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A Comparative Study on Impact of Nickel Nitrates and Nickel Chloride on the Structural Properties of ZnFe2O4 Nanostructures 硝酸镍和氯化镍对ZnFe2O4纳米结构性能影响的比较研究
Pub Date : 2018-01-01 DOI: 10.4172/2324-8777.1000256
G. Uzma, A. Siddiqa, Q. Hayat
Ni-Zn ferrite (NixZn1-xFe2O4, for x=0, 0.1, 0.3, 0.5, 0.7) nanoparticles have been successfully synthesized using chemical coprecipitation method for two different compositions of nickel nitrides (Ni(NO3)2.6H2O) and nickel chlorides (NiCl2.6H2O) respectively. X-ray analysis explored that nanoparticles for each value of x have cubic spinal structure. No extra peaks were observed in XRD spectra indicating the absence of any un-reacted component in the samples for both the series. The d-spacing and lattice parameter were found to lay in the range of 2.54 Ao to 2.51 Ao and 8.42 Ao to 8.33 Ao for nickel chloride series and 2.56 Ao to 2.54 Ao and 8.49 Ao to 8.42 Ao for nickel nitride series respectively. Both of these decreased by increasing Ni doping due to the less ionic radius of Ni2+ ions then Zn2+ and for strong preference of Ni2+ ions for octahedral sites. The crystallite size was observed to vary between 10-13 nm and its value is maximum for x=0.3 for nickel chloride series, whereas it vary between 18-36 nm and its value is maximum for x=0.5 and x=0.7 which shows that by adding nickel chloride a better result of 10 nm is achieved at x=0.7 whereas, 18 nm is achieved at x=0.1 and it increases by increasing nickel nitride.
采用化学共沉淀法,分别在Ni(NO3)2.6H2O和NiCl2.6H2O两种不同成分的氮化镍和氯化镍下成功合成了Ni- zn铁氧体(NixZn1-xFe2O4, x=0、0.1、0.3、0.5、0.7)纳米颗粒。x射线分析发现,每个x值的纳米颗粒具有立方脊柱结构。在XRD光谱中没有观察到额外的峰,表明样品中没有任何未反应的成分。发现氯化镍系的d间距和晶格参数分别在2.54 ~ 2.51、8.42 ~ 8.33、2.56 ~ 2.54、8.49 ~ 8.42之间。由于Ni2+离子的离子半径比Zn2+小,并且Ni2+离子对八面体位有很强的偏好,所以随着Ni掺杂量的增加,这两个指标都降低了。观察到氯化镍系列的晶粒尺寸变化在10 ~ 13 nm之间,在x=0.3时晶粒尺寸最大值,而在18 ~ 36 nm之间,在x=0.5和x=0.7时晶粒尺寸最大值,说明加入氯化镍后,在x=0.7时晶粒尺寸达到10 nm较好,而在x=0.1时晶粒尺寸达到18 nm,并随着氮化镍的加入而增大。
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引用次数: 1
Mechanical and thermal properties of polyethylene modified with different natural fillers 不同天然填料改性聚乙烯的力学和热性能
Pub Date : 2018-01-01 DOI: 10.4172/2324-8777-c7-039
J. Sikora
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引用次数: 0
New green nanomaterials for applications in energy sector 新型绿色纳米材料在能源领域的应用
Pub Date : 2018-01-01 DOI: 10.4172/2324-8777-c9-044
Moneer M. Basuni
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引用次数: 0
A New Method for Analysis of Anomalous Increases in Thermal Conductivity of TiO2-Water Nanofluid 二氧化钛-水纳米流体热导率异常升高分析新方法
Pub Date : 2018-01-01 DOI: 10.4172/2324-8777.1000253
M. Allahyari, K. Abbaspour-sani, I. Kotcioglu, M. Khalaji
Thermal conductivity is an important characteristic of a nanofluid. This paper presents models for the prediction of the effective thermal conductivity of titanium oxide based on water by used of dimensionless groups. The models express the thermal conductivity of a nanofluid as a function of the thermal conductivity of interfacial shell, interfacial thickness and volume fraction. The model of effective thermal conductivity is divided into four regions by analysis of present models for the regions and can be obtained an effective value of dependence parameter. The model showed for volume fraction less than 1% and diameters less than 20 nm intensity of increase thermal conductivity is much more than other region. As we know, with decrease of concentration, the viscosity of nanofluid decreased, so this region is the best region for application of heat transfer devices because the pressure drop also decreased.
热导率是纳米流体的一个重要特性。本文提出了用无量纲基团预测水基氧化钛有效导热系数的模型。该模型将纳米流体的导热系数表示为界面壳导热系数、界面厚度和体积分数的函数。通过对现有有效导热系数模型的分析,将有效导热系数模型划分为四个区域,得到了相关参数的有效值。该模型表明,在体积分数小于1%和直径小于20 nm的区域,导热系数的增加强度远远大于其他区域。我们知道,随着浓度的降低,纳米流体的粘度降低,因此该区域的压降也减小,是应用换热装置的最佳区域。
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引用次数: 0
Modification of cotton fibers with magnetite and magnetic core-shell mesoporous silica nanoparticles 磁铁矿和磁性核壳介孔二氧化硅纳米颗粒对棉纤维的改性
Pub Date : 2018-01-01 DOI: 10.4172/2324-8777-C10-047
David Patino Ruiz
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引用次数: 0
Challenges for materials science in the 21st century 21世纪材料科学面临的挑战
Pub Date : 2018-01-01 DOI: 10.4172/2324-8777-C3-025
Micha Silver
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引用次数: 0
Inorganic/organic hybridized polymers for use in various high performance applications 用于各种高性能应用的无机/有机杂化聚合物
Pub Date : 2018-01-01 DOI: 10.4172/2324-8777-C7-037
D. Parish
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引用次数: 0
Ion beam synthesis of multifunctional Ag nanocrystals embedded in a dielectric matrix 介电基质中多功能银纳米晶的离子束合成
Pub Date : 2018-01-01 DOI: 10.4172/2324-8777-C2-023
C. Bonafos
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引用次数: 0
Electronic structures of van der Waals graphene/periodically porous graphene heterostructures 范德华石墨烯/周期性多孔石墨烯异质结构的电子结构
Pub Date : 2018-01-01 DOI: 10.4172/2324-8777-c1-020
Gunn Kim
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引用次数: 0
Nanoparticle Shapes Effects on Non-Darcy Mixed Convection from a Horizontal Plate Embedded in Water, Ethylene Glycol and Engine Based Cu, Al2O3 and SWCNTs Porous Media 纳米颗粒形状对嵌入水、乙二醇和发动机基Cu、Al2O3和SWCNTs多孔介质的水平板非达西混合对流的影响
Pub Date : 2018-01-01 DOI: 10.4172/2324-8777.1000248
Nur Atikah bt Adnan, A. Ramasamy
Impact of nanoparticle shapes on non-Darcy mixed convection boundary layer flow over an impermeable horizontal flat plat embedded in a porous medium saturated by a nanofluid has been investigated. In distinctly most paramount studies, three types of nanoparticle shapes are employed into these studies namely sphere, cylinder and lamina. The controlling Partial Differential Equations are regenerated into a set of ordinary differential equations by manipulating similarity transformation and it is determined numerically by using Runge Kutta Fehlberg method with shooting technique from MAPLE 18. The surface of the plate is maintained at a constant temperature and constant nanoparticle volume fraction. Temperature profiles are graphically and tabular provided for the effects of mixed convection parameter, initial parameter, volume fraction parameter and empirical shape factor. The results show that solid volume fraction and nanoparticle shapes have powerful outputs in non-Darcy flow. Laminar nanoparticle shapes predicts a better results on heat transfer rather than other nanoparticle shapes.
研究了纳米颗粒形状对嵌入纳米流体饱和多孔介质的不透水水平平板上非达西混合对流边界层流动的影响。在最重要的研究中,三种类型的纳米颗粒形状被用于这些研究,即球形,圆柱形和片状。利用相似变换将控制偏微分方程重新生成为常微分方程,利用Runge - Kutta - Fehlberg方法结合MAPLE 18的射击技术进行数值求解。板的表面保持在恒定的温度和恒定的纳米颗粒体积分数。给出了混合对流参数、初始参数、体积分数参数和经验形状因子影响下的温度曲线。结果表明,固体体积分数和纳米颗粒形状在非达西流动中具有强大的输出。层流纳米颗粒的形状比其他纳米颗粒的形状预测更好的传热结果。
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引用次数: 0
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Journal of Nanomaterials & Molecular Nanotechnology
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