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Journal of Porphyrins and Phthalocyanines最新文献

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Effect of chemically modified natural porphyrins and copper and silver complexes derived from them on oxidative stress induced by paraquat and radiation 化学修饰的天然卟啉及其铜银配合物对百草枯和辐射诱导的氧化应激的影响
4区 化学 Q4 CHEMISTRY, MULTIDISCIPLINARY Pub Date : 2023-10-09 DOI: 10.1142/s1088424623501249
Elena E. Rasova, Ilya O. Velegzhaninov, Tatyana K. Rocheva, Irina S. Khudyaeva, Dmitry V. Belykh
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引用次数: 0
Transition metal dipyrromethenes: Seeking alternatives to BODIPY dyes 过渡金属二吡咯烯:寻找二吡啶染料的替代品
4区 化学 Q4 CHEMISTRY, MULTIDISCIPLINARY Pub Date : 2023-10-09 DOI: 10.1142/s1088424623300148
Shawn Swavey
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引用次数: 0
Broad photodynamic antibacterial activity of a functionalized, highly fluorinated sensitizer 一种功能化、高氟化敏化剂的广泛光动力抗菌活性
4区 化学 Q4 CHEMISTRY, MULTIDISCIPLINARY Pub Date : 2023-09-26 DOI: 10.1142/s1088424623501237
Mary C. Okorie, Ayuni Yussof, Tinchun Chu, Sergiu M. Gorun
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引用次数: 0
Fluoro-2,6-dimethylphenyl mono-hydroxychlorin and porphyrin congeners 氟-2,6-二甲基苯基单羟基氯和卟啉同系物
4区 化学 Q4 CHEMISTRY, MULTIDISCIPLINARY Pub Date : 2023-09-26 DOI: 10.1142/s1088424623501213
Cierra Brown, Brandon M. Campbell, Tina Chen, Richard K. Darkwa, Geena Kim, Danielle J. Kranchalk, Hannah Lamport, Colin M.-D. Le, Jenny Lu, Giovan N. McKnight, Nejc Nagelj, Nikhil V. Seshadri, Kristopher G. Reynolds, Shao-Liang Zheng, Dilek K. Dogutan
{"title":"Fluoro-2,6-dimethylphenyl mono-hydroxychlorin and porphyrin congeners","authors":"Cierra Brown, Brandon M. Campbell, Tina Chen, Richard K. Darkwa, Geena Kim, Danielle J. Kranchalk, Hannah Lamport, Colin M.-D. Le, Jenny Lu, Giovan N. McKnight, Nejc Nagelj, Nikhil V. Seshadri, Kristopher G. Reynolds, Shao-Liang Zheng, Dilek K. Dogutan","doi":"10.1142/s1088424623501213","DOIUrl":"https://doi.org/10.1142/s1088424623501213","url":null,"abstract":"","PeriodicalId":16876,"journal":{"name":"Journal of Porphyrins and Phthalocyanines","volume":"36 1","pages":"0"},"PeriodicalIF":0.0,"publicationDate":"2023-09-26","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"134957952","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Synthesis of chlorophyll-BODIPY conjugates and their intramolecular excitation energy transfer 叶绿素- bodipy缀合物的合成及其分子内激发能转移
4区 化学 Q4 CHEMISTRY, MULTIDISCIPLINARY Pub Date : 2023-09-26 DOI: 10.1142/s1088424623501225
Yuna Mori, Yugo Nakamura, Mizuki Yasui, Hitoshi Tamiaki
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引用次数: 0
Synthesis, physicochemical properties and theoretical calculations of a subphthalocyanine peripherally substituted by multiple anthryl-ethynyl-aniline moieties 邻苯二甲酸乙基苯胺取代亚酞菁的合成、理化性质及理论计算
4区 化学 Q4 CHEMISTRY, MULTIDISCIPLINARY Pub Date : 2023-09-22 DOI: 10.1142/s1088424623501201
Oscar Fernandez-Vera, Yifan Bo, Yusen Luo, Jorge Labella, Dirk M. Guldi, Tomas Torres, Giovanni Bottari
We report here the synthesis of a novel [Formula: see text]-subphthalocyanine (SubPc)-based electron donor-acceptor conjugate (1) in which the macrocycle has been functionalized at its peripheral positions with three anthryl-ethynyl-[Formula: see text],[Formula: see text]-dimethylaniline groups. The latter moiety, besides conferring increased stability and solubility to the resulting system, substantially broadens its absorption capability. In-depth spectroscopic, spectrometric, and electrochemical analyses as well as theoretical calculations carried out on 1 suggest a moderate ground state intramolecular interaction between the macrocycle and the orthogonally-arranged anthryl-ethynyl-[Formula: see text],[Formula: see text]-dimethylaniline moieties. Interestingly, such electronic communication significantly increases in the excited state in a process strongly depending on the polarity of the solvent. On the one hand, in toluene, upon photoexcitation of the anthryl-ethynyl-aniline, the formation of a [Formula: see text](SubPc) state is observed which decays into a [Formula: see text](SubPc) manifold before deactivating to the ground state. On the other hand, increasing the polarity of the solvent to tetrahydrofuran and benzonitrile, significantly modifies the fate of the photoexcited state. In this new scenario, the [Formula: see text](SubPc) state, formed directly upon 550 nm light stimulation or by [Formula: see text](anthryl-ethynyl-aniline) sensitization upon 405 nm excitation, transforms into a charge transfer (SubPc)[Formula: see text]-anthryl-ethynyl-aniline[Formula: see text] state which further evolves into a fully charge-separated (SubPc)[Formula: see text]-anthryl-ethynyl-aniline[Formula: see text] species before deactivating to the ground state.
我们在此报道了一种新型的[公式:见文]-亚酞菁(SubPc)基电子给受体缀合物(1)的合成,其中大环在其外围位置被三个苯基-乙基-[公式:见文],[公式:见文]-二甲苯胺基团功能化。后一部分,除了赋予增加稳定性和溶解性的结果体系,大大拓宽其吸收能力。深入的光谱学、光谱学和电化学分析以及对1进行的理论计算表明,大环与正交排列的蒽基-乙基-[公式:见文]、[公式:见文]-二甲苯胺部分之间存在适度的基态分子内相互作用。有趣的是,这种电子通信在激发态中显著增加,这一过程强烈依赖于溶剂的极性。一方面,在甲苯中,在光激发下,观察到一个[公式:见文](子pc)态的形成,在失活到基态之前衰变成一个[公式:见文](子pc)流形。另一方面,增加溶剂对四氢呋喃和苯腈的极性,显著地改变了光激发态的命运。在这种新的情况下,[公式:见文](SubPc)状态,直接形成550 nm光刺激或[公式:见文](anthryl-乙基苯胺)敏化在405 nm激发,转变为电荷转移(SubPc)[公式:见文]-anthryl-乙基苯胺[公式:见文]状态,进一步演变成完全电荷分离(SubPc)[公式:见文]-anthryl-乙基苯胺[公式:见文]物种失活性到基态。
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引用次数: 0
Factors controlling the reactivity of synthetic compound - I Analogs 合成化合物I类似物反应性的控制因素
4区 化学 Q4 CHEMISTRY, MULTIDISCIPLINARY Pub Date : 2023-09-18 DOI: 10.1142/s1088424623300136
Jithin Thomas, David P. Goldberg
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引用次数: 0
Synthesis, structures and alkane oxygenation reactivity of bioinspired fluoroalkyl iron phthalocyanines 仿生氟烷基酞菁铁的合成、结构及烷烃氧合反应性
IF 1.5 4区 化学 Q4 CHEMISTRY, MULTIDISCIPLINARY Pub Date : 2023-08-25 DOI: 10.1142/s1088424623501195
Mufeda Zhort, Hyunjoo Lee, S. Gorun
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引用次数: 0
Thermally stable dopant-free soluble phthalocyanines as hole transporting materials for Perovskite solar cells 热稳定的无掺杂可溶性酞菁作为钙钛矿太阳能电池的空穴传输材料
IF 1.5 4区 化学 Q4 CHEMISTRY, MULTIDISCIPLINARY Pub Date : 2023-08-21 DOI: 10.1142/s1088424623501183
K. S. Srivishnu, Sai Prasanna Palacharala, L. Giribabu
{"title":"Thermally stable dopant-free soluble phthalocyanines as hole transporting materials for Perovskite solar cells","authors":"K. S. Srivishnu, Sai Prasanna Palacharala, L. Giribabu","doi":"10.1142/s1088424623501183","DOIUrl":"https://doi.org/10.1142/s1088424623501183","url":null,"abstract":"","PeriodicalId":16876,"journal":{"name":"Journal of Porphyrins and Phthalocyanines","volume":" ","pages":""},"PeriodicalIF":1.5,"publicationDate":"2023-08-21","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"45705663","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Preface 前言
IF 1.5 4区 化学 Q4 CHEMISTRY, MULTIDISCIPLINARY Pub Date : 2023-08-07 DOI: 10.1142/s1088424623020029
J. Jayawickramarajah, G. Dan Pantoş, C. Bucher, H. Furuta
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引用次数: 0
期刊
Journal of Porphyrins and Phthalocyanines
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