub> from Sp-1 to Sp-3. The pyrite, sphalerite, and galena have δ<sup>34</sup>S values ranging from 11.3 to 17.8 ‰, 10.2 to 17.3 ‰, and 8.4 to 14.7 ‰, respectively, indicating that the reduced sulfur likely originated from the thermochemical reduction of sulfate (TSR) with multiple sources. High-precision in situ Pb isotope ratios of <sup>208</sup>Pb/<sup>204</sup>Pb, <sup>207</sup>Pb/<sup>204</sup>Pb, and <sup>206</sup>Pb/<sup>204</sup>Pb range from 39.609 to 40.230, 15.860 to 16.042, and 18.768 to 18.984, respectively, which implies that the lead was sourced primarily from the host rock and basement strata. On the basis of a comprehensive analysis of ore geology and geochemical data, the Zhugongtang deposit is classified as an MVT deposit. With the gradual decrease in temperature and <em>f</em>S<sub>2</sub>, sphalerite (Sp-2 and Sp-3) precipitated in large quantities with significant enrichment of Ge (mean 147 ppm).</div></div>","PeriodicalId":16336,"journal":{"name":"Journal of Geochemical Exploration","volume":"270 ","pages":"Article 107666"},"PeriodicalIF":3.4,"publicationDate":"2024-12-18","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143164047","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"地球科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Global distribution and sources of uranium and fluoride in groundwater: A comprehensive review
IF 3.4 2区 地球科学 Q1 GEOCHEMISTRY & GEOPHYSICS Pub Date : 2024-12-05 DOI: 10.1016/j.gexplo.2024.107665
C.N. Sridhar , M. Thirumurugan , T. Subramani , P. Gopinathan
Contamination of elements in water due to geogenic and anthropogenic activities is common around the world. Intake of contaminated water causes severe health hazards to the living community. To avoid the health hazards, World Health Organisation (WHO) has specified certain limit of the level of elements as well as ions present in the water for drinking purpose. Some common chemical contaminates in the groundwater are Uranium (U) and Fluoride (Fˉ). The intake of groundwater which is having excess amount of Uranium (U) and Fluoride (Fˉ) may lead to serious health issues. The permissible level of Uranium in water as is 30 ppb as per WHO, but in some regions due to the rock type, mining activity, chemical waste; the level of U present in water might be higher than the prescribed limit and its consumption may cause carcinogenic and non-carcinogenic diseases. As like Uranium, Fluoride has certain limit fixed by WHO that is 1.5 ppm. If the level of Fˉ is higher than 1.5 ppm it may cause dental fluorosis and skeletal fluorosis. To reduce the health risks due to intake of the elements or ions, the contaminated groundwater needs to be monitored and treated by means of constructing artificial recharge structures and other rainwater harvesting methods. However, certain ex-situ processes like membrane method, ion exchange, adsorption, and precipitation may be adopted to reduce or remove the contaminated elements/ions in the groundwater.
{"title":"Global distribution and sources of uranium and fluoride in groundwater: A comprehensive review","authors":"C.N. Sridhar ,&nbsp;M. Thirumurugan ,&nbsp;T. Subramani ,&nbsp;P. Gopinathan","doi":"10.1016/j.gexplo.2024.107665","DOIUrl":"10.1016/j.gexplo.2024.107665","url":null,"abstract":"<div><div>Contamination of elements in water due to geogenic and anthropogenic activities is common around the world. Intake of contaminated water causes severe health hazards to the living community. To avoid the health hazards, World Health Organisation (WHO) has specified certain limit of the level of elements as well as ions present in the water for drinking purpose. Some common chemical contaminates in the groundwater are Uranium (U) and Fluoride (Fˉ). The intake of groundwater which is having excess amount of Uranium (U) and Fluoride (Fˉ) may lead to serious health issues. The permissible level of Uranium in water as is 30 ppb as per WHO, but in some regions due to the rock type, mining activity, chemical waste; the level of U present in water might be higher than the prescribed limit and its consumption may cause carcinogenic and non-carcinogenic diseases. As like Uranium, Fluoride has certain limit fixed by WHO that is 1.5 ppm. If the level of Fˉ is higher than 1.5 ppm it may cause dental fluorosis and skeletal fluorosis. To reduce the health risks due to intake of the elements or ions, the contaminated groundwater needs to be monitored and treated by means of constructing artificial recharge structures and other rainwater harvesting methods. However, certain ex-situ processes like membrane method, ion exchange, adsorption, and precipitation may be adopted to reduce or remove the contaminated elements/ions in the groundwater.</div></div>","PeriodicalId":16336,"journal":{"name":"Journal of Geochemical Exploration","volume":"270 ","pages":"Article 107665"},"PeriodicalIF":3.4,"publicationDate":"2024-12-05","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143164551","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"地球科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
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Journal of Geochemical Exploration
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