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Structural, photophysical, and electrochemical redox properties of meso-tetrakis(pentafluorophenyl)porphyrins 中-四（五氟苯基）卟啉的结构、光物理和电化学氧化还原特性
IF 1.5 4区 化学 Q4 CHEMISTRY, MULTIDISCIPLINARY
Journal of Porphyrins and Phthalocyanines
Pub Date : 2024-02-15 DOI: 10.1142/s1088424624500019
Ankit Kumar Deval, Muniappan Sankar
<p>This study delineates the synthesis and comprehensive characterization of metal complexes of <i>meso</i>-tetrakis(pentafluorophenyl)porphyrin (H<sub>2</sub>TPF<span><math altimg="eq-00001.gif" display="inline" overflow="scroll"><msub><mrow></mrow><mrow><mn>2</mn><mn>0</mn></mrow></msub></math></span><span></span>P, <b>1</b>) with first-row transition metal ions (M = Mn(III) <b>2</b>, Fe(III) <b>3</b>, Co(II) <b>4</b>, Ni(II) <b>5</b>, Cu(II) <b>6</b>, and Zn(II) <b>7</b>) to elucidate their structural, electronic spectral, and electrochemical redox properties. Co, Ni, Cu and Zn Complexes exhibit planar structure (<span><math altimg="eq-00002.gif" display="inline" overflow="scroll"><mi mathvariant="normal">Δ</mi></math></span><span></span>24 = 0.003-0.021 Å and <span><math altimg="eq-00003.gif" display="inline" overflow="scroll"><mi mathvariant="normal">Δ</mi></math></span><span></span>C<span><math altimg="eq-00004.gif" display="inline" overflow="scroll"><msub><mrow></mrow><mrow><mi>β</mi></mrow></msub></math></span><span></span> = 0.004−0.041 Å) which is also confirmed by the single crystal data of complex ZnTPF<span><math altimg="eq-00005.gif" display="inline" overflow="scroll"><msub><mrow></mrow><mrow><mn>2</mn><mn>0</mn></mrow></msub></math></span><span></span>P, <b>7</b> shows the planar geometry, while Fe and Mn complexes show the slightly nonplanar structure (<span><math altimg="eq-00006.gif" display="inline" overflow="scroll"><mi mathvariant="normal">Δ</mi></math></span><span></span>24 = 0.101–0.143 Å and <span><math altimg="eq-00007.gif" display="inline" overflow="scroll"><mi mathvariant="normal">Δ</mi></math></span><span></span>C<span><math altimg="eq-00008.gif" display="inline" overflow="scroll"><msub><mrow></mrow><mrow><mi>β</mi></mrow></msub></math></span><span></span> = 0.080–0.112 Å), which are distorted due to their occupied axial sites by −Cl ligand as revealed by density functional theory (DFT) calculations. Furthermore, electronic spectroscopy revealed a gradual bathochromic shift following the order of NiTPF<span><math altimg="eq-00009.gif" display="inline" overflow="scroll"><msub><mrow></mrow><mrow><mn>2</mn><mn>0</mn></mrow></msub></math></span><span></span>P < CoTPF<span><math altimg="eq-00010.gif" display="inline" overflow="scroll"><msub><mrow></mrow><mrow><mn>2</mn><mn>0</mn></mrow></msub></math></span><span></span>P < CuTPF<span><math altimg="eq-00011.gif" display="inline" overflow="scroll"><msub><mrow></mrow><mrow><mn>2</mn><mn>0</mn></mrow></msub></math></span><span></span>PCl < H<sub>2</sub>TPF<span><math altimg="eq-00012.gif" display="inline" overflow="scroll"><msub><mrow></mrow><mrow><mn>2</mn><mn>0</mn></mrow></msub></math></span><span></span>P = FeTPF<span><math altimg="eq-00013.gif" display="inline" overflow="scroll"><msub><mrow></mrow><mrow><mn>2</mn><mn>0</mn></mrow></msub></math></span><span></span>PCl < ZnTPF<span><math altimg="eq-00014.gif" display="inline" overflow="scroll"><msub><mrow></mrow>
本研究描述了中-四（五氟苯基）卟啉（H2TPF20P，1）与第一排过渡金属离子（M = Mn(III) 2、Fe(III) 3、Co(II) 4、Ni(II) 5、Cu(II) 6 和 Zn(II) 7）的金属配合物的合成和综合表征，以阐明其结构、电子光谱和电化学氧化还原特性。钴、镍、铜和锌配合物显示出平面结构（Δ24 = 0.003-0.021 Å 和 ΔCβ = 0.004-0.041 Å），这也得到了配合物 ZnTPF20P 的单晶数据的证实。101-0.143 Å 和 ΔCβ = 0.080-0.112 Å），密度泛函理论（DFT）计算显示，这些结构由于-Cl 配体占据了它们的轴向位点而发生了扭曲。此外，电子能谱显示，通过在卟啉核心添加不同的金属离子，卟啉的浴色逐渐发生变化，其顺序为 NiTPF20P < CoTPF20P < CuTPF20PCl < H2TPF20P = FeTPF20PCl < ZnTPF20P < MnTPF20PCl。与 H2TPF20P 相比，MnTPF20PCl 在索雷特波段表现出最显著的浴色偏移（Δλmax = 63 nm）。此外，由于金属 d 轨道与周围配体之间的相互作用，MnTPF20PCl 和 FeTPF20PCl 在 364 纳米和 345 纳米附近显示出独特的索雷特带分裂模式。锌的 3d 填充轨道的电化学氧化还原电位赋予 ZnTPF20P（环中心）最低的氧化电位。
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Co, Ni, Cu and Zn Complexes exhibit planar structure (&lt;span&gt;&lt;math altimg=\"eq-00002.gif\" display=\"inline\" overflow=\"scroll\"&gt;&lt;mi mathvariant=\"normal\"&gt;Δ&lt;/mi&gt;&lt;/math&gt;&lt;/span&gt;&lt;span&gt;&lt;/span&gt;24 = 0.003-0.021 Å and &lt;span&gt;&lt;math altimg=\"eq-00003.gif\" display=\"inline\" overflow=\"scroll\"&gt;&lt;mi mathvariant=\"normal\"&gt;Δ&lt;/mi&gt;&lt;/math&gt;&lt;/span&gt;&lt;span&gt;&lt;/span&gt;C&lt;span&gt;&lt;math altimg=\"eq-00004.gif\" display=\"inline\" overflow=\"scroll\"&gt;&lt;msub&gt;&lt;mrow&gt;&lt;/mrow&gt;&lt;mrow&gt;&lt;mi&gt;β&lt;/mi&gt;&lt;/mrow&gt;&lt;/msub&gt;&lt;/math&gt;&lt;/span&gt;&lt;span&gt;&lt;/span&gt; = 0.004−0.041 Å) which is also confirmed by the single crystal data of complex ZnTPF&lt;span&gt;&lt;math altimg=\"eq-00005.gif\" display=\"inline\" overflow=\"scroll\"&gt;&lt;msub&gt;&lt;mrow&gt;&lt;/mrow&gt;&lt;mrow&gt;&lt;mn&gt;2&lt;/mn&gt;&lt;mn&gt;0&lt;/mn&gt;&lt;/mrow&gt;&lt;/msub&gt;&lt;/math&gt;&lt;/span&gt;&lt;span&gt;&lt;/span&gt;P, &lt;b&gt;7&lt;/b&gt; shows the planar geometry, while Fe and Mn complexes show the slightly nonplanar structure (&lt;span&gt;&lt;math altimg=\"eq-00006.gif\" display=\"inline\" overflow=\"scroll\"&gt;&lt;mi mathvariant=\"normal\"&gt;Δ&lt;/mi&gt;&lt;/math&gt;&lt;/span&gt;&lt;span&gt;&lt;/span&gt;24 = 0.101–0.143 Å and &lt;span&gt;&lt;math altimg=\"eq-00007.gif\" display=\"inline\" overflow=\"scroll\"&gt;&lt;mi mathvariant=\"normal\"&gt;Δ&lt;/mi&gt;&lt;/math&gt;&lt;/span&gt;&lt;span&gt;&lt;/span&gt;C&lt;span&gt;&lt;math altimg=\"eq-00008.gif\" display=\"inline\" overflow=\"scroll\"&gt;&lt;msub&gt;&lt;mrow&gt;&lt;/mrow&gt;&lt;mrow&gt;&lt;mi&gt;β&lt;/mi&gt;&lt;/mrow&gt;&lt;/msub&gt;&lt;/math&gt;&lt;/span&gt;&lt;span&gt;&lt;/span&gt; = 0.080–0.112 Å), which are distorted due to their occupied axial sites by −Cl ligand as revealed by density functional theory (DFT) calculations. Furthermore, electronic spectroscopy revealed a gradual bathochromic shift following the order of NiTPF&lt;span&gt;&lt;math altimg=\"eq-00009.gif\" display=\"inline\" overflow=\"scroll\"&gt;&lt;msub&gt;&lt;mrow&gt;&lt;/mrow&gt;&lt;mrow&gt;&lt;mn&gt;2&lt;/mn&gt;&lt;mn&gt;0&lt;/mn&gt;&lt;/mrow&gt;&lt;/msub&gt;&lt;/math&gt;&lt;/span&gt;&lt;span&gt;&lt;/span&gt;P &lt; CoTPF&lt;span&gt;&lt;math altimg=\"eq-00010.gif\" display=\"inline\" overflow=\"scroll\"&gt;&lt;msub&gt;&lt;mrow&gt;&lt;/mrow&gt;&lt;mrow&gt;&lt;mn&gt;2&lt;/mn&gt;&lt;mn&gt;0&lt;/mn&gt;&lt;/mrow&gt;&lt;/msub&gt;&lt;/math&gt;&lt;/span&gt;&lt;span&gt;&lt;/span&gt;P &lt; CuTPF&lt;span&gt;&lt;math altimg=\"eq-00011.gif\" display=\"inline\" overflow=\"scroll\"&gt;&lt;msub&gt;&lt;mrow&gt;&lt;/mrow&gt;&lt;mrow&gt;&lt;mn&gt;2&lt;/mn&gt;&lt;mn&gt;0&lt;/mn&gt;&lt;/mrow&gt;&lt;/msub&gt;&lt;/math&gt;&lt;/span&gt;&lt;span&gt;&lt;/span&gt;PCl &lt; H&lt;sub&gt;2&lt;/sub&gt;TPF&lt;span&gt;&lt;math altimg=\"eq-00012.gif\" display=\"inline\" overflow=\"scroll\"&gt;&lt;msub&gt;&lt;mrow&gt;&lt;/mrow&gt;&lt;mrow&gt;&lt;mn&gt;2&lt;/mn&gt;&lt;mn&gt;0&lt;/mn&gt;&lt;/mrow&gt;&lt;/msub&gt;&lt;/math&gt;&lt;/span&gt;&lt;span&gt;&lt;/span&gt;P = FeTPF&lt;span&gt;&lt;math altimg=\"eq-00013.gif\" display=\"inline\" overflow=\"scroll\"&gt;&lt;msub&gt;&lt;mrow&gt;&lt;/mrow&gt;&lt;mrow&gt;&lt;mn&gt;2&lt;/mn&gt;&lt;mn&gt;0&lt;/mn&gt;&lt;/mrow&gt;&lt;/msub&gt;&lt;/math&gt;&lt;/span&gt;&lt;span&gt;&lt;/span&gt;PCl &lt; ZnTPF&lt;span&gt;&lt;math altimg=\"eq-00014.gif\" display=\"inline\" overflow=\"scroll\"&gt;&lt;msub&gt;&lt;mrow&gt;&lt;/mrow&gt;","PeriodicalId":16876,"journal":{"name":"Journal of Porphyrins and Phthalocyanines","volume":"82 1","pages":""},"PeriodicalIF":1.5,"publicationDate":"2024-02-15","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"140156496","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Photodynamic antimicrobial activities of a series of meso-substituted 2,6-dibrominated 1,3,5,7-tetramethylBODIPY dyes 一系列中取代 2,6 二溴化 1,3,5,7 四甲基 BODIPY 染料的光动力抗菌活性
IF 1.5 4区 化学 Q4 CHEMISTRY, MULTIDISCIPLINARY
Journal of Porphyrins and Phthalocyanines
Pub Date : 2024-01-24 DOI: 10.1142/s1088424623501316
Aviwe K. May, Bokolombe P. Ngoy, John Mack, Tebello Nyokong

The photodynamic antimicrobial chemotherapy (PACT) activities of seven 1,3,5,7-tetramethyl-2,6-dibromoBODIPY dyes with 4-acetamidophenyl (2a), 2-iodophenyl (2b), 3-iodophenyl (2c), 4-iodophenyl (2d), 2-bromophenyl (2e), 5-bromothien-2-yl (2f), and methylphenyl ester (2g) meso-substituents were studied against Staphylococcus aureus through irradiation with a 530 nm Thorlabs M530L3 light emitting diode (LED) (110 mW.cm−2) to identify structure-property relationships related to modifying the meso-substituent. Significant differences are observed in the log10 reduction values obtained with 1 μM of 2a exhibiting the highest PACT activity with a value of 9.60 after 15 min of photoirradiation. In contrast, log10 reduction values < 1.20 were obtained after 60 min of photoirradiation for iodophenyl dyes 2b-2d. The data demonstrate that the singlet oxygen quantum yield of the dye is not the most important factor determining the PACT activity properties.

研究了含有 4-乙酰氨基苯基（2a）、2-碘苯基（2b）、3-碘苯基（2c）、4-碘苯基（2d）、2-溴苯基（2e）、5-溴噻吩-2-基（2f）和甲基苯基酯（2g）的七种 1,3,5,7-四甲基-2,6-二溴 BODIPY 染料的光动力抗菌化疗（PACT）活性、2-溴苯基 (2e)、5-溴噻吩-2-基 (2f) 和甲基苯基酯 (2g) 中取代基对金黄色葡萄球菌的作用进行了研究，采用 530 nm Thorlabs M530L3 发光二极管（LED）（110 mW.cm-2）进行照射，以确定与中层取代基修饰有关的结构-性质关系。光照射 15 分钟后，1 μM 的 2a 显示出最高的 PACT 活性，其对数值为 9.60。相比之下，碘苯基染料 2b-2d 在光照 60 分钟后的对数值为 1.20。这些数据表明，染料的单线态氧量子产率并不是决定 PACT 活性特性的最重要因素。
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引用次数: 0
A Young Infant with Skin Blisters Like Dew Drops Over Rose Petals. 婴儿皮肤上的水泡就像玫瑰花瓣上的露珠。
4区 化学 Q4 CHEMISTRY, MULTIDISCIPLINARY
Journal of Porphyrins and Phthalocyanines
Pub Date : 2023-11-30 eCollection Date: 2023-11-01 DOI: 10.5001/omj.2023.118
Chetan Khare, Ambalakkuthan Murugesan
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引用次数: 0
Structure, acidic properties and the coordination ability of sapphyrin with an unsymmetric substitution system 具有不对称取代体系的蓝藻素的结构、酸性和配位能力
IF 1.5 4区 化学 Q4 CHEMISTRY, MULTIDISCIPLINARY
Journal of Porphyrins and Phthalocyanines
Pub Date : 2023-11-22 DOI: 10.1142/s1088424623501298
Yulia B. Ivanova, S. Pukhovskaya, M. M. Lukanov, A. Semeikin, A. Vashurin, Sergey A. Syrbua
{"title":"Structure, acidic properties and the coordination ability of sapphyrin with an unsymmetric substitution system","authors":"Yulia B. Ivanova, S. Pukhovskaya, M. M. Lukanov, A. Semeikin, A. Vashurin, Sergey A. Syrbua","doi":"10.1142/s1088424623501298","DOIUrl":"https://doi.org/10.1142/s1088424623501298","url":null,"abstract":"","PeriodicalId":16876,"journal":{"name":"Journal of Porphyrins and Phthalocyanines","volume":"457 ","pages":""},"PeriodicalIF":1.5,"publicationDate":"2023-11-22","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"139249689","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Electrocatalytic oxidation of petroleum, toluene and xylene on the Ni-porphyrin-modified graphite electrode 镍卟啉改性石墨电极对石油、甲苯和二甲苯的电催化氧化作用
IF 1.5 4区 化学 Q4 CHEMISTRY, MULTIDISCIPLINARY
Journal of Porphyrins and Phthalocyanines
Pub Date : 2023-11-22 DOI: 10.1142/s1088424623501304
Arezo Bahrami, Majid Jafarian, G. S. Ferdowsi, Saeed Rayati
{"title":"Electrocatalytic oxidation of petroleum, toluene and xylene on the Ni-porphyrin-modified graphite electrode","authors":"Arezo Bahrami, Majid Jafarian, G. S. Ferdowsi, Saeed Rayati","doi":"10.1142/s1088424623501304","DOIUrl":"https://doi.org/10.1142/s1088424623501304","url":null,"abstract":"","PeriodicalId":16876,"journal":{"name":"Journal of Porphyrins and Phthalocyanines","volume":"203 ","pages":""},"PeriodicalIF":1.5,"publicationDate":"2023-11-22","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"139249680","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
An evaluation of systematic and random errors in ultrasound estimated fetal weight during serial ultrasound. 评估连续超声波检查中胎儿体重估算的系统误差和随机误差。
IF 4.4 4区 化学 Q4 CHEMISTRY, MULTIDISCIPLINARY
Journal of Porphyrins and Phthalocyanines
Pub Date : 2023-11-01 Epub Date: 2023-01-04 DOI: 10.1177/1742271X221139796
Nicholas John Dudley, Sucheta Jindal, Helen Varley

Introduction: Ultrasound estimated fetal weight is increasingly being used in the monitoring of fetal growth. Large systematic and random errors in estimated fetal weight have been reported; these may have an impact on the accuracy of fetal growth monitoring. The aim of this study was to attempt to evaluate these systematic and random errors by analysis of serial ultrasound data.

Methods: Ultrasound measurements and birthweights were retrospectively collected for 100 unselected patients who had undergone serial ultrasound. Birthweights were used to calculate expected fetal growth trajectories using a method for generating growth charts based on customised birthweights. Estimated fetal weight results were then compared with the expected growth trajectories to evaluate systematic and random differences.

Results: Incomplete measurement sets were excluded, reducing the number of scans to less than three for 13 subjects. A further 17 subjects with suspected pathological growth trajectories were excluded. The final analysis included 70 subjects with a total of 246 scans. The mean difference between estimated fetal weight and expected weight over three to six scans ranged from -17.5% to 38.3% with a mean of 8.4%, representing the systematic difference. The standard deviation of these differences ranged from 0.4% to 21% with a mean of 4.3%, representing random difference.

Conclusion: Systematic and random differences between estimated fetal weight and expected fetal weight are significant and make interpretation of fetal growth difficult. Further improvements to formulae and growth curves are required and audit of fetal measurements is essential to service improvement.

导言：超声估测胎儿体重越来越多地用于胎儿生长监测。有报道称，估计胎儿体重存在较大的系统误差和随机误差；这些误差可能会影响胎儿生长监测的准确性。本研究旨在通过分析连续的超声波数据来评估这些系统误差和随机误差：方法： 我们回顾性地收集了 100 名接受过连续超声检查的未入选患者的超声测量数据和出生体重。出生体重用于计算预期的胎儿生长轨迹，计算方法是根据定制的出生体重生成生长图表。然后将估计的胎儿体重结果与预期的生长轨迹进行比较，以评估系统性差异和随机差异：结果：剔除了不完整的测量数据集，使 13 名受试者的扫描次数减少到 3 次以下。另外还排除了 17 名疑似病理生长轨迹的受试者。最终分析包括 70 名受试者，共进行了 246 次扫描。在三至六次扫描中，估计胎儿体重与预期体重之间的平均差介于-17.5%至38.3%之间，平均差为8.4%，代表系统性差异。这些差异的标准差在 0.4% 至 21% 之间，平均值为 4.3%，代表随机差异：结论：估计胎儿体重与预期胎儿体重之间的系统性和随机性差异显著，给胎儿发育的解释带来困难。需要进一步改进计算公式和生长曲线，对胎儿测量结果进行审核对改善服务至关重要。
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引用次数: 0
Effect of π-extension and halogenation on the optical limiting properties of meso-pyrenylBODIPYdyes π延伸和卤化对中芘二吡啶染料光学限制性能的影响
4区 化学 Q4 CHEMISTRY, MULTIDISCIPLINARY
Journal of Porphyrins and Phthalocyanines
Pub Date : 2023-10-31 DOI: 10.1142/s1088424623501274
Gugu Kubheka, John Mack, Tebello Nyokong
{"title":"Effect of π-extension and halogenation on the optical limiting properties of <i>meso</i>-pyrenylBODIPYdyes","authors":"Gugu Kubheka, John Mack, Tebello Nyokong","doi":"10.1142/s1088424623501274","DOIUrl":"https://doi.org/10.1142/s1088424623501274","url":null,"abstract":"","PeriodicalId":16876,"journal":{"name":"Journal of Porphyrins and Phthalocyanines","volume":"27 ","pages":"0"},"PeriodicalIF":0.0,"publicationDate":"2023-10-31","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"135869826","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Photoinduced energy transfer in sulfur-based heterocyclic compounds and corrole dyads 硫基杂环化合物和光致能量转移
4区 化学 Q4 CHEMISTRY, MULTIDISCIPLINARY
Journal of Porphyrins and Phthalocyanines
Pub Date : 2023-10-31 DOI: 10.1142/s1088424623501286
Swathi Nenavath, B. Shivaprasad Achary, Lingamallu Giribabu
{"title":"Photoinduced energy transfer in sulfur-based heterocyclic compounds and corrole dyads","authors":"Swathi Nenavath, B. Shivaprasad Achary, Lingamallu Giribabu","doi":"10.1142/s1088424623501286","DOIUrl":"https://doi.org/10.1142/s1088424623501286","url":null,"abstract":"","PeriodicalId":16876,"journal":{"name":"Journal of Porphyrins and Phthalocyanines","volume":"64 1","pages":"0"},"PeriodicalIF":0.0,"publicationDate":"2023-10-31","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"135869918","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Steric effect on the photoreaction of chromium(III) porphyrin complexes with imidazole ligands 咪唑配体对铬(III)卟啉配合物光反应的位阻效应
4区 化学 Q4 CHEMISTRY, MULTIDISCIPLINARY
Journal of Porphyrins and Phthalocyanines
Pub Date : 2023-10-23 DOI: 10.1142/s1088424623501262
Mari Maeda, Kaiki Nakayama, Daiki Uehara, Mikio Hoshino, Masahiko Inamo
{"title":"Steric effect on the photoreaction of chromium(III) porphyrin complexes with imidazole ligands","authors":"Mari Maeda, Kaiki Nakayama, Daiki Uehara, Mikio Hoshino, Masahiko Inamo","doi":"10.1142/s1088424623501262","DOIUrl":"https://doi.org/10.1142/s1088424623501262","url":null,"abstract":"","PeriodicalId":16876,"journal":{"name":"Journal of Porphyrins and Phthalocyanines","volume":"57 6","pages":"0"},"PeriodicalIF":0.0,"publicationDate":"2023-10-23","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"135366156","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Bathochromically shifted absorption and near IR emission in bismuth(III) porphyrins with meso-fluorophenyl and methoxyphenyl substitutions 含中氟苯基和甲氧基取代的铋(III)卟啉的色移吸收和近红外发射
4区 化学 Q4 CHEMISTRY, MULTIDISCIPLINARY
Journal of Porphyrins and Phthalocyanines
Pub Date : 2023-10-23 DOI: 10.1142/s1088424623501250
Noah Holzer, Amanda Brown, Jam Riyan Hamza, Jatan K. Sharma, Francis D'Souza, Prashanth K. Poddutoori
{"title":"Bathochromically shifted absorption and near IR emission in bismuth(III) porphyrins with <i>meso</i>-fluorophenyl and methoxyphenyl substitutions","authors":"Noah Holzer, Amanda Brown, Jam Riyan Hamza, Jatan K. Sharma, Francis D'Souza, Prashanth K. Poddutoori","doi":"10.1142/s1088424623501250","DOIUrl":"https://doi.org/10.1142/s1088424623501250","url":null,"abstract":"","PeriodicalId":16876,"journal":{"name":"Journal of Porphyrins and Phthalocyanines","volume":"78 1","pages":"0"},"PeriodicalIF":0.0,"publicationDate":"2023-10-23","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"135366157","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
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