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Graft-Copolymerization of Acrylate Monomers onto Chitosan Induced by Gamma Radiation: Amphiphilic Polymers and Their Behavior at The Air-Water Interface γ辐射诱导丙烯酸酯单体在壳聚糖上的接枝共聚:两亲性聚合物及其在空气-水界面的行为
Pub Date : 2020-02-28 DOI: 10.15415/jnp.2020.72027
M. Caldera-Villalobos, B. Leal-Acevedo, V. M. Velázquez-Aguilar, M. P. Carreón-Castro
Graft polymerization induced by ionizing radiation is a powerful tool in materials science to modifying the physical properties of polymers. Chitosan is a biocompatible, biodegradable, antibacterial, and highly hydrophilic polysaccharide. In this work, we report the obtaining of amphiphilic polymers through graft polymerization of acrylic monomers (methyl acrylate, t-butyl acrylate, and hexyl acrylate) onto chitosan. The polymerization reaction was carried out by simultaneous irradiation of monomers and chitosan using a gamma radiation source of 60Co. The formation of Langmuir films of amphiphilic polymers was studied at the air-water interface through surface pressure versus main molecular area isotherms (Π-A) and hysteresis cycles of compression and decompression. Finally, it was analyzed the transferring of Langmuir films towards solid substrates to obtaining Langmuir-Blodgett films with potential application as an antibacterial coating. The microstructure of the Langmuir-Blodgett films was characterized by AFM microscopy observing a regular topography with roughness ranging between 0.53 and 0.6 μm.
电离辐射引发的接枝聚合是材料科学中改变聚合物物理性质的有力工具。壳聚糖是一种具有生物相容性、可生物降解性、抗菌性和高度亲水性的多糖。在这项工作中,我们报道了通过接枝聚合丙烯酸单体(丙烯酸甲酯,丙烯酸丁酯和丙烯酸己酯)在壳聚糖上获得两亲性聚合物。用60Co射线源同时照射单体和壳聚糖,进行聚合反应。通过表面压力与主分子面积等温线(Π-A)以及压缩和减压的滞后循环,研究了两亲性聚合物在空气-水界面上Langmuir膜的形成。最后,分析了Langmuir- blodgett薄膜在固体基质上的转移,得到了具有抗菌涂层潜力的Langmuir- blodgett薄膜。通过AFM显微镜对Langmuir-Blodgett薄膜的微观结构进行了表征,观察到其表面粗糙度在0.53 ~ 0.6 μm之间。
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引用次数: 0
Structural Variations Induced by Temperature Changes in Rotavirus VP6 Protein Immersed in an Electric Field and Their Effects on Epitopes of The Region 300-396 电场作用下轮状病毒VP6蛋白温度变化对300-396区表位的影响
Pub Date : 2020-02-28 DOI: 10.15415/jnp.2020.72024
C. Peña-Negrete, M. Fuentes-Acosta, J. Mulia, L. A. Mandujano-Rosas, D. Osorio-González
Rotavirus diarrhea is an infectious intestinal disease that causes about 215 thousand deaths annually in infants under five years old. This virus is formed by three layers of concentric proteins that envelop its genome, from which VP6 structural protein is the most conserved among rotavirus serotypes and an excellent vaccine candidate. Recent studies have shown that structural proteins are susceptible to losing their biological function when their conformation is modified by moderate temperature increments, and in the case of VP6, its antigen efficiency decreases. We performed an in silicoanalysis to identify the structural variations in the epitopes 301-315, 357-366, and 376-384 of the rotavirus VP6 protein -in a hydrated medium- when the temperature is increased from 310 K to 322 K. In the latter state, we applied an electric field equivalent to a low energy laser pulse and calculated the fluctuations per amino acid residue. We identified that the region 301-315 has greater flexibility and density of negative electrical charge; nevertheless, at 322 K it experiences a sudden change of secondary structure that could decrease its efficiency as an antigenic determinant. The applied electric field induces electrical neutrality in the region 357-366, whereas in 376-384 inverts the charge, implying that temperature changes in the range 310 K-322 K are a factor that promotes thermoelectric effects in the VP6 protein epitopes in the region 300-396.
轮状病毒腹泻是一种传染性肠道疾病,每年导致约21.5万5岁以下婴儿死亡。该病毒由包裹其基因组的三层同心蛋白构成,其中VP6结构蛋白在轮状病毒血清型中最为保守,是一种极好的候选疫苗。最近的研究表明,当结构蛋白的构象被适度的温度增加修饰时,结构蛋白容易失去其生物学功能,以VP6为例,其抗原效率降低。当温度从310 K升高到322 K时,我们对轮状病毒VP6蛋白表位301-315、357-366和376-384的结构变化进行了硅分析。在后一种状态下,我们施加了一个相当于低能量激光脉冲的电场,并计算了每个氨基酸残基的波动。我们发现301-315区域具有更大的灵活性和负电荷密度;然而,在322 K时,它经历了二级结构的突然变化,这可能会降低其作为抗原决定因子的效率。外加电场在357-366区诱导电中性,而在376-384区使电荷反转,这意味着310 K-322 K范围内的温度变化是促进300-396区VP6蛋白表位热电效应的一个因素。
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引用次数: 1
Analysis of DDM into Gamma Radiation DDM转化为伽马辐射的分析
Pub Date : 2020-02-28 DOI: 10.15415/JNP.2020.72019
C. Arellano-Celiz, A. Avilez-López, J. E. Barradas-Guevara, O. Félix-Beltrán, F. Gonzalez-Canales
We are interested in the purpose of a dipolar fermionic particle as a viable candidate of Dark Matter (DDM). Then, we study the annihilation of dark matter into photons, considering it as a neutral particle with non-vanishing magnetic (M) and electric (D) dipolar moments. The total annihilation cross section σ(χ → γ) is computed by starting from a general form of coupling χγ  in a framework beyond to Standard Model (BSM). We found that candidates with O(mχ )∽102GeV, D≈10−16 e cm are required in order to satisfy the current cosmic relic density.
我们对偶极费米子粒子作为暗物质(DDM)的可行候选物的目的感兴趣。然后,我们研究了暗物质湮灭成光子,将其视为具有不消失的磁(M)和电(D)偶极矩的中性粒子。总湮灭截面σ(χ →γ)是通过在超越标准模型(BSM)的框架中从一般形式的耦合χγ 开始计算的。我们发现,为了满足当前宇宙遗迹密度,需要O(mχ)∽102GeV, D≈10−16 e cm的候选粒子。
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引用次数: 0
How do Uncertainties in Atomic Parameters Influence Theoretical Predictions of X-Ray Production Cross Sections By Proton Impact? 原子参数的不确定性如何影响质子撞击x射线产生截面的理论预测?
Pub Date : 2020-02-28 DOI: 10.15415/jnp.2020.72007
J. Miranda
The emission of characteristic X-rays induced by proton impact is a phenomenon known since the first half of the 20th century. Its more widely known application is the analytical technique Particle Induced X-ray Emission (PIXE). Several models have been developed to calculate, first, ionization cross sections and then the subsequent X-ray production cross sections. However, to carry out the comparisons of these predictions with experimental data it is necessary to use atomic parameters databases (fluorescence yields, Coster-Kronig transition probabilities, emission rates) that also have experimental uncertainties. In this work it is demonstrated how these values do not allow to decide which model describes more accurately the cross sections, due to a final “theoretical uncertainty” obtained through the propagation of the original uncertainties.
质子撞击引起的特征x射线的发射是一种自20世纪上半叶以来已知的现象。它更广为人知的应用是粒子诱导x射线发射(PIXE)分析技术。已经开发了几个模型来计算电离截面和随后的x射线产生截面。然而,为了将这些预测与实验数据进行比较,有必要使用同样具有实验不确定性的原子参数数据库(荧光产率、科斯特-克朗格跃迁概率、发射率)。在这项工作中,它证明了这些值如何不允许决定哪个模型更准确地描述截面,由于最终的“理论不确定性”通过原始不确定性的传播获得。
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引用次数: 1
Study of the Erosion of Copper by Hot Plasma 热等离子体对铜的腐蚀研究
Pub Date : 2020-02-28 DOI: 10.15415/jnp.2020.72022
R. S. Monzamodeth, B. Campillo
An exhaustive study of the erosion process of a copper cathode exposed to a hot plasma column of 2kJ of energy (T≈0.5-2.0keV) and high electron density (n≈1019-1022cm3) was made, as well as, the radiation field of charged and neutral particles. The characterization of the cumulative damage generated by the plasma/cathode interaction was made by the use of metallographic techniques, scanning electron microscopy (SEM) and by the analysis of mechanical properties. Damage accumulation produced by the impacts of deuterium plasma discharge created in the copper electrode a deep cavity similar to a crater, modifying the morphology of the surface and below it. The microhardness Vickers test was carried out making indentations from the final part of the cavity to cover 1 cm with indentations every 200 μm. Different areas of hardening were observed, the profile suggests a hardening/recovery front and simultaneous recrystallization in the sample, phenomenon associated with the heating/cooling cycles to which the copper cathode is subjected. Images were captured by SEM at different distances from the center of the surface. The region that showed involvement at the macro level corresponds to 2/3 of the radius of the sample from the center to the outside. These phenomena studied are important to understand the nature of the plasma/wall interaction in any fusion device.
研究了铜阴极在2kJ能量(T≈0.5 ~ 2.0 kev)和高电子密度(n≈1019 ~ 1022cm3)的热等离子体柱下的腐蚀过程,以及带电粒子和中性粒子的辐射场。利用金相技术、扫描电子显微镜(SEM)和力学性能分析对等离子体/阴极相互作用产生的累积损伤进行了表征。氘等离子体放电的冲击产生的损伤积累在铜电极中形成了一个类似陨石坑的深腔,改变了表面及其下方的形态。进行显微硬度维氏测试,从空腔最终部分开始,每隔200 μm压痕覆盖1 cm。观察到不同的硬化区域,该剖面表明样品中存在硬化/恢复前沿和同时发生的再结晶,这一现象与铜阴极所经受的加热/冷却循环有关。扫描电镜在离表面中心不同距离处拍摄图像。在宏观层面显示受影响的区域对应于样品从中心到外部半径的2/3。这些现象的研究对于理解任何聚变装置中等离子体/壁相互作用的性质都是重要的。
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引用次数: 0
Stability of Pyruvic Acid Adsorbed Onto Clays and Exposed to Ionizing Radiation: Relevance in Chemical Evolution 丙酮酸吸附于粘土和电离辐射下的稳定性:与化学演化的相关性
Pub Date : 2020-02-28 DOI: 10.15415/jnp.2020.72011
R. Acosta-Fernández, A. Heredia-Barbero, A. Negrón-Mendoza
Chemical evolution studies focus on the synthesis and stability of organic molecules during various transformative physicochemical processes. Gaining insight into the possible mechanisms behind these processes requires the use of various energy sources and catalysts that can produce such transformations. In this work, ionizing radiation (60Co) was used as a source of energy, and two clays with different exchangeable cations-sodium and iron (III)-were combined with pyruvic acid, a key alpha keto acid in metabolism. The samples of pyruvic acid were prepared at a concentration of 0.01 M; then, adsorption experiments were carried out by combining sodium or iron montmorillonite at different times. The amount that adsorbed onto iron montmorillonite was greater than the amount that adsorbed onto sodium montmorillonite. Samples of alpha keto acid at the same concentration were irradiated-in the absence of clay-at 0 to 146.1 kGy and at two pHs (6.7 and 2.0). The suspended samples with sodium and iron clay were then irradiated at the same doses. The results show that keto acid decomposes more quickly at more acidic pHs. The main reaction to irradiation without clay involves the dimerization of pyruvic acid, and 2,3-dimethyltartaric acid is the majority product. When irradiated in the presence of clay, the main reaction is decarboxylation, and acetic acid is the majority product. The exchangeable cation type modifies the interactions between the organic molecule and the solid phase. The percentage of recovered pyruvic acid is higher for iron montmorillonite than for sodium montmorillonite.
化学进化研究的重点是在各种转化的物理化学过程中有机分子的合成和稳定性。为了深入了解这些过程背后的可能机制,需要使用各种能源和催化剂来产生这种转化。在这项工作中,电离辐射(60Co)作为能量来源,并将两种具有不同交换阳离子的粘土-钠和铁(III)-与代谢中的关键α酮酸丙酮酸结合。丙酮酸样品在0.01 M的浓度下制备;然后,在不同时间进行钠蒙脱土和铁蒙脱土的吸附实验。铁蒙脱土吸附量大于钠蒙脱土吸附量。相同浓度的α酮酸样品在没有粘土的情况下,在0至146.1 kGy和两个ph值(6.7和2.0)下辐照。然后以相同的剂量照射钠和铁粘土悬浮样品。结果表明,当ph值越高时,酮酸分解速度越快。无粘土辐照的主要反应是丙酮酸的二聚化反应,其中2,3-二甲基酒石酸是主要产物。在有粘土存在的情况下辐照时,主要反应是脱羧,乙酸是主要产物。交换阳离子类型改变了有机分子与固相之间的相互作用。铁蒙脱土的丙酮酸回收率高于钠蒙脱土。
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引用次数: 0
Preliminary Measurements of Be-10/Be-7 Ratio in Rainwater for Atmospheric Transport Analysis 雨水中Be-10/Be-7比值用于大气输送分析的初步测定
Pub Date : 2020-02-28 DOI: 10.15415/jnp.2020.72018
K. D. L. Ríos, C. Méndez-García, L. Acosta, R. García-Martínez, M. A. Martínez-Carrillo, M. E. Ortiz
The meteoric cosmogenic beryllium has been used as an essential geophysical tracer in the analysis of atmospheric flows and erosion soils since 1960. The first measurements Be-7 and Be-10 concentrations in rainwater from Mexico, have been carried out by using gamma decay spectroscopy and AMS techniques, respectively for each isotope. With this it was possible to report a preliminar value for the Be-10/Be-7 isotopic ratio in such environmental samples. The present work described preliminary results related to rainwater collected at mountain and metropolitan areas. Results are compared with predictions and previous measurements for both radioisotopes, observing a very sensible behavior particularly for the case of Be-7 activities.
自1960年以来,在大气流动和侵蚀土壤的分析中,大气宇宙成因铍被用作重要的地球物理示踪剂。首次测量了来自墨西哥的雨水中Be-7和Be-10的浓度,分别使用伽马衰变光谱和AMS技术对每种同位素进行了测量。这样就有可能报告这种环境样品中Be-10/Be-7同位素比率的初步值。本工作描述了山区和都市地区收集雨水的初步结果。将结果与对两种放射性同位素的预测和先前的测量结果进行比较,观察到一种非常合理的行为,特别是在Be-7活动的情况下。
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引用次数: 0
Analysis of the Radon-222 Concentration and Physical-chemical Quality, in Drinking Water of Taxco, Guerrero 格雷罗州塔斯科市饮用水中氡-222浓度及理化性质分析
Pub Date : 2020-02-28 DOI: 10.15415/jnp.2020.72026
A. H. Ramirez, O. Talavera, S. Souto, J. Golzarri, G. Espinosa
In this work the determination of radon gas (222Rn) and the characterization of chemical elements in drinking water of the city Taxco was carried out. Ingesting or inhaling a small number of radionuclides, as well as water of poor chemical quality, can become a potential public health problem. We are collecting 8 samples of water from a spring, physicochemical parameters were measured in field on different days of the dry season. Measurements of 222Rn were performed in the laboratory with an AlphaGUARD equipment. The chemical quality was analyzed in laboratory too by means of mayor and minor ions, by volumetry and colorimetry. The sodium was determined by Flama Atomic Absorption Spectroscopy (FAAS). Trace elements were analyzed by were determined by Atomic Emission Spectroscopy with Plasma Coupled by Induction (ICP-AES). The concentrations of 222Rn present an average of 22.06 ± 2.52 BqL-1. The results obtained from the main ions and field parameters show a type of diluted sodium-calcium-bicarbonate water. The trace elements present are very small and not exceed the limit of quantification. Radon gas is produced by the igneous rock that is the top of the stratigraphic column, of the hydric recharge. Rainwater when descending through the fractures is impregnated with 222Rn gas and accumulated in the underlying rock that has sufficient porosity to accumulate water and gas in the Chacualco´s spring.
本文对塔斯科市饮用水中氡气(222Rn)的测定和化学元素的表征进行了研究。摄入或吸入少量放射性核素以及化学质量差的水可能成为潜在的公共卫生问题。我们收集了8个泉水样本,在旱季的不同日子实地测量了理化参数。222Rn的测量在实验室用AlphaGUARD设备进行。在实验室用主离子法、次离子法、体积法和比色法分析了其化学性质。采用火焰原子吸收光谱法测定钠的含量。采用等离子体感应耦合原子发射光谱(ICP-AES)对样品中的微量元素进行了分析。222Rn的平均浓度为22.06±2.52 BqL-1。从主离子和场参数上得到的结果表明,这是一种稀释的碳酸氢钠-钙水。微量元素含量极少,未超过定量限度。氡气是由地层柱顶部的火成岩产生的,是水力补给的产物。雨水在穿过裂缝时浸透了222Rn气体,并积聚在具有足够孔隙度的下伏岩石中,从而在Chacualco的泉水中积聚水和气体。
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引用次数: 0
PADC-NTM Applied in 7Li+Pb at 31 MeV Reaction Products Study PADC-NTM在7Li+Pb 31 MeV反应产物中的应用研究
Pub Date : 2020-02-28 DOI: 10.15415/jnp.2020.72013
M. Cinausero, A. M. Sajo-Castelli, L. Sajo-Bohus, J. K. Palfalvi, G. Espinosa
Passive nuclear track methodology (NTM) is applied to study charged particles products of the reaction 7Li+Pb at ~ 31 MeV. It is a contribution to the 8pLP Project (LNL-INFN-Italy) in where we show an alternative approach to register charged particle from reaction fragments by PADC detection. The main advantage is that the passive system integrates data over the whole experiment and has its importance for low rate reaction processes. Reaction products as well as scattered beam particles are determined from track shape analysis. Some limitations are inherent to NTM since a priori knowledge is required to correlate track size distribution given by each type of particle emerging from the target. Results show that the passive technique gives useful information when applied in reaction data interpretation for a relatively large range of particle types.
应用被动核径迹法(NTM)研究了7Li+Pb在~ 31 MeV下的带电粒子反应产物。这是对8pLP项目(LNL-INFN-Italy)的贡献,在该项目中,我们展示了一种通过PADC检测从反应碎片中记录带电粒子的替代方法。主要优点是被动系统集成了整个实验的数据,对于低速率反应过程具有重要意义。通过轨迹形状分析确定了反应产物和散射束粒子。由于需要先验知识来关联从目标中出现的每种类型的粒子给出的轨迹尺寸分布,因此NTM固有的一些局限性。结果表明,该技术在较大范围的粒子类型的反应数据解释中提供了有用的信息。
{"title":"PADC-NTM Applied in 7Li+Pb at 31 MeV Reaction Products Study","authors":"M. Cinausero, A. M. Sajo-Castelli, L. Sajo-Bohus, J. K. Palfalvi, G. Espinosa","doi":"10.15415/jnp.2020.72013","DOIUrl":"https://doi.org/10.15415/jnp.2020.72013","url":null,"abstract":"Passive nuclear track methodology (NTM) is applied to study charged particles products of the reaction 7Li+Pb at ~ 31 MeV. It is a contribution to the 8pLP Project (LNL-INFN-Italy) in where we show an alternative approach to register charged particle from reaction fragments by PADC detection. The main advantage is that the passive system integrates data over the whole experiment and has its importance for low rate reaction processes. Reaction products as well as scattered beam particles are determined from track shape analysis. Some limitations are inherent to NTM since a priori knowledge is required to correlate track size distribution given by each type of particle emerging from the target. Results show that the passive technique gives useful information when applied in reaction data interpretation for a relatively large range of particle types.","PeriodicalId":16534,"journal":{"name":"Journal of Nuclear Physics, Material Sciences, Radiation and Applications","volume":"1992 1","pages":""},"PeriodicalIF":0.0,"publicationDate":"2020-02-28","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"89004647","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 1
Effects of Gamma Irradiation on Curcumin γ辐射对姜黄素的影响
Pub Date : 2020-02-28 DOI: 10.15415/jnp.2020.72012
E. Islas-Ortiz, E. O. Reyes-Salas, A. Negrón-Mendoza, A. Meléndez-López, G. Reyes-Garcia, J. A. C. Castañeda, E. Madrigal-Lagunas
In this study, remnants concentrations of curcumin in Curcuma longa (organic turmeric powder) were determined after it was exposed to irradiation doses of 1, 2 and 3 kGy. Curcumin analysis was performed using the analyte-sensitive impulse differential polarography technique (LOD: 0.621 ppm and LOQ: 2.130 ppm). The results obtained showed a decreasing concentration of curcumin as a function of the irradiation dose. This reduction is low in terms of affecting the product’s quality with respect to its concentration.
本研究测定了有机姜黄粉(Curcuma longa)在1、2和3 kGy辐照剂量下的残留姜黄素浓度。姜黄素分析采用分析物敏感脉冲差分极谱技术(LOD: 0.621 ppm, LOQ: 2.130 ppm)。结果表明,姜黄素浓度随辐照剂量的增加而降低。就其浓度而言,这种降低对产品质量的影响很小。
{"title":"Effects of Gamma Irradiation on Curcumin","authors":"E. Islas-Ortiz, E. O. Reyes-Salas, A. Negrón-Mendoza, A. Meléndez-López, G. Reyes-Garcia, J. A. C. Castañeda, E. Madrigal-Lagunas","doi":"10.15415/jnp.2020.72012","DOIUrl":"https://doi.org/10.15415/jnp.2020.72012","url":null,"abstract":"In this study, remnants concentrations of curcumin in Curcuma longa (organic turmeric powder) were determined after it was exposed to irradiation doses of 1, 2 and 3 kGy. Curcumin analysis was performed using the analyte-sensitive impulse differential polarography technique (LOD: 0.621 ppm and LOQ: 2.130 ppm). The results obtained showed a decreasing concentration of curcumin as a function of the irradiation dose. This reduction is low in terms of affecting the product’s quality with respect to its concentration.","PeriodicalId":16534,"journal":{"name":"Journal of Nuclear Physics, Material Sciences, Radiation and Applications","volume":"61 1","pages":""},"PeriodicalIF":0.0,"publicationDate":"2020-02-28","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"89196857","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 1
期刊
Journal of Nuclear Physics, Material Sciences, Radiation and Applications
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